公开(公告)号：US09428302B2

公开(公告)日：2016-08-30

申请号：US14057697

申请日：2013-10-18

Applicant: Corning Incorporated

Inventor： Andrei Gennadyevich Fadeev ,  Theresa Chang ,  Dana Craig Bookbinder ,  Santona Pal ,  Chandan Kumar Saha ,  Steven Edward DeMartino ,  Christopher Lee Timmons ,  John Stephen Peanasky ,  Robert Anthony Schaut ,  Paul Stephen Danielson ,  Melinda Ann Drake ,  Robert Michael Morena ,  Kaveh Adib ,  James Patrick Hamilton ,  Susan Lee Schiefelbein

IPC: B28B11/00 ,  B28B21/00 ,  A47G19/22 ,  B65D23/08 ,  B32B17/06 ,  B65D1/40 ,  B65D25/14 ,  C03C17/00 ,  C03C17/30 ,  C03C17/32 ,  C03C17/42 ,  C03C21/00 ,  C08G73/10 ,  C09D179/08

CPC classification number: B65D23/0814 ,  A61J1/1468 ,  B32B17/06 ,  B65D1/40 ,  B65D25/14 ,  C03C3/087 ,  C03C17/005 ,  C03C17/30 ,  C03C17/32 ,  C03C17/3405 ,  C03C17/42 ,  C03C21/002 ,  C03C2217/78 ,  C03C2218/111 ,  C08G73/105 ,  C08G73/1071 ,  C09D179/08 ,  C08K5/544

Abstract: Delamination resistant glass containers with heat-tolerant coatings are disclosed. In one embodiment, a glass container may include a glass body having an interior surface, an exterior surface and a wall thickness extending from the exterior surface to the interior surface. At least the interior surface of the glass body is delamination resistant. The glass container may further include a heat-tolerant coating positioned on at least a portion of the exterior surface of the glass body. The heat-tolerant coating may be thermally stable at temperatures greater than or equal to 260° C. for 30 minutes.

Abstract translation: 公开了具有耐热涂层的耐剥落玻璃容器。 在一个实施例中，玻璃容器可以包括具有内表面，外表面和从外表面延伸到内表面的壁厚的玻璃体。 至少玻璃体的内表面具有防分层性。 玻璃容器还可以包括位于玻璃体的外表面的至少一部分上的耐热涂层。 耐热涂层可以在大于或等于260℃的温度下热稳定30分钟。

公开(公告)号：US09340447B2

公开(公告)日：2016-05-17

申请号：US14701185

申请日：2015-04-30

Applicant: Corning Incorporated

Inventor： Paul Stephen Danielson ,  Steven Edward DeMartino ,  Melinda Ann Drake ,  Robert Michael Morena ,  Santona Pal ,  Robert Anthony Schaut

IPC: C03C3/087 ,  C03C21/00 ,  C03C4/20 ,  C03C3/091 ,  C03C4/18

CPC classification number: C03C3/091 ,  A61J1/00 ,  C03C3/087 ,  C03C4/18 ,  C03C4/20 ,  C03C21/002 ,  C03C2204/00 ,  Y10T428/131 ,  Y10T428/1317 ,  Y10T428/26 ,  Y10T428/315

Abstract: The embodiments described herein relate to chemically and mechanically durable glass compositions and pharmaceutical packaging formed from the same. According to one embodiment, a glass for pharmaceutical packaging includes from about 70 mol. % to about 80 mol. % SiO2; from about 4 mol. % to about 8 mol. % alkaline earth oxide, the alkaline earth oxide comprising MgO and CaO; X mol. % Al2O3, wherein X is from about 4 to about 8; and Y mol. % alkali oxide comprising non-zero amounts of Na2O and K2O, wherein Y is about 9-15 mol. % and a ratio of Y:X is greater than 1.

Abstract translation: 本文所述的实施方案涉及由其形成的化学和机械耐久的玻璃组合物和药物包装。 根据一个实施方案，用于药物包装的玻璃包括约70mol。 ％至约80mol。 ％SiO2; 约4mol。 ％至约8mol。 碱土金属氧化物，碱土金属氧化物包含MgO和CaO; X mol。 ％Al 2 O 3，其中X为约4至约8; 和Y mol。 包含非零量Na 2 O和K 2 O的碱金属氧化物，其中Y为约9-15mol。 ％，Y：X的比例大于1。

公开(公告)号：US20150329416A1

公开(公告)日：2015-11-19

申请号：US14812902

申请日：2015-07-29

Applicant: CORNING INCORPORATED

Inventor： Andrei Gennadyevich Fadeev ,  Theresa Chang ,  Dana Craig Bookbinder ,  Santona Pal ,  Chandan Kumar Saha ,  Steven Edward DeMartino ,  Christopher Lee Timmons ,  John Stephen Peanasky

IPC: C03C17/30 ,  A61J1/00 ,  C03C17/32 ,  B65D65/42 ,  C03C17/00 ,  C03C17/42

CPC classification number: A61J1/1468 ,  A61J1/00 ,  B65D23/0814 ,  B65D23/0821 ,  B65D25/14 ,  B65D25/34 ,  B65D65/42 ,  C03C17/005 ,  C03C17/30 ,  C03C17/32 ,  C03C17/42 ,  C03C21/002 ,  C03C2217/78 ,  C03C2218/111 ,  C09D179/08 ,  Y10T428/1321 ,  Y10T428/24942

Abstract: Coated pharmaceutical packages are disclosed. In embodiments, a coated pharmaceutical package includes a glass body comprising a first surface. A low-friction coating may be positioned on at least a portion of the first surface of the glass body. The low-friction coating may include a polymer chemical composition. A light transmission through the coated pharmaceutical package may be greater than or equal to about 55% of a light transmission through an uncoated pharmaceutical package for wavelengths from about 400 nm to about 700 nm. The low-friction coating may have a mass loss of less than about 5% of its mass when heated from a temperature of 150° C. to 350° C. at a ramp rate of about 10° C./minute.

Abstract translation: 公开了涂覆的药物包装。 在实施方案中，涂覆的药物包装包括包含第一表面的玻璃体。 低摩擦涂层可以位于玻璃体的第一表面的至少一部分上。 低摩擦涂层可以包括聚合物化学组成。 通过涂覆的药物包装的透光率可以大于或等于通过用于波长为约400nm至约700nm的未涂覆药物包装的透光率的约55％。 当以约10℃/分钟的升温速度从150℃升温至350℃时，低摩擦涂层的质量损失小于其质量的约5％。

公开(公告)号：US20150079318A1

公开(公告)日：2015-03-19

申请号：US14551773

申请日：2014-11-24

Applicant: Corning Incorporated

Inventor： Paul Stephen Danielson ,  Steven Edward DeMartino ,  Melinda Ann Drake ,  Robert Michael Morena ,  Santona Pal ,  Robert Anthony Schaut

IPC: C03C3/087 ,  C03C4/18 ,  A61J1/00 ,  C03C4/20

CPC classification number: C03C3/091 ,  A61J1/00 ,  C03C3/087 ,  C03C4/18 ,  C03C4/20 ,  C03C21/002 ,  C03C2204/00 ,  Y10T428/131 ,  Y10T428/1317 ,  Y10T428/26 ,  Y10T428/315

Abstract: The embodiments described herein relate to chemically and mechanically durable glass compositions and glass articles formed from the same. In another embodiment, a glass composition may include from about 70 mol. % to about 80 mol. % SiO2; from about 3 mol. % to about 13 mol. % alkaline earth oxide; X mol. % Al2O3; and Y mol. % alkali oxide. The alkali oxide may include Na2O in an amount greater than about 8 mol. %. A ratio of Y:X may be greater than 1 and the glass composition may be free of boron and compounds of boron. In some embodiments, the glass composition may also be free of phosphorous and compounds of phosphorous. Glass articles formed from the glass composition may have at least a class S3 acid resistance according to DIN 12116, at least a class A2 base resistance according to ISO 695, and a type HGA1 hydrolytic resistance according to ISO 720.

Abstract translation: 本文所述的实施方案涉及由其形成的化学和机械耐久的玻璃组合物和玻璃制品。 在另一个实施方案中，玻璃组合物可以包含约70mol。 ％至约80mol。 ％SiO2; 约3mol。 ％至约13mol。 ％碱土金属氧化物; X mol。 ％Al2O3; 和Y mol。 ％碱金属氧化物。 碱金属氧化物可以包括大于约8mol的量的Na 2 O。 ％。 Y：X的比例可以大于1，玻璃组合物可以不含硼和硼化合物。 在一些实施方案中，玻璃组合物还可以不含磷和磷的化合物。 由玻璃组合物形成的玻璃制品可以具有根据DIN 12116的至少S3级耐酸性，至少根据ISO 695的A2级耐碱性和根据ISO 720的HGA1型耐水解性。

公开(公告)号：US20140151371A1

公开(公告)日：2014-06-05

申请号：US14075605

申请日：2013-11-08

Applicant: Corning Incorporated

Inventor： Theresa Chang ,  Paul Stephen Danielson ,  Steven Edward DeMartino ,  Andrei Gennadyevich Fadeev ,  Robert Michael Morena ,  Santona Pal ,  John Stephen Peanasky ,  Robert Anthony Schaut ,  Natesan Venkataraman ,  Ronald Luce Verkleeran

IPC: B65D25/34

CPC classification number: C03C17/42 ,  A61J1/1468 ,  B32B17/06 ,  B65D1/0207 ,  B65D1/0215 ,  B65D1/40 ,  B65D23/02 ,  B65D23/0814 ,  B65D23/0821 ,  B65D25/14 ,  B65D25/34 ,  B65D65/42 ,  C03C15/02 ,  C03C17/00 ,  C03C17/005 ,  C03C17/30 ,  C03C17/32 ,  C03C17/3405 ,  C03C21/002 ,  C03C2217/78 ,  C03C2218/111 ,  C09D179/08 ,  Y10T428/13 ,  Y10T428/131 ,  Y10T428/1317 ,  Y10T428/315

Abstract: The glass containers described herein have at least two performance attributes selected from resistance to delamination, improved strength, and increased damage resistance. In one embodiment, a glass container with resistance to delamination and improved strength may include a body having an inner surface, an outer surface and a wall thickness extending between the outer surface and the inner surface. At least the inner surface of the body may have a delamination factor less than or equal to 10. The glass container may further include a compressively stressed layer extending from the outer surface of the body into the wall thickness. The compressively stressed layer may have a surface compressive stress greater than or equal to 150 MPa.

Abstract translation: 本文所述的玻璃容器具有至少两种性能属性，其选自抗分层，改善的强度和增加的耐损伤性。 在一个实施例中，具有耐分层性和改善强度的玻璃容器可以包括具有内表面，外表面和在外表面和内表面之间延伸的壁厚的主体。 至少本体的内表面可以具有小于或等于10的分层因子。玻璃容器还可以包括从主体的外表面延伸到壁厚的压缩应力层。 压应力层可具有大于或等于150MPa的表面压应力。

公开(公告)号：US20130344263A1

公开(公告)日：2013-12-26

申请号：US14011376

申请日：2013-08-27

Applicant: Corning Incorporated

Inventor： Paul Stephen Danielson ,  Steven Edward DeMartino ,  Melinda Ann Drake ,  Robert Michael Morena ,  Santona Pal ,  Robert Anthony Schaut

IPC: C03C4/20 ,  C03C3/087

CPC classification number: C03C3/091 ,  A61J1/00 ,  C03C3/087 ,  C03C4/18 ,  C03C4/20 ,  C03C21/002 ,  C03C2204/00 ,  Y10T428/131 ,  Y10T428/1317 ,  Y10T428/26 ,  Y10T428/315

Abstract: The embodiments described herein relate to chemically and mechanically durable glass compositions and glass articles formed from the same. In another embodiment, a glass composition may include from about 70 mol. % to about 80 mol. % SiO2; from about 3 mol. % to about 13 mol. % alkaline earth oxide; X mol. % Al2O3; and Y mol. % alkali oxide. The alkali oxide may include Na2O in an amount greater than about 8 mol. %. A ratio of Y:X may be greater than 1 and the glass composition may be free of boron and compounds of boron. In some embodiments, the glass composition may also be free of phosphorous and compounds of phosphorous. Glass articles formed from the glass composition may have at least a class S3 acid resistance according to DIN 12116, at least a class A2 base resistance according to ISO 695, and a type HGA1 hydrolytic resistance according to ISO 720.

公开(公告)号：US20240225956A1

公开(公告)日：2024-07-11

申请号：US18612447

申请日：2024-03-21

Applicant: Corning Incorporated

Inventor： Theresa Chang ,  Paul Stephen Danielson ,  Steven Edward DeMartino ,  Andrei Gennadyevich Fadeev ,  Robert Michael Morena ,  Santona Pal ,  John Stephen Peanasky ,  Robert Anthony Schaut ,  Christopher Lee Timmons ,  Natesan Venkataraman ,  Ronald Luce Verkleeren ,  Dana Craig Bookbinder

IPC: A61J1/14 ,  A61J1/06 ,  B32B17/06 ,  B65D1/02 ,  B65D1/40 ,  B65D23/02 ,  B65D23/08 ,  B65D25/14 ,  B65D25/34 ,  B65D65/42 ,  C03B23/04 ,  C03C15/02 ,  C03C17/00 ,  C03C17/22 ,  C03C17/30 ,  C03C17/32 ,  C03C17/34 ,  C03C17/42 ,  C03C21/00 ,  C09D179/08

CPC classification number: A61J1/1468 ,  A61J1/065 ,  B32B17/06 ,  B65D1/0207 ,  B65D1/0215 ,  B65D1/40 ,  B65D23/02 ,  B65D23/0814 ,  B65D23/0821 ,  B65D25/14 ,  B65D25/34 ,  B65D65/42 ,  C03B23/04 ,  C03C15/02 ,  C03C17/005 ,  C03C17/22 ,  C03C17/30 ,  C03C17/32 ,  C03C17/3405 ,  C03C17/42 ,  C03C21/002 ,  C09D179/08 ,  C03C2217/78 ,  C03C2218/111 ,  Y10T428/13 ,  Y10T428/131 ,  Y10T428/1317 ,  Y10T428/24802 ,  Y10T428/315

Abstract: A glass container for storing pharmaceutical formulations may include a glass body formed from a Type IA or Type IB glass composition according to ASTM Standard E438-92(2011). The glass body may include a wall portion with an inner surface and an outer surface, a heel portion and a floor portion, wherein the inner surface of the glass container is formed by the inner surface of the glass body. The glass body may include at least a class A2 base resistance or better according to ISO 695, at least a type HGB2 hydrolytic resistance or better according to ISO 719 and Type 1 chemical durability according to USP . The glass container does not comprise a boron-rich layer on the inner surface of the glass body in as formed condition.

公开(公告)号：US20240158293A1

公开(公告)日：2024-05-16

申请号：US18418471

申请日：2024-01-22

Applicant: CORNING INCORPORATED

Inventor： Kaveh Adib ,  Guangli Hu ,  William Joseph Hurley ,  Dana Ianson ,  Lin Lin ,  Santona Pal ,  James Joseph Price

IPC: C03C17/245 ,  C03C3/091 ,  C03C3/097 ,  C03C17/22

CPC classification number: C03C17/245 ,  C03C3/091 ,  C03C3/097 ,  C03C17/225 ,  C03C2217/281 ,  C03C2217/29 ,  C03C2217/78 ,  C03C2217/91 ,  C03C2218/155

Abstract: An article is described herein that includes: a substrate having a glass, glass-ceramic or a ceramic composition and comprising a primary surface; and a protective film disposed on the primary surface. The protective film comprises a thickness of greater than 1.5 microns and a maximum hardness of greater than 15 GPa at a depth of 500 nanometers, as measured on the film disposed on the substrate. Further, the protective film comprises a metal oxynitride that is graded such that an oxygen concentration in the film varies by 1.3 or more atomic %. In addition, the substrate comprises an elastic modulus less than an elastic modulus of the film.

公开(公告)号：US11939259B2

公开(公告)日：2024-03-26

申请号：US16925297

申请日：2020-07-09

Applicant: CORNING INCORPORATED

Inventor： John Frederick Bayne ,  Dana Craig Bookbinder ,  Theresa Chang ,  Steven Edward DeMartino ,  Andrei Gennadyevich Fadeev ,  Kyle Christopher Hoff ,  Jamie Lynne Morley ,  Santona Pal ,  John Stephen Peanasky ,  Chandan Kumar Saha ,  Christopher Lee Timmons

IPC: C03C17/30 ,  A61J1/00 ,  A61J1/14 ,  B65D1/09 ,  B65D23/08 ,  B65D25/14 ,  B65D65/42 ,  C03C17/00 ,  C03C17/32 ,  C03C17/42 ,  C03C21/00 ,  C08G73/10 ,  C08L77/02 ,  C09D179/08 ,  C09D183/08 ,  C08G77/26 ,  C09D4/00

CPC classification number: C03C17/30 ,  A61J1/00 ,  A61J1/1468 ,  B65D1/09 ,  B65D23/0821 ,  B65D25/14 ,  B65D65/42 ,  C03C17/005 ,  C03C17/32 ,  C03C17/42 ,  C03C21/002 ,  C08G73/105 ,  C08G73/1071 ,  C08L77/02 ,  C09D179/08 ,  C09D183/08 ,  C03C2217/78 ,  C03C2218/111 ,  C08G77/26 ,  C09D4/00 ,  Y10T428/1321 ,  Y10T428/24942 ,  Y10T428/265 ,  Y10T428/31612 ,  Y10T428/31623 ,  Y10T428/31721

Abstract: Embodiments of the present disclosure are directed to coated glass articles which reduce glass particle formation caused by glass to glass contact in pharmaceutical glass filling lines.

公开(公告)号：US11872189B2

公开(公告)日：2024-01-16

申请号：US16870657

申请日：2020-05-08

Applicant: CORNING INCORPORATED

Inventor： Andrei Gennadyevich Fadeev ,  Theresa Chang ,  Dana Craig Bookbinder ,  Santona Pal ,  Chandan Kumar Saha ,  Steven Edward DeMartino ,  Christopher Lee Timmons ,  John Stephen Peanasky

IPC: A61J1/14 ,  B65D23/08 ,  C03C17/30 ,  C03C21/00 ,  C03C17/32 ,  C03C17/42 ,  C03C17/00

CPC classification number: A61J1/1468 ,  B65D23/0821 ,  C03C17/005 ,  C03C17/30 ,  C03C17/32 ,  C03C17/42 ,  C03C21/002 ,  C03C2217/78 ,  Y10T428/1321 ,  Y10T428/24926 ,  Y10T428/265

Abstract: According to embodiments, a method of making a coated pharmaceutical container, may include: forming a glass tube; forming the glass tube into a pharmaceutical container comprising an interior surface and an exterior surface; and applying a coating to the exterior surface. The coating has a coefficient of friction less than or equal to 0.7 relative to a second pharmaceutical container when tested in a vial-on-vial testing jig under a normal load of 30 N. The coated pharmaceutical container may be thermally stable after depyrogenation at a temperature of at least 260° C. for 30 minutes in air.