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41.发明授权公开(公告)号：US06849343B2
公开(公告)日：2005-02-01
申请号：US10413091
申请日：2003-04-14
申请人： Roger W. Phillips , Charlotte R. LeGallee , Paul T. Kohlmann , Vladimir Raksha , Alberto Argoitia
发明人： Roger W. Phillips , Charlotte R. LeGallee , Paul T. Kohlmann , Vladimir Raksha , Alberto Argoitia
CPC分类号： G02B5/285 , C01P2006/60 , C01P2006/62 , C01P2006/63 , C01P2006/64 , C01P2006/65 , C01P2006/66 , C09C1/0015 , C09C1/0021 , C09C1/0066 , C09C1/0078 , C09C2200/1054 , C09C2200/1058 , C09C2200/301 , C09C2220/106 , C09C2220/20 , C09D5/36 , Y10T428/12028 , Y10T428/12056 , Y10T428/12181 , Y10T428/1259 , Y10T428/12618 , Y10T428/24942 , Y10T428/265 , Y10T428/2982 , Y10T428/2991 , Y10T428/2993 , Y10T428/2996
摘要： Interference pigment flakes and foils are provided which have color shifting properties. The pigment flakes can have a symmetrical coating structure on opposing sides of a reflector layer, can have an asymmetrical coating structure with all of the layers on one side of the reflector layer, or can be formed with encapsulating coatings around a core reflector layer. The coating structure of the flakes and foils includes a reflector layer, a dielectric layer on the reflector layer, and a titanium-containing absorber layer on the dielectric layer. The pigment flakes and foils exhibit a discrete color shift so as to have a first color at a first angle of incident light or viewing and a second color different from the first color at a second angle of incident light or viewing. The pigment flakes can be interspersed into liquid media such as paints or inks to produce colorant compositions for subsequent application to objects or papers. The foils can be laminated to various objects or can be formed on a carrier substrate.
摘要翻译： 提供具有颜色偏移特性的干涉颜料薄片和薄片。 颜料薄片可以在反射器层的相对侧上具有对称的涂层结构，可以具有不对称涂层结构，其中反射层的一侧上的所有层都可以，或者可以围绕芯反射器层形成封装涂层。 薄片和薄片的涂层结构包括反射层，反射层上的电介质层和介电层上的含钛吸收层。 颜料薄片和薄片呈现离散的颜色偏移，以便在入射光或观察的第一角度具有第一颜色，并且在入射光或观看的第二角度具有不同于第一颜色的第二颜色。 颜料薄片可以散布到液体介质如油漆或油墨中，以产生用于随后应用于物体或纸张的着色剂组合物。 箔可以层压到各种物体上，或者可以在载体基底上形成。
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公开(公告)号：US06699313B2
公开(公告)日：2004-03-02
申请号：US10401198
申请日：2003-03-27
IPC分类号： C09D1700
CPC分类号： C09C1/0051 , C01P2004/20 , C01P2004/84 , C09C1/0015 , C09C1/0024 , C09C1/0078 , C09C2200/1008 , C09C2200/1012 , C09C2200/1025 , C09C2200/1029 , C09C2200/1041 , C09C2200/1045 , C09C2200/1091 , C09C2200/1095 , C09C2200/301 , C09C2200/304 , C09D5/36 , Y10T428/2991 , Y10T428/2993 , Y10T428/2998
摘要： A flake-based pigment is provided having improved specular reflectance characteristics in the visible wavelength range. The flake-based pigment has a plurality of composite reflective flakes each formed of a support layer and a reflector layer on one or both opposing sides of the support layer. This flake structure exhibits a uniaxial compressive strength much greater than a corresponding uniaxial tensile strength. The structure of the flakes provides the benefits of rigidity and brittle fracture during manufacture and application processes, which ultimately provides favorable planar and specular reflectance characteristics to the pigment in the visible wavelength range. A variety of outer coating layers can be formed around the composite reflective flakes, such as various dielectric and/or absorber layers, to produce desired optical characteristics in the pigment.
摘要翻译： 提供了在可见光波长范围内具有改进的镜面反射特性的片状颜料。 片状颜料具有多个复合反射片，各自由支撑层和支撑层的一个或两个相对侧上的反射层形成。 该片状结构表现出比相应的单轴拉伸强度大得多的单轴抗压强度。 薄片的结构在制造和应用过程中提供刚性和脆性断裂的优点，其最终在可见波长范围内为颜料提供有利的平面和镜面反射特性。 可以在复合反射薄片周围形成各种外涂层，例如各种介电层和/或吸收层，以在颜料中产生所需的光学特性。
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43.发明授权公开(公告)号：US06569529B1
公开(公告)日：2003-05-27
申请号：US09685468
申请日：2000-10-10
申请人： Roger W. Phillips , Charlotte R. LeGallee , Paul T. Kohlmann , Vladimir Raksha , Alberto Argoitia
发明人： Roger W. Phillips , Charlotte R. LeGallee , Paul T. Kohlmann , Vladimir Raksha , Alberto Argoitia
IPC分类号： B32B516
CPC分类号： G02B5/285 , C01P2006/60 , C01P2006/62 , C01P2006/63 , C01P2006/64 , C01P2006/65 , C01P2006/66 , C09C1/0015 , C09C1/0021 , C09C1/0066 , C09C1/0078 , C09C2200/1054 , C09C2200/1058 , C09C2200/301 , C09C2220/106 , C09C2220/20 , C09D5/36 , Y10T428/12028 , Y10T428/12056 , Y10T428/12181 , Y10T428/1259 , Y10T428/12618 , Y10T428/24942 , Y10T428/265 , Y10T428/2982 , Y10T428/2991 , Y10T428/2993 , Y10T428/2996
摘要： Interference pigment flakes and foils are provided which have color shifting properties. The pigment flakes can have a symmetrical coating structure on opposing sides of a reflector layer, can have an asymmetrical coating structure with all of the layers on one side of the reflector layer, or can be formed with encapsulating coatings around a core reflector layer. The coating structure of the flakes and foils includes a reflector layer, a dielectric layer on the reflector layer, and a titanium-containing absorber layer on the dielectric layer. The pigment flakes and foils exhibit a discrete color shift so as to have a first color at a first angle of incident light or viewing and a second color different from the first color at a second angle of incident light or viewing. The pigment flakes can be interspersed into liquid media such as paints or inks to produce colorant compositions for subsequent application to objects or papers. The foils can be laminated to various objects or can be formed on a carrier substrate.
摘要翻译： 提供具有颜色偏移特性的干涉颜料薄片和薄片。 颜料薄片可以在反射器层的相对侧上具有对称的涂层结构，可以具有不对称的涂层结构，其中反射器层的一侧上的所有层都可以，或者可以围绕芯反射器层形成封装涂层。 薄片和薄片的涂层结构包括反射层，反射层上的电介质层和介电层上的含钛吸收层。 颜料薄片和薄片呈现离散的颜色偏移，以便在入射光或观察的第一角度具有第一颜色，并且在入射光或观看的第二角度具有不同于第一颜色的第二颜色。 颜料薄片可以散布到液体介质如油漆或油墨中，以产生用于随后应用于物体或纸张的着色剂组合物。 箔可以层压到各种物体上，或者可以在载体基底上形成。
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44.发明授权Flexible plastic substrate with anti-reflection coating having low reflective color and method 失效具有防反射涂层的柔性塑料基板具有低反射颜色和方法
公开(公告)号：US5939189A
公开(公告)日：1999-08-17
申请号：US438197
申请日：1995-05-09
IPC分类号： G02B1/11 , B05D5/06 , B05D7/02 , B32B7/02 , B32B7/06 , C08J7/06 , C23C14/08 , C23C14/56 , B32B17/00
CPC分类号： C23C14/562 , B32B7/06 , Y10T428/265 , Y10T428/2817 , Y10T428/2839 , Y10T428/2857 , Y10T428/31786
摘要： An optical article comprising a flexible plastic substrate having an index of refraction ranging from 1.55 to 1.71 and having first and second surfaces and an anti-reflection coating carried by the first surface. The anti-reflection coating consists of a high index material and a low index material in which the high index material has an index of refraction of 2.0 and greater to provide the index of refraction difference between the substrate and the high index material of 0.29 to 0.75. The low index material is formed of a material having an index of refraction of 1.38 or less to provide an index of refraction difference between the high index material to the low index material ranging from approximately 0.59 to 0.92.
摘要翻译： 一种光学制品，包括柔性塑料基材，其折射率范围为1.55至1.71，并具有第一和第二表面以及由第一表面承载的抗反射涂层。 抗反射涂层由高折射率材料和低折射率材料组成，其中高折射率材料的折射率为2.0及更大，以提供基底和高折射率材料之间的折射率差为0.29至0.75 。 低折射率材料由折射率为1.38或更小的材料形成，以提供高折射率材料与低折射率材料之间的约0.59至0.92的折射率差。
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公开(公告)号：US5783360A
公开(公告)日：1998-07-21
申请号：US781454
申请日：1997-01-10
申请人： Roger W. Phillips , Lauren R. Wendt
发明人： Roger W. Phillips , Lauren R. Wendt
CPC分类号： G11B7/2548 , G11B2007/25417 , G11B7/003 , G11B7/246 , G11B7/2535 , G11B7/2585 , Y10S430/146
摘要： Flexible optical medium comprising a flexible substrate having a surface. An imaging layer is carried by the surface and a protective overcoat of silicon dioxide is provided on the imaging layer to provide abrasion resistance for said imaging layer.
摘要翻译： 柔性光学介质包括具有表面的柔性基底。 成像层由表面承载，并且在成像层上提供二氧化硅的保护外涂层，以为所述成像层提供耐磨性。
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公开(公告)号：US5135812A
公开(公告)日：1992-08-04
申请号：US675799
申请日：1991-03-27
申请人： Roger W. Phillips , Thomas Mayer , Gary S. Ash
发明人： Roger W. Phillips , Thomas Mayer , Gary S. Ash
CPC分类号： C09C1/0051 , B05D1/286 , B05D5/06 , B41M3/00 , B41M3/14 , C03C17/00 , C09C1/0015 , C09C1/0078 , C09D11/50 , F24J2/485 , C01P2004/54 , C09C2200/1054 , C09C2200/24 , C09C2220/20 , Y02E10/40 , Y10S428/913 , Y10S428/916 , Y10T428/256 , Y10T428/257 , Y10T428/258 , Y10T428/259 , Y10T428/2991 , Y10T428/2993 , Y10T428/31507 , Y10T428/31786 , Y10T428/31797 , Y10T428/31855
摘要： Articles and methods for forming optically variable thin film flakes and replicated coatings having preselected optical properties. The articles generally comprise a flexible web of material and an optically variable thin film coating formed on one surface of the web. The optically variable coating is separated from the web to form optically variable thin film flakes. The flakes are disposed in ink and paint vehicles to provide optically variable inks, paints and the like.
摘要翻译： 用于形成具有预选光学性质的光学可变薄膜薄片和复制涂层的制品和方法。 制品通常包括形成在幅材的一个表面上的柔性材料幅材和可变光薄膜涂层。 将光学可变涂层与纤维网分离以形成光学可变的薄膜薄片。 将薄片放置在油墨和油漆车辆中以提供光学可变的油墨，油漆等。
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公开(公告)号：US4702963A
公开(公告)日：1987-10-27
申请号：US367382
申请日：1982-04-12
CPC分类号： C08J7/06 , Y10T428/1321 , Y10T428/1338 , Y10T428/1341 , Y10T428/31786
摘要： Flexible polymer packaging films having thin films of inorganic coatings deposited thereon to reduce the vapor permeability of the article. Inorganic thin film coatings comprising a composite of two materials are disclosed to confer both substantial transparency and retortability on the overall packaging film structure. The two material film composite involves either sequentially deposited films with the first thin film layer serving as an adhesion layer and the second thin film layer serving as a barrier layer. Alternatively, the two materials may be co-deposited to form a single thin film layer which provides sufficient adhesion to confer retortability on the overall film structure and also functions as relatively impermeable gas and vapor barrier for reducing the vapor transmission rate through the product. Various coated single film articles and dual film laminated articles are disclosed.
摘要翻译： 具有沉积在其上的无机涂层的薄膜的柔性聚合物包装膜以降低制品的透气性。 公开了包含两种材料的复合材料的无机薄膜涂层，以在整个包装膜结构上赋予基本的透明度和可蒸馏性。 两种材料膜复合物包括顺序沉积的膜，其中第一薄膜层用作粘合层，第二薄膜层用作阻挡层。 或者，可以共同沉积两种材料以形成单个薄膜层，其提供足够的粘合力以赋予整个膜结构上的蒸馏性能，并且还用作相对不可渗透的气体和蒸气阻挡层，以降低通过产品的蒸气透过率。 公开了各种涂布的单膜制品和双层层压制品。
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公开(公告)号：US07773284B2
公开(公告)日：2010-08-10
申请号：US12241331
申请日：2008-09-30
申请人： Eric W. Kurman , Roger W. Phillips
发明人： Eric W. Kurman , Roger W. Phillips
CPC分类号： G02F1/155 , E06B3/6722 , E06B9/24 , E06B2009/2464
摘要： One exemplary embodiment of an electrochromic device comprises a single cavity Fabry-Pérot filter in which the metal conductive layers forming the cavity are sandwiched by conductive dielectric layers. Another exemplary embodiment of an electrochromic device comprises a dual-cavity Fabry-Pérot filter.
摘要翻译： 电致变色器件的一个示例性实施例包括单腔法布里 - 珀罗滤波器，其中形成空腔的金属导电层被导电介电层夹在中间。 电致变色装置的另一示例性实施例包括双腔法布里 - 珀罗过滤器。
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公开(公告)号：US20100060987A1
公开(公告)日：2010-03-11
申请号：US12584339
申请日：2009-09-03
CPC分类号： G02B5/285 , B29D11/00605 , B41M3/14 , B42D15/00 , B42D25/324 , B42D25/36 , B42D25/373 , B42D25/378 , B42D25/425 , G02B5/286
摘要： An optical device exhibiting a color shift upon rotation is disclosed. The optical device has a textured surface having a relief structure finer than a human eye resolution but large enough not to exhibit diffraction effects. The textured surface is coated with an interference thin film that exhibits a color shift with tilt. A uniform color seen at one angle of rotation changes to another uniform color when the optical device is rotated in its own plane. A method of manufacturing of such an optical device, as well as the use of the optical device as an optical security and authentication element, is also disclosed.
摘要翻译： 公开了一种在旋转时呈现色移的光学装置。 光学装置具有纹理表面，其具有比人眼分辨率更细的浮雕结构，但是足够大以不显示衍射效应。 纹理化表面涂有表现出倾斜色移的干涉薄膜。 当光学装置在其自身的平面中旋转时，以一个旋转角度看到的均匀的颜色变为另一种均匀的颜色。 还公开了这种光学装置的制造方法以及光学装置作为光学安全和认证元件的使用。
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公开(公告)号：US20090323161A1
公开(公告)日：2009-12-31
申请号：US12165598
申请日：2008-06-30
IPC分类号： G02F1/153
CPC分类号： G02F1/1533 , G02F1/155 , G02F2001/1536 , G02F2001/1555 , G02F2201/07
摘要： One exemplary embodiment of an electrochromic device comprises a tantalum-nitride ion-blocking layer formed between a transparent conductive layer and an electrochromic layer. Another exemplary embodiment of an electrochromic device comprises a tantalum-nitride ion-blocking layer formed between a transparent conductive layer and a counter electrode. Yet another exemplary embodiment of an electrochromic device comprises a type-2 ion-blocking layer formed on a transparent conductive layer as an ion diffusion barrier overlayer. Still another exemplary embodiment of an electrochromic device comprises a transparent conductive layer formed from tantalum nitride.
摘要翻译： 电致变色器件的一个示例性实施例包括形成在透明导电层和电致变色层之间的氮化钽 - 氮化物离子阻挡层。 电致变色器件的另一示例性实施例包括在透明导电层和对电极之间形成的氮化钽 - 氮化物离子阻挡层。 电致变色器件的另一示例性实施例包括形成在作为离子扩散阻挡层的透明导电层上的2型离子阻挡层。 电致变色器件的另一示例性实施例包括由氮化钽形成的透明导电层。
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