公开(公告)号：US07087266B2

公开(公告)日：2006-08-08

申请号：US10710112

申请日：2004-06-18

申请人： Ramgopal Darolia ,  Boris A. Movchan ,  Yuriy E. Rudoy ,  Leonella M. Nerodenko ,  Irene Spitsberg ,  David John Wortman

发明人： Ramgopal Darolia ,  Boris A. Movchan ,  Yuriy E. Rudoy ,  Leonella M. Nerodenko ,  Irene Spitsberg ,  David John Wortman

IPC分类号： C23C16/32 ,  C23C16/40

CPC分类号： C23C28/3215 ,  C23C14/06 ,  C23C28/321 ,  C23C28/345 ,  C23C28/3455 ,  C23C30/00 ,  F01D5/288 ,  F05D2300/15 ,  Y10T428/249954 ,  Y10T428/249956 ,  Y10T428/249957 ,  Y10T428/249976 ,  Y10T428/24999

摘要： A thermal barrier coating, or TBC, and method for forming the TBC. The TBC is formed of a thermal-insulating material that contains yttria-stabilized zirconia (YSZ) alloyed with at least a third oxide. The TBC is formed to also contain elemental carbon, and may potentially contain carbides and/or a carbon-containing gas that forms from the thermal decomposition of carbon. The TBC is characterized by lower density and thermal conductivity, high temperature stability and improved mechanical properties. To exhibit the desired effect, the third oxide is more particularly one that increases the lattice strain energy of the TBC microstructure as a result of having an ion size that is sufficiently different than a zirconium ion.

摘要翻译： 热障涂层或TBC，以及形成TBC的方法。 TBC由含有与至少第三氧化物合金的氧化钇稳定的氧化锆（YSZ）的绝热材料形成。 TBC形成也含有元素碳，并且可能含有从碳的热分解形成的碳化物和/或含碳气体。 TBC具有较低的密度和导热性，高温稳定性和改善的机械性能。 为了表现出期望的效果，由于具有与锆离子充分不同的离子尺寸的结果，第三氧化物更特别地增加了TBC微结构的晶格应变能。

公开(公告)号：US20050129869A1

公开(公告)日：2005-06-16

申请号：US10735369

申请日：2003-12-12

申请人： John Ackerman ,  Venkat Venkataramani ,  Irene Spitsberg ,  Brett Boutwell ,  Ramgopal Darolia

发明人： John Ackerman ,  Venkat Venkataramani ,  Irene Spitsberg ,  Brett Boutwell ,  Ramgopal Darolia

IPC分类号： C23C28/00 ,  F01D5/28 ,  C23C16/00 ,  B05D1/08

CPC分类号： C23C28/3215 ,  C23C28/321 ,  C23C28/325 ,  C23C28/345 ,  C23C28/3455

摘要： A protected article is prepared by providing the article, depositing a bond coat onto an exposed surface of the article, and producing a thermal barrier coating on an exposed surface of the bond coat. The step of producing the thermal barrier coating includes the steps of depositing a primary ceramic coating onto an exposed surface of the bond coat, and depositing a stabilization composition onto an exposed surface of the primary ceramic coating. The stabilization composition includes a first element selected from Group 2 or Group 3 of the periodic table, and a second element selected from Group 5 of the periodic table. The atomic ratio of the amount of the first element to the amount of the second element is at least 1:3, more preferably at least 1:1.

摘要翻译： 通过提供制品来制备受保护制品，将粘合涂层沉积在制品的暴露表面上，并在粘合涂层的暴露表面上产生热障涂层。 生产热障涂层的步骤包括以下步骤：将初级陶瓷涂层沉积在粘合涂层的暴露表面上，并将稳定化组合物沉积到初级陶瓷涂层的暴露表面上。 稳定化组合物包括选自元素周期表第2族或第3族的第一元素和选自元素周期表第5族的第二元素。 第一元素的量与第二元素的量的原子比为至少1:3，更优选至少1:1。

公开(公告)号：US06565672B2

公开(公告)日：2003-05-20

申请号：US09944706

申请日：2001-08-31

申请人： Irene Spitsberg ,  Ramgopal Darolia

发明人： Irene Spitsberg ,  Ramgopal Darolia

IPC分类号： C23C880

CPC分类号： C23C28/321 ,  C21D7/06 ,  C22F1/10 ,  C23C8/02 ,  C23C8/80 ,  C23C28/325 ,  C23C28/345 ,  C23C28/3455 ,  Y10T428/12549

摘要： An article protected by a protective coating system is fabricated by providing an article substrate having a substrate surface; and thereafter producing a protective coating having a flattened, pre-oxidized protective-coating surface on the substrate surface by depositing a protective coating on the substrate surface, the protective coating having a protective-coating surface, processing the protective coating to achieve a flattened protective-coating surface, and controllably oxidizing the protective-coating surface. A thermal barrier coating may be deposited overlying the flattened, pre-oxidized protective coating.

摘要翻译： 通过提供具有基底表面的制品基底来制造由保护涂层系统保护的物品; 然后通过在基板表面上沉积保护涂层，在基板表面上产生具有平坦的，预氧化的保护涂层表面的保护涂层，保护涂层具有保护涂层表面，加工保护涂层以实现平坦的保护 涂层表面，并可控地氧化保护涂层表面。 可以将平整的预氧化保护涂层覆盖在隔热层上。

公开(公告)号：US20050142395A1

公开(公告)日：2005-06-30

申请号：US10748520

申请日：2003-12-30

申请人： Irene Spitsberg ,  Venkat Venkataramani ,  Brett Boutwell ,  Mark Gorman ,  Robert Bruce

发明人： Irene Spitsberg ,  Venkat Venkataramani ,  Brett Boutwell ,  Mark Gorman ,  Robert Bruce

IPC分类号： C04B35/48 ,  C04B35/486 ,  C04B35/66 ,  C23C4/02 ,  C23C4/10 ,  C23C14/08 ,  C23C28/00 ,  C23C30/00 ,  F01D5/28 ,  F01D25/00 ,  F02C7/00 ,  F23R3/42 ,  B32B9/00 ,  C23C16/00

CPC分类号： C04B35/486 ,  C04B2235/3206 ,  C04B2235/3208 ,  C04B2235/3224 ,  C04B2235/3225 ,  C04B2235/3227 ,  C04B2235/3229 ,  C04B2235/3244 ,  C04B2235/3286 ,  C04B2235/9607 ,  C23C4/02 ,  C23C4/11 ,  C23C14/08 ,  C23C14/083 ,  C23C28/042 ,  C23C28/321 ,  C23C28/3215 ,  C23C28/325 ,  C23C28/345 ,  C23C28/3455 ,  C23C30/00 ,  F01D5/288 ,  F05D2230/90 ,  F05D2300/2118 ,  F05D2300/611 ,  Y10T428/12611 ,  Y10T428/12618 ,  Y10T428/265

摘要： Ceramic compositions comprising at least about 91 mole % zirconia and up to about 9 mole % of a stabilizer component comprising a first metal oxide having selected from the group consisting of yttria, calcia, ceria, scandia, magnesia, india and mixtures thereof. This stabilizer component further comprises a second metal oxide of a trivalent metal atom selected from the group consisting of lanthana, gadolinia, neodymia, samaria, dysprosia, erbia, ytterbia, and mixtures thereof. These ceramic compositions are useful in preparing thermal barrier coatings having reduced thermal conductivity for the metal substrate of articles that operate at, or are exposed to, high temperatures.

摘要翻译： 包含至少约91摩尔％氧化锆和至多约9摩尔％的稳定剂组分的陶瓷组合物，其包含选自氧化钇，氧化钙，二氧化铈，钪，氧化镁，印度的第一金属氧化物及其混合物。 该稳定剂组分还包含选自氧化镧，氧化钆，钕，麝香，恶臭，er虫，bia bia的三价金属原子的第二金属氧化物及其混合物。 这些陶瓷组合物可用于制备在高温下操作或暴露于其中的制品的金属基材具有降低的热导率的热障涂层。

公开(公告)号：US20050142392A1

公开(公告)日：2005-06-30

申请号：US10748508

申请日：2003-12-30

申请人： Irene Spitsberg ,  Venkat Venkataramani ,  Brett Boutwell ,  Mark Gorman

发明人： Irene Spitsberg ,  Venkat Venkataramani ,  Brett Boutwell ,  Mark Gorman

IPC分类号： C04B35/48 ,  C04B35/486 ,  C04B35/66 ,  C04B37/02 ,  C23C4/08 ,  C23C4/10 ,  C23C14/08 ,  C23C28/00 ,  C23C30/00 ,  F01D5/28 ,  F02C7/00 ,  B32B9/00 ,  C23C16/00

CPC分类号： F01D5/288 ,  C04B35/486 ,  C04B2235/3206 ,  C04B2235/3208 ,  C04B2235/3224 ,  C04B2235/3225 ,  C04B2235/3229 ,  C04B2235/3244 ,  C04B2235/9607 ,  C23C14/08 ,  C23C14/083 ,  C23C28/321 ,  C23C28/3215 ,  C23C28/3455 ,  C23C30/00 ,  F05D2230/90 ,  F05D2300/2116 ,  F05D2300/611 ,  Y10T428/12611 ,  Y10T428/12618 ,  Y10T428/26 ,  Y10T428/265

摘要： Ceramic compositions comprising at least about 91 mole % zirconia and up to about 9 mole % of a stabilizer component comprising a first metal oxide having selected from the group consisting of yttria, calcia, ceria, scandia, magnesia, india and mixtures thereof. This stabilizer component further comprises a second metal oxide of a trivalent metal atom selected from the group consisting of lanthana, gadolinia, neodymia, samaria, dysprosium, and mixtures thereof and a third metal oxide of a trivalent metal atom selected from the group consisting of erbia, ytterbia and mixtures thereof. These ceramic compositions are useful in preparing thermal barrier coatings having reduced thermal conductivity for the metal substrate of articles that operate at, or are exposed to, high temperatures.

公开(公告)号：US20060280926A1

公开(公告)日：2006-12-14

申请号：US11160164

申请日：2005-06-10

申请人： Irene Spitsberg ,  Brett Boutwell ,  Robert Bruce ,  Curtis Johnson ,  Bangalore Nagaraj ,  William Walston

发明人： Irene Spitsberg ,  Brett Boutwell ,  Robert Bruce ,  Curtis Johnson ,  Bangalore Nagaraj ,  William Walston

IPC分类号： B32B3/26 ,  B32B3/06

CPC分类号： C23C28/321 ,  C23C28/3215 ,  C23C28/325 ,  C23C28/345 ,  C23C28/3455 ,  Y10T428/249953 ,  Y10T428/249955

摘要： A thermal barrier coating and deposition process for a component intended for use in a hostile thermal environment, such as the turbine, combustor and augmentor components of a gas turbine engine. The TBC has a first coating portion on at least a first surface portion of the component. The first coating portion is formed of a ceramic material to have at least an inner region, at least an outer region overlying the inner region, and a columnar microstructure whereby the inner and outer regions comprise columns of the ceramic material. The columns of the inner region are more closely spaced than the columns of the outer region so that the inner region of the first coating portion is denser than the outer region of the first coating portion, wherein the higher density of the inner region promotes the impact resistance of the first coating portion.

摘要翻译： 用于在敌对热环境中使用的部件的热障涂层和沉积工艺，例如燃气轮机的涡轮机，燃烧器和增压器部件。 所述TBC在所述部件的至少第一表面部分上具有第一涂覆部分。 第一涂覆部分由陶瓷材料形成，至少具有内部区域，至少覆盖内部区域的外部区域和柱状微结构，由此内部和外部区域包括陶瓷材料的列。 内部区域的列与外部区域的列紧密地间隔开，使得第一涂覆部分的内部区域比第一涂覆部分的外部区域更致密，其中内部区域的较高密度促进了冲击 第一涂布部分的电阻。

公开(公告)号：US20140072469A1

公开(公告)日：2014-03-13

申请号：US13607899

申请日：2012-09-10

申请人： Elizabeth Ann Binky Sargent ,  Sudhir Brahmandam ,  Christopher D. Dunn ,  Irene Spitsberg ,  Michael James Verti ,  William Roy Huston

发明人： Elizabeth Ann Binky Sargent ,  Sudhir Brahmandam ,  Christopher D. Dunn ,  Irene Spitsberg ,  Michael James Verti ,  William Roy Huston

IPC分类号： B32B15/02 ,  B29C33/00 ,  B22F3/12

CPC分类号： C04B35/638 ,  B22F2998/10 ,  C04B35/5626 ,  C04B2235/3839 ,  C04B2235/404 ,  C04B2235/72 ,  C04B2235/77 ,  C04B2235/96 ,  C22C29/08 ,  B22F3/02 ,  B22F3/1021

摘要： In one aspect, tungsten carbide material systems are described herein which, in some embodiments, can provide desirable characteristics including chemical inertness, high hardness, reduced sensitivity to local compositional fluctuations and/or enhanced machining properties. In some embodiments, a tungsten carbide material described herein comprises 5.85-6.13 wt. % carbon, 0.85-1.05 wt. % chromium, less than 0.3 wt. % binder, less than 0.3 wt. % impurities and a balance being tungsten.

摘要翻译： 在一个方面，本文描述了碳化钨材料体系，其在一些实施方案中可以提供期望的特性，包括化学惰性，高硬度，对局部组成波动的敏感性降低和/或增强的机械性能。 在一些实施方案中，本文所述的碳化钨材料包含5.85-6.13重量％ ％碳，0.85-1.05重量％ ％铬，小于0.3wt。 ％粘合剂，小于0.3wt。 ％杂质，余量为钨。

公开(公告)号：US07910173B2

公开(公告)日：2011-03-22

申请号：US12183665

申请日：2008-07-31

申请人： Irene Spitsberg ,  Brett Allen Rohrer Boutwell ,  Robert William Bruce ,  Curtis Alan Johnson ,  Bangalore Aswatha Nagaraj ,  William Scott Walston ,  Rudolfo Viguie ,  Joshua Leigh Miller ,  Roger Dale Wustman

发明人： Irene Spitsberg ,  Brett Allen Rohrer Boutwell ,  Robert William Bruce ,  Curtis Alan Johnson ,  Bangalore Aswatha Nagaraj ,  William Scott Walston ,  Rudolfo Viguie ,  Joshua Leigh Miller ,  Roger Dale Wustman

IPC分类号： B05D5/00 ,  B05D1/36 ,  C23C26/00 ,  B32B9/00

CPC分类号： C23C28/321 ,  C23C28/3215 ,  C23C28/325 ,  C23C28/345 ,  C23C28/3455 ,  Y10T428/249953 ,  Y10T428/249955

摘要： A thermal barrier coating and deposition process for a component intended for use in a hostile thermal environment, such as the turbine, combustor and augmentor components of a gas turbine engine. The TBC has a first coating portion on at least a first surface portion of the component. The first coating portion is formed of a ceramic material to have at least an inner region, at least an outer region overlying the inner region, and a columnar microstructure whereby the inner and outer regions comprise columns of the ceramic material. The columns of the inner region are more closely spaced than the columns of the outer region so that the inner region of the first coating portion is denser than the outer region of the first coating portion, wherein the higher density of the inner region promotes the impact resistance of the first coating portion.

摘要翻译： 用于在敌对热环境中使用的部件的热障涂层和沉积工艺，例如燃气轮机的涡轮机，燃烧器和增压器部件。 所述TBC在所述部件的至少第一表面部分上具有第一涂覆部分。 第一涂覆部分由陶瓷材料形成，至少具有内部区域，至少覆盖内部区域的外部区域和柱状微结构，由此内部和外部区域包括陶瓷材料的列。 内部区域的列与外部区域的列紧密地间隔开，使得第一涂覆部分的内部区域比第一涂覆部分的外部区域更致密，其中内部区域的较高密度促进了冲击 第一涂布部分的电阻。

公开(公告)号：US07867575B2

公开(公告)日：2011-01-11

申请号：US11977336

申请日：2007-10-23

申请人： Brett Allen Rohrer Boutwell ,  Irene Spitsberg ,  Christine Govern ,  Bangalore A. Nagaraj ,  Brian Thomas Hazel

发明人： Brett Allen Rohrer Boutwell ,  Irene Spitsberg ,  Christine Govern ,  Bangalore A. Nagaraj ,  Brian Thomas Hazel

IPC分类号： B05D5/00 ,  B32B15/04 ,  B32B15/00

CPC分类号： C04B41/009 ,  C04B41/52 ,  C04B41/89 ,  C23C28/042 ,  F01D5/288 ,  F05D2230/90 ,  F05D2300/2118 ,  F05D2300/50211 ,  F05D2300/611 ,  C04B41/4527 ,  C04B41/5096 ,  C04B41/5024 ,  C04B41/5037 ,  C04B41/5042 ,  C04B41/5031 ,  C04B41/522 ,  C04B41/4529 ,  C04B35/565 ,  C04B35/584 ,  C04B35/806 ,  C04B35/597

摘要： A method for producing a thermal barrier coating/environmental barrier coating system on a silicon containing material substrate includes applying an environmental barrier coating (EBC) over the silicon containing material substrate; and applying a thermal barrier coating (TBC) over the EBC. The thermal barrier coating includes a compound having a primary constituent portion and a stabilizer portion stabilizing said primary constituent. The primary constituent portion of the thermal barrier coating includes hafnia present in an amount of at least about 5 mol % of the primary constituent and the stabilizer portion of said thermal barrier coating includes at least one metal oxide comprised of cations with a +2 or +3 valence present in the amount of about 10 to about 40 mol % of the thermal barrier coating.

摘要翻译： 在含硅材料基板上制造隔热涂层/环境阻挡涂层系统的方法包括在含硅材料基材上施加环境阻挡涂层（EBC）; 并在EBC上施加热障涂层（TBC）。 热障涂层包括具有主要构成部分和稳定所述主要成分的稳定剂部分的化合物。 热障涂层的主要构成部分包括以主要成分的至少约5mol％的量存在的铪，并且所述热障涂层的稳定剂部分包括至少一种由阳离子组成的金属氧化物，所述阳离子具有+2或+ 3价以约10至约40摩尔％的量存在于热障涂层中。

公开(公告)号：US07407718B2

公开(公告)日：2008-08-05

申请号：US11160185

申请日：2005-06-13

申请人： Brian Thomas Hazel ,  Irene Spitsberg ,  Christine Govern ,  Bangalore Aswatha Nagaraj

发明人： Brian Thomas Hazel ,  Irene Spitsberg ,  Christine Govern ,  Bangalore Aswatha Nagaraj

IPC分类号： B32B9/00

CPC分类号： C23C28/04 ,  C04B41/009 ,  C04B41/52 ,  C04B41/89 ,  F01D5/284 ,  F01D5/288 ,  Y10T428/12576 ,  C04B41/4527 ,  C04B41/5096 ,  C04B41/5037 ,  C04B41/5024 ,  C04B41/5031 ,  C04B41/5044 ,  C04B41/5042 ,  C04B41/4529 ,  C04B41/522 ,  C04B35/565 ,  C04B35/584 ,  C04B35/806

摘要： A coating system for Si-containing materials, particularly Si-based composites used to produce articles exposed to high temperatures. The coating system is a compositionally-graded thermal/environmental barrier coating (T/EBC) system that includes an intermediate layer containing yttria-stabilized hafnia (YSHf) and mullite, alumina and/or an aluminosilicate, which is used in combination with an inner layer between a Si-containing substrate and the intermediate layer and a thermal-insulating top coat overlying the intermediate layer. The intermediate layer provides environmental protection to the silicon-containing substrate, and has a coefficient of thermal expansion between that of the top coat and that of the inner layer so as to serve as a transition layer therebetween. The intermediate layer is particular well suited for use in combination with an inner layer of an alkaline earth metal aluminosilicate (such as BSAS) and a top coat formed of YSZ or YSHf.

摘要翻译： 用于含Si材料的涂层系统，特别是用于生产暴露于高温的制品的Si基复合材料。 涂层系统是一种组成分级的热/环境屏障涂层（T / EBC）系统，其包括含有氧化钇稳定的铪（YSHf）和莫来石，氧化铝和/或铝硅酸盐的中间层，其与内部 在含Si衬底和中间层之间的层和覆盖中间层的绝热顶涂层。 中间层为含硅基材提供环境保护，并且具有顶涂层与内层层之间的热膨胀系数，以便在其间作为过渡层。 中间层特别适用于与碱土金属硅铝酸盐（如BSAS）的内层和由YSZ或YSHf形成的顶层组合使用。