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1.发明授权Low and high temperature drilling fluids based on sulfonated terpolymer ionomers 失效基于磺化三元共聚物离聚物的低温高温钻井液
公开(公告)号：US4537688A
公开(公告)日：1985-08-27
申请号：US547906
申请日：1983-11-02
CPC分类号： C09K8/32 , Y10S507/91
摘要： The present invention relates to sulfonated thermoplastic terpolymers which are terpolymers of t-butyl styrene, styrene and sodium styrene sulfonate wherein these sulfonated terpolymers function as viscosification agents when added to oil-based drilling muds which are the fluids used to maintain pressure, cool drill bits and lift cuttings from the holes in the drilling operation for oil and gas wells. The sulfonated thermoplastic terpolymer of the latex have about 5 to 100 meg. of sulfonate groups per 100 grams of the sulfonated thermoplastic terpolymer, wherein the sulfonated groups are neutralized with a metallic cation or an amine or ammonium counterion. A polar cosolvent can optionally be added to the mixture of oil drilling mud and sulfonated thermoplastic polymer, wherein the polar cosolvent increases the solubility of the sulfonated thermoplastic terpolymer in the oil drilling mud by decreasing the strong ionic interactions between the sulfonate groups of the sulfonated polymer.The drilling muds formed from these latices of the sulfonated thermoplastic terpolymers exhibits markedly improved low and high temperature rheological properties as compared to drilling muds formed from sulfonated thermoplasitc copolymers.
摘要翻译： 本发明涉及作为叔丁基苯乙烯，苯乙烯和苯乙烯磺酸钠的三元共聚物的磺化热塑性三元共聚物，其中当将这些磺化三元共聚物加入到用作维持压力的流体的油基钻井泥浆中时，其作为增粘剂起作用， 并在石油和天然气井的钻井作业中从孔中提起切屑。 乳液的磺化热塑性三元共聚物具有约5至100mcg。 每100克磺化热塑性三元共聚物的磺酸盐基团，其中磺化基团被金属阳离子或胺或铵抗衡离子中和。 可以任选地将极性助溶剂加入到油钻泥浆和磺化热塑性聚合物的混合物中，其中极性助溶剂通过降低磺化聚合物的磺酸盐基团之间的强离子相互作用而增加磺化热塑性三元共聚物在石油钻井泥浆中的溶解度 。 与磺化热塑性共聚物形成的钻井泥浆相比，磺化热塑性三元共聚物的这些胶乳形成的钻井泥浆显示出显着改善的低温和高温流变性能。
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2.发明授权Polyampholytes - high temperature viscosifiers for high ionic strength drilling fluids 失效聚阴离子 - 高离子强度钻井液的高温增粘剂
公开(公告)号：US4637882A
公开(公告)日：1987-01-20
申请号：US562163
申请日：1983-12-16
IPC分类号： C08F226/10 , C09K8/24 , C09K7/00
CPC分类号： C09K8/24 , C08F226/10
摘要： A new family of terpolymers based on V-vinyl-2-pyrrolidone/sodium styrene sulfonate/methacrylamidopropyltrimethylammonium chloride has been found to be an improved viscosity control additive for water-based drilling muds. The resultant muds display good viscosity characteristics, thermal stability and gel strength when formulated from the terpolymer intramolecular complex having the appropriate polymer concentration and salt level.
摘要翻译： 已经发现，一种新的基于N-乙烯基-2-吡咯烷酮/苯乙烯磺酸钠/甲基丙烯酰胺丙基三甲基氯化铵的三元共聚物是用于水基钻井泥浆的改进的粘度控制添加剂。 当由具有适当聚合物浓度和盐水平的三元共聚物分子内复合物配制时，所得泥浆显示出良好的粘度特性，热稳定性和凝胶强度。
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3.发明授权Controlled hydraulic fracturing via nonaqueous solutions containing low charge density polyampholytes 失效通过含有低电荷密度聚阴离子的非水溶液控制水力压裂
公开(公告)号：US4739834A
公开(公告)日：1988-04-26
申请号：US521
申请日：1987-01-05
CPC分类号： C09K8/64 , Y10S507/922
摘要： A process for fracturing a subterranean formation surrounding a gas or oil well which comprises:(a) injecting into said subterranean formation under hydraulic pressure a fluid comprising a solution of terpolymer dissolved in a solvent system, said solvent system comprising an organic liquid and a polar cosolvent, said polar cosolvent being less than about 15 weight percent of said solvent system, said terpolymer comprising a water-insoluble, oil-soluble terpolymer dissolved in said solvent system, the concentration of said terpolymer in said solution being about 0.2 to about 10 weight percent and the viscosity of said solution being less than about 2,000 cps, said terpolymer having the formula: ##STR1## wherein R.sub.1 =C.sub.6 H.sub.5, C.sub.6 H.sub.4 --CH.sub.3, C.sub.6 H.sub.4 --(CH.sub.3).sub.3, Cn H.sub.2 NH; wherein n=1-30; wherein x is about 50 to about 98 mole percent; y is about 1 to about 50 mole percent; z is about 1 to about 50 mole percent; wherein y and z are less than 60 mole percent; and M is an amine or a metal cation selected from the group consisting of antimony, tin, lead, Groups IA, IIA, IB and IIB of the Periodic Table of Elements; and(b) adding water to said solution of said polymer, said polar cosolvent transferring from said organic liquid to said water, thereby causing said organic liquid to gel within the fractures of said subterranean formation.
摘要翻译： 一种用于压裂围绕气体或油井的地层的方法，其包括：（a）在液压下将包含溶解在溶剂体系中的三元共聚物溶液的流体注入所述地层中，所述溶剂体系包含有机液体和极性 共溶剂，所述极性助溶剂小于所述溶剂体系的约15重量％，所述三元共聚物包含溶解在所述溶剂体系中的水不溶性油溶性三元共聚物，所述三元共聚物在所述溶液中的浓度为约0.2至约10重量％ 所述三元共聚物具有下式：其中R1 = C6H5，C6H4-CH3，C6H4-（CH3）3，CnH2NH; 其中n = 1-30; 其中x为约50至约98摩尔％; y为约1至约50摩尔％; z为约1至约50摩尔％; 其中y和z小于60摩尔％; M是选自元素周期表的锑，锡，铅，IA，IIA，IB和IIB族的胺或金属阳离子; 和（b）向所述聚合物的所述溶液中加入水，所述极性助溶剂从所述有机液体转移到所述水中，从而使所述有机液体在所述地层的裂缝内凝胶化。
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公开(公告)号：US4738997A
公开(公告)日：1988-04-19
申请号：US807674
申请日：1985-12-11
IPC分类号： C08L95/00
CPC分类号： C08L95/00
摘要： A bitumen-containing composition which comprises;(a) bitumen;(b) about 0.5 to about 30 parts by weight of a polymer complex per 100 parts by weight of the bitumen; and(c) about 0 to about 100 parts by weight of a filler per 100 parts by weight of the bitumen.
摘要翻译： 含有沥青的组合物，其包含： （a）沥青; （b）每100重量份沥青约0.5至约30重量份的聚合物复合物; 和（c）每100重量份沥青约0至约100重量份的填料。
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公开(公告)号：US4683952A
公开(公告)日：1987-08-04
申请号：US903450
申请日：1986-09-04
CPC分类号： C09K8/46 , C04B24/2688 , C09K8/42
摘要： A cement fluid-loss composition and its use in a well cementing process are disclosed. The cement fluid loss composition comprises an aqueous slurry of about 35 to about 90 weight percent of water based on weight percent of dry cement; and about 0.1 to about 2 weight percent of a terpolymer based on weight percent of dry cement, said terpolymer having the formula: ##STR1## wherein x is about 40 to about 98 mole %, more preferably about 50 to about 95 mole %, and most preferably about 80 to about 90, y is about 1 to about 50 mole %, more preferably about 2 to about 20 mole %, and most preferably about 5 to about 10 mole %, and z is about 1 to about 50 mole %, more preferably about 2 to about 20, and most preferably about 5 to about 10, y is equal to z, B is about 1 to about 50 mole %, more preferably about 2 to about 20 mole %, and most preferably about 5 to about 10 mole %, wherein B, y and z are less than 60 mole %.
摘要翻译： 公开了一种水泥流体损失组合物及其在井固定方法中的应用。 水泥流体损失组合物包含基于干燥水泥重量百分数的约35至约90重量％的水的含水浆料; 和约0.1至约2重量％的基于重量百分比的干燥水泥的三元共聚物，所述三元共聚物具有下式：其中x为约40至约98摩尔％，更优选约50至约95摩尔％，以及 最优选约80至约90，y为约1至约50摩尔％，更优选约2至约20摩尔％，最优选约5至约10摩尔％，z为约1至约50摩尔％ 更优选约2至约20，最优选约5至约10，y等于z，B为约1至约50摩尔％，更优选约2至约20摩尔％，最优选约5至约20摩尔％ 10摩尔％，其中B，y和z小于60摩尔％。
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公开(公告)号：US4656204A
公开(公告)日：1987-04-07
申请号：US547929
申请日：1983-11-02
CPC分类号： B05D5/08 , C09K3/00 , C10L1/146 , C10L1/2368 , C10L1/2462
摘要： The present invention relates to an improved process for the use of drag reduction agents, which are polymer complexes of a cationic polymer and an anionic polymer.
摘要翻译： 本发明涉及使用作为阳离子聚合物和阴离子聚合物的聚合物配合物的减阻剂的改进方法。
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7.发明授权High charge density polymeric complexes - viscosifiers for acid, base and salt (aqueous) solutions 失效高电荷密度聚合复合物 - 酸，碱和盐（水溶液）的增粘剂
公开(公告)号：US4608425A
公开(公告)日：1986-08-26
申请号：US747427
申请日：1985-06-21
IPC分类号： C08F212/14 , C08F220/60 , C08F20/60
CPC分类号： C08F212/14 , C08F220/60
摘要： The present invention relates to improved viscosification agents for a variety of aqueous solutions which comprise a family of intramolecular polymeric complexes (i.e., polyampholytes) which are copolymers of metal styrene sulfonate/methacrylamidoproplytrimethylammonium chloride (MAPTAC). The metal styrene sulfonate is an anionic monomer, while MAPTAC is cationically charged. These polyampholytes have approximately 1 to about 99 mole % of the anionic monomer and approximately 1 to about 99 mole % of the cationic moiety present within the macromolecular structure. These groups are not necessarily present in an equimolar charge ratio. The excess undissociated charge allows for facile dispensability or solubility of the polyampholytes into low ionic strength aqueous solutions.
摘要翻译： 本发明涉及用于各种水溶液的改性增稠剂，其包含金属苯乙烯磺酸盐/甲基丙烯酰胺丙基三甲基氯化铵（MAPTAC）的共聚物的分子内聚合物复合物（即聚阴离子）家族。 金属苯乙烯磺酸盐是阴离子单体，而MAPTAC是阳离子充电的。 这些多聚电解质具有约1至约99摩尔％的阴离子单体和约1至约99摩尔％的存在于大分子结构内的阳离子部分。 这些基团不一定以等摩尔电荷比存在。 过量的未解离的电荷使得多聚电解质易于分配或溶解于低离子强度的水溶液中。
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8.发明授权
公开(公告)号：US4579669A
公开(公告)日：1986-04-01
申请号：US600976
申请日：1984-04-16
CPC分类号： C09K8/36 , Y10S507/91
摘要： A new class of viscosification agents based on water insoluble and oil insoluble neutralized sulfonated thermoplastic resins is described for oil-based drilling muds. The resultant muds display good viscosity characteristics and good stability when formulated from water insoluble and oil insoluble neutralized sulfonated thermoplastic polymers having an appropriate sulfonate level and cation type.
摘要翻译： 描述了一类新的基于水不溶性和油不溶性中和磺化热塑性树脂的增稠剂，用于油基钻井泥浆。 当由具有适当磺酸盐水平和阳离子类型的水不溶性和油不溶性中和的磺化热塑性聚合物配制时，所得泥浆表现出良好的粘度特性和良好的稳定性。
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9.发明授权Intramolecular polymer complexes - viscosifiers for high ionic strength drilling fluids 失效分子内聚合物复合物 - 用于高离子强度钻井液的增粘剂
公开(公告)号：US4540496A
公开(公告)日：1985-09-10
申请号：US478683
申请日：1983-03-25
IPC分类号： C09K8/04 , C08F20/52 , C08F220/56 , C08F220/60 , C09K8/12 , C09K8/24 , C09K7/02
CPC分类号： C09K8/12 , C08F220/56 , C09K8/24
摘要： A new family of terpolymers based on acrylamide/sodium styrene sulfonate/methacrylamidopropyltrimethylammonium chloride has been found to be an improved viscosity control additive for water-based drilling muds. The resultant muds display good viscosity characteristics, thermal stability and gel strength when formulated from the terpolymer intramolecular complex having the appropriate polymer concentration and salt level.
摘要翻译： 已经发现，一种新的基于丙烯酰胺/苯乙烯磺酸钠/甲基丙烯酰胺基丙基三甲基氯化铵的三元共聚物是用于水基钻井泥浆的改进的粘度控制添加剂。 当由具有适当聚合物浓度和盐水平的三元共聚物分子内复合物配制时，所得泥浆显示出良好的粘度特性，热稳定性和凝胶强度。
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10.发明授权Controlled gelation on nonaqueous solutions containing low charge density polyampholytes 失效含有低电荷密度聚阴离子的非水溶液的控制凝胶化
公开(公告)号：US4522960A
公开(公告)日：1985-06-11
申请号：US638218
申请日：1984-08-06
CPC分类号： C08J3/09
摘要： A process for gelling a fluid having a viscosity of at least about 50 cps which includes the steps of: forming a solvent system of the nonpolar organic liquid and a polar cosolvent, the polar cosolvent being less than about 15 weight percent of the solvent system and a viscosity of the solvent system being less than about 100 cps; dissolving a water insoluble, oil soluble terpolymer in the solvent system to form a solution, a concentration of the terpolymer in the solution being about 0.2 to about 10 weight percent and a viscosity of the solution being less than about 2000 cps, the terpolymer having the formula: ##STR1## wherein x is about 40 to about 98 mole %, y is about 1 to about 50 mole %, and z is about 1 to about 50 mole %, wherein y and z are less than 60 mole %, and M is an amine or a metal cation selected from the group consisting of antimony tin, lead, Groups IA, IIA, IB and IIB of the Periodic Table of Elements; and adding about 5 to about 500 volume percent water to the solution of the terpolymer, said water being immiscible with the solution of the terpolymer, the polar cosolvent transferring from the nonpolar organic liquid to the water thereby causing the viscosity of the organic liquid to increase to at least 5000 cps.
摘要翻译： 一种胶粘具有至少约50cps的粘度的流体的方法，其包括以下步骤：形成非极性有机液体和极性助溶剂的溶剂体系，极性助溶剂小于溶剂体系的约15重量％ 溶剂系统的粘度小于约100cps; 将水不溶性油溶性三元共聚物溶解在溶剂体系中以形成溶液，溶液中三元共聚物的浓度为约0.2至约10重量％，溶液的粘度小于约2000cps，三元共聚物具有 式：其中x为约40至约98摩尔％，y为约1至约50摩尔％，z为约1至约50摩尔％，其中y和z为小于60摩尔％，M为 是选自元素周期表的锑锡，铅，IA，IIA，IB和IIB族的胺或金属阳离子; 并向三元共聚物的溶液中加入约5至约500体积％的水，所述水与三元共聚物溶液不混溶，极性助溶剂从非极性有机液体转移到水中，从而导致有机液体的粘度增加 至少5000厘泊。
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