摘要:
Aromatic polyesters and polyestercarbonates based on diphenols and iso- and/or terephthalic acids become flame-proof if admixed with small quantities of ammonium or alkali metal salts of inorganic or organic acids and optionally halophthalimides and optionally polytetrafluoroethylene. The mechanical and chemical properties of the polyester (carbonates) remain unchanged.
摘要:
Thermoplastic polyphosphonatocarbonate prepared by polycondensing at least one aromatic dihydroxy compound with a diaryl carbonate and a phosphonic acid diaryl ester in the presence of a basic polycondensation catalyst at a temperature of from 80.degree. to 340.degree. and under a pressure of 600 to 0.1 mm Hg in an inert gaseous atmosphere, the molar ratio of diaryl carbonate to phosphonic diaryl ester being from 5:95 to 95:5 and the molar ratio of aromatic dihydroxy compound to the sum of diaryl carbonate and phosphonic acid diaryl ester being from 0.91:1 to 0.99:1, and following polycondensation, neutralizing said basic catalyst.
摘要:
The present invention relates to flame resistant aromatic polycarbonate molding compositions which are blends containing between about 0.1 to 15 wt.% of sulphur. The blends of the present invention may also contain up to about 30 wt.% of glass fibers. The present invention also relates to improving the flame resistance of polycarbonate molding compositions by physically incorporating 0.1 to 15 wt.% of sulphur therein.
摘要:
The invention relates to a thermoplastic moulding composition comprising an aromatic high-molecular weight polycarbonate based on a diphenol, with a weight-average molecular weight (M.sub.w) of at least 10,000 and from 0.5 to 5% by weight, relative to the high molecular weight polycarbonate, of a polycarbonate which has an M.sub.w of from 1,200 to 9,000 and which corresponds to the formula (I): ##STR1## wherein "E" represents a radical of the formula (II): ##STR2## in which THE GROUPS R' are identical and denote H or halogenx is an integer of from 7 to 24"Z" is a divalent aromatic radical, and"n", the degree of polymerization, results from the M.sub.w between 1,200 and 9,000.
摘要:
The invention relates to mixtures of special polyesters and/or special polyester carbonates with amorphous thermoplastics and/or with partly crystalline thermoplastics and/or with rubbers and/or with graft polymers useful for molding articles.
摘要:
The present invention relates to thermoplastic moulding materials of (A) thermoplastic polycarbonates mixed with (B) thermoplastic polyalkylene terephthalates and, if appropriate, with (C) elastomeric polymers, which are characterized in that they contain (D) a polycarbonate-polyphenylene oxide block co-condensate.
摘要:
This invention relates to flame-resistant polymer mixtures of polycarbonate, styrene polymer and/or graft polymer and polyphosphate, which mixtures may contain organic chlorine and bromine compounds and polytetrafluoroethylene used for the production of moulded articles such as electrical housings, electrical insulators, and for moulded automobile parts such as coverings, dashboards and so forth.
摘要:
High molecular weight aromatic polycarbonates having molecular weights M.sub.w (weight average) of between about 10,000 and 200,000, which are based on diphenols and monofunctional chain stoppers, which correspond to the general formula ##STR1## in which Z denotes the radical of a diphenol,n denotes an integer from 20 to 400,E denotes ##STR2## m is 0 or 1 and R denotes a hydrogen atom or a C.sub.1 to C.sub.3 alkyl group, and in which between about 0.5 and 5 mol % of Z are radicals of aromatic dihydroxyketones. These polycarbonates share mechanical and thermal properties with known polycarbonates but in addition are suitable for crosslinking, for example in the presence of photoinitiators and optionally photo-reducing agents and under irradiation with UV light. When crosslinked they are resistant to organic solvents and insensitive to stress-cracking, and have particularly good flame-repellent properties when additionally incorporating flameproofing agents.
摘要:
The new polyester carbonate-polysiloxane block copolymers having recurrent structural units of the following formulae ##STR1## have improved resistance to petrol compared with known polyester carbonate-polysiloxane block copolymers. They are used for the manufacture of moulded products, in particular those used under the engine bonnet of a motor vehicle or as external parts of motor vehicles.
摘要:
A process for the preparation of multinuclear phenols alkylated in the nucleus, wherein bisphenol A is reacted with a phenyl alkenyl compound in the presence of a catalytic quantity of aluminium phenolate and resols obtained from said alkylated phenols.