Novel process and catalyst for carbon dioxide conversion to energy generating products
    44.
    发明申请
    Novel process and catalyst for carbon dioxide conversion to energy generating products 审中-公开
    二氧化碳转化为能源产品的新工艺和催化剂

    公开(公告)号:US20080287555A1

    公开(公告)日:2008-11-20

    申请号:US11751026

    申请日:2007-05-20

    CPC classification number: C07C29/157 C07C1/12 C07C2523/84 C07C11/22 C07C31/04

    Abstract: A catalytic process and a nano material for the conversion of moist carbon dioxide into methanol, propyne and oxygen have been developed. In the process invented, hydrogen is produced from water in a catalytic reaction, when the moist carbon dioxide enters into the catalytic reactor, resulting in C—O and H—OH bond breakage at a relatively low temperature and at atmospheric pressure in a single step using a combination of catalytic materials comprising at least three metals dispersed on a catalyst support, preferably anatase form of titanium dioxide, to induce a multifunctional surface chemical reaction for the production of oxygenated products such as hydrocarbons of different chain lengths.

    Abstract translation: 已经开发了用于将湿二氧化碳转化成甲醇,丙炔和氧气的催化方​​法和纳米材料。 在所发明的方法中,当催化反应中产生氢气时,当潮湿的二氧化碳进入催化反应器时,在相对较低的温度和大气压下在单个步骤中导致CO和H-OH键断裂,使用 包含分散在催化剂载体上的至少三种金属的催化材料的组合,优选锐钛矿形式的二氧化钛,以诱导用于生产不同链长的烃的氧化产物的多功能表面化学反应。

    Production of substituted acetylenic compounds
    45.
    发明授权
    Production of substituted acetylenic compounds 失效
    取代的炔属化合物的生产

    公开(公告)号:US4871868A

    公开(公告)日:1989-10-03

    申请号:US163849

    申请日:1988-03-03

    CPC classification number: C07D309/12 C07B37/04 C07C11/22 C07C41/30

    Abstract: A method of producing substituted acetylenic compounds which comprises: reacting an organic compound having the general formula ofA--X (I)wherein A represents a saturated or unsaturated aliphatic hydrocarbon residue of 1-20 carbon atoms which may have one or more substituents inactive in the reaction, and X represents a halogen atom or an arylsulfonyloxy group, with a metal acetylide having the general formula ofM--C.tbd.C--B (II)wherein M represents an alkali metal, and B represents (a) a hydrogen, (b) a saturated or unsaturated hydrocarbon residue which may have one or more substituents inactive in the reaction, or (c) a saturated or unsaturated hydrocarbon residue which has a substituent having the general formula of--C.tbd.C--M (III)wherein M represents an alkali metal, in the presence of an alkyl-2-imidazolidinone having the general formula of ##STR1## wherein R.sup.1 and R.sup.2 independently represent a lower alkyl, and R.sup.3 represents a hydrogen or a lower alkyl.

    Method of transporting acetylene
    47.
    发明授权
    Method of transporting acetylene 失效
    运输乙酰乙酸的方法

    公开(公告)号:US3767725A

    公开(公告)日:1973-10-23

    申请号:US3767725D

    申请日:1972-01-07

    Applicant: TENNECO CHEM

    Inventor: WALKER D KEYWORTH D

    CPC classification number: C10L3/04 C07C7/152 C07F5/069 C07C11/22

    Abstract: ACETYLENE IS TRANSPORTED SAFELY AND ECONOMICALLY BY CONTACTING AN ACETYLENE-CONTAINING GAS IN A FIRST LOCATION WITH A SOLUTION OF CUPROUS ALUMINUM TETRACHLORIDE IN AN AROMATIC HYDROCARBON OR HALOGENATED AROMATIC HYDROCARBON TO FORM A SOLUTION OF AN ACETYLENE-CUPROUS ALUMINUM TETRACHLORIDE COMPLEX IN THE AROMATIC SOLVENT, TRANSPORTING THE SOLUTION CONTAINING THE ACETYLENE COMPLEX FROM THE FIRST LOCATION TO A SECOND LOCATION, CONTACTING THE SOLUTION IN THE SECOND LOCATION WITH A COUNTERCURRENT STREAM OF A HYDROCARBON VAPOR AT 75* C. TO 180* C., AND RECOVERING SUBSTANTIALLY PURE ACETYLENE FROM THE RESULTING GAS STREAM.

    Isomerization of allenes into their corresponding terminal acetylenic isomers
    48.
    发明授权
    Isomerization of allenes into their corresponding terminal acetylenic isomers 失效
    将它们与相应的末端乙酰基异构体进行同位异构

    公开(公告)号:US3671605A

    公开(公告)日:1972-06-20

    申请号:US3671605D

    申请日:1970-12-14

    Abstract: A catalyst for the isomerization of allenes into their corresponding terminal acetylenic isomers is prepared by combining an alkali metal having an atomic weight greater than that of lithium with alumina in the presence of sufficient heat for the free alkali metal to melt and react with the alumina. Passing a stream of an allene compound through a bed of this catalyst converts the allene into the corresponding terminal acetylenic isomer.

    Abstract translation: 通过在足够的热存在下将原子量大于锂的碱金属与氧化铝相结合,使游离碱金属熔化并与氧化铝反应,制备将烯异构化成其相应末端炔属异构体的催化剂。 将丙烯化合物流通过该催化剂的床将丙烯转化为相应的末端炔属异构体。

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