公开(公告)号：US06602604B2

公开(公告)日：2003-08-05

申请号：US09914561

申请日：2001-08-27

Applicant: Minoru Kurisaki ,  Takamasa Harada ,  Katsuyuki Sakamoto ,  Junichi Fukuzawa

Inventor： Minoru Kurisaki ,  Takamasa Harada ,  Katsuyuki Sakamoto ,  Junichi Fukuzawa

IPC: B32B2738

CPC classification number: C09D201/08 ,  C09D201/06 ,  Y10T428/31511 ,  Y10T428/31525 ,  Y10T428/31663

Abstract: The present invention is to provide a coating composition capable of forming a protective film excellent in adhesion properties. Such a coating composition comprises a specific polymer containing carboxyl group, a specific multifunctional epoxide-containing compound having two or more epoxy groups, an organic solvent, and an amino-containing silane coupling agent represented by the following general formula (I): H2N—R1—Si—(OR2)3  (I) wherein, R1 is an unsubstituted alkylene group, and R2's are independently an unsubstituted alkyl group.

Abstract translation: 本发明提供能够形成粘合性优异的保护膜的涂料组合物。 这种涂料组合物包含含羧基的特定聚合物，具有两个以上环氧基的特定多官能环氧化物的化合物，有机溶剂和由以下通式（I）表示的含氨基的硅烷偶联剂：其中， R1为未取代的亚烷基，R2为独立的未取代的烷基。

公开(公告)号：US06303706B1

公开(公告)日：2001-10-16

申请号：US09597414

申请日：2000-06-19

Applicant: Satoru Miyake ,  Hisao Ikeda ,  Motohiko Hidaka ,  Takeo Moro

Inventor： Satoru Miyake ,  Hisao Ikeda ,  Motohiko Hidaka ,  Takeo Moro

IPC: C08F2000

CPC classification number: C09D167/00 ,  C08L63/06 ,  C09D133/064 ,  C09D163/06 ,  C09D201/08 ,  C08L2666/02 ,  C08L2666/14 ,  C08L2666/28 ,  C08L2666/36 ,  C08L2666/18

Abstract: A resin composition for powder coating, which comprises the following components (A), (B) and (C): (A) a carboxyl group-containing resin having a number average molecular weight of from 1,000 to 20,000, an acid value of from 5 to 200 and a glass transition temperature of from 30 to 120° C.; (B) tris(&bgr;-methylglycidyl) isocyanurate of the formula (1): (C) as a ring opening polymerization inhibitor, at least one compound selected from the group consisting of amines having in their molecules a bond of the formula (2): and onium salts.

Abstract translation: 一种粉末涂料用树脂组合物，其含有以下成分（A），（B）和（C）:( A）数均分子量为1,000〜20,000的含羧基树脂，酸值为 5至200，玻璃化转变温度为30至120℃;（B）作为开环聚合抑制剂的式（1）:( C）的三（β-甲基缩水甘油基）异氰脲酸酯：至少一种选自 由在其分子中具有式（2）的键的胺和鎓盐组成的组。

公开(公告)号：US6114473A

公开(公告)日：2000-09-05

申请号：US836876

申请日：1997-05-28

Applicant: Satoru Miyake ,  Hisao Ikeda ,  Motohiko Hidaka ,  Takeo Moro

Inventor： Satoru Miyake ,  Hisao Ikeda ,  Motohiko Hidaka ,  Takeo Moro

IPC: C08L63/06 ,  C09D133/06 ,  C09D163/06 ,  C09D167/00 ,  C09D201/08 ,  C08F20/00

CPC classification number: C09D167/00 ,  C09D133/064 ,  C09D163/06 ,  C09D201/08 ,  C08L63/06

Abstract: A resin composition for powder coating, which comprises the following components (A), (B) and (C): (A) a carboxyl group-containing resin having a number average molecular weight of from 1,000 to 20,000, an acid value of from 5 to 200 and a glass transition temperature of from 30 to 120.degree. C.; (B) tris(.beta.-methylglycidyl) isocyanurate of formula (1); and (C) as a ring opening polymerization inhibitor, at least one compound selected from the group consisting of amines having in their molecules a bond of formula (2); and onium salts.

Abstract translation: PCT No.PCT / JP95 / 02318 Sec。 371日期1997年5月28日 102（e）日期1997年5月28日PCT提交1995年11月14日PCT公布。 出版物WO96 / 17026 日本1996年6月6日用于粉末涂料的树脂组合物，其包含以下组分（A），（B）和（C））：（A）数均分子量为1,000至20,000的含羧基的树脂， 酸值为5〜200，玻璃化转变温度为30〜120℃。 （B）式（1）的三（β-甲基缩水甘油基）异氰脲酸酯; 和（C）作为开环聚合抑制剂，至少一种选自在其分子中具有式（2）的键的胺的化合物; 和鎓盐。

公开(公告)号：US5686511A

公开(公告)日：1997-11-11

申请号：US673285

申请日：1996-06-28

Applicant: William S. Bobo

Inventor： William S. Bobo

IPC: C09D163/00 ,  C09D201/08 ,  C08K5/04 ,  C08L33/02 ,  C08L63/02

CPC classification number: C09D163/00 ,  C09D201/08

Abstract: A method of preparing a water-dispersible epoxy resin coating composition comprises: (a) Reacting an epoxy polymer with a carboxyl bearing polymer in the presence of an esterification catalyst; (b) Quenching with an excess of tertiary amine before the esterification reaction is completed; and (c) adding water to form an aqueous dispersion.

Abstract translation: 制备水分散性环氧树脂涂料组合物的方法包括：（a）在酯化催化剂存在下，使含羧基的聚合物反应环氧聚合物; （b）在酯化反应完成之前用过量的叔胺淬灭; 和（c）加水以形成水分散体。

公开(公告)号：US5635251A

公开(公告)日：1997-06-03

申请号：US442702

申请日：1995-05-17

Applicant: Hiroaki Oda ,  Yasumasa Okumura ,  Hiroshi Inoue ,  Hisashi Isaka

Inventor： Hiroaki Oda ,  Yasumasa Okumura ,  Hiroshi Inoue ,  Hisashi Isaka

IPC: B05D7/00 ,  C09D201/08 ,  B05D1/36 ,  B05D3/02 ,  B05D7/26

CPC classification number: B05D7/542 ,  C09D201/08

Abstract: The present invention provides a wet-on-wet coating method comprising applying a thermosetting aqueous coating composition (A), and applying a thermosetting aqueous coating composition (B) to the uncured coating surface of the aqueous coating composition (A) wherein the aqueous coating composition (A) contains a base resin with a neutralization value of 20 to 30 KOH mg/g and the aqueous coating composition (B) contains a base resin with a neutralization value higher by 10 to 20 KOH mg/g than the base resin of the aqueous coating composition (A).

Abstract translation: 本发明提供一种湿式湿式涂布方法，其包括涂布热固性水性涂料组合物（A），并向所述水性涂料组合物（A）的未固化涂料表面涂布热固性水性涂料组合物（B），其中所述水性涂料 组合物（A）含有中和值为20〜30KOHmg / g的基础树脂，水性涂料组合物（B）含有中和值高于10〜20KOHmg / g的基础树脂， 水性涂​​料组合物（A）。

公开(公告)号：US5157073A

公开(公告)日：1992-10-20

申请号：US684808

申请日：1991-04-15

Applicant: Barbara L. Kunz

Inventor： Barbara L. Kunz

IPC: C08G18/08 ,  C08G18/83 ,  C08K3/26 ,  C09D151/08 ,  C09D167/02 ,  C09D201/08

CPC classification number: C09D201/08 ,  C08G18/0823 ,  C08G18/838 ,  C08K3/26 ,  C09D151/08 ,  C09D167/02

Abstract: Non-aqueous ionomeric coatings useful as protective surface coatings applied to a substrate are produced by combining a carboxyl functional polymer with zinc carbonate. Upon heat curing the applied film, the zinc cation clusters with the carboxyl polymer to produce a thermoset coating film.

Abstract translation: 通过将羧基官能聚合物与碳酸锌组合，可以制备用作保护性表面涂层的非水性离聚物涂料。 在加热固化所施加的膜时，锌阳离子与羧基聚合物聚集以产生热固性涂膜。

公开(公告)号：US5155162A

公开(公告)日：1992-10-13

申请号：US684811

申请日：1991-04-15

Applicant: Barbara L. Kunz ,  Gary P. Craun

Inventor： Barbara L. Kunz ,  Gary P. Craun

IPC: C08F8/44 ,  C08G18/08 ,  C08G18/83 ,  C08K5/098 ,  C09D133/02 ,  C09D151/08 ,  C09D167/00 ,  C09D201/08

CPC classification number: C09D201/08 ,  C08F8/44 ,  C08G18/0823 ,  C08G18/838 ,  C08K5/098 ,  C09D133/02 ,  C09D151/08 ,  C09D167/00

Abstract: Ionomeric paint coatings are produced from an ionomeric polymer containing carboxyl functionality which is coreacted or neutralized with an organic zinc salt. The ionomeric polymer coreacted with a zinc organic salt functions as a binder and exhibits thermosetting-like properties.

Abstract translation: 离子聚合漆涂料由含有羧基官能团的离聚物聚合物生产，所述羧基官能团被核心反应或用有机锌盐中和。 与锌有机盐共核反应的离聚物聚合物起粘合剂的作用，具有热固性。

公开(公告)号：US4535128A

公开(公告)日：1985-08-13

申请号：US567314

申请日：1983-12-30

Applicant: Hirotoshi Umemoto ,  Hisaki Tanabe ,  Shinji Nakano

Inventor： Hirotoshi Umemoto ,  Hisaki Tanabe ,  Shinji Nakano

IPC: C08F8/30 ,  C08G18/08 ,  C08G63/88 ,  C08G63/91 ,  C09D133/04 ,  C09D167/00 ,  C09D167/08 ,  C09D201/02 ,  C09D201/08 ,  C08L61/28

CPC classification number: C09D201/08 ,  C08G18/0823 ,  C09D167/00

Abstract: A resinous composition for coating use comprising a resin obtained by the reaction of base resin having as essential groups, both carboxyl groups derived from a polycarboxylic acid whose titration midpoint potential in non-aqueous potentiometric titration is more than -300 mV in a state capable of developing a resinous acid value and a functional group reactive with a crosslinking agent, and an alkyleneimine compound in an amount equivalent to resinous acid value of 0.01 to 50, the resinous acid value based on said polycarboxylic acid in the final composition being 2 to 50.This is useful for the preparation of a coating composition having improved curing property, storage stability and time color stability.

Abstract translation: 一种用于涂料用途的树脂组合物，其包含通过基本树脂作为必要基团反应获得的树脂，两个来自多元羧酸的羧基，其在非水电位滴定中的滴定中点电位大于-300mV， 形成树脂酸值和与交联剂反应的官能团，以及相当于树脂酸值为0.01〜50的烯丙基亚胺化合物，最终组合物中所述多元羧酸的树脂酸值为2-50。 这对于制备具有改进的固化性能，储存稳定性和时间颜色稳定性的涂料组合物是有用的。

公开(公告)号：US4187204A

公开(公告)日：1980-02-05

申请号：US906386

申请日：1978-05-16

Applicant: Jerald D. Howard

Inventor： Jerald D. Howard

IPC: C09D201/08 ,  C09D3/58 ,  C09D3/64 ,  C09D3/74 ,  C09D5/02

CPC classification number: C09D201/08

Abstract: A paint composition which can be applied from a spray can yet which can be cleaned with water. The composition comprises a water-soluble, neutralized resin film former contained in a water-soluble solvent, but has a maximum water content of 10 weight percent. Formulations can be provided to obtain coatings ranging from flat to high gloss.

Abstract translation: 可以从喷雾施用的涂料组合物还可以用水清洗。 该组合物包含水溶性中和的树脂成膜剂，其包含在水溶性溶剂中，但最大含水量为10重量％。 可以提供配方以获得从平光到高光泽的涂层。

公开(公告)号：US3308077A

公开(公告)日：1967-03-07

申请号：US33225363

申请日：1963-12-20

Applicant: CANADIAN IND

Inventor： PARKER PATTISON JAMES ,  ADELBERT PREIK REINHOLD

IPC: C08F8/14 ,  C08G59/42 ,  C08G63/48 ,  C08G63/52 ,  C08G63/553 ,  C08G63/676 ,  C08G63/91 ,  C08L67/06 ,  C09D155/04 ,  C09D163/00 ,  C09D167/08 ,  C09D201/08

CPC classification number: C09D201/08 ,  C08F8/14 ,  C08F2810/20 ,  C08F2810/30 ,  C08G59/4292 ,  C08G63/48 ,  C08G63/52 ,  C08G63/553 ,  C08G63/676 ,  C08G63/918 ,  C08L67/06 ,  C09D155/04 ,  C09D163/00 ,  C09D167/08 ,  C08L2666/16

Abstract: Aqueous coating compositions are produced by treating a polyol having at least 3 hydroxy-groups and a molecular weight of at least 500 successively with (a) a drying oil fatty acid and (b) a maleinized fatty acid and partially or completely neutralizing the product with a base. Polyols specified include: a copolymer of styrene and allyl alcohol, and epoxy-resins, e.g. an epochlorohydrin/bisphenol A adduct. Drying oil fatty acids specified include those of linseed oil, soya bean oil, dehydrated castor oil and tall oil. 2 moles per mole of polyol may be used at 350-450 DEG F. Maleinized fatty acids specified include maleinized tall oil, and linseed oil. This treatment may be at 200-260 DEG F. for a sufficient time that half the maleic acid carboxyl groups are reacted. The neutralization may be at room temperature. Bases specified are ammonia, triethylamine, diethanolamine and diethylethanolamine. The base may be added in aqueous solution or dispersion which may contain an organic solvent, e.g. ethylene glycol monobutyl ether. The product may be diluted to a coating composition with water or organic solvents, e.g. hexanol, octanol, hexamethylene glycol and ethylene glycol monobutyl ether. The coating composition may also contain a drier, e.g. cobalt naphthenate in ethanol, and a filler or pigment, e.g. Fe2O3, rutile TiO2, barytes, carbon black or fibrous talc. It may be converted to a baking enamel by adding 5-100% of an aminoplast resin, e.g. a melamine-form-aldehyde resin and 0.01-2% of a catalyst therefore. In examples, the esterification is carried out in toluene or xylene solution. Potassium tripolyphosphate is used as a dispersing agent. In Example VIII the polyol is an acrylic copolymer of methyl methacrylate, butyl methacrylate, glycidyl methacrylate, thiophenol, and azodi-isobutyronitrile prepared by heating the reactants in isopropanol containing toluol.