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公开(公告)号：US06878669B2
公开(公告)日：2005-04-12
申请号：US10329236
申请日：2002-12-23
CPC分类号： B01J20/3234 , B01J20/0244 , B01J20/06 , B01J20/08 , B01J20/10 , B01J20/106 , B01J20/3078 , C10G25/003
摘要： The attrition resistance of sorbent compositions are enhanced by acid-treating the perlite component of the sorbent. The efficiency of making a promoter metal-containing sorbent composition is enhanced using a novel method for incorporating the promoter metal into the sorbent.
摘要翻译： 吸附剂组合物的耐磨性通过酸处理吸附剂的珍珠岩组分得到增强。 使用将助催化剂金属掺入吸附剂的新方法，提高了制备含助催化剂金属的吸附剂组合物的效率。
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公开(公告)号：US06864215B2
公开(公告)日：2005-03-08
申请号：US10072209
申请日：2002-02-06
IPC分类号： B01J20/06 , B01J20/02 , B01J20/08 , B01J20/10 , B01J20/16 , B01J20/30 , B01J23/80 , C10G25/00 , C10G29/04 , C10G29/16 , C10L1/08 , B01J20/00
CPC分类号： B01J20/06 , B01J20/02 , B01J20/08 , B01J20/103 , B01J20/106 , B01J20/28019 , B01J20/28042 , B01J20/3021 , B01J20/3204 , B01J20/3236 , B01J23/06 , B01J23/16 , B01J23/22 , B01J23/28 , B01J23/30 , B01J23/34 , B01J23/50 , B01J23/72 , B01J23/745 , B01J23/75 , B01J23/755 , B01J23/80 , B01J27/1853 , B01J35/023 , B01J35/026 , B01J37/0009 , B01J37/0045 , B01J37/0201 , B01J37/18 , B01J2220/42 , C10G25/003 , C10G2300/104 , C10G2300/1055 , C10G2300/202 , C10G2300/207 , C10G2300/4093 , C10G2300/703 , C10G2400/02 , C10G2400/04 , Y10S502/514 , Y10S502/517
摘要： Attrition resistant, sorbent compositions for the removal of elemental sulfur and sulfur compounds, such as hydrogen sulfide and organic sulfides, from cracked-gasoline and diesel fuels are prepared by the impregnation of a sorbent support comprising zinc oxide, expanded perlite, and alumina with a promoter such as nickel, nickel oxide or a precursor of nickel oxide followed by reduction of the valence of the promoter metal in the resulting promoter metal sorbent support composition.
摘要翻译： 通过将包含氧化锌，膨胀珍珠岩和氧化铝的吸附剂载体浸渍在包含氧化锌，膨胀珍珠岩和氧化铝的吸附剂载体上来制备用于从裂化汽油和柴油燃料中除去元素硫和硫化合物如硫化氢和有机硫化物的吸附剂组合物 促进剂如镍，氧化镍或氧化镍的前体，随后在所得助催化剂金属吸附剂载体组合物中降低助催化剂金属的价态。
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公开(公告)号：US06716338B2
公开(公告)日：2004-04-06
申请号：US10190992
申请日：2002-07-08
申请人： Rostam Madon , David H. Harris , Mingting Xu , David Stockwell , Bruce Lerner , Glenn W. Dodwell
发明人： Rostam Madon , David H. Harris , Mingting Xu , David Stockwell , Bruce Lerner , Glenn W. Dodwell
IPC分类号： B01J2908
CPC分类号： B01J37/0045 , B01J29/084 , B01J29/088 , B01J2229/42 , B01J2229/64 , C10G2300/107
摘要： A fluid catalytic cracking catalyst made from microspheres that initially contain kaolin, a dispersible boehmite alumina and a sodium silicate or silica sol binder. The kaolin portion contains hydrous kaolin and optionally spinel, or mullite, or both spinel and mullite made via kaolin which has been calcined through its characteristic exotherm. Calcination of the hydrous clay to metakaolin and formation of in-situ zeolite by treatment with sodium silicate yields a catalyst containing Y-faujasite and transforms the dispersible boehmite into a transitional alumina. The catalyst can be used to crack resid or resid-containing feeds as the alumina phase formed from the dispersible boehmite passivates nickel and vanadium contaminants.
摘要翻译： 由微球制成的流化催化裂化催化剂，其最初含有高岭土，可分散勃姆石氧化铝和硅酸钠或硅溶胶粘结剂。 高岭土部分含有水合高岭土和任选的尖晶石或莫来石，或通过其特征放热煅烧的高岭土制成的尖晶石和莫来石两者。 通过用硅酸钠处理将含水粘土煅烧成偏高岭土并形成原位沸石产生含有Y型八面沸石的催化剂，并将可分散的勃姆石转变为过渡型氧化铝。 该催化剂可用于裂解残渣或渣油进料，因为由可分散勃姆石形成的氧化铝相钝化镍和钒污染物。
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公开(公告)号：US06635795B2
公开(公告)日：2003-10-21
申请号：US10025343
申请日：2001-12-19
IPC分类号： C10G2904
CPC分类号： C10G25/12 , B01J20/06 , B01J20/3433 , B01J20/3458 , C10G25/003
摘要： While contacting under regeneration conditions an oxygen-containing stream with a sorbent comprising a promoter metal and zinc sulfide which has been sulfurized by contact with sulfur-containing hydrocarbons such as cracked-gasolines and diesel fuel, the oxygen partial pressure is controlled in a range of 0.5 to 2.0 psig to minimize sulfation of the sorbent.
摘要翻译： 当在再生条件下接触含氧流与包含助催化剂金属和硫化锌的吸附剂，其通过与含硫烃如裂化汽油和柴油燃料接触而被硫化时，将氧分压控制在 0.5至2.0psig以使吸附剂的硫酸化最小化。
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公开(公告)号：US06544410B1
公开(公告)日：2003-04-08
申请号：US10025345
申请日：2001-12-19
IPC分类号： B01J3804
CPC分类号： C10G25/12 , B01J20/0244 , B01J20/06 , B01J20/08 , B01J20/3433 , B01J20/3458 , C10G25/003
摘要： During the regeneration of a sulfurized sorbent comprising zinc aluminate, a promoter metal and zinc sulfide by contact with an oxygen-containing stream to convert at least a portion of said zinc sulfide to zinc oxide the average sulfur dioxide partial pressure in the regeneration zone is controlled within the range of from about 0.1 to about 10 psig to minimize sulfation of the sorbent.
摘要翻译： 在通过与含氧流接触以将至少一部分所述硫化锌转化为氧化锌的含铝酸锌，助催化剂金属和硫化锌的硫化吸附剂的再生期间，控制再生区中的平均二氧化硫分压 在约0.1至约10psig的范围内，以使吸附剂的硫酸化最小化。
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56.发明授权Removal of heavy metals, especially lead, from aqueous systems containing competing ions utilizing amorphous tin and titanium silicates 失效从含有竞争离子的含水体系中去除重金属，特别是铅，利用无定形锡和硅酸钛
公开(公告)号：US5053139A
公开(公告)日：1991-10-01
申请号：US625731
申请日：1990-12-04
申请人： Glenn W. Dodwell , BethAnn Smith
发明人： Glenn W. Dodwell , BethAnn Smith
CPC分类号： C01B33/20 , B01J39/14 , C22B3/24 , C22B3/42 , Y02P10/234 , Y10S210/912 , Y10S210/913 , Y10S210/914
摘要： A process for the removal of heavy metals such as lead, cadmium, zinc, chromium, arsenic and mercury from aqueous solutions containing one or more of said metals as well as competing ions such as calcium and/or magnesium by contacting said aqueous solution with amorphous titanium or tin silicates is disclosed. Said amorphous titanium and tin silicates are characterized by a silicon-to-titanium or tin molar ratio of from 1:4 to 1.9:1 and a cumulative desorption pore volume ranging from about 0.03 to about 0.25 cubic centimeters per gram.
摘要翻译： 从含有一种或多种所述金属的水溶液以及竞争离子如钙和/或镁中除去重金属如铅，镉，锌，铬，砷和汞的方法，通过使所述水溶液与无定形的 公开了钛或硅酸锡。 所述无定形钛和硅酸锡的特征在于硅与钛或锡的摩尔比为1:4至1.9:1，累积解吸孔体积为约0.03至约0.25立方厘米/克。
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