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公开(公告)号：US07524999B2
公开(公告)日：2009-04-28
申请号：US11792644
申请日：2005-12-19
摘要： A process for the preparation of 1,1,1,3,3,3-hexafluoropropane is disclosed. The process involves (a) contacting at least one halopropane of the formula CF3CH2CHyX3-y (where each X is independently F, Cl or Br, and y is 3, 2, or 1) with Cl?2#191 in the presence of light or a free radical initiator to produce a mixture comprising CF3CH2CCIyX3-y; (b) contacting the CF3CH2CCIyX3-y produced in step (a) with HF, optionally in the presence of a fluorination catalyst, to produce a product mixture comprising CF3CH2CF3; and (c) recovering CF3CH2CF3 from the mixture produced in step (b).
摘要翻译： 公开了制备1,1,1,3,3,3-六氟丙烷的方法。 该方法包括（a）在光存在下，将Cl 3 CH 2 CHyX 3-y（其中每个X独立地为F，Cl或Br，y为2,3或2）的至少一种卤代丙烷与Cl 2 或自由基引发剂以产生包含CF 3 CH 2 CCl 3 X 3-y的混合物; （b）任选地在氟化催化剂存在下使步骤（a）中产生的CF 3 CH 2 CCl 3 X 3-y与HF接触，以产生包含CF 3 CH 2 CF 3的产物混合物; 和（c）从步骤（b）中制备的混合物中回收CF 3 CH 2 CF 3。
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42.发明授权Azeotrope compositions comprising 2,3,3,3-tetrafluoropropene and hydrogen fluoride and uses thereof 有权包含2,3,3,3-四氟丙烯和氟化氢的共沸组合物及其用途公开(公告)号：US07476771B2
公开(公告)日：2009-01-13
申请号：US11590454
申请日：2006-10-31
申请人： Ralph Newton Miller , Mario Joseph Nappa , Velliyur Nott Mallikarjuna Rao , Allen Capron Sievert
发明人： Ralph Newton Miller , Mario Joseph Nappa , Velliyur Nott Mallikarjuna Rao , Allen Capron Sievert
CPC分类号： C07C21/18 , C01B7/196 , C07C17/25 , C07C17/38 , C07C17/383 , C07C17/386
摘要： Disclosed herein are azeotrope or near-azeotrope compositions comprising 2,3,3,3-tetrafluoropropene (HFC-1234yf) and hydrogen fluoride (HF). These compositions are useful in processes to produce and purify HFC-1234yf. Additionally, disclosed herein are processes for the manufacture of HFC-1234yf.
摘要翻译： 本文公开了包含2,3,3,3-四氟丙烯（HFC-1234yf）和氟化氢（HF）的共沸物或近共沸组合物。 这些组合物可用于生产和纯化HFC-1234yf的方法。 此外，本文公开了制造HFC-1234yf的方法。
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43.发明授权1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone compositions comprising a hydrofluorocarbon and uses thereof 失效包含氢氟烃的1,1,1,2,2,4,5,5,5-九氟-4-（三氟甲基）-3-戊酮组合物及其用途公开(公告)号：US07314576B2
公开(公告)日：2008-01-01
申请号：US11437024
申请日：2006-05-19
IPC分类号： C09K5/04
CPC分类号： G01M3/047 , C07C19/08 , C07C49/167 , C09K5/045 , C09K2205/108 , C09K2205/112 , G01M3/20
摘要： Disclosed herein are refrigerant and heat transfer fluid compositions comprising 1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and at least one hydrofluorocarbon for use in refrigeration and air conditioning systems employing a centrifugal compressor. The compositions may be azeotropic or near-azeotropic.
摘要翻译： 本文公开了包含1,1,1,2,2,4,5,5,5-九氟-4-（三氟甲基）-3-戊酮和至少一种用于制冷和空气中的氢氟烃的制冷剂和传热流体组合物 采用离心压缩机的空调系统。 组合物可以是共沸或近共沸的。
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公开(公告)号：US08907145B2
公开(公告)日：2014-12-09
申请号：US13594007
申请日：2012-08-24
摘要： Disclosed herein are propellants comprising fluorocarbons and/or hydrofluorocarbons. Also disclosed are sprayable compositions comprising the propellants.
摘要翻译： 本文公开了包含碳氟化合物和/或氢氟烃的推进剂。 还公开了包含推进剂的可喷雾组合物。
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公开(公告)号：US08535556B2
公开(公告)日：2013-09-17
申请号：US12161842
申请日：2007-03-26
申请人： Thomas J. Leck , Nandini C. Mouli , Jon Lee Howell , Velliyur Nott Mallikarjuna Rao , Andrew Edward Feiring , Viacheslav A. Petrov , Allen Capron Sievert , Mario Joseph Nappa , Barbara Haviland Minor , Ekaterina N. Swearingen , Schmitz Corneille , Deepak Perti
发明人： Thomas J. Leck , Nandini C. Mouli , Jon Lee Howell , Velliyur Nott Mallikarjuna Rao , Andrew Edward Feiring , Viacheslav A. Petrov , Allen Capron Sievert , Mario Joseph Nappa , Barbara Haviland Minor , Ekaterina N. Swearingen , Schmitz Corneille , Deepak Perti
IPC分类号： C09K5/04
CPC分类号： C09K5/045 , C09K2205/122
摘要： The present invention relates to compositions comprising iodotrifluoromethane and an effective amount of at least one stabilizer selected from the group consisting of hindered phenols, thiophosphates, butylated triphenylphosphorothionates, organo phosphates, phosphites, aryl alkyl ethers, terpenes, terpenoids, epoxides, fluorinated epoxides, oxetanes, ascorbic acid, thiols, lactones, thioethers, amines, nitromethane, alkylsilanes, benzophenone derivatives, aryl sulfides, divinyl terephalic acid, diphenyl terephalic acid, ionic liquids, and mixtures thereof. These stabilized iodotrifluoromethane compositions may be useful as working fluids in multiple applications including cooling apparatus, such as refrigeration, air-conditioning, chillers, and heat pumps.
摘要翻译： 本发明涉及包含三氟甲烷和有效量的至少一种选自受阻酚，硫代磷酸酯，丁基化三苯基硫代磷酸酯，有机磷酸酯，亚磷酸酯，芳基烷基醚，萜烯，萜类化合物，环氧化物，氟化环氧化物，氧杂环丁烷 ，抗坏血酸，硫醇，内酯，硫醚，胺，硝基甲烷，烷基硅烷，二苯甲酮衍生物，芳基硫醚，二乙烯基对苯二酸，二苯基对苯二酸，离子液体及其混合物。 这些稳定的三氟甲烷组合物可用作多种应用中的工作流体，包括冷却装置，例如制冷，空调，冷却器和热泵。
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公开(公告)号：US08288597B2
公开(公告)日：2012-10-16
申请号：US12440062
申请日：2007-09-05
IPC分类号： C07C17/00
CPC分类号： C09K5/045 , C07C17/25 , C09K2205/126 , C07C21/18
摘要： Disclosed is a process for the manufacture of hydrofluoroolefins of the structure CF3CF═CHY, wherein Y can be H or F, comprising reacting at least one fluoropropane reactant of the structure CF3CFXCFYH, wherein X can be either F or H, and Y can be either F or H, provided that both X and Y′ are not both F, with a basic aqueous solution in the presence of a non-aqueous, non-alcoholic solvent, and in the presence of a phase transfer catalyst.
摘要翻译： 公开了一种制备结构CF 3 CF = CHY的氢氟烯烃的方法，其中Y可以是H或F，包括使至少一种结构CF 3 CFXCFYH的氟丙烷反应物，其中X可以是F或H，Y可以是 F或H，条件是在非水非醇溶剂的存在下，并且在相转移催化剂的存在下，X和Y'都不是F都与碱性水溶液一起使用。
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47.发明授权Processes for producing 2,3,3,3-tetrafluoropropene and/or 1,2,3,3-tetrafluoropropene 失效制备2,3,3,3-四氟丙烯和/或1,2,3,3-四氟丙烯的方法公开(公告)号：US08133406B2
公开(公告)日：2012-03-13
申请号：US12446063
申请日：2007-10-31
摘要： A process is disclosed for making CF3CF═CH2 or mixtures thereof with CHF2CF═CHF. This process involves (a) reacting CHCl2CF2CF3, and optionally CHClFCF2CClF2, with H2 in the presence of a catalytically effective amount of a hydrogenation catalyst to form CH3CF2CF3 and, when CHClFCF2CClF2 is present, CH2FCF2CHF2; (b) dehydrofluorinating CH3CF2CF3, and optionally any CH2FCF2CHF2, from (a) to form a product mixture including CF3CF═CH2 and, if CH2FCF2CHF2 is present, CHF2CF═CHF; and optionally (c) recovering CF3CF═CH2, or a mixture thereof with CHF2CF═CHF from the product mixture formed in (b) and/or (d) separating at least a portion of any CHF2CF═CHF in the product mixture formed in (b) from the CF3CF═CH2 in the product mixture formed in (b).
摘要翻译： 公开了制备CF 3CF≡CH2或其与CHF 2 CF = CHF的混合物的方法。 该方法包括（a）在催化有效量的氢化催化剂存在下使CHCl 2 CF 2 CF 3和任选的CHClFCF 2 CClF 2与H 2反应以形成CH 3 CF 2 CF 3，并且当CHClFCF 2 CClF 2存在时，CH 2 FCF 2 CHF 2; （b）从（a）得到（CF 3 CF 2 CH 2）和（如果存在CH 2 CF 2 CHF 2）的产物混合物的CH 3 CF 2 CF 3和任选的任何任何CH 2 CF 2 CHF 2脱氟氟化CHF 2 CF = CHF; 和（c）从（b）和/或（d）中形成的产物混合物中回收CF 3 CF = CH 2或其与CHF 2 CF = CHF的混合物，从而分离出在（b）中形成的产物混合物中的至少一部分CHF 2 CF = CHF， b）从（b）中形成的产品混合物中的CF 3CF≡CH2。
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公开(公告)号：US20110237847A1
公开(公告)日：2011-09-29
申请号：US13153580
申请日：2011-06-06
CPC分类号： C07C17/38 , C07C17/206 , C07C17/386 , C07C19/08 , C07C19/10 , C09K5/045 , C09K2205/126
摘要： Halocarbons of the structure CF3CF2CH2X, wherein X is either F or Cl or mixtures thereof prepared by: contacting at least one 2-fluorochloropropane with hydrogen fluoride in a first fluorination step in the gas phase or liquid phase under substantially anhydrous conditions, in the absence of added catalyst to partially fluorinate said 2-fluorochloropropane; contacting said partially fluorinated 2-fluorochloropropane with at least the stoichiometric molar equivalent of hydrogen fluoride under substantially anhydrous conditions, in the presence of at least one fluorination catalyst in a second fluorination step; removing said reaction products from contact with said catalyst, and isolating a substantial yield of at least 1,1,1,2,2,3-hexafluoropropane or 1,1,1,2,2, penta-3-chloropropane, or mixtures thereof, respectively.
摘要翻译： 结构CF 3 CF 2 CH 2 X的卤代烃，其中X是F或Cl或其混合物，其通过以下步骤制备：在基本上无水条件下，在气相或液相中的第一氟化步骤中使至少一种2-氟氯丙烷与氟化氢接触， 加入催化剂部分氟化所述2-氟氯丙烷; 在第二次氟化步骤中，在至少一种氟化催化剂的存在下，在基本无水的条件下使所述部分氟化的2-氟氯丙烷与化学计量摩尔当量的氟化氢接触; 除去所述反应产物不与所述催化剂接触，并分离出至少1,1,1,2,2,3-六氟丙烷或1,1,1,2,2，五-3-氯丙烷或其混合物的实质产率 分别。
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公开(公告)号：US07959828B2
公开(公告)日：2011-06-14
申请号：US12714709
申请日：2010-03-01
CPC分类号： C08J9/146 , B01F17/0085 , C03C23/0075 , C07C21/18 , C08G18/4208 , C08G18/4883 , C08G2101/0025 , C08J9/0019 , C08J9/144 , C08J2205/05 , C08J2205/052 , C08J2325/06 , C08J2375/06 , C08J2375/08 , C10M105/52 , C10M107/38 , C10M147/04 , C10M169/04 , C10M169/041 , C10M177/00 , C10M2211/022 , C10M2211/06 , C10M2213/04 , C10M2213/06 , C10N2230/06 , C10N2230/22 , C10N2240/20 , C10N2240/204 , C10N2250/121 , C10N2270/00 , C11D3/245 , C11D3/43 , C11D7/5018 , C11D11/0023 , C11D11/0029 , C11D11/0035 , C11D11/0047 , C23G5/02803 , C23G5/02825 , G11B5/71 , G11B5/725 , G11B5/8408 , G11B23/505
摘要： This invention relates to cleaning compositions comprising unsaturated fluorinated hydrocarbons. The invention further relates to use of said cleaning compositions in methods to clean, degrease, deflux, dewater, and deposit fluorolubricant. The invention further relates to novel unsaturated fluorinated hydrocarbons and their use as cleaning compositions and in the methods listed above.
摘要翻译： 本发明涉及包含不饱和氟化烃的清洁组合物。 本发明还涉及所述清洁组合物在清洗，脱脂，除油，脱水和沉积氟橄榄油的方法中的用途。 本发明还涉及新型不饱和氟化烃及其作为清洁组合物和上述方法的用途。
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公开(公告)号：US07722781B2
公开(公告)日：2010-05-25
申请号：US12301070
申请日：2007-06-22
CPC分类号： B01J37/26 , B01J21/04 , B01J27/125 , C07C17/25 , C07C17/386 , C07C21/18 , C07C19/08
摘要： A process is disclosed for the manufacture of CF3CF═CH2 and CF3CH═CHF. The process involves dehydrofluorinating CF3CHFCH2F in the presence of a dehydrofluorination catalyst to produce a product mixture comprising CF3CF═CH2 and CF3CH═CHF, and recovering said CF3CF═CH2 and CF3CH═CHF from the product mixture. The present invention also provides a composition comprising (a) the Z-isomer of CF3CH═CHF and (b) HF; wherein the HF is present in an effective amount to form an azeotropic combination with the Z—CF3CH═CHF.
摘要翻译： 公开了用于制造CF 3CF≡CH2和CF 3 CH = CHF的方法。 该方法包括在脱氟化氢催化剂存在下对CF 3 CHFCH 2 F进行脱氟化氢，以产生包含CF 3CF≡CH2和CF 3 CH = CHF的产物混合物，并从产物混合物中回收所述CF 3CF≡CH2和CF 3 CH = CHF。 本发明还提供了包含（a）CF 3 CH = CHF的Z-异构体和（b）HF的组合物; 其中HF以有效量存在以与Z-CF 3 CH = CHF形成共沸组合。
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