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公开(公告)号：US4584339A
公开(公告)日：1986-04-22
申请号：US625972
申请日：1984-06-29
CPC分类号： C10M173/02 , C08L57/04 , C09K3/18 , C09K8/588 , C10M2217/02 , C10M2221/02 , C10N2240/08 , C10N2250/02 , Y10S260/31 , Y10T137/0391
摘要： The present invention relates to aqueous solutions having dilatant properties in which the aqueous solution contains a polymer complex which is a water soluble polymer backbone containing an anionic comonomer and a copolymer of a water soluble polymer backbone containing a cationic comonomer.
摘要翻译： 本发明涉及具有膨胀特性的水溶液，其中水溶液含有聚合物配合物，其是含有阴离子共聚单体的水溶性聚合物主链和含有阳离子共聚单体的水溶性聚合物主链的共聚物。
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42.发明授权Hydrocarbon soluble polymer complexes useful as viscosifiers in fracturing operations 失效用于压裂作业中的增粘剂的烃溶性聚合物配合物
公开(公告)号：US4579671A
公开(公告)日：1986-04-01
申请号：US651899
申请日：1984-09-19
CPC分类号： C09K8/64 , Y10S507/922
摘要： A process for fracturing a subterranean formation surrounding a gas or oil well which comprises injecting said subterranean formation under hydraulic pressure with a fluid comprising about 0.1 to about 75 percent of an interpolymer complex dissolved in a solvent system of a nonpolar organic liquid and a polar cosolvent (as desired), said polymer complex comprises the interaction product of a sulfonated polymer and an amine containing polymer, wherein the sulfonate content of the sulfonated polymer is about 4 meq. per 100 gram of polymer to about 200 meq. per 100 gram of polymer and the basic nitrogen content of the amine containing polymer is about 4 meq. per 100 gram of polymer to about 500 meq. per 100 gram of polymer, and by the addition of polar cosolvent to such solution of polymer complex modifying its rheological properties over a wide range and their subsequent use as fracturing fluids.
摘要翻译： 一种用于压裂围绕气体或油井的地下地层的方法，其中包括在液压下用含有约0.1至约75％的溶解在非极性有机液体和极性助溶剂的溶剂体系中的互聚物络合物的流体注入所述地下地层 （根据需要），所述聚合物复合物包括磺化聚合物和含胺聚合物的相互作用产物，其中磺化聚合物的磺酸盐含量为约4meq。 每100克聚合物至约200meq。 每100克聚合物，并且含胺聚合物的碱性氮含量为约4meq。 每100克聚合物至约500meq。 每100克聚合物，并通过向这种聚合物络合物溶液加入极性助溶剂，改变其在很宽的范围内的流变性能，并随后用作压裂液。
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公开(公告)号：US4575530A
公开(公告)日：1986-03-11
申请号：US747253
申请日：1985-06-21
IPC分类号： C08F8/44 , C10M151/02 , C08L39/00
CPC分类号： C10M151/02 , C08F8/44 , C10M2205/04 , C10M2217/028 , C10M2221/02
摘要： A water insoluble and oil soluble polymeric additive in combination with a hydrocarbon liquid, said polymeric additive being dissolved in said hydrocarbon liquid at a concentration level of about 0.001 to about 10 wt. %, said polymeric additive comprising a polyampholyte having the formula: ##STR1## wherein x is about 40 to about 98 mole %, y is about 1 to about 50 mole %, and z is about 1 to about 50 mole %, wherein y and z are less than 60 mole %, and M is an amine or a metal cation selected from the group consisting of aluminum, iron, lead, Groups IA, IIA, IB and IIB of the Periodic Table of Elements.
摘要翻译： 与烃液体组合的水不溶性和油溶性聚合物添加剂，所述聚合物添加剂以约0.001至约10重量％的浓度溶解在所述烃液体中。 ％，所述聚合物添加剂包含具有下式的聚阴离子：其中x为约40至约98摩尔％，y为约1至约50摩尔％，z为约1至约50摩尔％，其中y和 z小于60摩尔％，M是选自元素周期表的铝，铁，铅，IA，IIA，IB和IIB族的胺或金属阳离子。
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44.发明授权Low and high temperature drilling fluids based on sulfonated terpolymer ionomers 失效基于磺化三元共聚物离聚物的低温高温钻井液
公开(公告)号：US4537688A
公开(公告)日：1985-08-27
申请号：US547906
申请日：1983-11-02
CPC分类号： C09K8/32 , Y10S507/91
摘要： The present invention relates to sulfonated thermoplastic terpolymers which are terpolymers of t-butyl styrene, styrene and sodium styrene sulfonate wherein these sulfonated terpolymers function as viscosification agents when added to oil-based drilling muds which are the fluids used to maintain pressure, cool drill bits and lift cuttings from the holes in the drilling operation for oil and gas wells. The sulfonated thermoplastic terpolymer of the latex have about 5 to 100 meg. of sulfonate groups per 100 grams of the sulfonated thermoplastic terpolymer, wherein the sulfonated groups are neutralized with a metallic cation or an amine or ammonium counterion. A polar cosolvent can optionally be added to the mixture of oil drilling mud and sulfonated thermoplastic polymer, wherein the polar cosolvent increases the solubility of the sulfonated thermoplastic terpolymer in the oil drilling mud by decreasing the strong ionic interactions between the sulfonate groups of the sulfonated polymer.The drilling muds formed from these latices of the sulfonated thermoplastic terpolymers exhibits markedly improved low and high temperature rheological properties as compared to drilling muds formed from sulfonated thermoplasitc copolymers.
摘要翻译： 本发明涉及作为叔丁基苯乙烯，苯乙烯和苯乙烯磺酸钠的三元共聚物的磺化热塑性三元共聚物，其中当将这些磺化三元共聚物加入到用作维持压力的流体的油基钻井泥浆中时，其作为增粘剂起作用， 并在石油和天然气井的钻井作业中从孔中提起切屑。 乳液的磺化热塑性三元共聚物具有约5至100mcg。 每100克磺化热塑性三元共聚物的磺酸盐基团，其中磺化基团被金属阳离子或胺或铵抗衡离子中和。 可以任选地将极性助溶剂加入到油钻泥浆和磺化热塑性聚合物的混合物中，其中极性助溶剂通过降低磺化聚合物的磺酸盐基团之间的强离子相互作用而增加磺化热塑性三元共聚物在石油钻井泥浆中的溶解度 。 与磺化热塑性共聚物形成的钻井泥浆相比，磺化热塑性三元共聚物的这些胶乳形成的钻井泥浆显示出显着改善的低温和高温流变性能。
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公开(公告)号：US4489180A
公开(公告)日：1984-12-18
申请号：US560515
申请日：1983-12-12
CPC分类号： C08J3/03 , B63B1/38 , C09K3/00 , C09K8/035 , C09K8/588 , C08J2300/10 , C10M2201/02 , C10M2217/024 , C10M2217/06 , C10M2221/02 , C10N2240/06 , C10N2240/08 , C10N2250/02 , Y02T70/122 , Y10S260/31 , Y10S525/919
摘要： The present invention discloses a class of water soluble complex polymers of relatively low molecular weight, which have been found to be improved drag reducing agents. These complex polymers are a mixture of a cationic copolymer having a water soluble polymer backbone and an anionic copolymer having a water soluble polymer backbone. The solutions of these complex polymers are improved drag reducing agents for aqueous systems at low concentrations (i.e., 10 to 500 ppm) relative to individual solutions of the copolymers which make upon the polymer complex.
摘要翻译： 本发明公开了一类相对低分子量的水溶性复合聚合物，已被发现是改进的减阻剂。 这些复合聚合物是具有水溶性聚合物主链和具有水溶性聚合物主链的阴离子共聚物的阳离子共聚物的混合物。 这些复合聚合物的溶液相对于在聚合物复合物上形成的共聚物的各个溶液，在低浓度（即10至500ppm）的水性体系中是改进的减阻剂。
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46.发明授权Intramolecular polymeric complexes-viscosifiers for acid, base and salt (aqueous) solutions 失效分子内聚合复合物 - 用于酸，碱和盐（水溶液）的增粘剂
公开(公告)号：US4461884A
公开(公告)日：1984-07-24
申请号：US478657
申请日：1983-03-25
IPC分类号： C08F12/00 , C08F20/00 , C08F20/52 , C08F212/00 , C08F212/14 , C08F220/00 , C08F220/56 , C08F220/60 , C09K3/00 , C09K8/24 , C08F30/04 , C08F130/04 , C08F230/04
CPC分类号： C08F220/56 , C09K8/24
摘要： The present invention relates to improved viscosification agents for a variety of aqueous solutions which comprise a family of intramolecular polymeric complexes (i.e., polyampholytes) which are terpolymers of acrylamide/metal styrene sulfonate/methacrylamidopropyltrimethylammonium chloride (MAPTAC).The metal styrene sulfonate is an anionic monomer, while MAPTAC is cationically charged. These acrylamide-based polyampholytes have approximately 1 to about 50 mol % of the anionic monomer and approximately 1 to about 50 mole % of the cationic moiety present within the macromolecular structure. These groups are not necessarily present in an equimolar charge ratio. The excess undissociated charge allows for facile dispensability or solubility of the polyampholytes into fresh water.
摘要翻译： 本发明涉及用于各种水溶液的改性增稠剂，其包含作为丙烯酰胺/金属苯乙烯磺酸盐/甲基丙烯酰胺基丙基三甲基氯化铵（MAPTAC）的三元共聚物的分子内聚合物复合物（即聚阴离子）家族。 金属苯乙烯磺酸盐是阴离子单体，而MAPTAC是阳离子充电的。 这些基于丙烯酰胺的聚阴离子聚合物具有约1至约50mol％的阴离子单体和约1至约50mol％的存在于大分子结构内的阳离子部分。 这些基团不一定以等摩尔电荷比存在。 过量的未解离的电荷使得聚氨基甲酸酯易于分配或溶解在淡水中。
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公开(公告)号：US4460758A
公开(公告)日：1984-07-17
申请号：US547910
申请日：1983-11-02
IPC分类号： C08F220/56 , C08F20/00
CPC分类号： C08F220/56 , Y10S507/925 , Y10T137/0391
摘要： The present invention relates to improved drag reduction agents for aqueous solutions which comprises a polymeric complex which is a terpolymer of acrylamide/metal styrene sulfonate/methacrylamidopropyltrimethyl ammonium chloride.The metal styrene sulfonate is an anionic monomer, while MAPTAC is cationically charged. These acrylamide-based polyampholytes have approximately 1 to about 50 mole % of the anionic monomer and approximately 1 to about 50 mole % of the cationic moiety present within the macromolecular structure. These groups are not necessarily present in an equimolar charge ratio. The excess undissociated charge allows for facile dispensability or solubility of the polyampholytes into fresh water.
摘要翻译： 本发明涉及用于水溶液的改进的减阻剂，其包含聚合物络合物，其是丙烯酰胺/金属苯乙烯磺酸盐/甲基丙烯酰胺丙基三甲基氯化铵的三元共聚物。 金属苯乙烯磺酸盐是阴离子单体，而MAPTAC是阳离子充电的。 这些基于丙烯酰胺的聚阴离子聚合物具有约1至约50摩尔％的阴离子单体和约1至约50摩尔％的存在于大分子结构内的阳离子部分。 这些基团不一定以等摩尔电荷比存在。 过量的未解离的电荷使得聚氨基甲酸酯易于分配或溶解在淡水中。
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公开(公告)号：US4448926A
公开(公告)日：1984-05-15
申请号：US416926
申请日：1982-09-13
CPC分类号： C09K8/82 , C08J3/05 , C10L7/02 , C10M119/00 , C08J2353/00 , Y10S524/916
摘要： The present invention relates to the gelation or viscosification of hydrocarbon fluids, wherein a polymer having the structure xB-[AB].sub.n -yA wherein the A block is hydrophobic and the B block is hydrophilic, n is an integer .gtoreq.1, x and y are 0 to 1 and y is 1 when n is 1, is mixed with an aqueous phase at a critical concentration level of about 0.001 to about 5.0 grams of polymer per 100 ml. of the aqueous phase, more preferably about 0.01 to about 3.0, and most preferably about 0.01 to about 1.0, thereby obtaining a turbid suspension of the polymer in the aqueous phase; adding with stirring about 0.1 to about 15.0 wt. % of a cosolvent to the turbid suspension, more preferably about 2.0 to about 15.0, and most preferably about 5.0 to about 15.0 to form an opalescent solution; stirring the opalescent solution for a sufficient period of time to ensure the formation of a uniform polymeric solution; adding the polymeric solution to a hydrocarbon liquid; and stirring for a sufficient period of time the mixture of polymeric solution and hydrocarbon liquid until phase separation occurs, wherein the hydrocarbon layer is a cloudy viscous pseudo-emulsion and the aqueous phase is clear and nonviscous.
摘要翻译： 本发明涉及烃流体的凝胶化或增稠，其中具有xB- [AB] n-yA结构的聚合物，其中A嵌段是疏水性的，B嵌段是亲水性的，n是整数> / = 1，x 当n为1时，y为0至1，y为1，与水相以每100毫升约0.001至约5.0克聚合物的临界浓度水平混合。 的水相，更优选约0.01至约3.0，最优选约0.01至约1.0，从而获得聚合物在水相中的混浊悬浮液; 向混浊悬浮液中搅拌约0.1至约15.0重量％的助溶剂，更优选约2.0至约15.0，最优选约5.0至约15.0，以形成乳白色溶液; 将乳白色溶液搅拌足够的时间以确保形成均匀的聚合物溶液; 将聚合物溶液加入到烃液体中; 并搅拌足够的时间，聚合溶液和烃液体的混合物直到发生相分离，其中烃层是浑浊的粘性假乳液，水相是透明和非粘性的。
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49.发明授权Interfacial viscosification of salt water systems utilizing sulfonated ionomers 失效使用磺化离聚物的盐水系统的界面粘度
公开(公告)号：US4427812A
公开(公告)日：1984-01-24
申请号：US374251
申请日：1982-05-03
CPC分类号： C08J3/07 , B01J13/0052 , C08J2357/06 , Y10S260/31
摘要： The present invention relates to a process for the gelation (i.e. thickening) of salt water which includes the steps of forming a solvent system of an organic liquid or oil and a polar cosolvent, the polar cosolvent being less than about 15 weight percent of the solvent system, a viscosity of the solvent system being less than about 100 cps; dissolving a nonionic surfactant and water insoluble, neutralized or unneutralized sulfonated polymer in the solvent system to form a solution, a concentration of the neutralized, or unneutralized sulfonated polymer in the solution being about 0.01 to about 0.5 weight percent, the concentration of the nonionic surfactant in the solvent system being about 0.0001 to about 1.0 weight percent, a viscosity of the solution being less than about 2,000 cps; and admixing or contacting said solution with about 5 to about 500 volume precent of salt water, the salt water being immiscible with the organic liquid and the polar cosolvent, nonionic surfactant and the water insoluble, neutralized or unneutralized sulfonated polymer transferring from the organic liquid to the salt water phase, thereby causing the salt water phase to gel.
摘要翻译： 本发明涉及一种盐水凝胶化（即增稠）的方法，其包括形成有机液体或油和极性助溶剂的溶剂体系的步骤，极性助溶剂小于溶剂的约15重量％ 系统，溶剂系统的粘度小于约100cps; 将非离子表面活性剂和水不溶性，中和或未中和的磺化聚合物溶解在溶剂体系中以形成溶液，溶液中的中和或未中和的磺化聚合物的浓度为约0.01至约0.5重量％，非离子表面活性剂 在溶剂体系中为约0.0001至约1.0重量％，溶液的粘度小于约2,000cps; 并且将所述溶液与约5至约500体积的盐水混合或接触，所述盐水与有机液体和极性助溶剂，非离子表面活性剂和水不溶性，中和或未中和磺化聚合物不混溶，从有机液体转移到 盐水相，从而使盐水相凝胶化。
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公开(公告)号：US4425455A
公开(公告)日：1984-01-10
申请号：US416945
申请日：1982-09-13
CPC分类号： C08L25/18 , C09K8/36 , Y10S507/91
摘要： The present invention relates to powdered sulfonated thermoplastic polymers which function as viscosification agents when added to oil-based drilling muds which are the fluids used to maintain pressure, cool drill bits and lift cuttings from the holes in the drilling operation for oil and gas wells. The powdered sulfonated thermoplastic polymer has about 5 to about 100 meq. of sulfonate groups per 100 grams of the sulfonated thermoplastic polymer, wherein the sulfonated groups are neutralized with a metallic cation or an amine or ammonium counterion. The powdered sulfonated thermoplastic polymers have a particle size range of 0.25 .mu.m to 2.5 .mu.m and are prepared by spray drying an emulsion of the sulfonated thermoplastic polymer which has been prepared by a free radical copolymerization process. A polar cosolvent can optionally be added to the mixture of oil drilling mud and sulfonated polymer, wherein the polar cosolvent increases the solubility of the sulfonated polymer in the oil drilling mud by decreasing the strong ionic interactions between the sulfonate groups of the sulfonated polymer.
摘要翻译： 本发明涉及粉末状磺化热塑性聚合物，当添加到油基钻井泥浆中时，其作为增粘剂，其是用于在油气井的钻井操作中从孔中保持压力的液体，冷钻头和提升切屑。 粉状磺化热塑性聚合物具有约5至约100meq。 的磺酸盐基团/ 100克磺化热塑性聚合物，其中磺化基团被金属阳离子或胺或铵抗衡离子中和。 粉状磺化热塑性聚合物的粒度范围为0.25μm至2.5μm，并通过喷雾干燥已经通过自由基共聚方法制备的磺化热塑性聚合物的乳液制备。 可以任选地将极性助溶剂加入到石油钻井泥浆和磺化聚合物的混合物中，其中极性助溶剂通过降低磺化聚合物的磺酸盐基团之间的强离子相互作用而增加磺化聚合物在石油钻井泥浆中的溶解度。
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