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公开(公告)号：US09293314B2
公开(公告)日：2016-03-22
申请号：US14130428
申请日：2012-07-06
CPC分类号： H01J49/0059 , G01N27/624 , H01J49/0027 , H01J49/0031 , H01J49/062 , H01J49/10 , H01J49/26 , H01J49/40 , H01J49/422 , H01J49/4245
摘要： A method of mass spectrometry is disclosed comprising automatically and repeatedly performing multiple cycles of operation, wherein a cycle of operation comprises the steps of: (i) mass analyzing first ions; (ii) exposing the first ions to a first photo-dissociation device to form a plurality of second ions and mass analyzing the second ions; and (iii) exposing the first ions to a first photo-dissociation device to form a plurality of second ions, fragmenting the second ions to form a plurality of third ions and mass analyzing the third ions.
摘要翻译： 公开了一种自动重复执行多个操作循环的质谱法，其中操作循环包括以下步骤：（i）质量分析第一离子; （ii）将第一离子暴露于第一光离解装置以形成多个第二离子并质量分析第二离子; 和（iii）将第一离子暴露于第一光解离装置以形成多个第二离子，使第二离子碎裂以形成多个第三离子并大量分析第三离子。
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公开(公告)号：US20140291501A1
公开(公告)日：2014-10-02
申请号：US14130440
申请日：2012-07-06
CPC分类号： H01J49/0059 , G01N27/624 , H01J49/0027 , H01J49/0031 , H01J49/062 , H01J49/10 , H01J49/26 , H01J49/40 , H01J49/422 , H01J49/4245
摘要： A method of mass spectrometry is disclosed comprising directing first photons from a laser onto ions located within a 2D or linear ion guide or ion trap. The frequency of the first photons is scanned and first photons and/or second photons emitted by the ions are detected. The ions are then mass analysed using a Time of Flight mass analyser.
摘要翻译： 公开了一种质谱方法，其包括将来自激光器的第一光子引导到位于2D或线性离子导向器或离子阱内的离子上。 扫描第一光子的频率，并检测由离子发射的第一光子和/或第二光子。 然后使用飞行时间质量分析仪对离子进行质量分析。
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公开(公告)号：US09136098B2
公开(公告)日：2015-09-15
申请号：US14130465
申请日：2012-07-06
申请人： Jason Lee Wildgoose , Steven Derek Pringle , Kevil Giles , Jeffery Mark Brown , Paul Murray , Daniel James Kenny
发明人： Jason Lee Wildgoose , Steven Derek Pringle , Kevil Giles , Jeffery Mark Brown , Paul Murray , Daniel James Kenny
CPC分类号： H01J49/10 , H01J49/0031 , H01J49/061 , H01J49/065 , H01J49/161
摘要： A pulsed ion source is disclosed wherein the ion source is energized one or more times to generate a first group of ions and a second group of ions. The first and second groups of ions are simultaneously transmitted through an ion guide whilst keeping the first and second groups of ions isolated from each other.
摘要翻译： 公开了脉冲离子源，其中离子源被激发一次或多次以产生第一组离子和第二组离子。 第一和第二组离子同时透过离子导向器同时保持第一和第二组离子彼此隔离。
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公开(公告)号：US20150034814A1
公开(公告)日：2015-02-05
申请号：US14130453
申请日：2012-07-06
CPC分类号： H01J49/062 , H01J49/0004 , H01J49/0463 , H01J49/065 , H01J49/164 , H01J49/26
摘要： An ion source for a mass spectrometer is disclosed comprising a lens and mirror arrangement which focuses a laser beam onto the upper surface of a target substrate. The lens has an effective focal length ≦300 mm. The laser beam is directed onto the target substrate at an angle θ with respect to the perpendicular to the target substrate, wherein θ≦3°. One or more ion guides receive ions released from the target substrate and onwardly transmit the ions along an ion path which substantially bypasses the lens and mirror.
摘要翻译： 公开了一种用于质谱仪的离子源，其包括将激光束聚焦到目标衬底的上表面上的透镜和反射镜装置。 镜头具有有效的焦距＆nlE; 300 mm。 激光束以一定角度被引导到靶基底上; 相对于与靶基板的垂直度，其中＆amp; nlE; 3°。 一个或多个离子导向器接收从目标衬底释放的离子，并沿基本上绕过透镜和反射镜的离子路径向上透射离子。
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公开(公告)号：US20140191123A1
公开(公告)日：2014-07-10
申请号：US14130465
申请日：2012-07-06
申请人： Jason Lee Wildgoose , Steven Derek Pringle , Kevil Giles , Jeffery Mark Brown , Paul Murray , Daniel James Kenny
发明人： Jason Lee Wildgoose , Steven Derek Pringle , Kevil Giles , Jeffery Mark Brown , Paul Murray , Daniel James Kenny
CPC分类号： H01J49/10 , H01J49/0031 , H01J49/061 , H01J49/065 , H01J49/161
摘要： A pulsed ion source is disclosed wherein the ion source is energised one or more times to generate a first group of ions and a second group of ions. The first and second groups of ions are simultaneously transmitted through an ion guide whilst keeping the first and second groups of ions isolated from each other.
摘要翻译： 公开了脉冲离子源，其中离子源被激发一次或多次以产生第一组离子和第二组离子。 第一和第二组离子同时透过离子导向器同时保持第一和第二组离子彼此隔离。
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公开(公告)号：US09508537B2
公开(公告)日：2016-11-29
申请号：US14130440
申请日：2012-07-06
CPC分类号： H01J49/0059 , G01N27/624 , H01J49/0027 , H01J49/0031 , H01J49/062 , H01J49/10 , H01J49/26 , H01J49/40 , H01J49/422 , H01J49/4245
摘要： A method of mass spectrometry is disclosed comprising directing first photons from a laser onto ions located within a 2D or linear ion guide or ion trap. The frequency of the first photons is scanned and first photons and/or second photons emitted by the ions are detected. The ions are then mass analyzed using a Time of Flight mass analyzer.
摘要翻译： 公开了一种质谱方法，其包括将来自激光器的第一光子引导到位于2D或线性离子导向器或离子阱内的离子上。 扫描第一光子的频率，并检测由离子发射的第一光子和/或第二光子。 然后使用飞行时间质量分析仪对离子进行质量分析。
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公开(公告)号：US09190256B2
公开(公告)日：2015-11-17
申请号：US14130453
申请日：2012-07-06
CPC分类号： H01J49/062 , H01J49/0004 , H01J49/0463 , H01J49/065 , H01J49/164 , H01J49/26
摘要： An ion source for a mass spectrometer is disclosed comprising a lens and mirror arrangement which focuses a laser beam onto the upper surface of a target substrate. The lens has an effective focal length ≦300 mm. The laser beam is directed onto the target substrate at an angle θ with respect to the perpendicular to the target substrate, wherein θ≦3°. One or more ion guides receive ions released from the target substrate and onwardly transmit the ions along an ion path which substantially bypasses the lens and mirror.
摘要翻译： 公开了一种用于质谱仪的离子源，其包括将激光束聚焦到目标衬底的上表面上的透镜和反射镜装置。 镜头具有有效的焦距＆nlE; 300 mm。 激光束以一定角度被引导到靶基底上; 相对于与靶基板的垂直度，其中＆amp; nlE; 3°。 一个或多个离子导向器接收从目标衬底释放的离子，并沿基本上绕过透镜和反射镜的离子路径向上透射离子。
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公开(公告)号：US20140224974A1
公开(公告)日：2014-08-14
申请号：US14130428
申请日：2012-07-06
CPC分类号： H01J49/0059 , G01N27/624 , H01J49/0027 , H01J49/0031 , H01J49/062 , H01J49/10 , H01J49/26 , H01J49/40 , H01J49/422 , H01J49/4245
摘要： A method of mass spectrometry is disclosed comprising automatically and repeatedly performing multiple cycles of operation, wherein a cycle of operation comprises the steps of: (i) mass analysing first ions; (ii) exposing the first ions to a first photo-dissociation device to form a plurality of second ions and mass analysing the second ions; and (iii) exposing the first ions to a first photo-dissociation device to form a plurality of second ions, fragmenting the second ions to form a plurality of third ions and mass analysing the third ions.
摘要翻译： 公开了一种自动重复执行多个操作循环的质谱法，其中操作循环包括以下步骤：（i）质量分析第一离子; （ii）将第一离子暴露于第一光离解装置以形成多个第二离子并质量分析第二离子; 和（iii）将第一离子暴露于第一光解离装置以形成多个第二离子，使第二离子碎裂以形成多个第三离子并大量分析第三离子。
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公开(公告)号：US07851744B2
公开(公告)日：2010-12-14
申请号：US11722663
申请日：2005-12-23
CPC分类号： G02B27/0955 , G02B27/0927 , G02B27/0977 , H01J49/0004 , H01J49/164
摘要： A Matrix Assisted Laser Desorption Ionization ion source or ion imaging device is disclosed comprising a laser (1) and a zoom lens (3, 4, 5). The zoom lens (3, 4, 5) is arranged to be able to vary the magnification of a laser beam which is directed onto a target region, sample surface or target plate (13) of the ion source or ion imaging device.
摘要翻译： 公开了一种矩阵辅助激光解吸电离离子源或离子成像装置，其包括激光器（1）和变焦透镜（3,4,5）。 变焦透镜（3,4,5）被布置成能够改变被引导到离子源或离子成像装置的目标区域，样品表面或靶板（13）上的激光束的放大率。
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公开(公告)号：US07297960B2
公开(公告)日：2007-11-20
申请号：US10989646
申请日：2004-11-16
CPC分类号： H01J49/405 , H01J49/421
摘要： A mass filter is disclosed comprising an orthogonal acceleration electrode 9. Ions entering the mass filter are orthogonally accelerated by the orthogonal acceleration electrode 9 in a primary acceleration region 2 and enter a flight region 3. The ions 6,7,8 are then reflected by a reflectron 4 and are directed towards an exit region of the mass filter. Ions having a desired mass to charge ratio are arranged to arrive in the primary acceleration region 2 at a time when a voltage pulse applied to the orthogonal acceleration electrode 9 falls from a maximum to zero. Ions having a desired mass to charge ratio are orthogonally decelerated such that they have a zero component of velocity in the orthogonal direction. Accordingly, ions having a desired mass to charge ratio exit the mass filter in an axial direction.
摘要翻译： 公开了一种包括正交加速电极9的质量过滤器。 进入质量过滤器的离子通过正加速电极9在主加速区域2中正交加速并进入飞行区域3。 然后离子6,7,8被反射器4反射并且被引向质量过滤器的出口区域。 具有期望的质荷比的离子被布置成在施加到正交加速电极9的电压脉冲从最大值降到零的时刻到达主加速区域2。 具有期望的质荷比的离子正交减速，使得它们在正交方向上具有零分量的速度。 因此，具有期望质荷比的离子沿轴向离开质量过滤器。
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