摘要:
The invention relates to a method for drying and degassing polyolefins in which the polymerization product leaving a polymerization reactor is brought into contact with a degassing medium and simultaneously decompressed. The degassing medium employed according to the invention is the monomer to be polymerized, which, in particular, flows through a decompression tank in a circulation process and which is preferably also enriched with ethylene or other low-boiling olefins in an amount in the range from 0 to 100 mol %, based on the total amount of circulating gas. A polymerization in an amount of up to 10%, based on the total polymerization conversion, takes place in accordance with the invention inside the decompression tank.
摘要:
In a low-odor polyethylene blend made from a high-molecular-weight ethylene copolymer obtainable by polymerization in the presence of a Ziegler catalyst and from a low-molecular-weight ethylene homopolymer or ethylene copolymer obtainable by polymerization in the presence of a chromocene catalyst on an oxidic support, the Al content of the high-molecular-weight component is from 5 to 60 mg/kg, the Al content of the low-molecular-weight component is from 0 to 5 mg/kg and the Al content of the blend is from 1 to 55 mg/kg. Processes are described for preparing blends of this type. Their use is described for producing moldings, in particular hollow articles and pipes. Moldings, in particular hollow articles and pipes, are produced from low-odor polyethylene blends.
摘要:
In a fiber-optical sensor used for measuring the Doppler broadening of scattered laser light by the principle of quasi-elastic light scattering (QELS), the scattered light originating from particles in movement, the emergence surface (7) for the laser light at the end of a single-mode or multimode light guide (3) used as an immersion probe is inclined at an angle 0
摘要:
A transparent high density polyethylene (HDPE) sheet is disclosed. The sheet has a thickness greater than or equal to 0.05 mm and a bulk haze less than 2%. The HDPE resin is converted into a sheet by thermal processing and the sheet is then uniaxially oriented at a temperature above the melting point of the HDPE resin. The transparent HDPE sheet of the invention can be used for windows and plastic containers.
摘要:
Monomodal copolymers of ethylene and molding compositions comprising such copolymers, wherein the copolymers have a density determined according to DIN EN ISO 1183-1, variant A in the range from 0.938 to 0.944 g/cm3, a melt index MFR21 determined according to ISO 1133 at 190° C. under a load of 21.6 kg in the range from 12 to 17 g/10 min, a weight average molar mass Mw, in the range from 140 000 g/mol to 330 000 g/mol, a polydispersity Mw/Mn in the range from 9 to 17, and a content of comonomer side chains per 1000 carbon atoms C x equal to or above a value defined via equation (I) Cx=128.7−134.62×d′, wherein d′ is the numerical value of the density of the copolymer in g/cm3, the use of the copolymers for producing injection-molded articles, as well as injection-molded articles comprising the copolymers, and process for the preparation of such monomodal copolymers.
摘要翻译:乙烯的单共聚物和包含这种共聚物的模塑组合物,其中共聚物具有根据DIN EN ISO 1183-1,变体A在0.938至0.944g / cm 3范围内测定的密度,根据ISO 1133测定的熔体指数MFR 21 190℃,21.6kg,12-17g / 10min范围内的重均摩尔质量Mw,140,000g / mol〜330000g / mol,多分散性Mw / Mn 在9至17的范围内,每1000个碳原子的共聚单体侧链的含量C x等于或高于通过式(I)定义的值Cx = 128.7-134.62×d',其中d'是 共聚物的密度(g / cm 3),用于制备注射成型制品的共聚物的使用,以及包含共聚物的注模制品以及制备这种单峰共聚物的方法。
摘要:
Novel supported, titanized chromium catalysts for the homopolymerization of ethylene and the copolymerization of ethylene with α-olefins, a process for preparing them and to their use for the polymerization of olefins.
摘要:
Novel supported, titanized chromium catalysts for the homopolymerization of ethylene and the copolymerization of ethylene with α-olefins, a process for preparing them and to their use for the polymerization of olefins.
摘要:
The present invention relates to a semicrystalline propylene polymer composition prepared by polymerizing propylene, ethylene and/or C4-C18-1-alkenes, where at least 50 mol % of the monomer units present stem from the polymerization of propylene and at least 20% by weight of the propylene polymer composition is the result of a polymerization using metallocene catalysts, with a melting point TM of from 65 to 170° C., where the semicrystalline propylene polymer composition can be broken down into from 65 to 85% by weight of a principal component A, from 10 to 35% by weight of an ancillary component B and from 0 to 25% by weight of an ancillary component C, and where the proportions of components A, B and C are determined by carrying out TREF (temperature rising elution fractionation) in which that fraction of the propylene polymer composition which is soluble in xylene at (TM/2)+7.5° C. is firstly dissolved and separated off and then, as the temperature rises, at all of the higher temperatures 70° C., 75° C., 80° C., 85° C., 90° C., 94° C., 98° C., 102° C., 107° C., 112° C., 117° C., 122° C. and 125° C., the fractions soluble within the temperature range between this elution temperature and the preceding elution temperature are eluted, and the principal component A is formed by all of the fractions which are eluted at above (TM/2)+7.5° C. and have an average molar mass MN [sic] (number average)≧120,000 g/mol, the ancillary component B is formed by the fraction which is eluted at (TM/2)+7.5° C., and the ancillary component C is formed by all of the fractions which are eluted at above (TM/2)+7.5° C. and have an average molar mass Mn (number average)
摘要:
Random copolymers of propylene with other 1-alkenes having up to carbon atoms, whose content of comonomers is in the range from 0.7 to 1.4% by weight if the only comonomer present in the propylene copolymers is ethylene, or whose content of comonomers is in the range from 0.7 to 3.0% by weight if at least one C4–C10-1-alkene is present as comonomer, and whose cold-xylene-soluble fraction is from 1.0 to 2.5% by weight if ethylene is present as a comonomer in the propylene copolymers, or whose cold-xylene-soluble fraction is from 0.75 to 2.0% by weight if the only comonomers present are C4–C10-1-alkenes, and a process for preparing the random copolymers of propylene is described, as is their use for producing films, fibers or moldings, and also the films, fibers and moldings themselves and biaxially stretched films made from random propylene copolymers of this type and processes for their production.