摘要:
The present invention relates to novel blocked, elimination-free polyurethane (PUR) crosslinking agents, to a process for their preparation and to their use as starting components for the production of polyurethane plastics, especially as crosslinking agents for thermally crosslinkable powder coatings.
摘要:
The present invention relates to aliphatic oligocarbonate polyols prepared by the transesterification of organic carbonates with aliphatic polyols in the presence of at least one catalyst which contains i) at least one rare earth metal or compounds thereof or ii) at least one metal of group III B of the periodic table of the elements or compounds thereof or iii) mixtures of i) and ii) and to a process for preparing the same.
摘要:
Blocked polyisocyanates, their preparation and use in one-component coating materials. In organic polyisocyanates having at least two isocyanate groups, the isocyanate groups are blocked with OH acidic cyclic ketones of the general formula (I). The blocked polyisocyanate system of the invention reacts without elimination of the blocking agent and possesses low crosslinking temperatures.
摘要:
The invention relates to polyurethane-polyurea dispersions, also called PU dispersion, which contain aralkylamine-blocked isocyanate groups, and to their preparation and use. This blocking agent ahs a significantly lower deblocking temperature as compared with the prior art. Coatings produced from this dispersion have high hydrolysis resistances. The arylamine-blocked isocyanate groups are composed of polyisocyanates, polymeric polyols having average molar weights of 400 to 6000, at least one blocking agent, and either or both of nonionically hydrophilicizing compounds or compounds having at least one ionic or potentially ionic group.
摘要:
The present invention relates to thermosetting two-component coating compositions containing A) at least one NCO prepolymer, B) at least one amine-free chain extender, C) at least one catalyst selected from metal 1,3-dicarbonylates and metal-oxo 1,3-dicarbonylates, wherein i) the metal 1,3-dicarbonylate contains as a neutral complex a metal cation with the electron configuration d0 of sub-group 3 or a lanthanide and ii) the metal-oxo 1,3-dicarbonylate contains a metal-oxo cation of sub-group 6 with the electron configuration d0. The present invention also relates to a process for preparing these coating compositions and to coated substrates prepared therefrom.
摘要:
The present invention relates to a process for preparing a dinitronaphthalene isomer mixture having an increased proportion of 1,5-dinitronaphthalene by nitrating naphthalene in the presence of at least one ionic liquid.
摘要:
The present invention relates to a process for the preparation of polyether carbonate polyols by catalytic copolymerization of carbon dioxide (CO2) with alkylene oxides in the presence of one or more H-functional starter substances with the aid of double metal cyanide (DMC) catalysts and in the presence of additives A) chosen from the group consisting of sterically non-hindered phenols, catechols, pyrocatechols, thiazines, phenothiazines, thiazoles, benzothiazoles, oxazines, phenoxazines, 2,2,6,6-tetramethylpiperidine 1-oxyl and nitrostyrenes and optionally in the presence of metal salts B).
摘要:
The present invention relates to a process for the preparation of polyether carbonate polyols from one or more H-functional starter substances, one or more alkylene oxides and carbon dioxide in the presence of at least one double metal cyanide catalyst, wherein the cyanide-free metal salt, the metal cyanide salt or both the mentioned salts used for the preparation of the double metal cyanide catalyst contain(s) from 0.3 to 1.8 mol base equivalents (based on 1 mol of the metal cyanide salt used for the synthesis of the catalyst) of alkaline metal hydroxide, metal carbonate and/or metal oxide.
摘要:
The present invention relates to a process for the activation of double metal cyanide (DMC) catalysts for the preparation of polyether carbonate polyols by catalytic copolymerisation of carbon dioxide (CO2) with alkylene oxides in the presence of one or more H-functional starter substances.