公开(公告)号：US06855847B2

公开(公告)日：2005-02-15

申请号：US10198930

申请日：2002-07-22

申请人： Kazuhiko Matsumura ,  Takao Saito

发明人： Kazuhiko Matsumura ,  Takao Saito

IPC分类号： B01J31/24 ,  C07B61/00 ,  C07C231/12 ,  C07C231/18 ,  C07C233/05 ,  C07C233/47 ,  C07C233/65 ,  C07F9/50 ,  C07F9/6568 ,  C07F15/00 ,  C07F19/00

CPC分类号： C07F9/65683 ,  C07B2200/07 ,  C07C231/12 ,  C07C233/05 ,  C07C233/47 ,  C07C233/65

摘要： A novel process for producing an optically active amide excellent in chemical selectivity and enantioselectivity by asymmetric hydrogenation of an α,β-unsaturated amide and also allowing the reaction to proceed efficiently even when a trace amount of a catalyst is used relative to the substrate as compared with the amount in a conventional process. An optically active amide is produced by asymmetric hydrogenation of an α,β-unsaturated amide derivative in the presence of a transition metal complex containing a specific phosphine-phosphorane compound.

摘要翻译： 通过α，β-不饱和酰胺的不对称氢化制备具有优异的化学选择性和对映体选择性的光学活性酰胺的新方法，并且即使当相对于底物使用微量的催化剂时也允许反应有效地进行 以常规方法的量。 通过α，β-不饱和酰胺衍生物在含有特定膦 - 正膦烷化合物的过渡金属配合物存在下的不对称氢化制备光学活性酰胺。

公开(公告)号：US06624320B2

公开(公告)日：2003-09-23

申请号：US10291364

申请日：2002-11-12

申请人： Kazuhiko Matsumura ,  Takao Saito

发明人： Kazuhiko Matsumura ,  Takao Saito

IPC分类号： C07F900

CPC分类号： C07F15/04 ,  B01J31/2295 ,  B01J31/2476 ,  B01J2231/645 ,  B01J2531/821 ,  B01J2531/822 ,  B01J2531/824 ,  B01J2531/827 ,  B01J2531/847 ,  C07B53/00 ,  C07B2200/07 ,  C07C231/18 ,  C07F9/5027 ,  C07F9/65683 ,  C07F15/0033 ,  C07F15/0046 ,  C07F15/006 ,  C07F15/0073 ,  C07C233/65

摘要： A novel phosphine compound having excellent properties (chemical selectivity, enantioselectivity, catalytic activity) as a catalyst for asymmetric syntheses, especially asymmetric hydrogenation. A phosphine-phosphorane compound represented by the following general formula: (wherein R1 represents hydrogen atom or a linear or branched alkyl group having 1 to 4 carbon atoms, R2, R3, R4, and R5 are the same or different, and each represents hydrogen atom, or an alkyl group having 1 to 6 carbon atoms, etc., and each of R2 and R3, R3 and R4, and R4 and R5 may be together combined to form a ring which may contain one or more (preferably 1 to 2) oxygen atoms, and R6 and R7 are the same or different, and each represents a linear or branched alkyl group having 1 to 6 carbon atoms, etc.).

摘要翻译： 具有优异性能（化学选择性，对映选择性，催化活性）的不对称合成催化剂，特别是不对称氢化的新型膦化合物。 由以下通式表示的膦 - 正膦烷化合物（其中R 1表示氢原子或具有1至4个碳原子的直链或支链烷基，R 2，R 3，R 4， R 5和R 5相同或不同，各自表示氢原子或碳原子数1〜6的烷基等，R 2，R 3，R 3，R 3 R 4和R 5可以一起组合形成可以含有一个或多个（优选1至2个）氧原子的环，并且R 6和R 7是相同的 或不同，并且各自表示具有1至6个碳原子的直链或支链烷基等）。

公开(公告)号：US06613855B1

公开(公告)日：2003-09-02

申请号：US09446866

申请日：2000-03-23

申请人： Munekazu Satake ,  Masahito Inoue ,  Takao Saito

发明人： Munekazu Satake ,  Masahito Inoue ,  Takao Saito

IPC分类号： C08F1418

CPC分类号： C08F220/28

摘要： The invention provides a polymerizable resin capable of forming thin insulating films excellent in heat resistance, solvent resistance, low water absorption, insulating property, low dielectric constant, etc. The polymerizable resin comprises a copolymer of a monomer (1) represented by the general formula (1) and at least one monomer selected from the group consisting of monomers (2) to (6) respectively represented by the general formulas (2) to (6), wherein the weight ratio of the monomer (1)/[sum total of monomers (2) to (6)] is 5/95 to 95/5 and the number average molecular weight of the copolymer is 2000 to 1000000:

摘要翻译： 本发明提供能够形成耐热性，耐溶剂性，低吸水性，绝缘性，低介电常数等优异的绝缘薄膜的聚合性树脂。可聚合树脂包括由通式（1）表示的单体（1） （1）和分别由通式（2）〜（6）表示的单体（2）〜（6））中选择的至少一种单体，其中单体（1）/ [总计 的单体（2）〜（6）]为5/95〜95/5，共聚物的数均分子量为2000〜1000000：

公开(公告)号：US06472539B1

公开(公告)日：2002-10-29

申请号：US09899207

申请日：2001-07-06

申请人： Tohru Yokozawa ,  Takao Saito ,  Noboru Sayo ,  Takero Ishizaki

发明人： Tohru Yokozawa ,  Takao Saito ,  Noboru Sayo ,  Takero Ishizaki

IPC分类号： C07F940

CPC分类号： C07F9/65517

摘要： A process for producing a diphosphine oxide or diphosphonate represented by formula (1) as defined, which comprises treating, with a base, a phosphine compound represented by formula (2) as defined and adding the thus-treated phosphine compound to a nonpolar solvent having an oxidative metal compound suspended therein so as to effect dimerization. The present invention makes it possible to produce, conveniently, in a high yield and safely, a diphosphine oxide or diphosphonate which is an intermediate for producing a diphosphine compound useful as a ligand of a metal complex serving as a catalyst for asymmetric synthesis reaction.

摘要翻译： 一种制备由式（1）表示的二膦氧化物或二膦酸盐的方法，该方法包括用碱处理如上定义的式（2）表示的膦化合物，并将如此处理的膦化合物加入到具有 悬浮在其中以实现二聚化的氧化金属化合物。 本发明使得可以以高产率和安全地生产作为用作不对称合成反应催化剂的金属络合物的配位体的二膦化合物的中间体的二氧化膦或二膦酸盐的方法。

公开(公告)号：US6099761A

公开(公告)日：2000-08-08

申请号：US209332

申请日：1998-12-11

申请人： Akio Aoki ,  Toshio Murata ,  Akira Azuma ,  Ikuo Kobayashi ,  Takao Saito

发明人： Akio Aoki ,  Toshio Murata ,  Akira Azuma ,  Ikuo Kobayashi ,  Takao Saito

IPC分类号： G04B19/12 ,  G04B19/14 ,  G04C10/02 ,  B29D11/00 ,  G02B1/00

CPC分类号： G04B19/14 ,  G04B19/12 ,  G04C10/02

摘要： A solar-cell watch dial to be disposed on or above a solar cell housed in a watch, the solar-cell watch dial including an alumina of the formula Al.sub.2 O.sub.3 whose purity is at least 99.90% and exhibiting a light transmission ranging from 40 to 60%. The invention also includes a process for producing a solar-cell watch dial, which includes the steps of: mixing together an alumina of the formula Al.sub.2 O.sub.3 whose purity is at least 99.90%, an organic binder and water to thereby obtain an Al.sub.2 O.sub.3 mixture (A); drying and granulating the Al.sub.2 O.sub.3 mixture to thereby obtain a granular material (B); molding the granular material into a plate dial precursor (C); firing the dial precursor at 700 to 1500.degree. C. in atmospheric environment to thereby obtain a preliminary firing product (D); and firing the preliminary firing product at 1500 to 1800.degree. C. under a pressure of 1.times.10.sup.-2 to 1.times.10.sup.-5 torr for 1 to 10 hr to thereby obtain a solar-cell watch dial (E). The solar-cell watch dial of the present invention enables preventing the solar cell from being sighted from outside without hindering the supply of light energy to the solar cell.

摘要翻译： 太阳能电池表盘设置在容纳在手表中的太阳能电池上或其上方，太阳能电池表盘包括纯度为99.90％且透光率为40至60的式Al2O3氧化铝 ％。 本发明还包括一种生产太阳能电池表盘的方法，其包括以下步骤：将纯度为至少99.90％的式Al2O3的氧化铝，有机粘合剂和水混合在一起，从而获得Al 2 O 3混合物（A ）; 干燥并造粒Al 2 O 3混合物，从而获得颗粒状材料（B）; 将颗粒状材料成型为板式表盘前体（C）; 在大气环境中在700〜1500℃下烧制表盘前体，得到预焙烧产物（D）; 在1500〜1800℃，1×10 -2〜1×10 -5乇的压力下烧成1〜10小时，得到太阳能电池表盘（E）。 本发明的太阳能电池表盘能够防止太阳能电池从外部看到，而不会阻碍向太阳能电池供应光能。

公开(公告)号：US6030679A

公开(公告)日：2000-02-29

申请号：US131864

申请日：1998-08-10

申请人： Takao Saito ,  Hiroshi Shingai ,  Tatsuya Kato ,  Hajime Utsunomiya ,  Katsuaki Yanagiuchi

发明人： Takao Saito ,  Hiroshi Shingai ,  Tatsuya Kato ,  Hajime Utsunomiya ,  Katsuaki Yanagiuchi

IPC分类号： G11B7/24 ,  G11B7/243 ,  G11B7/257 ,  G11B7/26 ,  B32B3/00

CPC分类号： G11B7/26 ,  G11B7/2403 ,  G11B7/243 ,  G11B7/257 ,  G11B2007/24308 ,  G11B2007/2431 ,  G11B2007/24316 ,  G11B2007/25706 ,  G11B2007/2571 ,  G11B2007/25715 ,  G11B2007/25716 ,  G11B7/00454 ,  G11B7/24 ,  G11B7/2534 ,  G11B7/2542 ,  G11B7/258 ,  G11B7/2585 ,  G11B7/2595 ,  Y10S428/913 ,  Y10S430/146 ,  Y10T428/21

摘要： An optical recording medium comprises a substrate and a multilayer structure on the substrate. The multilayer structure comprises a phase change type recording layer and a pair of dielectric layers, at least one of which contains zinc sulfide optionally with silicon oxide. When a depth profile of the multilayer structure in a thickness direction thereof is found by Auger electron spectroscopy, a region having an intensity ratio S/Zn of 2 or lower exists across a thickness of at least 6.0 nm, calculated as SiO.sub.2, from the vicinity of an interface between the dielectric layer and the recording layer into the recording layer. In the vicinity of the interface between the dielectric layer and the recording layer, there is also a region having an intensity ratio S/Zn vs. O/Si relation that satisfies S/Zn

摘要翻译： 光学记录介质包括基底和基底上的多层结构。 多层结构包括相变型记录层和一对电介质层，其中至少一层含有任选含有氧化硅的硫化锌。 通过俄歇电子能谱法发现其厚度方向上的多层结构的深度分布，从附近存在以SiO 2计算的至少6.0nm的厚度的区域，其强度比S / Zn为2以下。 介电层和记录层之间的界面的记录层。 在电介质层和记录层之间的界面附近，还存在具有满足S / Zn

公开(公告)号：US5824822A

公开(公告)日：1998-10-20

申请号：US677226

申请日：1996-07-09

申请人： Takao Saito ,  Akifumi Yoshida ,  Kazuhiko Matsumura ,  Takashi Miura ,  Hidenori Kumobayashi

发明人： Takao Saito ,  Akifumi Yoshida ,  Kazuhiko Matsumura ,  Takashi Miura ,  Hidenori Kumobayashi

IPC分类号： C07D205/08 ,  C07F9/09 ,  C07F9/50 ,  C07F9/655 ,  C07F9/02 ,  C07D205/00

CPC分类号： C07F9/65517 ,  C07D205/08 ,  C07F9/5022 ,  Y02P20/55

摘要： A phosphine-phosphinite compound represented by formula (I): ##STR1## wherein R.sup.1 and R.sup.2, which may be the same or different, each represent a substituted or unsubstituted phenyl group or a substituted or unsubstituted naphthyl group, and a process for preparing a 4-�(R)-1'-formylethyl!azetidin-2-one derivative using the compound (I). The compound (I), either in combination, or as a complex, with a transition metal compound, is useful as a catalyst for asymmetric hydroformylation and makes it possible to easily synthesize an important intermediate for carbapenem antibiotics or a precursor thereof at high regioselectivity and diastereo-selectivity.

摘要翻译： 由式（I）表示的膦 - 磷化合物：其中R 1和R 2可以相同或不同，各自表示取代或未取代的苯基或取代或未取代的萘基， 用于使用化合物（I）制备4 - [（R）-1'-甲酰乙基]氮杂环丁-2-酮衍生物。 与过渡金属化合物组合或作为络合物的化合物（I）可用作不对称加氢甲酰化的催化剂，并且可以容易地以高区域选择性合成碳青霉烯类抗生素或其前体的重要中间体， 非对映选择性。

公开(公告)号：US5440030A

公开(公告)日：1995-08-08

申请号：US167201

申请日：1993-12-16

申请人： Takao Saito ,  Hidenori Kumobayashi ,  Shunichi Murahashi

发明人： Takao Saito ,  Hidenori Kumobayashi ,  Shunichi Murahashi

IPC分类号： B01J27/128 ,  B01J31/12 ,  B01J31/30 ,  C07B61/00 ,  C07D205/08 ,  C07F7/18 ,  C07B41/12

CPC分类号： C07F7/186 ,  C07D205/08 ,  C07F7/1892

摘要： A process for preparing a 4-acyloxyazetidinone or a derivative thereof represented by formula (IV): ##STR1## wherein R.sup.1 represents a hydrogen atom, a lower alkyl group, a hydroxyethyl group, or a protected hydroxyethyl group; R.sup.3 represents an alkyl group having from 1 to 10 carbon atoms which may be substituted with a halogen atom, a cyano group, a lower alkoxy group or a phenyl group, or a substituted or unsubstituted phenyl group, provided that the .alpha.-positioned carbon atom of said alkyl group should not have more than two halogen atoms; and R.sup.4 represents a hydrogen atom, a lower alkyl group, or a lower alkoxycarbonyl group,which is useful as an intermediate for penera antibiotics is disclosed, comprising reacting azetidinone or a derivative thereof represented by formula (II): ##STR2## wherein R.sup.1 is as defined above, and R.sup.2 represents a hydrogen atom, a lower alkyl group, a lower alkoxycarbonyl group, or a carboxyl group,with a carboxylic acid represented by formula (III):R.sup.3 COOH (III)wherein R.sup.3 is as defined above,in the presence of (1) a transition metal compound selected from a ruthenium compound, an osmium compound, and a cobalt compound, (2) an aldehyde having 2 or more carbon atoms, provided that the carbon atom at the .alpha.-position thereof should not have two or more halogen atoms, and (3) oxygen. The compound (IV) can be prepared with safety through simple and easy operations.

摘要翻译： 制备由式（IV）表示的4-酰氧基氮杂环丁酮或其衍生物的方法：n原子，低级烷基，羟乙基或被保护的羟乙基; R3表示可以被卤素原子，氰基，低级烷氧基或苯基取代的具有1至10个碳原子的烷基或取代或未取代的苯基，条件是α-位置的碳原子 的所述烷基不应具有多于两个的卤素原子; 其中R 4表示氢原子，低级烷基或低级烷氧基羰基，其可用作倍他安抗生素的中间体，包括使由式（II）表示的氮杂环丁酮或其衍生物： 其中R 1如上所定义，R 2表示氢原子，低级烷基，低级烷氧基羰基或羧基，与式（III）表示的羧酸：R3COOH（III）其中R3如上定义 在（1）选自钌化合物，锇化合物和钴化合物的过渡金属化合物的存在下，（2）具有2个或更多个碳原子的醛，条件是其α位上的碳原子 不应该有两个或更多的卤素原子，和（3）氧。 化合物（IV）可以通过简单和容易的操作安全地制备。

公开(公告)号：US5191076A

公开(公告)日：1993-03-02

申请号：US799150

申请日：1991-11-26

申请人： Takao Saito ,  Hidenori Kumobayashi ,  Shunichi Murahashi

发明人： Takao Saito ,  Hidenori Kumobayashi ,  Shunichi Murahashi

IPC分类号： C07D205/08 ,  B01J23/46 ,  B01J27/08 ,  C07B61/00 ,  C07D205/085

CPC分类号： C07D205/085

摘要： A process for producing a 4-acetoxyazetidinone represented by formula (I): ##STR1## wherein Z represents a hydrogen atom, a lower alkyl group, or a protected or unprotected hydroxyethyl group; and W represents a hydrogen atom, a lower alkyl group, or a group of --COOR.sup.1, wherein R.sup.1 represents a lower alkyl group, is disclosed, which comprises reacting an azetidinone represented by formula (II): ##STR2## wherein Z is as defined above; and Y represents a hydrogen atom, carboxyl group, a lower alkyl group, or a group of --COOR.sup.1, wherein R.sup.1 represents a lower alkyl group, with acetic acid and an oxidizing agent in the presence of, as a catalyst, an anhydrous or hydrous osmium compound represented by OsX.sub.3, wherein X represents a chlorine atom, a bromine atom, or an iodine atom.

公开(公告)号：US4760275A

公开(公告)日：1988-07-26

申请号：US54833

申请日：1987-05-27

申请人： Yoshihisa Sato ,  Yuji Hirabayashi ,  Katsunori Ito ,  Susumu Akiyama ,  Takao Saito ,  Naoki Maeda

发明人： Yoshihisa Sato ,  Yuji Hirabayashi ,  Katsunori Ito ,  Susumu Akiyama ,  Takao Saito ,  Naoki Maeda

IPC分类号： G08C19/00 ,  B60G17/00 ,  B60G17/0195 ,  B60K31/02 ,  B60R16/02 ,  B60W50/00 ,  F02D41/26 ,  F02D45/00 ,  G05B15/02 ,  G07C5/10 ,  H04J99/00 ,  H04Q9/00 ,  H04J15/00

CPC分类号： B60W50/00 ,  B60G17/0195 ,  B60K31/02 ,  B60W10/04 ,  B60W10/18 ,  B60W30/1819 ,  F02D41/266 ,  G07C5/10 ,  B60G2202/42 ,  B60G2400/106 ,  B60G2400/204 ,  B60G2400/90 ,  B60G2500/10 ,  B60G2800/22

摘要： Sensors detect parameters. Control units control vehicle equipments in accordance with the detected parameters. In each of the control units, at least one of the detected parameters and internally produced data is converted into serial data as communication data, and serial data is converted into other form data. A transmission medium connects the control units via a serial data link. Serial interfaces are associated with the control units respectively. Each of the serial interfaces includes a connection terminal connected to the transmission medium, an input terminal and an output terminal both connected to the associated control unit. Each of the serial interfaces inputs serial data from the associated control unit via its input terminal and outputs the inputted data to the transmission medium via its connection terminal. Each of the serial interfaces inputs serial data from the transmission medium via its connection terminal and outputs the inputted data to the associated control unit via its output terminal.

摘要翻译： 传感器检测参数。 控制单元根据检测参数控制车辆设备。 在每个控制单元中，检测到的参数和内部产生的数据中的至少一个被转换为串行数据作为通信数据，串行数据被转换为其他形式数据。 传输介质通过串行数据链路连接控制单元。 串行接口分别与控制单元相关联。 每个串行接口包括连接到传输介质的连接终端，两个连接到相关控制单元的输入端和输出端。 每个串行接口通过其输入端口输入来自关联控制单元的串行数据，并通过其连接端口将输入的数据输出到传输介质。 每个串行接口通过其连接端口输入来自传输介质的串行数据，并通过其输出端将输入的数据输出到相关联的控制单元。