L-lactic acid polymer composition, molded product and film
    52.
    发明授权
    L-lactic acid polymer composition, molded product and film 失效
    L-乳酸聚合物组合物,成型产品和薄膜

    公开(公告)号:US5763513A

    公开(公告)日:1998-06-09

    申请号:US434540

    申请日:1995-05-04

    摘要: A lactic acid polymer composition comprising formulating 100 parts by weight of a mixture consisting of 80-95% by weight of an L-lactic acid polymer having an L-lactic acid proportion of 75% or more and 5-20% by weight of a plasticizer selected from the group consisting of a polyhydric alcohol ester and a hydroxypolycarboxylic acid ester, 0.1-5 parts by weight of an anti-bloking agent having a SiO.sub.2 content of 90% or more and an average particle size of 7-50 nm, and 0.1-2 parts by weight of a slip agent; a molded product and film obtained from the composition; and a preparation process of the same are disclosed. The molded product and film are excellent in processability, transparency, flexibility, anti-blocking property and slip, and can be degraded into harmless water and carbon dioxide under natural environment, when abandoned.

    摘要翻译: 一种乳酸聚合物组合物,其包含配制100重量份的由80-95重量%的L-乳酸比例为75%以上的L-乳酸聚合物和5-20重量%的由 选自多元醇酯和羟基多羧酸酯的增塑剂,0.1-5重量份SiO 2含量为90%以上,平均粒径为7-50nm的抗血清剂,以及 0.1-2重量份的滑爽剂; 由该组合物获得的成型品和膜; 并公开了其制备方法。 成型品和膜的加工性,透明性,柔软性,防粘连性和滑爽性优异,在被废弃时可以在自然环境下降解成无害的水和二氧化碳。

    Dyeing method
    54.
    发明授权
    Dyeing method 失效
    染色方法

    公开(公告)号:US5630849A

    公开(公告)日:1997-05-20

    申请号:US612578

    申请日:1996-03-08

    IPC分类号: D06P1/00 D06P3/54 D06P3/16

    CPC分类号: D06P1/0032 D06P3/54 Y10S8/922

    摘要: The invention is a method of dyeing aliphatic polyester filaments with a disperse dye by selecting a dyeing temperature, dyeing pH, and dyeing time in such a way that the weight average molecular weight of the aliphatic polyester filament has a lowering ratio of 20% or less.The invention is a method for dyeing the aliphatic polyester filament with good reproducibility and level dyeing property while substantially maintaining the molecular weight and the essential excellent properties of the aliphatic polyester filament, and can provide dyed articles which have high strength, are excellent in level dyeing property and color fastness to light, and have various hues.

    摘要翻译: 本发明是通过选择染色温度,染色pH和染色时间,使脂族聚酯长丝的重均分子量具有20%以下的降低比例的方式,用分散染料染色脂肪族聚酯长丝的方法 。 本发明是一种染色脂肪族聚酯长丝的方法,具有良好的再现性和染色性,同时基本上保持了脂肪族聚酯长丝的分子量和基本优异的性能,并且可以提供具有高强度,染色性优异的染色制品 性能和色牢度轻,并具有各种色调。

    Purification process of aliphatic polyester
    56.
    发明授权
    Purification process of aliphatic polyester 失效
    脂肪族聚酯的净化过程

    公开(公告)号:US5496923A

    公开(公告)日:1996-03-05

    申请号:US305785

    申请日:1994-09-14

    IPC分类号: C08G63/90 C08F6/02

    CPC分类号: C08G63/90

    摘要: A purification process of an aliphatic polyester prepared in the presence of a catalyst from a hydroxycarboxylic acid or a cyclic ester of a hydroxycarboxylic acid, or a combination of an aliphatic polyhydric alcohol with an aliphatic polybasic acid, or a mixture of these compounds, comprising deactivating the catalyst while maintaining the aliphatic polyester in a molten or dissolved state, or insolubilizing and separating the catalyst and successively removing low molecular compounds. The process can provide aliphatic polyester which has a low content of unreacted monomers and low molecular weight compounds and is excellent in heat resistance and weatherability.

    摘要翻译: 在催化剂存在下由羟基羧酸或羟基羧酸的环酯或脂族多元醇与脂族多元酸的混合物或这些化合物的混合物制备的脂族聚酯的纯化方法,包括钝化 催化剂,同时保持脂族聚酯处于熔融或溶解状态,或不溶化和分离催化剂并连续除去低分子化合物。 该方法可以提供具有低含量的未反应单体和低分子量化合物的脂族聚酯,并且耐热性和耐候性优异。

    Preparation process of .alpha.-aspartyl-L-phenylalanine methyl ester
    58.
    发明授权
    Preparation process of .alpha.-aspartyl-L-phenylalanine methyl ester 失效
    α-天门冬酰基-L-苯丙氨酸甲酯的制备方法

    公开(公告)号:US5424477A

    公开(公告)日:1995-06-13

    申请号:US128739

    申请日:1993-09-30

    CPC分类号: C07K5/0613

    摘要: .alpha.-L-Aspartyl-L-phenylalanine methyl ester (.alpha.-APM) is prepared by catalytic hydrogenation of N-benzyloxycarbonyl-.alpha.-L-aspartyl-L-phenylalanine methyl ester (Z-.alpha.-APM). The catalytic hydrogenation is conducted in an aqueous suspension containing the Z-.alpha.-APM in the form of particles whose average particle size is not greater than 800 .mu.m. The starting Z-.alpha.-APM may contain up to 30 wt. % of its .beta.-isomer provided that the process additionally includes recrystallization of the .alpha.-APM, collection of the .alpha.-APM by filtration and recycling of the filtrate for use in the aqueous suspension of Z-.alpha.-APM.

    摘要翻译: 通过N-苄氧羰基-α-L-天冬氨酰-L-苯丙氨酸甲酯(Z-α-APM)的催化氢化制备α-L-天冬氨酰-L-苯丙氨酸甲酯(α-APM)。 催化氢化在含有平均粒径不大于800μm的颗粒形式的Z-α-APM的水性悬浮液中进行。 起始的Z-α-APM可含有至多30wt。 %的β-异构体,条件是该方法另外包括α-APM的重结晶,通过过滤收集α-APM并再循环用于Z-α-APM的水悬浮液中的滤液。

    Method for extracting an amino acid ester from a hydrous solution of a
mineral acid salt thereof
    59.
    发明授权
    Method for extracting an amino acid ester from a hydrous solution of a mineral acid salt thereof 失效
    从其无机酸盐的含水溶液中提取氨基酸酯的方法

    公开(公告)号:US5374765A

    公开(公告)日:1994-12-20

    申请号:US015931

    申请日:1993-01-19

    IPC分类号: C07C227/40 C07C709/00

    CPC分类号: C07C227/40

    摘要: Disclosed is a method for extracting an amino acid ester from a hydrous solution which comprises adding thereto a water-insoluble organic solvent and then an amount of a base effective to liberate only a portion of the amino acid ester in free base form, and transferring the thus liberated amino acid ester in the free base form into the organic layer, and repeating the neutralization-extraction steps until all of the amino acid ester has been extracted.

    摘要翻译: 公开了一种从含水溶液中提取氨基酸酯的方法,该方法包括向其中加入水不溶性有机溶剂,然后加入一定量的碱以有效释放一部分游离碱形式的氨基酸酯,并转移 从而将游离碱形式的氨基酸酯释放到有机层中,并重复中和提取步骤,直到所有的氨基酸酯被提取出来。

    Industrial process for the separation and recovery of chlorine
    60.
    发明授权
    Industrial process for the separation and recovery of chlorine 失效
    用于分离和回收氯的工业过程

    公开(公告)号:US5254323A

    公开(公告)日:1993-10-19

    申请号:US921606

    申请日:1992-08-03

    IPC分类号: C01B7/07 C01B7/01 B01D53/34

    CPC分类号: C01B7/0743

    摘要: A gaseous mixture containing chlorine, carbon dioxide and non-condensable gas is compressed and cooled to separate it into a residual gas formed principally of a major portion of the non-condensable gas and a condensate formed primarily of chlorine. The condensate is fed to a stripping column to desorb carbon dioxide and a minor portion of the non-condensable gas dissolved in the condensate. The stripped gas formed primarily of chlorine and carbon dioxide may be treated further. Namely, the stripped gas is mixed with the residual gas. At least a portion of the mixed gas is fed into an absorption column, whereby a major portion of remaining chlorine is absorbed to lower the chlorine content Removal of chlorine from such a gaseous mixture or an off-gas from the above process can be achieved by washing it with an aqueous solution or suspension containing an alkali metal sulfite and/or an alkaline earth metal sulfite while controlling the pH of the solution or suspension within a range of 1.9-6.3.

    摘要翻译: 将含有氯,二氧化碳和不可冷凝气体的气体混合物压缩并冷却,将其分离成主要由不可冷凝气体主要形成的残留气体和主要由氯气形成的冷凝物。 将冷凝物供入汽提塔以解吸二氧化碳和少部分溶解在冷凝物中的不可冷凝气体。 主要由氯和二氧化碳形成的汽提气体可以进一步处理。 即,将汽提的气体与残留气体混合。 将混合气体的至少一部分进料到吸收塔中,从而吸收主要部分的剩余氯以降低氯含量从上述方法从这种气体混合物或废气中除去氯可以通过 用包含碱金属亚硫酸盐和/或碱土金属亚硫酸盐的水溶液或悬浮液洗涤,同时将溶液或悬浮液的pH控制在1.9-6.3的范围内。