Abstract:
To provide a fluorinated ether compound, a fluorinated ether composition and a coating liquid that are able to form a surface layer which is excellent in water/oil repellency, abrasion resistance, fingerprint stain removability, lubricity and outer appearance, and an article having such a surface layer. A fluorinated ether compound represented by A1-O—(Rf1O)m1Q1-[C(O)N(R1)]p1—R11—C[—R12—SiR13n1X13-n1]3, wherein A1 is a C1-20 perfluoroalkyl group; Rf1 is a fluoroalkylene group having no branched structure; m1 is an integer from 2 to 210; Q1 is a single bond or a fluoroalkylene group having no branched structure; R1 is a hydrogen atom, etc.; p1 is 0 or 1; R11 is a single bond, an alkylene group, etc.; R12 is an alkylene group, etc.; R13 is a monovalent hydrocarbon group, etc.; X1 is a hydrolyzable group; and n1 is an integer of from 0 to 2.
Abstract:
An erodible antifouling coating composition for application, for example, to ship's hulls to potentially prevent the adhesion and build-up of fouling agents on the hull is described. The coating composition includes 10 to 60% by solids weight of an erodible binder system that excludes a triorgano tin based binder; one or more antifouling agents; and 1 to 10% solids weight of a mixture of silicone oils, wherein the mixture includes a first and second silicone oil each comprising alkyl and aryl groups attached to silicone in a different ratio. A process for producing the composition, a substrate coated with the composition, and a process of coating a substrate with the composition are also described.
Abstract:
The present invention relates to a process for repairing a coating film by applying an adhesion primer comprising a hydroxy-functional (meth)acrylate resin, a hydroxy-functional epoxy resin, a polyisocyanate, and an epoxy-functional organosilane directly to a substrate that is a substrate body with an original coating that has defects, to form an adhesion-promoting film and, applying at least one further layer of coating to the resultant adhesion-promoting film. The invention further relates to the use of the adhesion primer to improve the adherence of a further coating layer to such substrate, preferably to a substrate with a substrate body of glass fiber-reinforced unsaturated polyester resin, of glass fiber-reinforced epoxy resin, or of glass fiber-reinforced vinyl ester resin, wherein the further coating layer preferably is a polyurethane-based coating. The present invention further relates to a substrate coated with a coating film that has been repaired according to such a process.
Abstract:
The present invention provides an organic silicon coating including 20 to 40 parts of methyl vinyl organic silicon polymer by weight, 1 to 6 parts of methyl phenyl organic silicon polymer by weight, 5 to 15 parts of hydrogenated silicone oil, 5 to 10 parts of fluorinated acrylate monomer by weight, 5 to 15 parts of silicon dioxide by weight, 0.2 to 2 parts of inhibitor by weight, 0.1 to 1 part of auxiliary by weight, 0.1 to 1 part of thermal initiator by weight, 30 to 50 parts of organic solvent by weight, and 2 to 5 parts of metal catalyst by weight. The organic silicon coating provided by the present invention has good adhesion for a silicone rubber or fluororubber base material with no surface treatment.
Abstract:
To provide a fluorinated ether compound, a fluorinated ether composition and a coating liquid that are able to form a surface layer which is excellent in water/oil repellency, abrasion resistance, fingerprint stain removability, lubricity and outer appearance, and an article having such a surface layer. A fluorinated ether compound represented by A1—O—(Rf1O)m1-Q1-[C(O)N(R1)]p1—R11—C[—R12—SiR13n1X13−n1]3, wherein A1 is a C1-20 perfluoroalkyl group; Rf1 is a fluoroalkylene group having no branched structure; m1 is an integer from 2 to 210; Q1 is a single bond or a fluoroalkylene group having no branched structure; R1 is a hydrogen atom, etc.; p1 is 0 or 1; R11 is a single bond, an alkylene group, etc.; R12 is an alkylene group, etc.; R13 is a monovalent hydrocarbon group, etc.; X1 is a hydrolyzable group; and n1 is an integer of from 0 to 2.
Abstract:
The present invention provides an organic silicon coating including 20 to 40 parts of methyl vinyl organic silicon polymer by weight, 1 to 6 parts of methyl phenyl organic silicon polymer by weight, 5 to 15 parts of hydrogenated silicone oil, 5 to 10 parts of fluorinated acrylate monomer by weight, 5 to 15 parts of silicon dioxide by weight, 0.2 to 2 parts of inhibitor by weight, 0.1 to 1 part of auxiliary by weight, 0.1 to 1 part of thermal initiator by weight, 30 to 50 parts of organic solvent by weight, and 2 to 5 parts of metal catalyst by weight. The organic silicon coating provided by the present invention has good adhesion for a silicone rubber or fluororubber base material with no surface treatment.
Abstract:
A composition comprising a hydrolyzable organosilicon compound and porous fine particles, a coating made from the composition and a laminated plate comprising a substrate and the coating are provided. The coating is superior in adhering properties to a substrate and is equipped with an adequate hardness.
Abstract:
A coating fluid for forming a coating on a support for use in inkjet printing comprises a liquid medium having dispersed therein (a) an inorganic oxide selected from aluminium oxide and silica, (b) a binder polymer, and (c) a polymeric crosslinking agent containing functional groups for reaction with the inorganic oxide. The components (a), (b) and (c) are preferably dispersed in an aqueous liquid and the relative amounts of inorganic oxide to polymeric crosslinking agent are from 500:1 to 15:1 preferably 250:1 to 20:1, the relative amounts of inorganic oxide to binder polymer are from 50:1 to 2:1 preferably 20:1 to 4:1 and the relative amounts of binder polymer to polymeric crosslinking agent are from 40:1 to 2:1 preferably from 20:1 to 3:1 the amounts being by weight on a dry basis.
Abstract:
A radiation-curable composition for use as an optical fiber material or coating comprising the combination of the following pre-mixture ingredients:(A) about 5 wt. % to about 95 wt. % of one or more radiation-curable oligomers,(B) about 5 wt. % to about 95 wt. % of one or more monomer diluents,(C) optionally, one or more photoinitiators,(D) about 0.1 wt. % to about 30 wt. % of one or more adhesion promoters represented by:(R.sup.1 --L).sub.4-X --Si(OR.sup.2).sub.Xwherein R.sup.1 is a group comprising an ethylenically unsaturated radiation-curable group; and said three R.sup.2 groups independently of each other are C.sub.1 -C.sub.10 groups; wherein X=1-3; and L is a linking group which comprises one or more alkoxy or branched propoxy groups.
Abstract:
Curable composition comprising a stable, water dispersible, curable polymer containing a sterically hindered alkoxylated silane group at 0.1 to 75 weight percent of the total composition; a water dispersible or water soluble, hydrolytically stable organotin catalyst, at 0.1 to 10 weight percent of the total composition; and water at 99.8 to 24.9 weight percent of the total composition are taught herein. These compositions are useful as adhesives, sealants and paints. The compositions have improved properties including solvent resistance, adhesion, hardness, abrasion resistance and mar resistance. Particular catalysts for use herein include mercaptoalcohol, mercaptide and sulfide forms of diorganotins having either a Sn--S or Sn.dbd.S bond, and include dibutyltin dimercaptide and dibutyltin bis(1-thioglycerol).