摘要:
Esters of citric acid or acetylcitric anhydride with compounds of at least 3 OH groups selected from the group consisting of polyglycerol, sugarcarboxylic acids, alkyl glucosides, derivatives of oligosaccharides, aminosorbitol, aminodisorbitol, glucosamine, triethanolamine and trishydroxyethylmelamine, each OH group of the alcohol component of the esters being esterified on average with from 0.15 to 1 molecule of citric acid or acetylcitric anhydride, are useful as additives in low-phosphate or phosphate-free detergents.
摘要:
Agglomerated polymer particles of finely divided, water-soluble or water-swellable polymers are prepared by azeotropic dewatering of water-in-oil emulsions of water-soluble or water-swellable polymers in the presence of from 1 to 40% by weight, based on the polymers, of polyalkylene glycols which(a) are obtainable by an addition reaction of C.sub.2 -C.sub.4 -alkylene oxides with alcohols, phenols, amines or carboxylic acids and(b) contain not less than 2 polymerized alkylene oxide unitsand isolation of the agglomerated polymer particles. The water-soluble agglomerated polymer particles are used as flocculants and retention and drainage aids, while the water-swellable polymer powders are employed as thickeners for aqueous systems, in particular as thickeners for textile print pastes.
摘要:
A cementing composition useful in cementing oil, gas and water wells, comprising water, hydraulic cement and an effective amount of water soluble fluid loss additive comprised of a blend of a copolymer (i) of acrylamide/vinyl imidazole in a weight percent ratio of from about 95:5 to 5:95, said copolymer (i) having a molecular weight range of from about 100,000 to 3,000,000, and a copolymer (ii) of vinyl pyrrolidone and the sodium salt of vinyl sulfonate in a weight percent ratio of 80:20 to 20:80, said copolymer (ii) having a molecular weight range of from about 100,000 to 3,000,000. The blend is comprised of a weight percent ratio of copolymer (i) to copolymer (ii) in the range of 20:80 to 80:20. The composition can also optionally include a dispersant such as sodium or potassium salts or a sulfonated naphthalene formaldehyde condensate.
摘要:
Graft copolymers obtainable by free radical-initiated copolymerization of(A) a monomer mixture comprising(a) a monoethylenically unsaturated C.sub.4 - to C.sub.8 -dicarboxylic acid, or an anhydride, alkali metal salt or ammonium salt thereof,(b) a monoethylenically unsaturated C.sub.3 - to C.sub.10 -carboxylic acid, or an alkali metal salt or ammonium salt thereof,(c) if desired another monoethylenically unsaturated monomer which can be copolymerized with monomer (a) and (b), and(d) a monomer containing two or more ethylenically unsaturated, non-conjugated double bonds in the molecule, in the presence of(B) a monosaccharide, oligosaccharide, polysaccharide, oxidatively, hydrolytically or enzymatically degraded polysaccharide, oxidized, hydrolytically or enzymatically degraded polysaccharide, or chemically modified monosaccharide, oligosaccharide or polysaccharide,in the weight ratio (A):(B) of (95 to 20):(5 to 80), a process for the preparation of the graft copolymers, and detergents and cleaners containing the graft copolymers in amounts of from 0.1 to 20% by weight, are described.
摘要:
Abstract of the Disclosure: Crosslinked acrylic or methacrylic acid copolymers with crosslinkable groups that are useful as thickeners for textile print pastes are obtainable by copolymerization of(a) from 50 to 99 parts by weight of acrylic acid and/or methacrylic acid,(b) from 1 to 50 parts by weight of at least one N-methylol (meth)acrylamide or derivatives thereof,(c) from 50 to 10,000 ppm, based on the monomers (a) and (b), of an at least bifunctional crosslinker, and(d) from 0 to 49 parts by weight of other monoethylenically unsaturated monomersin the presence of a free radical polymerization initiator in the aqueous phase of a water-in-oil emulsion.
摘要:
Crude oil middle distillates with improved cold flow properties, containing small amounts ofA. conventional flow improver on an ethylene base, andB. copolymers which consist of 10 to 95 mol-% of one or more acrylacrylates or alkylmethacrylates with C.sub.1 - to C.sub.26 -alkyl chains, and of 5 to 90 mol-% of one or more ethylenically unsaturated dicarboxylic acids or their anhydrides, where the copolymer is reacted to a large extent with one or several primary or secondary amines into the monoamide or amide/ammonia salt of dicarboxylic acid, and the quantitative proportion of A to B is from 40 to 60 up to 95 to 5.
摘要:
Finely divided, gel-like, water-swellable copolymers are prepared by copolymerizing(a) 100 parts by weight of water-soluble, monoethylenically unsaturated monomers,(b) from 0.01 to 5 parts by weight of monomers containing two or more ethylenically unsaturated double bonds and(c) from 0 to 20 parts by weight of water-insoluble, monoethylenically unsaturated monomersin 20-80% strength by weight aqueous solution in the presence of a polymerization initiator and from 0.1 to 10% by weight, based on the monomers used in the copolymerization, of a surfactant, by a process in which the monomers are copolymerized in the presence of initially from 0 to 50% by weight of the amount of surfactant to a conversion of not less than 60%, the remaining amount of surfactant is then added to the reaction mixture and the copolymerization is completed and the resulting gel particles dried.
摘要:
Pulverulent polymers of acrylic acid and methacrylic acid are prepared by polymerizing (a) from 100 to 70% by weight of acrylic acid, methacrylic acid or a mixture thereof and (b) from 0 to 30% by weight of vinylsulfonic acid or an alkali metal salt thereof in a monohydric C.sub.1 -C.sub.8 -alcohol, water or a mixture thereof in a pulverulent bed in the presence of a polymerization initiator and from 0.05 to 10 mol % of thiocarboxylic acid and/or a mercaptoalcohol and from 0.05 to 10 mol % of propionic acid or formic acid as regulators, each percentage being based on the monomers used in the polymerization, by maintaining the pulverulent state during the polymerization, removing the heat of polymerization by distilling off the solvent and recirculating the reaction mixture.
摘要:
Oxyalkylated, carboxyl-containing polymers are prepared by reacting(A) a polymer which contains one or more monoethylenically unsaturated C.sub.3 -C.sub.6 -carboxylic acids as copolymerized units with(B) an alkylene oxidein an aqueous medium at not more than 120.degree. C. by a process in which the reaction is started at a pH of from 5.0 to 5.9 and is ended after a pH of from 5.5 to 8.5 has been reached. As a result of monitoring of the pH, the selectivity of the addition reaction of alkylene oxides with the polymers (A) is substantially improved compared with known processes.
摘要:
Paper, board, and cardboard having high dry strength are made by adding to the paper stock a dry strength agent which is obtainable by mixing enzymatically digested starch having a viscosity of from 20 to 2,000 mPa.s (measured in 7.5% strength aqueous solution at 45.degree. C.) and a cationic polymer which contains, as typical copolymerized monomers,(a) diallyldimethylammonium chloride,(b) N-vinylamine or(c) an unsubstituted or substituted N-vinylimidazoline, the K value of the cationic polymer in each case being not less than 30, and draining the paper stock with sheet formation.