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    N-Arylsulfonyl-N'-pyrimidinylureas
    41.
    发明授权
    N-Arylsulfonyl-N'-pyrimidinylureas 失效
    N-芳基磺酰基-N'-嘧啶基脲

    公开(公告)号：US4478635A

    公开(公告)日：1984-10-23

    申请号：US455175

    申请日：1983-01-03

    申请人： Willy Meyer ,  Karl Gass ,  Werner Topfl ,  Rolf Schurter ,  Georg Pissiotas

    发明人： Willy Meyer ,  Karl Gass ,  Werner Topfl ,  Rolf Schurter ,  Georg Pissiotas

    IPC分类号： A01N47/36 ,  C07D239/46 ,  C07D239/47 ,  C07D239/48 ,  C07D239/52 ,  C07D239/56 ,  C07D251/46 ,  C07D239/69 ,  A01N43/54

    CPC分类号： C07D239/47 ,  A01N47/36 ,  C07D239/48 ,  C07D239/52 ,  C07D239/56 ,  C07D251/46

    摘要： The invention relates to N-arylsulfonyl-N'-pyrimidinyl ureas of the general formula ##STR1## and to the salts thereof with amines, alkali metal hydroxides or alkaline earth metal hydroxides or with quaternary ammonium bases. These compounds have good pre- and postemergence selective herbicidal and growth regulating properties.In the formula, R.sub.18 is hydrogen, alkyl or alkoxy, X is an unsubstituted or substituted phenyl radical or an unsubstituted or substituted naphthyl radical, Y is C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 haloalkyl, C.sub.1 -C.sub.3 alkoxy, C.sub.1 -C.sub.3 haloalkoxy, C.sub.1 -C.sub.3 alkylthio, C.sub.2 -C.sub.3 alkoxyalkyl, halogen or an unsubstituted amino group and Z is oxygen or sulfur.

    摘要翻译： 本发明涉及通式为（I）的N-芳基磺酰基-N'-嘧啶基脲，以及其与胺，碱金属氢氧化物或碱土金属氢氧化物或季铵碱的盐。 这些化合物具有良好的芽前和芽后选择性除草和生长调节性质。 式中，R 18为氢，烷基或烷氧基，X为未取代或取代的苯基或未取代或取代的萘基，Y为C1-C3烷基，C1-C3卤代烷基，C1-C3烷氧基，C1-C3卤代烷氧基，C1-C3烷硫基， C 2 -C 3烷氧基烷基，卤素或未取代的氨基，Z是氧或硫。

    Oxime derivatives for protecting plant crops
    43.
    发明授权
    Oxime derivatives for protecting plant crops 失效

    公开(公告)号：US4388106A

    公开(公告)日：1983-06-14

    申请号：US398168

    申请日：1982-07-14

    申请人： Werner Fory ,  Henry Martin ,  Georg Pissiotas

    发明人： Werner Fory ,  Henry Martin ,  Georg Pissiotas

    IPC分类号： A01N25/32 ,  A01N37/32 ,  A01N37/34 ,  C07C67/00 ,  C07C251/32 ,  C07C251/54 ,  C07C313/00 ,  C07C315/04 ,  C07C317/28 ,  C07C317/44 ,  C07C323/47 ,  C07C325/00 ,  C07C327/28 ,  C07D207/26 ,  C07D207/273 ,  C07D207/325 ,  C07D207/404 ,  C07D207/408 ,  C07D207/44 ,  C07D207/452 ,  C07D207/456 ,  C07D209/48 ,  C07C121/80

    CPC分类号： C07D207/273 ,  A01N25/32 ,  C07D207/452 ,  C07D207/456 ,  C07D209/48

    摘要： Oxime derivatives of the formula (I) ##STR1## wherein n is 0, 1 or 2 and m is 0 or 1, and Ar is a phenyl radical ##STR2## a naphthyl radical substituted by R.sub.2 and R.sub.3, a 5- to 10-membered heterocyclic radical which contains not more than 3 identical or different heteroatoms N, O and/or S and which is substituted by R.sub.2, R.sub.3 and R.sub.4 and can be substituted by oxo or thiono, or if m is 0, Ar is a radical R--CO, wherein R is a radical --OR.sub.5, in which R.sub.5 is an aliphatic group containing not more than 8 carbon atoms or is an araliphatic group containing not more than 15 carbon atoms or is a cycloaliphatic or aromatic group, each containing not more than 10 carbon atoms, while the possible substituents of the aromatic radicals or of the cycloaliphatic radical are halogen, --CN, --NO.sub.2, lower alkyl, lower alkoxy, haloalkyl; or R is a radical --NH--CO--NH--R.sub.7 or a radical --N(R.sub.6)(R.sub.7), wherein R.sub.6 is hydrogen or lower alkyl and R.sub.7 is hydrogen or an aliphatic group containing not more than 8 carbon atoms or an araliphatic group containing not more than 15 carbon atoms, or a cycloaliphatic ##STR3## wherein R.sub.9 is hydrogen, a cycloaliphatic, araliphatic or aromatic group which is unsubstituted or mono- or polysubstituted at the ring by CN, NO.sub.2, halogen, lower alkyl, lower alkoxy or haloalkyl, or is lower alkenyl, lower haloalkenyl or lower alkynyl, R.sub.10 is an aliphatic group or a cycloaliphatic, araliphatic or aromatic group which is unsubstituted or mono- or polysubstituted at the ring by CN, NO.sub.2, halogen, lower alkyl, lower alkoxy or haloalkyl, R.sub.11 is hydrogen, lower alkyl or cycloalkyl, R.sub.12 is lower alkyl or an aromatic group, while Y is 0, S SO, SO.sub.2 or ##STR4## and A is C.sub.2 -C.sub.3 alkylene or C.sub.2 -C.sub.3 alkenylene which is unsubstituted or substituted by halogen, CN or lower alkyl and which together with a carbon chain which is unsubstituted or substituted by halogen, CN or lower alkyl can form a fused ring, and Hal is halogen. These compounds are used for protecting plant crops form the action of aggressive agricultural chemicals.

    Oxime derivatives for protecting plant crops
    44.
    发明授权
    Oxime derivatives for protecting plant crops 失效

    公开(公告)号：US4353735A

    公开(公告)日：1982-10-12

    申请号：US68263

    申请日：1979-08-20

    申请人： Werner Fory ,  Henry Martin ,  Georg Pissiotas

    发明人： Werner Fory ,  Henry Martin ,  Georg Pissiotas

    IPC分类号： A01N25/32 ,  A01N37/32 ,  A01N37/34 ,  C07C67/00 ,  C07C251/32 ,  C07C251/54 ,  C07C313/00 ,  C07C315/04 ,  C07C317/28 ,  C07C317/44 ,  C07C323/47 ,  C07C325/00 ,  C07C327/28 ,  C07D207/26 ,  C07D207/273 ,  C07D207/325 ,  C07D207/404 ,  C07D207/408 ,  C07D207/44 ,  C07D207/452 ,  C07D207/456 ,  C07D209/48 ,  C07C121/52

    CPC分类号： C07D207/273 ,  A01N25/32 ,  C07D207/452 ,  C07D207/456 ,  C07D209/48

    摘要： Oxime derivatives of the formula (I) ##STR1## wherein n is 0, 1 or 2 and m is 0 or 1, and Ar is a phenyl radical ##STR2## a naphthyl radical substituted by R.sub.2 and R.sub.3, a 5- to 10-membered heterocyclic radical which contains not more than 3 identical or different heteroatoms N, O and/or S and which is substituted by R.sub.2, R.sub.3 and R.sub.4 and can be substituted by oxo or thiono, or if m is 0, Ar is a radical R--CO, wherein R is a radical --OR.sub.5, in which R.sub.5 is an aliphatic group containing not more than 8 carbon atoms or is an araliphatic group containing not more than 15 carbon atoms or is a cycloaliphatic or aromatic group, each containing not more than 10 carbon atoms, while the possible substituents of the aromatic radicals or of the cycloaliphatic radical are halogen, --CN, --NO.sub.2, lower alkyl, lower alkoxy, haloalkyl; or R is a radical --NH--CO--NH--R.sub.7 or a radical --N(R.sub.6)(R.sub.7), wherein R.sub.6 is hydrogen or lower alkyl and R.sub.7 is hydrogen or an aliphatic group containing not more than 8 carbon atoms or an araliphatic group containing not more than 15 carbon atoms, or a cycloaliphatic ##STR3## wherein R.sub.9 is hydrogen, a cycloaliphatic, araliphatic or aromatic group which is unsubstituted or mono- or polysubstituted at the ring by CN, NO.sub.2, halogen, lower alkyl, lower alkoxy or haloalkyl, or is lower alkenyl, lower haloalkenyl or lower alkynyl, R.sub.10 is an aliphatic group or a cycloaliphatic, araliphatic or aromatic group which is unsubstituted or mono- or polysubstituted at the ring by CN, NO.sub.2, halogen, lower alkyl, lower alkoxy or haloalkyl, R.sub.11 is hydrogen, lower alkyl or cycloalkyl, R.sub.12 is lower alkyl or an aromatic group, while Y is O, S SO, SO.sub.2 or ##STR4## and A is C.sub.2 -C.sub.3 alkylene or C.sub.2 -C.sub.3 alkenylene which is unsubstituted or substituted by halogen, CN or lower alkyl and which together with a carbon chain which is unsubstituted or substituted by halogen, CN or lower alkyl can form a fused ring, and Hal is halogen. These compounds are used for protecting plant crops from the action of aggressive agricultural chemicals.

    Pyrazde herbicides
    45.
    发明授权
    Pyrazde herbicides 失效
    吡唑除草剂

    公开(公告)号：US06339046B1

    公开(公告)日：2002-01-15

    申请号：US08959437

    申请日：1997-10-28

    申请人： Kurt Nebel ,  Juraj Tuleja ,  Georg Pissiotas ,  Hans-Georg Brunner

    发明人： Kurt Nebel ,  Juraj Tuleja ,  Georg Pissiotas ,  Hans-Georg Brunner

    IPC分类号： A01N4356

    CPC分类号： A01N43/56 ,  C07D231/14

    摘要： Compounds of the formula I in which R1 is C1-C4alkyl; R2 is cyano or NH2C(S)—; R3 is hydrogen, C1-C4alkyl, C1-C4haloalkyl, C3- or C4alkenyl, C3- or C4alkynyl, C3-C8haloalkenyl, NC—CH2—, HOC(O)—CH2— or C1-C4alkoxy-C(O)—CH2—; W is a group  and R4 to R6, R60, R61, R70, X1, X2, n1 and A1—B1 are as defined in claim 1, and the pyrazole N-oxide, agronomically acceptable salts and stereomers of these compounds of the formula I, with the exclusion of the compound of the formula  have good selective herbicidal properties when used pre- and post-emergence. The preparation of these compounds and their use as herbicidally active ingredients are described.

    摘要翻译： R1为C1-C4烷基的式Iin化合物; R2为氰基或NH2C（S） - ; R3为氢，C1-C4烷基，C1-C4卤代烷基，C3-或C4-烯基，C3-或C4-炔基，C3-C8卤代烯基，NC-CH2 - ，HOC（O）-CH 2 - 或C 1 -C 4烷氧基-C（O）-CH 2 - ; W是基团，R 4 -R 6，R 60，R 61，R 70，X 1，X 2，n 1和A 1 -B 1如权利要求 1和吡唑N-氧化物，这些式I化合物的农学上可接受的盐和立体异构体，排除下式化合物在出苗前和出苗后使用时具有良好的选择性除草性质。 描述了这些化合物的制备及其作为除草活性成分的用途。

    Pyrazole herbicides
    46.
    发明授权
    Pyrazole herbicides 失效
    吡唑除草剂

    公开(公告)号：US5731267A

    公开(公告)日：1998-03-24

    申请号：US820758

    申请日：1997-03-19

    申请人： Georg Pissiotas ,  Kurt Nebel ,  Hans-Georg Brunner

    发明人： Georg Pissiotas ,  Kurt Nebel ,  Hans-Georg Brunner

    IPC分类号： A01N43/56 ,  C07D231/12 ,  C07D231/14 ,  C07D231/16 ,  C07D231/18 ,  C07D307/79 ,  C07D307/85 ,  C07D405/04 ,  C07D405/02

    CPC分类号： C07D405/04 ,  A01N43/56 ,  C07D231/14 ,  C07D231/16 ,  C07D231/18 ,  C07D307/79 ,  C07D307/85

    摘要： Compounds of the formula I ##STR1## in which R is hydrogen, fluorine or chlorine; R.sub.1 is hydrogen, halogen, trifluoromethyl, C.sub.1 -C.sub.4 haloalkoxy, cyano, nitro or amino; A-B is a group ##STR2## in which the 2 carbon atom is bonded to the oxygen atom; W is a group ##STR3## R.sub.2 is hydrogen or C.sub.1 -C.sub.6 -alkyl; R.sub.3 is C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 haloalkyl, cyano-C.sub.1 -C.sub.4 alkyl, hydroxy-C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 alkoxy-C.sub.1 -C.sub.6 alkyl, C.sub.3 -C.sub.6 alkenyloxy-C.sub.1 -C.sub.4 -alkyl, C.sub.3 -C.sub.6 alkynyloxy-C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.6 alkylcarbonyloxy-C.sub.1 -C.sub.6 alkyl, carboxyl, C.sub.1 -C.sub.6 alkoxycarbonyl, C.sub.1 -C.sub.6 haloalkoxycarbonyl, C.sub.3 -C.sub.6 alkenyloxycarbonyl, C.sub.3 -C.sub.6 alkynyloxycarbonyl, C.sub.3 -C.sub.6 cycloalkoxycarbonyl, C.sub.1 -C.sub.4 alkoxy-C.sub.1 -C.sub.4 alkoxycarbonyl, C.sub.1 -C.sub.4 alkylaminocarbonyl, di-C.sub.1 -C.sub.4 alkylaminocarbonyl, aminocarbonyl, benzyloxycarbonyl, phenyloxycarbonyl, C.sub.1 -C.sub.4 alkyl-SO.sub.2 NHC(O)--, C.sub.1 -C.sub.6 alkyl -ON.dbd.CH--, C.sub.1 -C.sub.6 alkoxycarbonyl-C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.3 alkylcarbonyl, ClC(O)--, NH.sub.2 C(S)--, OHC-- or cyano;R.sub.4 is hydrogen, fluorine, chlorine or bromine; R.sub.5 is carboxyl, C.sub.1 -C.sub.6 alkoxycarbonyl, NH.sub.2 C(O)--, NH.sub.2 C(S)--, HON.dbd.CH--, OHC-- or cyano; R.sub.6 is hydrogen or C.sub.1 -C.sub.4 alkyl; n is 0, 1 or 2, with the proviso that n is 0 if R.sub.6 is hydrogen; and R.sub.7 is hydrogen or C.sub.1 -C.sub.4 alkyl, and agronomically acceptable salts and stereoisomers of these compounds are suitable as herbicides.

    摘要翻译： 式I的化合物（I）其中R是氢，氟或氯; R1是氢，卤素，三氟甲基，C1-C4卤代烷氧基，氰基，硝基或氨基; A-B是其中2个碳原子键合到氧原子上的组 （W1）或（IMA）（W2）R2是氢或C1-C6-烷基; R 3是C 1 -C 6烷基，C 1 -C 6卤代烷基，氰基-C 1 -C 4烷基，羟基-C 1 -C 6烷基，C 1 -C 6烷氧基-C 1 -C 6烷基，C 3 -C 6烯氧基-C 1 -C 4烷基，C 3 -C 6炔氧基-C 1 -C 4烷基， C 1 -C 4烷基羰基氧基-C 1 -C 6烷基，羧基，C 1 -C 6烷氧基羰基，C 1 -C 6卤代烷氧基羰基，C 3 -C 6烯氧基羰基，C 3 -C 6炔氧基羰基，C 3 -C 6环烷氧基羰基，C 1 -C 4烷氧基-C 1 -C 4烷氧基羰基，C 1 -C 4烷基氨基羰基，二-C 1 -C 4烷基氨基羰基，氨基羰基，苄氧基羰基， 苯氧基羰基，C 1 -C 4烷基-SO 2 NHC（O） - ，C 1 -C 6烷基-ON = CH-，C 1 -C 6烷氧基羰基-C 1 -C 4烷基，C 1 -C 3烷基羰基，ClC（O） - ，NH 2 C（S） - ，OHC-或氰基; R4是氢，氟，氯或溴; R5是羧基，C1-C6烷氧基羰基，NH2C（O） - ，NH2C（S） - ，HON = CH-，OHC-或氰基; R6是氢或C1-C4烷基; n为0,1或2，条件是如果R6为氢，n为0; 并且R 7是氢或C 1 -C 4烷基，并且这些化合物的农学上可接受的盐和立体异构体适合作为除草剂。

    Herbicidal sulfonylureas
    49.
    发明授权
    Herbicidal sulfonylureas 失效
    除草磺酰脲类

    公开(公告)号：US4833252A

    公开(公告)日：1989-05-23

    申请号：US252022

    申请日：1988-09-28

    申请人： Werner Topfl ,  Georg Pissiotas

    发明人： Werner Topfl ,  Georg Pissiotas

    IPC分类号： A01N47/36 ,  C07C67/00 ,  C07C301/00 ,  C07C303/40 ,  C07C311/16 ,  C07C313/00 ,  C07C317/22 ,  C07C317/44 ,  C07C323/62 ,  C07C323/65 ,  C07C325/00 ,  C07C327/26 ,  C07D213/32 ,  C07D213/70 ,  C07D233/54 ,  C07D233/84 ,  C07D239/26 ,  C07D239/36 ,  C07D239/38 ,  C07D239/42 ,  C07D239/47 ,  C07D239/52 ,  C07D239/56 ,  C07D249/08 ,  C07D249/12 ,  C07D251/22 ,  C07D271/10 ,  C07D277/10 ,  C07D277/20 ,  C07D277/36 ,  C07D401/12 ,  C07D403/12 ,  C07D405/12 ,  C07D413/12 ,  C07D417/12 ,  C07D521/00

    CPC分类号： C07D233/64 ,  A01N47/36 ,  C07D213/32 ,  C07D239/26 ,  C07D239/36 ,  C07D249/08 ,  C07D277/10 ,  C07D521/00

    摘要： Substituted N-phenylsulfonyl-N'-pyrimidinylureas and N-phenylsulfonyl-N'-triazinylureas of the general formula ##STR1## and the salts thereof with amines, alkali metal bases or alkaline earth metal bases, or with quaternary ammonium bases, have good pre- and postemergence selective herbicidal and growth regulating properties.In the above formula the symbols have the following meanings:R.sup.1 is hydrogen, halogen, nitro, cyano, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkylthio, C.sub.1 -C.sub.4 alkylsulfonyl, C.sub.1 -C.sub.4 alkylsulfinyl, --CO--R.sup.8, --NR.sup.9 R.sup.10, --CO--NR.sup.11 R.sup.12 or --SO.sub.2 --NR.sup.13 R.sup.14,R.sup.2 is hydrogen, halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkylthio, C.sub.1 -C.sub.4 alkylsulfinyl or C.sub.1 -C.sub.4 alkylsulfonyl,R.sup.3 is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl or cyano,R.sup.4 is hydrogen or C.sub.1 -C.sub.4 alkyl,R.sup.5 is hydrogen, C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkoxy,R.sup.6 and R.sup.7 are each independently hydrogen, halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 haloalkoxy, C.sub.1 -C.sub.4 alkylthio, C.sub.1 -C.sub.4 haloalkylthio, C.sub.2 -C.sub.4 alkoxyalkyl, C.sub.3 -C.sub.6 cycloalkyl or --NR.sup.15 R.sup.16,R.sup.8 is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 haloalkoxy, C.sub.1 -C.sub.4 alkylthio or C.sub.2 -C.sub.4 alkoxyalkoxy,R.sup.9, R.sup.10, R.sup.11, R.sup.12, R.sup.13, R.sup.15 and R.sup.16 are each independently hydrogen or C.sub.1 -C.sub.4 alkyl,A is a radical --Y--(CH.sub.2).sub.n --R.sup.17 or ##STR2## R.sup.17 is a 5- or 6-membered unsaturated heterocyclic radical, R.sup.18 and R.sup.19 are each independently hydrogen, halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 haloalkoxy, nitro or cyano,E is nitrogen or --CH.dbd.,Y is oxygen, sulfur or a direct bond,T and Z are each independently oxygen or sulfur, andn is 0 or 1.

    摘要翻译： 具有通式“IMAGE”的N-取代的N-苯基磺酰基-N'-嘧啶基脲和N-苯基磺酰基-N'-三嗪基脲及其与胺，碱金属碱或碱土金属碱或季铵碱的盐具有良好的预 - 和芽后选择性除草和生长调节性质。 在上式中，符号具有以下含义：R 1是氢，卤素，硝基，氰基，C 1 -C 4烷基，C 1 -C 4卤代烷基，C 1 -C 4烷氧基，C 1 -C 4烷硫基，C 1 -C 4烷基磺酰基，C 1 -C 4烷基亚磺酰基，-CO-R 8， -NR9R10，-CO-NR11R12或-SO2-NR13R14，R2是氢，卤素，C1-C4烷基，C1-C4烷氧基，C1-C4烷硫基，C1-C4烷基亚磺酰基或C1-C4烷基磺酰基，R3是氢，C1-C4烷基，C1-C4卤代烷基 或氰基，R 4是氢或C 1 -C 4烷基，R 5是氢，C 1 -C 4烷基或C 1 -C 4烷氧基，R 6和R 7各自独立地是氢，卤素，C 1 -C 4烷基，C 1 -C 4烷氧基，C 1 -C 4卤代烷基，C 1 -C 4卤代烷氧基， C 1-4烷硫基，C 1 -C 4卤代烷硫基，C 2 -C 4烷氧基烷基，C 3 -C 6环烷基或-NR 15 R 16，R 8是氢，C 1 -C 4烷基，C 1 -C 4卤代烷基，C 1 -C 4烷氧基，C 1 -C 4卤代烷氧基，C 1 -C 4烷硫基或C 2 -C 4烷氧基烷氧基， R 11，R 12，R 13，R 15和R 16各自独立地为氢或C 1 -C 4烷基，A为基团-Y-（CH 2）n -R 17或R 17为5-或6-元不饱和杂环基，R 18和 R19各自独立 氢，卤素，C1-C4烷基，C1-C4卤代烷基，C1-C4烷氧基，C1-C4卤代烷氧基，硝基或氰基，E是氮或-CH =，Y是氧，硫或直接键，T和Z各自独立地是氧或 硫，n为0或1。