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公开(公告)号：US09508537B2
公开(公告)日：2016-11-29
申请号：US14130440
申请日：2012-07-06
CPC分类号： H01J49/0059 , G01N27/624 , H01J49/0027 , H01J49/0031 , H01J49/062 , H01J49/10 , H01J49/26 , H01J49/40 , H01J49/422 , H01J49/4245
摘要： A method of mass spectrometry is disclosed comprising directing first photons from a laser onto ions located within a 2D or linear ion guide or ion trap. The frequency of the first photons is scanned and first photons and/or second photons emitted by the ions are detected. The ions are then mass analyzed using a Time of Flight mass analyzer.
摘要翻译： 公开了一种质谱方法，其包括将来自激光器的第一光子引导到位于2D或线性离子导向器或离子阱内的离子上。 扫描第一光子的频率，并检测由离子发射的第一光子和/或第二光子。 然后使用飞行时间质量分析仪对离子进行质量分析。
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公开(公告)号：US09190256B2
公开(公告)日：2015-11-17
申请号：US14130453
申请日：2012-07-06
CPC分类号： H01J49/062 , H01J49/0004 , H01J49/0463 , H01J49/065 , H01J49/164 , H01J49/26
摘要： An ion source for a mass spectrometer is disclosed comprising a lens and mirror arrangement which focuses a laser beam onto the upper surface of a target substrate. The lens has an effective focal length ≦300 mm. The laser beam is directed onto the target substrate at an angle θ with respect to the perpendicular to the target substrate, wherein θ≦3°. One or more ion guides receive ions released from the target substrate and onwardly transmit the ions along an ion path which substantially bypasses the lens and mirror.
摘要翻译： 公开了一种用于质谱仪的离子源，其包括将激光束聚焦到目标衬底的上表面上的透镜和反射镜装置。 镜头具有有效的焦距＆nlE; 300 mm。 激光束以一定角度被引导到靶基底上; 相对于与靶基板的垂直度，其中＆amp; nlE; 3°。 一个或多个离子导向器接收从目标衬底释放的离子，并沿基本上绕过透镜和反射镜的离子路径向上透射离子。
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公开(公告)号：US09159541B2
公开(公告)日：2015-10-13
申请号：US14123537
申请日：2012-06-01
申请人： Daniel James Kenny
发明人： Daniel James Kenny
CPC分类号： H01J49/0495 , H01J49/0418 , H01J49/062 , H01J49/067 , H01J49/24
摘要： A mass spectrometer is disclosed comprising two vacuum chambers maintained at different pressures. The two vacuum chambers are interconnected by a differential pumping aperture. The effective area of the opening between the two vacuum chambers may be varied by rotating a disk having an aperture in front of the differential pumping aperture so as to vary the gas flow rate through the opening and between the two chambers.
摘要翻译： 公开了一种质谱仪，其包括保持在不同压力下的两个真空室。 两个真空室通过差动泵浦孔互连。 两个真空室之间的开口的有效面积可以通过旋转具有在差动泵送孔前面的孔的盘来改变通过开口和两个室之间的气体流速。
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公开(公告)号：US20140224974A1
公开(公告)日：2014-08-14
申请号：US14130428
申请日：2012-07-06
CPC分类号： H01J49/0059 , G01N27/624 , H01J49/0027 , H01J49/0031 , H01J49/062 , H01J49/10 , H01J49/26 , H01J49/40 , H01J49/422 , H01J49/4245
摘要： A method of mass spectrometry is disclosed comprising automatically and repeatedly performing multiple cycles of operation, wherein a cycle of operation comprises the steps of: (i) mass analysing first ions; (ii) exposing the first ions to a first photo-dissociation device to form a plurality of second ions and mass analysing the second ions; and (iii) exposing the first ions to a first photo-dissociation device to form a plurality of second ions, fragmenting the second ions to form a plurality of third ions and mass analysing the third ions.
摘要翻译： 公开了一种自动重复执行多个操作循环的质谱法，其中操作循环包括以下步骤：（i）质量分析第一离子; （ii）将第一离子暴露于第一光离解装置以形成多个第二离子并质量分析第二离子; 和（iii）将第一离子暴露于第一光解离装置以形成多个第二离子，使第二离子碎裂以形成多个第三离子并大量分析第三离子。
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公开(公告)号：US08658970B2
公开(公告)日：2014-02-25
申请号：US13375076
申请日：2010-05-28
申请人： Daniel James Kenny
发明人： Daniel James Kenny
IPC分类号： H01J49/42
CPC分类号： H01J49/062 , H01J49/02 , H01J49/065 , H01J49/422
摘要： An ion guide is disclosed comprising a plurality of axial groupings of electrodes, wherein each axial grouping of electrodes comprises a ring or annular electrode which has been radially segmented into a plurality of electrode segments.
摘要翻译： 公开了一种离子导向器，其包括多个轴向分组的电极，其中电极的每个轴向分组包括已经被径向分割成多个电极段的环形或环形电极。
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公开(公告)号：US20120280123A1
公开(公告)日：2012-11-08
申请号：US13375076
申请日：2010-05-28
申请人： Daniel James Kenny
发明人： Daniel James Kenny
IPC分类号： H01J49/42
CPC分类号： H01J49/062 , H01J49/02 , H01J49/065 , H01J49/422
摘要： An ion guide is disclosed comprising a plurality of axial groupings of electrodes, wherein each axial grouping of electrodes comprises a ring or annular electrode which has been radially segmented into a plurality of electrode segments.
摘要翻译： 公开了一种离子导向器，其包括多个轴向分组的电极，其中电极的每个轴向分组包括已经被径向分割成多个电极段的环形或环形电极。
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公开(公告)号：US09293314B2
公开(公告)日：2016-03-22
申请号：US14130428
申请日：2012-07-06
CPC分类号： H01J49/0059 , G01N27/624 , H01J49/0027 , H01J49/0031 , H01J49/062 , H01J49/10 , H01J49/26 , H01J49/40 , H01J49/422 , H01J49/4245
摘要： A method of mass spectrometry is disclosed comprising automatically and repeatedly performing multiple cycles of operation, wherein a cycle of operation comprises the steps of: (i) mass analyzing first ions; (ii) exposing the first ions to a first photo-dissociation device to form a plurality of second ions and mass analyzing the second ions; and (iii) exposing the first ions to a first photo-dissociation device to form a plurality of second ions, fragmenting the second ions to form a plurality of third ions and mass analyzing the third ions.
摘要翻译： 公开了一种自动重复执行多个操作循环的质谱法，其中操作循环包括以下步骤：（i）质量分析第一离子; （ii）将第一离子暴露于第一光离解装置以形成多个第二离子并质量分析第二离子; 和（iii）将第一离子暴露于第一光解离装置以形成多个第二离子，使第二离子碎裂以形成多个第三离子并大量分析第三离子。
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公开(公告)号：US20140306103A1
公开(公告)日：2014-10-16
申请号：US14123566
申请日：2012-06-01
IPC分类号： H01J49/04
CPC分类号： H01J49/04 , H01J49/067 , H01J49/24
摘要： An ion inlet for a mass spectrometer is disclosed comprising a housing having a sampling orifice and an atmospheric pressure orifice. One or more gas outlets are provided in the housing. Gas is drawn through the sampling orifice by a pump so that the gas exits via the one or more gas outlets.
摘要翻译： 公开了一种用于质谱仪的离子入口，其包括具有采样孔和大气压力孔的壳体。 一个或多个气体出口设置在壳体中。 通过泵将气体抽吸通过采样孔，使得气体经由一个或多个气体出口排出。
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公开(公告)号：US20140217279A1
公开(公告)日：2014-08-07
申请号：US14123537
申请日：2012-06-01
申请人： Daniel James Kenny
发明人： Daniel James Kenny
CPC分类号： H01J49/0495 , H01J49/0418 , H01J49/062 , H01J49/067 , H01J49/24
摘要： A mass spectrometer is disclosed comprising two vacuum chambers maintained at different pressures. The two vacuum chambers are interconnected by a differential pumping aperture. The effective area of the opening between the two vacuum chambers may be varied by rotating a disk having an aperture in front of the differential pumping aperture so as to vary the gas flow rate through the opening and between the two chambers.
摘要翻译： 公开了一种质谱仪，其包括保持在不同压力下的两个真空室。 两个真空室通过差动泵浦孔互连。 两个真空室之间的开口的有效面积可以通过旋转具有在差动泵送孔前面的孔的盘来改变通过开口和两个室之间的气体流速。
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公开(公告)号：US08445843B2
公开(公告)日：2013-05-21
申请号：US13145375
申请日：2010-01-20
申请人： Daniel James Kenny
发明人： Daniel James Kenny
CPC分类号： H01J49/0045 , H01J49/0031 , H01J49/06 , H01J49/10
摘要： A mass spectrometer is disclosed comprising an ion trap and a fragmentation device. Ions are fragmented in the ion trap to form first generation fragment ions. The ion trap has a relatively high mass cut-off. The first generation fragment ions are then transferred to a fragmentation device which is arranged to have a substantially lower low mass cut-off. The first generation fragment ions are fragmented within the fragmentation device any may optionally be stored in an ion accumulation region prior to being passed to a mass analyser for subsequent mass analysis.
摘要翻译： 公开了一种质谱仪，其包括离子阱和碎裂装置。 离子阱中的离子被分散以形成第一代碎片离子。 离子阱具有较高的质量截止。 然后将第一代碎片离子转移到碎片装置，碎裂装置被布置成具有基本上较低的低质量截止值。 第一代碎片离子在碎裂装置内碎裂，任何可以任选地存储在离子聚集区域中，然后被传递到质量分析器进行后续的质量分析。
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