摘要:
A process for the simultaneous production of gasoline blending components and a phthalate ester useful as a plasticizer. C.sub.3 to C.sub.4 olefins are reacted in an oligomerization zone to form a mixture containing C.sub.6 to C.sub.10 olefinic hydrocarbons. A three carbon number boiling range intermediate fraction is recovered from this mixture. The less highly branched olefins in this intermediate fraction are selectively hydroformylated to yield alcohols which are then reacted with an aromatic carboxylic acid or an aromatic anhydride. The unhydroformylated olefins are combined with the other olefinic hydrocarbon fractions to form a high octane motor fuel.
摘要:
A process for making a low viscosity, low volatility .alpha.-olefin oligomer suitable for use as a functional fluid or lubricating oil comprising dimerizing a C.sub.6-12 .alpha.-olefin, reacting the resultant dimer with a C.sub.6-18 .alpha.-olefin in the presence of a Friedel-Crafts catalyst, distilling out volatile components and hydrogenating the residual product.
摘要:
The present invention provides a process for aralkylation of alkylbenzenes wherein an alkylbenzene or alkylbenzenes containing in the substituent alkyl group or groups from 1 to 4 carbon atoms in total is aralkylated with at least one styrene selected from the group consisting of styrene, vinyltoluenes and .alpha.-methylstyrene which comprises carrying out the reaction by continuously feeding to a catalyst layer the above-mentioned alkylbenzene or alkylbenzenes and styrene sources in liquid phase at a temperature from 100.degree. C. to 200.degree. C., said catalyst layer being filled with synthetic silica-alumina containing from 20% by weight to 50% by weight alumina that has been calcined at a temperature in the range from 450.degree. C. to 600.degree. C.
摘要:
This invention relates to the preparation of linear alpha-olefin oligomers and more particularly to the catalyst system which consists of a two component mixture comprising an aluminium halide and a compound capable of reacting with said aluminium halide and selected among(a) halogens or interhalogenic compounds,(b) halogenated compounds having the formula ##STR1## in which R', R", R'", represent H or alkyl or aryl (C) METAL HALIDESBy the above catalyst system oligomers can be prepared with high yields and with an easier control and performance of the reaction, starting from linear alpha-olefins having 3 to 12 carbon atoms.
摘要:
There is disclosed a method for preparing a catalyst useful for olefin metathesis comprising a mixture of a salt of a metal selected from tungsten, molybdenum, rhenium and tantalum, an oxygenated organic compound selected from the group represented by the formula: ##STR1## said mixture being exposed to ultraviolet radiation to give approximately 0.4 kilowatt hours per mole of the metal salt.A process of olefin metathesis utilizing this catalyst is also disclosed.
摘要:
Novel heterogeneous, nickel-containing catalysts comprising A. A nickel carbonyl complex, and B. An acidic, solid, silica-based material are active in numerous reactive environments such as oligomerization, including homo- and co-dimerization, and polymerization of various olefins. In specific aspects, bis(triphenylphosphine) nickel dicarbonyl supported on an acidic, calcined, silicaalumina support containing a separate alumina phase, is active in, for instance, the oligomerization, particularly dimerization, of ethylene and propylene, the codimerization of a conjugated diene and an alpha-olefin and the polymerization of conjugated dienes.
摘要:
Synthetic, high quality lubricating oils are produced through the polymerization of a single alpha-olefin or a mixture of alpha-olefins from ''''wax-cracking'''' having the formula R - CH CH2 wherein R is an alkyl radical containing from 2 to 16 C atoms, by the use, in a dry nitrogen atmosphere, of a catalyst system constituted by a compound of a transition metal selected from groups IV to VIII of the periodic system (e.g., TiCl4) and by two coordinate anionic cocatalysts, one of which is an aluminum compound of inorganic nature devoid of any metal-carbon bond and consisting of a polyiminic linear polymer (e.g., a polyimine alane represented by the formula:
WHEREIN R is alkyl, aryl or cycloalkyl and n is a whole number from 4 to 25) and the other of which is an aluminum compound of the conventional Ziegler type with a metal-carbon link (e.g., an aluminum alkyl sesquichloride or an aluminum dialkyl monochloride.