公开(公告)号：US08802019B2

公开(公告)日：2014-08-12

申请号：US13331362

申请日：2011-12-20

申请人： Gerhard Olbert ,  Ulrike Wegerle ,  Grigorios Kolios ,  Albena Kostova ,  Jasmina Kessel ,  Alexander Weck ,  Alireza Rezai

发明人： Gerhard Olbert ,  Ulrike Wegerle ,  Grigorios Kolios ,  Albena Kostova ,  Jasmina Kessel ,  Alexander Weck ,  Alireza Rezai

IPC分类号： B01J19/00 ,  B01J8/00 ,  B01J8/02 ,  B01J8/04 ,  B01J35/02 ,  C07C13/00 ,  C07C5/32 ,  C07C5/42

CPC分类号： B01J19/2485 ,  B01J8/0484 ,  B01J23/626 ,  B01J23/96 ,  B01J37/18 ,  B01J38/12 ,  B01J2219/00085 ,  B01J2219/182 ,  B01J2219/1925 ,  B01J2219/1943 ,  B01J2219/2414 ,  B01J2219/2416 ,  B01J2219/2419 ,  B01J2219/2422 ,  B01J2219/2443 ,  C07C5/48 ,  C07C2523/06 ,  C07C2523/42 ,  Y02P20/52 ,  Y02P20/584 ,  C07C11/06 ,  C07C11/08 ,  C07C11/09 ,  C07C11/167 ,  C07C15/46

摘要： A reactor includes an essentially horizontal cylinder for carrying out an autothermal gas-phase dehydrogenation of a hydrocarbon-comprising gas stream using an oxygen-comprising gas stream to give a reaction gas mixture over a heterogeneous catalyst configured as monolith. The interior of the reactor is divided by a detachable, cylindrical or prismatic housing, which is arranged in the longitudinal direction of the reactor and is gastight in the circumferential direction, into an inner region having one or more catalytically active zones, each having a packing composed of monoliths stacked on top of one another, next to one another and behind one another and before each catalytically active zone in each case a mixing zone having solid internals are provided and into an outer region, which is supplied with an inert gas, arranged coaxially to the inner region. A heat exchanger is connected to the housing at one end of the reactor.

摘要翻译： 反应器包括基本上水平的气缸，用于使用含氧气流进行含烃气流的自热气相脱氢，以在构成为整料的多相催化剂上产生反应气体混合物。 反应器的内部由可拆卸的圆柱形或棱柱形壳体分隔，该壳体沿反应器的纵向方向布置并且在圆周方向上气密地进入具有一个或多个催化活性区域的内部区域，每个区域具有包装 由堆叠在彼此顶部，彼此相邻并且彼此相邻并且在每种情况下的每个催化活性区域之间的整体堆叠提供具有固体内部部分的混合区域并且设置在被供应有惰性气体的外部区域中，该外部区域被供应有惰性气体， 与内部区域同轴。 热交换器在反应器的一端连接到壳体。

公开(公告)号：US20240253008A1

公开(公告)日：2024-08-01

申请号：US18561138

申请日：2022-05-25

申请人： Topsoe A/S

发明人： Martin ØSTBERG

IPC分类号： B01J19/24

CPC分类号： B01J19/2485 ,  B01J2219/00121 ,  B01J2219/2416 ,  B01J2219/2428 ,  B01J2219/2438

摘要： An electrical heater is provided, which comprises a ceramic monolith and a metal resistance wire supported on the ceramic monolith. At least a portion of the metal resistance wire, and optionally at least a portion of the ceramic monolith, is coated with a ceramic coating. At least a portion of the ceramic coating is—in turn—impregnated with a catalytic metal. A process for manufacturing the electrical heater, and various uses of the heater are also provided.

公开(公告)号：US08852538B2

公开(公告)日：2014-10-07

申请号：US13564028

申请日：2012-08-01

申请人： Gerhard Olbert ,  Ulrike Wegerle ,  Grigorios Kolios ,  Carlos Tellaeche Herranz ,  Reinhold Höchst ,  Andrea Gienger ,  Roland Bauer

发明人： Gerhard Olbert ,  Ulrike Wegerle ,  Grigorios Kolios ,  Carlos Tellaeche Herranz ,  Reinhold Höchst ,  Andrea Gienger ,  Roland Bauer

IPC分类号： B01J19/24 ,  C07C5/48 ,  B01J7/00 ,  B01J8/00 ,  B01J8/02 ,  B01J19/00 ,  B01J19/02 ,  B01J16/00

CPC分类号： B01J19/2485 ,  B01J2219/00155 ,  B01J2219/2411 ,  B01J2219/2416 ,  B01J2219/2419 ,  B01J2219/2422 ,  B01J2219/2443 ,  C07C5/48 ,  Y02P20/52 ,  C07C11/06 ,  C07C11/08 ,  C07C11/09 ,  C07C11/167 ,  C07C11/22

摘要： A reactor in the form of a cylinder or prism wherein the interior of the reactor is divided by a cylindrical or prismatic gastight housing G which is arranged in the longitudinal direction of the reactor into an inner region having one or more catalytically active zones, in which in each case a packing composed of monoliths stacked on top of one another, next to one another and behind one another and before each catalytically active zone in each case a mixing zone having solid internals are provided, and an outer region B arranged coaxially to the inner region A, wherein the inner region A is insulated from the outer region B of the reactor by means of a microporous high-performance insulation material having a thermal conductivity 1 at temperatures up to 700° C. of less than 0.05 W/m*K is proposed.

摘要翻译： 反应器为圆筒或棱柱形式，其中反应器的内部被圆柱形或棱镜气密的外壳G分隔开，该外壳G在反应器的纵向被布置成具有一个或多个催化活性区域的内部区域，其中 在每种情况下，由堆叠在彼此顶部，彼此相邻并且彼此相邻并且在每种情况下的每个催化活性区域之间的整体组成的填料提供有具有实心内部的混合区域，以及与该区域同轴设置的外部区域B 内部区域A，其中内部区域A通过具有小于0.05W / m 2的温度高达700℃的导热率1的微孔高性能绝缘材料与反应器的外部区域B绝缘; 提出K。

公开(公告)号：US20240269662A1

公开(公告)日：2024-08-15

申请号：US18565902

申请日：2022-06-27

申请人： Topsoe A/S

发明人： Peter Mølgaard MORTENSEN ,  Sebastian Thor WISMANN ,  Anders Helbo HANSEN

IPC分类号： B01J35/56 ,  B01J19/24 ,  B01J19/32 ,  B01J35/33

CPC分类号： B01J35/56 ,  B01J19/2485 ,  B01J19/32 ,  B01J35/33 ,  B01J2219/00135 ,  B01J2219/2416 ,  B01J2219/2432 ,  B01J2219/2438 ,  B01J2219/32425 ,  B01J2219/32466

摘要： A structured catalyst for catalyzing an endothermic reaction of a feed gas to convert it to a product gas is provided.

公开(公告)号：US11905173B2

公开(公告)日：2024-02-20

申请号：US17046475

申请日：2019-05-15

申请人： HALDOR TOPSØE A/S

发明人： Peter Mølgaard Mortensen ,  Robert Klein ,  Kim Aasberg-Petersen

IPC分类号： C01B3/38 ,  B01J15/00 ,  B01J19/24 ,  C01B3/40

CPC分类号： C01B3/384 ,  B01J15/005 ,  B01J19/2485 ,  C01B3/40 ,  B01J2219/00135 ,  B01J2219/00155 ,  B01J2219/243 ,  B01J2219/2416 ,  B01J2219/2428 ,  B01J2219/2438 ,  C01B2203/0233 ,  C01B2203/085 ,  C01B2203/0883 ,  C01B2203/1023 ,  C01B2203/1264

摘要： A reactor system for carrying out steam reforming of a feed gas comprising hydrocarbons, including: a structured catalyst arranged for catalyzing steam reforming of a feed gas including hydrocarbons, the structured catalyst including a macroscopic structure of electrically conductive material, the macroscopic structure supporting a ceramic coating, wherein the ceramic coating supports a catalytically active material; a pressure shell housing the structured catalyst; heat insulation layer between the structured catalyst and the pressure shell; at least two conductors electrically connected to the macroscopic structure and to an electrical power supply placed outside the pressure shell, wherein the electrical power supply is dimensioned to heat at least part of the structured catalyst to a temperature of at least 500° C. by passing an electrical current through the macroscopic structure. Also, a process for steam reforming of a feed gas comprising hydrocarbons.

公开(公告)号：US11806705B2

公开(公告)日：2023-11-07

申请号：US17051298

申请日：2019-06-24

申请人： HALDOR TOPSØE A/S

发明人： Martin Østberg

IPC分类号： B01J8/06 ,  B01J19/24

CPC分类号： B01J8/062 ,  B01J19/2415 ,  B01J2208/065 ,  B01J2219/2416

摘要： The invention relates to a catalytic reactor comprising a combustion reaction chamber with catalytic reactor tubes filled with catalyst elements and metal radiation surfaces arranged in the chamber to improve heat transfer.

公开(公告)号：US09901898B2

公开(公告)日：2018-02-27

申请号：US13853405

申请日：2013-03-29

申请人： Catacel Corp.

发明人： William A. Whittenberger ,  Joseph W. Whittenberger ,  Brian L. Davis ,  James A. Rundo

IPC分类号： B01J19/24 ,  B01J19/32 ,  B01J19/30

CPC分类号： B01J19/32 ,  B01J19/244 ,  B01J19/2485 ,  B01J19/30 ,  B01J19/325 ,  B01J2219/2402 ,  B01J2219/2416 ,  B01J2219/2422 ,  B01J2219/2443 ,  B01J2219/2448 ,  B01J2219/2496 ,  B01J2219/30226 ,  B01J2219/30408 ,  B01J2219/32275

摘要： Described herein are expandable center arrangements for use in a tubular reactor, such as a reformer, for enhancing heat transfer and reactor efficiency. The expandable center arrangement can include a cone being expandable in the radial direction and an expansion weight for promoting expansion of the cone. The cone and expansion weight can be slidably arranged on a center support. Expansion of the cones in the radial direction forces reactor components radially outward to an outer tube that houses the reactor components and expandable center arrangement. Expansion of reactor components towards the outer tube promotes heat for carrying out catalytic reactions.

公开(公告)号：US20130035531A1

公开(公告)日：2013-02-07

申请号：US13564028

申请日：2012-08-01

申请人： Gerhard Olbert ,  Ulrike Wegerle ,  Grigorios Kolios ,  Carlos Tellaeche Herranz ,  Reinhold Höchst ,  Andrea Gienger ,  Roland Bauer

发明人： Gerhard Olbert ,  Ulrike Wegerle ,  Grigorios Kolios ,  Carlos Tellaeche Herranz ,  Reinhold Höchst ,  Andrea Gienger ,  Roland Bauer

IPC分类号： C07C5/48 ,  B01J8/04

CPC分类号： B01J19/2485 ,  B01J2219/00155 ,  B01J2219/2411 ,  B01J2219/2416 ,  B01J2219/2419 ,  B01J2219/2422 ,  B01J2219/2443 ,  C07C5/48 ,  Y02P20/52 ,  C07C11/06 ,  C07C11/08 ,  C07C11/09 ,  C07C11/167 ,  C07C11/22

摘要： A reactor in the form of a cylinder or prism wherein the interior of the reactor is divided by a cylindrical or prismatic gastight housing G which is arranged in the longitudinal direction of the reactor into an inner region having one or more catalytically active zones, in which in each case a packing composed of monoliths stacked on top of one another, next to one another and behind one another and before each catalytically active zone in each case a mixing zone having solid internals are provided, and an outer region B arranged coaxially to the inner region A, wherein the inner region A is insulated from the outer region B of the reactor by means of a microporous high-performance insulation material having a thermal conductivity 1 at temperatures up to 700° C. of less than 0.05 W/m*K is proposed.

摘要翻译： 反应器为圆筒或棱柱形式，其中反应器的内部被圆柱形或棱镜气密的外壳G分隔开，该外壳G在反应器的纵向被布置成具有一个或多个催化活性区域的内部区域，其中 在每种情况下，由堆叠在彼此顶部，彼此相邻并且彼此相邻并且在每种情况下的每个催化活性区域之间的整体组成的填料提供有具有实心内部的混合区域，以及与该区域同轴设置的外部区域B 内部区域A，其中内部区域A通过具有小于0.05W / m 2的温度高达700℃的导热率1的微孔高性能绝缘材料与反应器的外部区域B绝缘; 提出K。

公开(公告)号：US20230365872A1

公开(公告)日：2023-11-16

申请号：US18030507

申请日：2021-10-08

申请人： Gianluca PAULETTO

发明人： Gianluca PAULETTO

IPC分类号： C10G9/24 ,  C10G9/20 ,  B01J19/08 ,  B01J19/24 ,  B01J19/00 ,  B01J19/02 ,  C10G9/16

CPC分类号： C10G9/24 ,  C10G9/203 ,  B01J19/087 ,  B01J19/2485 ,  C10G9/206 ,  B01J19/0026 ,  B01J19/0053 ,  B01J19/02 ,  C10G9/16 ,  B01J2219/00135 ,  B01J2219/2411 ,  B01J2219/2416 ,  B01J2219/2419 ,  B01J2219/2438 ,  B01J2219/2428 ,  B01J2219/0236 ,  C10G2300/4006 ,  C10G2300/4012 ,  C10G2300/708

摘要： A reactor shell for producing olefins via steam cracking from a fed reactive mixture stream composed of steam and hydrocarbons comprising: at least one reactive stream duct formed within said reactor shell, at least one structured ceramic bed having a plurality of hollow flow paths, at least one electrical resistance heating element for heating the reactive mixture stream up to a predetermined reaction temperature and a coating provided on a surface contacting with the reactive mixture stream is provided. The reactor shell is characterized by that said electrical resistance heating element that is arranged inside at least some of said hollow flow paths in a manner that there still remains a flowing passage inside the hollow flow paths.

公开(公告)号：US09985307B2

公开(公告)日：2018-05-29

申请号：US13546432

申请日：2012-07-11

申请人： Karsten Reiners ,  Andreas Kaupert

发明人： Karsten Reiners ,  Andreas Kaupert

IPC分类号： C01B3/16 ,  H01M8/06 ,  C01B3/56 ,  H01M8/0612 ,  H01M8/0662 ,  C01B3/38 ,  B01J19/24

CPC分类号： H01M8/0618 ,  B01J19/2485 ,  B01J2219/2416 ,  B01J2219/2428 ,  C01B3/16 ,  C01B3/386 ,  C01B3/56 ,  C01B2203/0261 ,  C01B2203/0283 ,  C01B2203/042 ,  C01B2203/0455 ,  C01B2203/0485 ,  C01B2203/066 ,  C01B2203/1276 ,  C01B2203/1288 ,  H01M8/04097 ,  H01M8/04223 ,  H01M8/04225 ,  H01M8/0625 ,  H01M8/0675

摘要： A fuel treatment device (2) converts a hydrocarbon-containing fuel into a fuel for a fuel cell (3). The fuel treatment device (2) has for this purpose a mixture formation space (7) for forming and processing a mixture of fuel and another component, a reformer (8) for converting the mixture into a synthesis gas and a desulfurization stage (9) for removing sulfur from the synthesis gas or from the mixture. The reformer (8) and desulfurization stage (9) are arranged adjacent to each other in a housing (10) along an axis of the housing (10).