Multiautoclave with set of vessels for combinatorial synthesis of zeolites and other materials
    42.
    发明授权
    Multiautoclave with set of vessels for combinatorial synthesis of zeolites and other materials 有权
    具有一组用于组合合成沸石和其他材料的容器的多孔板

    公开(公告)号:US07341872B1

    公开(公告)日:2008-03-11

    申请号:US10834648

    申请日:2004-04-29

    摘要: A vessel arrangement having a base and multiple vessels suited for simultaneously conducting a plurality of isolated experimental reactions or treatments at atmospheric process conditions or elevated temperatures and pressure condition has been developed. A component of a first material is introduced into one independent vessel through an opening in its top of the first vessel and another component of a second material is introduced into a different independent vessel through its top. Both vessels are removably located about a base at different first locations. Transformation of the components in the vessels then occurs to produce different materials therein. After completion of the experiments a displacement medium simultaneously urges the vessels from their respective locations about the base for discard or reuse after any necessary cleaning. Typically at least one property of the materials from the vessels is determined either within the vessel or after recovery of the materials.

    摘要翻译: 已经开发了具有底座和多个容器的容器装置,其适用于在大气工艺条件或升高的温度和压力条件下同时进行多个分离的实验反应或处理。 第一材料的组分通过其第一容器的顶部中的开口引入一个独立的容器中,并且第二材料的另一组分通过其顶部被引入到不同的独立容器中。 两个容器可移除地位于不同第一位置的基部周围。 然后发生容器中的组分的转化,以在其中产生不同的材料。 在完成实验之后,置换介质同时将各容器从其各自的位置推向基座,以便在任何必要的清洁之后丢弃或重新使用。 通常来自容器的材料的至少一种性质是在容器内或在材料回收之后确定的。

    Process for preparing a hydrocarbon conversion catalyst
    46.
    发明授权
    Process for preparing a hydrocarbon conversion catalyst 失效
    烃转化催化剂的制备方法

    公开(公告)号:US5482910A

    公开(公告)日:1996-01-09

    申请号:US270351

    申请日:1994-07-05

    摘要: A process for preparing catalysts has been developed. The process involves the use of a chelating ligand such as ethylenediaminetetraacetic acid. The aqueous solution of the chelating ligand and a promoter metal salt is first prepared heated to a temperature of about 80.degree. C. to about its boiling point and then combined with an aqueous solution containing a Group VIII metal compound. Next this mixed solution is aged at a temperature of about 40.degree. C. to about 100.degree. C. and then used to impregnate a support, e.g., alumina spheres. The impregnated support is then dried, calcined and reduced with hydrogen. Prior to reduction the catalyst may optionally be treated with a chlorine or chloride stream.

    摘要翻译: 已经开发了制备催化剂的方法。 该方法包括使用螯合配体如乙二胺四乙酸。 首先将螯合配体和助催化剂金属盐的水溶液加热至约80℃至约沸点,然后与含有第VIII族金属化合物的水溶液合并。 接下来,将该混合溶液在约40℃至约100℃的温度下老化,然后用于浸渍载体,例如氧化铝球体。 然后将浸渍的载体干燥,煅烧并用氢还原。 在还原之前,催化剂可任选地用氯或氯化物流处理。

    Catalyst for treatment of exhaust gases from internal combustion engines
    47.
    发明授权
    Catalyst for treatment of exhaust gases from internal combustion engines 失效
    用于处理内燃机废气的催化剂

    公开(公告)号:US4919902A

    公开(公告)日:1990-04-24

    申请号:US269389

    申请日:1988-11-09

    摘要: This invention relates to a catalytic composite for treating an exhaust gas comprising a support which is a refractory inorganic oxide having dispersed thereon lanthanum, at least one other rare earth component and at least one noble metal component selected from the group consisting of platinum, palladium, rhodium, ruthenium and iridium. An essential feature of said catalytic composite is that the lanthanum be present as crystalline particles of lanthanum oxide which have an average crystallite size of less than about 25 Angstroms. The support may be selected from the group consisting of alumina, silica, titania, zirconia, aluminosilicates and mixtures thereof with alumina being preferred. Illustrative of the other rare earth components are cerium, neodymium, praeseodymium, dysprosium, europium, holmium and ytterbium. An important feature in manufacturing the catalytic composite is the dispersion of lanthanum oxide onto said refractory inorganic oxide support. In a specific example, lanthanum may be dispersed on alumina as follows. A solution of a lanthanum salt is mixed with a hydrosol of aluminum, particles are formed from said lanthanum containing hydrosol, calcined to form an inorganic oxide particle containing lanthanum oxide, ground to give a powder of alumina containing finely dispersed lanthanum oxide. This powder in turn can be mixed with another rare earth oxide such as cerium oxide to a slurry which in turn is used to coat a solid monolithic carrier. Finally, at least one noble metal component is dispersed on said coated solid monolithic carrier.

    摘要翻译: 本发明涉及一种用于处理废气的催化剂复合材料,其包括:分散在其上的难熔无机氧化物的载体,至少一种其它稀土组分和至少一种贵金属组分,所述至少一种贵金属组分选自铂,钯, 铑,钌和铱。 所述催化复合材料的一个基本特征是镧作为平均微晶尺寸小于约25埃的氧化镧晶体颗粒存在。 载体可以选自氧化铝,二氧化硅,二氧化钛,氧化锆,铝硅酸盐及其与氧化铝的混合物。 其他稀土成分的说明是铈,钕,镨,镝,铕,钬和镱。 制造催化复合材料的一个重要特征是氧化镧在所述耐火无机氧化物载体上的分散。 在具体实例中,镧可以如下分散在氧化铝上。 将镧盐溶液与铝的水溶胶混合,由所述含镧水溶胶形成颗粒,煅烧形成含有氧化镧的无机氧化物,研磨得到含有细分散的氧化镧的氧化铝粉末。 这种粉末又可以与另一种稀土氧化物如氧化铈混合到一种浆料中,浆料又用于涂覆固体整体载体。 最后,将至少一种贵金属组分分散在所述涂覆的固体单片载体上。