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公开(公告)号：US20090131701A1
公开(公告)日：2009-05-21
申请号：US10585427
申请日：2004-01-29
CPC分类号： C12P7/6472 , C12P7/6454
摘要： A process for enzymatic production of glyceride compositions, specifically industrially practicable production of triglycerides, including conjugated linoleic and linolenic acid triglycerides, and the compositions produced by such process. An enzymatic reaction zone is first utilized, in which a mixture of glycerol and fatty acids or fatty acid derivatives is reacted in the presence of an enzymatic catalyst to form 1,3 diglycerides. The mixture is then circulated through a second thermal rearrangement zone, maintained at a higher temperature, to promote rearrangement of the 1,3 diglycerides to 1,2 diglycerides. Triglycerides are produced by re-circulating the mixture through the enzymatic production zone.
摘要翻译： 用于酶促生产甘油酯组合物的方法，特别是在工业上可行地生产甘油三酯，包括共轭亚油酸和亚麻酸甘油三酸酯，以及通过该方法制备的组合物。 首先使用酶反应区，其中甘油和脂肪酸或脂肪酸衍生物的混合物在酶催化剂的存在下反应以形成1,3-甘油二酯。 然后将混合物循环通过保持在较高温度的第二热重排区域，以促进1,3-甘油二酯重新配置为1,2-甘油二酯。 通过将混合物再循环通过酶促生产区产生甘油三酸酯。
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公开(公告)号：US07087771B2
公开(公告)日：2006-08-08
申请号：US10953327
申请日：2004-09-29
IPC分类号： C11C1/00
摘要： A method for making alkyl esters (e.g., methyl ester), such as biodiesel, from an oil source is described. The method involves converting the free fatty acids of the oil source into a mixture of mono-, di-, and tri-glycerides and subsequently transesterifying the newly formed glycerides as well as the originally present glycerides into fatty acid alkyl esters.
摘要翻译： 描述了从油源制备烷基酯（例如甲酯），例如生物柴油的方法。 该方法包括将油源的游离脂肪酸转化成单甘油酯，甘油二酯和甘油三酯的混合物，然后将新形成的甘油酯以及最初存在的甘油酯酯交换成脂肪酸烷基酯。
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公开(公告)号：US4675422A
公开(公告)日：1987-06-23
申请号：US790486
申请日：1985-10-23
IPC分类号： A61K8/58 , A61K47/24 , A61L26/00 , A61Q17/04 , C07F5/06 , C07F7/00 , C07F9/11 , G03C1/76 , G03C1/815 , G03C1/85 , G03F7/004 , G03F7/029
CPC分类号： A61K8/26 , A61K47/24 , A61K8/58 , A61L26/00 , A61Q17/04 , C07F5/069 , C07F7/003 , C07F7/006 , C07F9/11 , G03C1/7614 , G03C1/815 , G03C1/85 , G03F7/004 , G03F7/029
摘要： Organometallic compounds and compositions comprising a metal, an amido carboxyl moiety bonded to the metal, an active moiety bonded to the metal, and at least one modifier moiety sufficient to satisfy the valency of the metal. These compounds and compositions are capable of combining the substantivity of the amido carboxyl metal system, functional efficacy of an active moiety, and film-forming properties in a single compound or composition.
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公开(公告)号：US20130281688A1
公开(公告)日：2013-10-24
申请号：US13867542
申请日：2013-04-22
IPC分类号： C07H1/00 , C07C41/06 , C07F9/09 , C07C41/03 , C07C67/08 , C07C43/178 , C07C69/007
CPC分类号： C07C29/147 , C07C29/095 , C07C29/74 , C07C41/03 , C07C41/06 , C07C43/178 , C07C67/08 , C07C69/007 , C07F9/09 , C07H1/00 , C08F210/00 , C08F216/04 , C07C33/025
摘要： Unsaturated alcohol compositions are obtained by reducing a metathesis-derived hydrocarbyl unsaturated ester. Also disclosed is a process for preparing an unsaturated alcohol composition, where a metathesis derived hydrocarbyl carbonyl compound is reacted in the presence of a silane compound, an organic solvent, and a catalyst system prepared from a metallic complex and a reducing agent. This mixture is then hydrolyzed with a metallic base, and then mixed with organic solvent. The resultant mixture is then separated, washed, dried, and/or purified to produce the unsaturated alcohol composition. The unsaturated alcohol derivatives are useful in many end-use applications, including, for example, lubricants, functional fluids, fuels, functional additives for such lubricants, functional fluids and fuels, plasticizers, asphalt additives, friction reducing agents, plastics, and adhesives.
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45.发明授权Process for preparing conjugated linoleic acid and derivatives thereof from ricinoleic acid 有权由蓖麻油酸制备共轭亚油酸及其衍生物的方法公开(公告)号：US08203012B2
公开(公告)日：2012-06-19
申请号：US11991688
申请日：2006-12-05
IPC分类号： C07B37/00
CPC分类号： C07C51/09 , A23K20/158 , A23L33/12 , C07C51/353 , C07C51/377 , C07C67/03 , C07C67/08 , C07C67/327 , C07C57/12 , C07C69/73 , C07C69/587
摘要： A process for preparing conjugated linoleic acid (CLA) or derivatives thereof from ricinoleic acid, lower alkyl esters of ricinoleic acid, or salts thereof. The CLA is formed by reacting a carboxylic acid, or anhydride, anhydride equivalent, or ester thereof with the ricinoleic acid or derivative to form an intermediate having a carboxylic ester at the 12-hydroxy position of the ricinoleic acid or derivative, and reacting the intermediate with a base to form a cis-9, trans-11 conjugated linoleic acid.
摘要翻译： 由蓖麻油酸制备共轭亚油酸（CLA）或其衍生物的方法，蓖麻油酸的低级烷基酯或其盐。 CLA通过使羧酸或酸酐，酸酐当量或其酯与蓖麻酸或衍生物反应形成在蓖麻油酸或其衍生物的12-羟基位置具有羧酸酯的中间体，并使中间体 与碱形成顺式-9反式-11共轭亚油酸。
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46.发明授权Hard surface cleaner compositions of sulfonated estolides and other derivatives of fatty acids and uses thereof 有权磺化的耳内酯和其它脂肪酸衍生物的硬表面清洁剂组合物及其用途公开(公告)号：US08119588B2
公开(公告)日：2012-02-21
申请号：US12507786
申请日：2009-07-22
IPC分类号： C11D1/28
CPC分类号： C11D1/28 , A01N25/30 , A01N33/12 , A01N2300/00
摘要： Sulfo-estolides and formulations of sulfo-estolides in and as hard surface cleaners, glass cleaners, toilet bowl cleaners, carpet cleaners, all purpose cleaners, floor cleaners, and others are described. Further details of cleaning performance, stability of diluted and concentrated forms and contemplated cleaning applications are provided.
摘要翻译： 描述了磺基 - 耳塞内酯和作为硬表面清洁剂中的磺基 - 内酯的制剂，玻璃清洁剂，马桶清洁剂，地毯清洁剂，全能清洁剂，地板清洁剂等。 提供清洁性能，稀释和浓缩形式的稳定性以及考虑的清洁应用的更多细节。
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公开(公告)号：US07759096B2
公开(公告)日：2010-07-20
申请号：US10585427
申请日：2004-01-29
IPC分类号： C12P7/64
CPC分类号： C12P7/6472 , C12P7/6454
摘要： A process for enzymatic production of glyceride compositions, specifically industrially practicable production of triglycerides, including conjugated linoleic and linolenic acid triglycerides, and the compositions produced by such process. An enzymatic reaction zone is first utilized, in which a mixture of glycerol and fatty acids or fatty acid derivatives is reacted in the presence of an enzymatic catalyst to form 1,3 diglycerides. The mixture is then circulated through a second thermal rearrangement zone, maintained at a higher temperature, to promote rearrangement of the 1,3 diglycerides to 1,2 diglycerides. Triglycerides are produced by re-circulating the mixture through the enzymatic production zone.
摘要翻译： 用于酶促生产甘油酯组合物的方法，特别是在工业上可行地生产甘油三酯，包括共轭亚油酸和亚麻酸甘油三酸酯，以及通过该方法制备的组合物。 首先使用酶反应区，其中甘油和脂肪酸或脂肪酸衍生物的混合物在酶催化剂的存在下反应以形成1,3-甘油二酯。 然后将混合物循环通过保持在较高温度的第二热重排区域，以促进1,3-甘油二酯重新配置为1,2-甘油二酯。 通过将混合物再循环通过酶促生产区产生甘油三酸酯。
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公开(公告)号：US06897327B2
公开(公告)日：2005-05-24
申请号：US10434011
申请日：2003-05-08
申请人： Joseph C. Rongione , Jenifer Heydinger Galante , Steven L. Clauss , Randal J. Bernhardt , Phouvieng Xayariboun
发明人： Joseph C. Rongione , Jenifer Heydinger Galante , Steven L. Clauss , Randal J. Bernhardt , Phouvieng Xayariboun
IPC分类号： C07C51/09 , C07C51/347
摘要： A process to manufacture conjugated linoleic acid (CLA)-containing materials such as conjugated linoleic salts and acids that are enriched in desirable cis-9, trans-11- and trans-10, cis-12-CLA isomers and are low in certain undesirable isomers. The process generally entails isomerization of an alkyl ester of a linoleic acid-containing material at a temperature typically between about 90 to 140° C. to effectuate conjugation of the double bonds, followed by saponification of the resultant CLA-containing fatty acid ester to produce a CLA-containing fatty acid salt, optionally followed by neutralization of the CLA-containing fatty acid salt with an acid source to produce a CLA-containing fatty acid.
摘要翻译： 一种制备共轭亚油酸（CLA）的物质，例如共轭亚油酸盐和酸的方法，其富含所需的顺式-9，反式-11-和反式-10，顺式-12-CLA异构体，并且在某些不期望的情况下是低的 异构体。 该方法通常需要含有亚油酸的材料的烷基酯在典型地在约90至140℃之间的温度下进行异构化，以实现双键的共轭化，然后将所得的含CLA脂肪酸酯皂化以产生 含CLA的脂肪酸盐，任选地随后用酸源中和含CLA的脂肪酸盐以产生含CLA的脂肪酸。
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公开(公告)号：US4788054A
公开(公告)日：1988-11-29
申请号：US884350
申请日：1986-07-11
CPC分类号： C08K5/29 , A61K8/4973 , A61Q17/04 , Y10S424/10 , Y10S514/937 , Y10S514/938
摘要： A class of N-phenylphthalisoimides is provided which demonstrate broad spectrum ultraviolet radiation absorbing capacities for protecting various substrate materials including plastics, fibers, human skin, hair and the like, from the effects of such radiation. Such compounds can be incorporated either into coating compositions for such substrates or into the substrates themselves, depending upon the substrate materials, use conditions, etc.
摘要翻译： 提供了一类N-苯基邻苯二甲酰亚胺，其表现出广谱的紫外线吸收能力，用于保护各种底物材料，包括塑料，纤维，人体皮肤，头发等，不受这种辐射的影响。 根据基材，使用条件等，这些化合物可以掺入用于这种基材的涂料组合物或基材本身中。
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公开(公告)号：US5840985A
公开(公告)日：1998-11-24
申请号：US683707
申请日：1996-07-18
IPC分类号： C07C209/50 , C07C211/08
CPC分类号： C07C209/50
摘要： Disclosed is a process for the preparation of primary, secondary and tertiary amines with high conversion and high selectivity via low pressure catalytic hydrogenation of unsubstituted, N-substituted, and N,N-disubstituted amides. Amide hydrogenation is conducted using a catalyst system comprising copper chromite and a nucleophilic reagent, in combination with hydrogen gas. The process allows for production of amines which may be directly used as chemical intermediates in the manufacture of surfactants, quaternary ammonium compounds, bactericides, disinfectants, lubricants, petroleum additives, ion exchange resins and the like, without the need of purification, such as distillation.
摘要翻译： 公开了通过未取代的N-取代的和N，N-二取代的酰胺的低压催化氢化制备具有高转化率和高选择性的伯，仲和叔胺的方法。 酰胺氢化使用包含亚铬酸铜和亲核试剂的催化剂体系与氢气组合进行。 该方法允许生产可直接用作制造表面活性剂，季铵化合物，杀菌剂，消毒剂，润滑剂，石油添加剂，离子交换树脂等的化学中间体的胺，而不需要纯化如蒸馏 。
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