公开(公告)号：US20170022214A1

公开(公告)日：2017-01-26

申请号：US15102281

申请日：2014-11-19

Applicant: ARCHER DANIELS MIDLAND COMPANY

Inventor： Kenneth Stensrud ,  Erik Hagberg ,  Erin Rockafellow

IPC: C07D493/04

CPC classification number: C07D493/04

Abstract: A method for preparing esters from isohexide compounds, and a means by which color bodies that may be made in situ during esterification of isohexide compounds are either prevented from forming or their amounts are minimized in the resultant product mixture are described.

Abstract translation: 描述了用于从异己烯化合物制备酯的方法，以及在所得产物混合物中防止在异癸二烯化合物的酯化期间可原位制备的颜色体或其数量被最小化的方法。

公开(公告)号：US09533930B2

公开(公告)日：2017-01-03

申请号：US14613877

申请日：2015-02-04

Applicant: ARCHER DANIELS MIDLAND COMPANY

Inventor： Kevin J. Adlaf ,  Paul D. Bloom ,  William Chris Hoffman ,  Chicheng Ma ,  John G. Soper ,  Brad Zenthoefer

IPC: C07C29/80 ,  C07B63/00 ,  C07C29/88 ,  C07C31/20 ,  B01D3/14 ,  C07C29/76 ,  B01D3/34 ,  B01D15/36 ,  C07C29/60

CPC classification number: C07C29/80 ,  B01D3/143 ,  B01D3/34 ,  B01D15/362 ,  C07B63/00 ,  C07C29/60 ,  C07C29/76 ,  C07C29/88 ,  C07C31/20 ,  C07C31/202 ,  C07C31/205

Abstract: In the process of distilling a polyol product mixture including one or both of a biobased propylene glycol and a biobased ethylene glycol from the reaction of hydrogen with a biobased feed, it has been discovered that undesirable epoxides can form, and the present invention provides means for guarding against their formation, for removing epoxides which do form by particular methods of distilling, and for removing the epoxides from a finished, otherwise commercially acceptable biobased glycol product.

Abstract translation: 在从氢与生物基进料的反应中蒸馏包含生物基丙二醇和生物基乙二醇中的一种或两种的多元醇产物混合物的过程中，已经发现可以形成不期望的环氧化物，并且本发明提供了用于 防止其形成，用于去除通过特定蒸馏方法形成的环氧化物，以及从成品的商业上可接受的生物基二醇产物中除去环氧化物。

公开(公告)号：US09522369B2

公开(公告)日：2016-12-20

申请号：US15075467

申请日：2016-03-21

Applicant: ARCHER DANIELS MIDLAND COMPANY

Inventor： Shireen S. Baseeth ,  Teodora R. Tabuena-Salyers ,  Bruce R. Sebree

IPC: C07F9/165 ,  C08K5/00 ,  C04B7/00 ,  C04B16/00 ,  C04B24/00 ,  B01F17/00 ,  C09D17/00 ,  C08K5/521 ,  A61Q1/02 ,  A61K8/36 ,  A61K8/365 ,  A61K8/55 ,  C09D7/02

CPC classification number: B01F17/0092 ,  A61K8/361 ,  A61K8/365 ,  A61K8/553 ,  A61K2800/413 ,  A61Q1/02 ,  B01F17/0021 ,  C08K5/521 ,  C09D7/20 ,  C09D7/45 ,  C09D17/003 ,  C09D17/004 ,  C09D17/005 ,  C09D17/008

Abstract: The present disclosure is directed to compositions having lecithin and an organic acid and related methods. The disclosed compositions may also include one or more co-surfactants such as anionic surfactants and/or non-ionic surfactants, and may be used as a dispersant.

公开(公告)号：US09517442B2

公开(公告)日：2016-12-13

申请号：US15075452

申请日：2016-03-21

Applicant: ARCHER DANIELS MIDLAND COMPANY

Inventor： Shireen S. Baseeth ,  Teodora R. Tabuena-Salyers ,  Bruce R. Sebree

IPC: C07F9/165 ,  C08K5/00 ,  C04B7/00 ,  C04B16/00 ,  C04B24/00 ,  B01F17/00 ,  C09D17/00 ,  C08K5/521 ,  A61Q1/02 ,  A61K8/36 ,  A61K8/365 ,  A61K8/55 ,  C09D7/02

CPC classification number: B01F17/0092 ,  A61K8/361 ,  A61K8/365 ,  A61K8/553 ,  A61K2800/413 ,  A61Q1/02 ,  B01F17/0021 ,  C08K5/521 ,  C09D7/20 ,  C09D7/45 ,  C09D17/003 ,  C09D17/004 ,  C09D17/005 ,  C09D17/008

Abstract: The present disclosure is directed to compositions having lecithin and an organic acid and related methods. The disclosed compositions may also include one or more co-surfactants such as anionic surfactants and/or non-ionic surfactants, and may be used as a dispersant.

Abstract translation: 本公开涉及具有卵磷脂和有机酸的组合物及相关方法。 所公开的组合物还可以包括一种或多种辅助表面活性剂，例如阴离子表面活性剂和/或非离子表面活性剂，并且可以用作分散剂。

公开(公告)号：US20160304479A1

公开(公告)日：2016-10-20

申请号：US15038061

申请日：2014-12-12

Applicant: ARCHER DANIELS MIDLAND COMPANY

Inventor： Kenneth Stensrud

IPC: C07D307/42 ,  C07D307/52 ,  C07F9/54 ,  C07D307/24 ,  C07D307/10 ,  C07D307/44 ,  C07D307/12

CPC classification number: C07D307/42 ,  C07D307/10 ,  C07D307/12 ,  C07D307/24 ,  C07D307/44 ,  C07D307/48 ,  C07D307/52 ,  C07F9/5456

Abstract: A process for preparing furanic mono- and/or di-sulfonate molecules from the reduction products of HMF, in particular, from either 2,5-bis-hydroxymethyltetrahydrofurans (THF-diols) or furan-2,5-dimethanol (FDM) under relatively mild conditions is described. The process involves reacting THF-diols or FDM with at least a sulfonate species, and a reagent of either 1) a nucleophilic base or 2) combination of a non-nucleophilic base and a nucleophile, as two separate reagents. The furanic sulfonates synthesized according to the process and some of the associated compounds that can be derivatized from the sulfonates are also provided.

Abstract translation: 从HMF的还原产物，特别是来自2,5-双羟甲基四氢呋喃（THF-二醇）或呋喃-2,5-二甲醇（FDM）的还原产物制备呋喃单一和/或二磺酸盐分子的方法， 描述相对温和的条件。 该方法包括使THF-二醇或FDM与至少一种磺酸盐物质反应，以及1）亲核碱或2）非亲核碱和亲核试剂的组合的试剂作为两种分开的试剂。 还提供根据该方法合成的呋喃磺酸盐和可从磺酸盐衍生化的一些相关化合物。

公开(公告)号：US09464026B2

公开(公告)日：2016-10-11

申请号：US14650453

申请日：2013-12-09

Applicant: Archer Daniels Midland Company

Inventor： Kenneth Stensrud ,  Padmesh Venkitasubramanian

IPC: C07C69/00 ,  C07C67/08 ,  C12P7/44 ,  C07C29/149 ,  C12P7/40 ,  C12P7/42 ,  C12P7/46 ,  C12P7/48

CPC classification number: C07C67/08 ,  C07C29/149 ,  C12P7/40 ,  C12P7/42 ,  C12P7/44 ,  C12P7/46 ,  C12P7/48 ,  Y02E50/343 ,  Y02P20/544 ,  C07C31/207 ,  C07C69/40 ,  C07C69/675 ,  C07C69/704

Abstract: A process for recovering and using an carboxylic acid derived from a fermentation broth by means of making an ester of the free carboxylic acid and alcohol in carbon dioxide (CO2) without the presence of any other acid catalyst at a reaction temperature and pressure that corresponds to supercritical, critical or near critical conditions for the alcohol and/or CO2 is described. The process can constitute part of a general process of refining carboxylic acids derived from a fermentation broth for use in the production of a variety of chemical compounds, such as C4 platform compounds, polymers, or fuels.

Abstract translation: 一种通过在二氧化碳（CO 2）中制备游离羧酸和醇的酯而不存在任何其它酸催化剂的反应温度和压力下回收和使用衍生自发酵液的羧酸的方法，所述反应温度和压力对应于 描述了醇和/或CO 2的超临界，临界或近临界条件。 该方法可构成精制来自发酵液的羧酸的一般方法的一部分，所述发酵液用于生产各种化学化合物，例如C4平台化合物，聚合物或燃料。

公开(公告)号：US20160289241A1

公开(公告)日：2016-10-06

申请号：US14777680

申请日：2014-03-05

Applicant: ARCHER DANIELS MIDLAND COMPANY

Inventor： Kenneth Stensrud

IPC: C07D493/04

CPC classification number: C07D493/04

Abstract: A method of making a mono-ether of an isohexide and art assemblage of novel. Song-chain isohexide mono-ethers are described. In particular, the method involves reacting an isohexide stereoisomer with a Bronsted base and an alkyl species. The resultant mono-ethers can serve as attractive antecedents or chemical scaffolds for making a derivative compound, such as various amphiphiles with potential uses as surfactants, dispersants, and lubricants, among others.

Abstract translation: 制备异己烯单醚的方法和新颖的艺术组合。 宋链异构醚单醚描述。 特别地，该方法包括使异六聚物立体异构体与布朗斯台德碱和烷基物质反应。 所得单醚可用作制备衍生化合物的有吸引力的前体或化学支架，例如具有潜在用途的各种两亲物作为表面活性剂，分散剂和润滑剂等。

公开(公告)号：US20160289161A1

公开(公告)日：2016-10-06

申请号：US15177488

申请日：2016-06-09

Applicant: ARCHER DANIELS MIDLAND COMPANY

Inventor： Kenneth Stensrud ,  Mitchell Schultz ,  Padmesh VENKITASUBRAMANIAN

IPC: C07C67/10 ,  C07D307/68

CPC classification number: C07C67/10 ,  C07C67/11 ,  C07D307/68 ,  C07C69/40 ,  C07C69/675 ,  C07C69/716 ,  C07C69/704 ,  C07C69/44

Abstract: Esters and a process for making esters from organic acids by means of reacting a carboxylic acid with dialkylcarbonate in an alcohol-containing solvent without any extrinsic acid or base catalyst is described. A benefit of the preparation process is that it can make the separation and extraction of ester products simpler and more facile vis-à-vis conventional isolation techniques.

Abstract translation: 酯和通过使羧酸与碳酸二烷基酯在含醇溶剂中反应而无任何外来酸或碱催化剂从有机酸制备酯的方法。 制备过程的一个好处是它可以使酯类产品的分离和提取比传统的隔离技术更简单和更容易。

公开(公告)号：US09422258B2

公开(公告)日：2016-08-23

申请号：US14215157

申请日：2014-03-17

Applicant: ARCHER DANIELS MIDLAND COMPANY

Inventor： Paul Bloom ,  Alexandra Sanborn

IPC: C07D307/54 ,  C07D307/16 ,  C07C41/26 ,  C07C43/13 ,  C07D307/12 ,  C07D307/44 ,  C08K5/06

CPC classification number: C07D307/54 ,  C07C41/26 ,  C07C43/13 ,  C07D307/12 ,  C07D307/16 ,  C07D307/44 ,  C08K5/06 ,  C09K3/00

Abstract: Methods of making reduced derivatives of hydroxymethyl furfural using metal catalysts are described. The derivatives may have tetrahydrofuran or furan nucleus with alkoxymethyl ether or ester moieties on the 5′ carbon and methanol on the 2′ carbon. Suitable metal catalyst include Raney nickel, a nickel catalyst with a zirconium promoter, a chromite catalyst with a barium, a palladium catalyst, such as palladium on carbon, or a ruthenium catalyst. Also provided are a new class of compounds, which are n-alkoxy hexane diols (i.e., 1,2 or 1,5 hexane diol ethers) and methods of making the same by reduction of furan or tetrahydrofuran derivatives.

公开(公告)号：US09388116B2

公开(公告)日：2016-07-12

申请号：US14437750

申请日：2013-10-11

Applicant: ARCHER DANIELS MIDLAND COMPANY

Inventor： Kenneth F. Stensrud ,  Mitchell J. Schultz ,  Padmesh Venkitasubramanian

IPC: C07C67/10 ,  C07C67/11

CPC classification number: C07C67/10 ,  C07C67/11 ,  C07D307/68 ,  C07C69/40 ,  C07C69/675 ,  C07C69/716 ,  C07C69/704 ,  C07C69/44

Abstract: A process for making esters from organic acids by means of reacting a carboxylic acid with dialkylcarbonate in an alcohol-containing solvent without any extrinsic acid or base catalyst is described. A benefit of the preparation process is that it can make the separation and extraction of ester products simpler and more facile vis-a-vis conventional isolation techniques.

Abstract translation: 描述了通过使羧酸与碳酸二烷基酯在含醇溶剂中反应而不用任何外部酸或碱催化剂从有机酸制备酯的方法。 制备过程的一个好处是它可以使酯产物的分离和提取比传统的分离技术更简单和更容易。