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61.发明授权UZM-12 and UZM-12HS: crystalline aluminosilicate zeolitic compositions and processes for preparing and using the compositions 有权UZM-12和UZM-12HS：结晶硅铝酸盐沸石组合物和制备和使用组合物的方法公开(公告)号：US07344694B2
公开(公告)日：2008-03-18
申请号：US10959453
申请日：2004-10-06
IPC分类号： C01B39/30
CPC分类号： C01B39/48 , B01J29/50 , C01B39/305
摘要： A series of crystalline alumino-silicate zeolites identified as UZM-12 have been synthesized. These UZM-12 compositions have the ERI topology, a Si/Al>5.5 and can be prepared as nanocrystallites having an average particle size of about 15 to about 50 nanometers and a spheroidal morphology. The UZM-12 composition can be treated to remove at least a fraction of the framework aluminum atoms thereby providing zeolites with a Si/Al>5.75 and identified as UZM-12HS. Both the UZM-12 and UZM-12HS can catalyze various hydrocarbon conversion processes.
摘要翻译： 已经合成了一系列标准为UZM-12的结晶铝硅酸盐沸石。 这些UZM-12组合物具有ERI拓扑结构，Si / Al> 5.5，并且可以制备为具有约15至约50纳米的平均粒度和球形形态的纳米晶体。 可以处理UZM-12组合物以除去至少一部分骨架铝原子，从而提供具有Si / Al> 5.75的沸石并鉴定为UZM-12HS。 UZM-12和UZM-12HS都可以催化各种烃转化过程。
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公开(公告)号：US06982074B2
公开(公告)日：2006-01-03
申请号：US10251590
申请日：2002-09-20
申请人： Deng-Yang Jan , Jaime G. Moscoso , Gregory J. Lewis , Michael G. Gatter , Beckay J. Mezza , Susan C. Koster
发明人： Deng-Yang Jan , Jaime G. Moscoso , Gregory J. Lewis , Michael G. Gatter , Beckay J. Mezza , Susan C. Koster
IPC分类号： C01B39/06
CPC分类号： C10G45/12 , B01J29/70 , B01J2229/16 , B01J2229/183 , B01J2229/32 , B01J2229/37 , C01B39/026 , C01B39/06 , C01B39/065 , C01B39/46 , C10G11/05 , C10G35/06
摘要： A family of crystalline aluminosilicate zeolites designated UZM-5HS and derived from UZM-5 have been synthesized. The aluminum content of the UZM-5HS is lower than that of the starting UZM-5 thus changing its ion exchange capacity and acidity. These UZM-5HS are represented by the empirical formula: M1an+Al(1−x)ExSiy′Oz″ and are prepared by treatments such as acid extraction and AFS treatments.
摘要翻译： 已经合成了一系列名为UZM-5HS并衍生自UZM-5的结晶硅铝酸盐沸石。 UZM-5HS的铝含量低于起始UZM-5的铝含量，从而改变其离子交换能力和酸度。 这些UZM-5HS由经验公式表示：<？in-line-formula description =“In-line Formulas”end =“lead”？> M1 n + （1-x） x description =“In-Line Formulas”end =“tail”？>，并通过酸萃取和AFS处理等方法制备。
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63.发明授权UZM-5, UZM-5P, and UZM-6 crystalline aluminosilicate zeolites and methods for preparing the same 有权UZM-5，UZM-5P和UZM-6结晶硅铝酸盐沸石及其制备方法公开(公告)号：US08747807B2
公开(公告)日：2014-06-10
申请号：US13171890
申请日：2011-06-29
CPC分类号： B01J29/70 , C01B39/48 , C07C1/20 , C07C2/12 , C07C2/66 , C07C5/23 , C07C5/2518 , C07C5/2737 , C07C2529/70 , C10G50/00 , Y02P20/52 , C07C15/08
摘要： A method for preparing a family of zeolites, examples of which have been designated UZM-5, UZM-5P and UZM-6, and are represented by the empirical formula Mmn+Cgh+Rrp+Al(1-x)ExSiyOz The method includes forming a Charge Density Mismatch (CDM) reaction mixture comprising reactive sources of Al, Si, optionally a framework element, E, and at least one organic nitrogen containing cation template, C, in the hydroxide form. After the CDM mixture is mixed while aging, an organic cation crystallization template, R, and at least one alkali metal or alkaline earth metal, M, is added. The combined final reaction mixture is reacted with mixing to produce the zeolite, which may be used in various hydrocarbon conversion processes.
摘要翻译： 一种制备沸石族的方法，其实例被称为UZM-5，UZM-5P和UZM-6，并由经验式Mmn + Cgh + Rrp + Al（1-x）ExSiyOz表示。该方法包括 形成电荷密度不匹配（CDM）反应混合物，其包含氢氧化物形式的Al，Si，任选的骨架元素E和至少一种含有机氮的阳离子模板C的反应源。 在老化之后混合CDM混合物后，加入有机阳离子结晶模板R和至少一种碱金属或碱土金属M。 将组合的最终反应混合物与混合反应以产生可用于各种烃转化方法的沸石。
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64.发明授权Aromatic alkylation process using UZM-5, UZM-5P and UZM-6 zeolites 有权使用UZM-5，UZM-5P和UZM-6沸石的芳香族烷基化方法公开(公告)号：US08212097B2
公开(公告)日：2012-07-03
申请号：US13172016
申请日：2011-06-29
IPC分类号： C07C2/66
CPC分类号： C07C2/66 , B01J29/70 , B01J35/002 , B01J35/1019 , B01J35/1038 , B01J37/08 , B01J37/30 , B01J2229/42 , C01B39/48 , C07C6/126 , C07C2529/70 , Y02P20/52 , C07C15/073 , C07C15/085
摘要： A process for alkylating aromatic compounds using a family of zeolites, examples of which have been designated UZM-5, UZM-5P and UZM-6, and are represented by the empirical formula: Mmn+Cgh+Rrp+Al(1-x)ExSiyOz where M is an alkali or alkaline earth metal, E is an optional framework element, C organic nitrogen containing cation template, and R is an organic cation crystallization template. The zeolites have at least two x-ray diffraction peaks, one at a d-spacing of 3.9±0.12 Å and one at a d-spacing 8.6±0.20 Å; a tetragonal unit cell; and a micropore volume ranging from about 0.10 cc/g to about 0.18 cc/g.
摘要翻译： 使用一系列沸石烷基化芳族化合物的方法，其实例被称为UZM-5，UZM-5P和UZM-6，并且由经验式：Mmn + Cgh + Rrp + Al（1-x） ExSiyOz其中M是碱金属或碱土金属，E是可选的骨架元素，C有机氮阳离子模板，R是有机阳离子结晶模板。 沸石具有至少两个x射线衍射峰，一个在d-间隔为3.9±0.12A处，一个在d-间隔为8.6±0.20处; 四方晶胞; 和微孔体积为约0.10cc / g至约0.18cc / g。
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65.发明授权Alkylation process using catalysts with low olefin skeletal isomerization activity 有权使用具有低烯烃骨架异构化活性的催化剂的烷基化方法公开(公告)号：US08158839B2
公开(公告)日：2012-04-17
申请号：US13101450
申请日：2011-05-05
IPC分类号： C07C2/66
CPC分类号： B01J29/80 , B01J29/087 , B01J29/088 , B01J29/18 , B01J29/70 , B01J2229/42 , C07C2/66 , C07C2529/08 , C07C2529/80 , C07C15/107
摘要： A process is presented for the production of linear alkylbenzenes. The process includes contacting an aromatic compound with an olefin in the presence of a selective zeolite catalyst. The catalyst includes two zeolites combined to improve the linearity, and to produce detergent grade LAB. The two zeolites are selected to limit skeletal isomerization while producing a desired 2-phenyl content for the LAB.
摘要翻译： 介绍了生产线性烷基苯的方法。 该方法包括在选择性沸石催化剂存在下使芳族化合物与烯烃接触。 催化剂包括两种结合以提高线性的沸石，并生产洗涤剂级LAB。 选择两种沸石以限制骨架异构化，同时为LAB产生所需的2-苯基含量。
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公开(公告)号：US08158105B2
公开(公告)日：2012-04-17
申请号：US12750911
申请日：2010-03-31
申请人： Jaime G. Moscoso , Deng-Yang Jan
发明人： Jaime G. Moscoso , Deng-Yang Jan
CPC分类号： C01B39/48
摘要： A new family of crystalline aluminosilicate zeolites has been synthesized. These zeolites are represented by the empirical formula. Mmn+Rr+Al(1-x)ExSiyOz where M represents a combination of potassium and sodium exchangeable cations, R is a singly charged organoammonium cation such as the propyltrimethylammonium cation and E is a framework element such as gallium. These zeolites are similar to MWW but are characterized by unique x-ray diffraction patterns and compositions and have catalytic properties for carrying out various hydrocarbon conversion processes.
摘要翻译： 已经合成了一系列结晶硅铝酸盐沸石。 这些沸石由经验公式表示。 Mmn + Rr + Al（1-x）ExSiyOz其中M表示钾和钠可交换阳离子的组合，R是单电荷的有机铵阳离子，例如丙基三甲基铵阳离子，E是骨架元素如镓。 这些沸石类似于MWW，但是其特征在于独特的x射线衍射图和组成，并且具有用于进行各种烃转化方法的催化性能。
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公开(公告)号：US20110308998A1
公开(公告)日：2011-12-22
申请号：US12820095
申请日：2010-06-21
CPC分类号： C07C4/06 , B01J29/40 , B01J29/50 , B01J29/70 , B01J29/80 , C07C2529/70 , C10G11/05 , C10G2300/1022 , C10G2300/1044 , C10G2300/1059 , C10G2300/107 , C10G2300/1088 , C10G2300/301 , C10G2400/20 , Y02P20/52 , C07C11/04 , C07C11/06 , C07C11/08
摘要： Catalytic cracking processes such as fluidized catalytic cracking, naphtha cracking, and olefin cracking are catalyzed by the UZM-35 family of crystalline aluminosilicate zeolitic compositions represented by the empirical formula: Mmn+Rr+Al(1-x)ExSiyOz where M represents a combination of potassium and sodium exchangeable cations, R is a singly charged organoammonium cation such as the dimethyldipropylammonium cation and E is a framework element such as gallium. These UZM-35 zeolitic compositions are active and selective in the catalytic cracking of hydrocarbons.
摘要翻译： 催化裂解过程如流化催化裂化，石脑油裂解和烯烃裂解由经验式：Mmn + Rr + Al（1-x）ExSiyOz表示的结晶硅铝酸盐沸石组合的UZM-35族催化，其中M表示组合 的钾和钠可交换阳离子，R是单电荷的有机铵阳离子，例如二甲基二丙基铵阳离子，E是骨架元素如镓。 这些UZM-35沸石组合物在烃的催化裂化中具有活性和选择性。
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公开(公告)号：US20110301397A1
公开(公告)日：2011-12-08
申请号：US13151780
申请日：2011-06-02
IPC分类号： C07C2/68
CPC分类号： C07C2/66 , B01J29/70 , C01B39/48 , C07C2529/40 , Y02P20/52 , C07C15/085 , C07C15/073
摘要： Alkylation processes such as the alkylation of aromatics, are catalyzed by the UZM-35 family of crystalline aluminosilicate zeolites represented by the empirical formula: Mmn+Rr+Al(1-x)ExSiyOz where M represents a combination of potassium and sodium exchangeable cations, R is a singly charged organoammonium cation such as the dimethyldipropylammonium cation and E is a framework element such as gallium. These UZM-35 zeolites are active and selective in alkylation processes.
摘要翻译： 烷基化方法如芳族化合物的烷基化由UZM-35族结晶硅铝酸盐沸石催化，其经验式为Mmn + Rr + Al（1-x）ExSiyOz，其中M表示钾和钠可交换阳离子的组合， R是单电荷的有机铵阳离子，例如二甲基二丙基铵阳离子，E是骨架元素如镓。 这些UZM-35沸石在烷基化过程中是活性的和选择性的。
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公开(公告)号：US08071831B1
公开(公告)日：2011-12-06
申请号：US12820088
申请日：2010-06-21
IPC分类号： C07C5/27
CPC分类号： C07C5/2737 , C07C5/2791 , C07C2523/06 , C07C2523/08 , C07C2523/12 , C07C2523/14 , C07C2523/36 , C07C2523/42 , C07C2523/44 , C07C2523/46 , C07C2523/75 , C07C2523/755 , C07C2527/13 , C07C2529/80 , C07C15/08
摘要： Xylene and ethylbenzene isomerization process is catalyzed by the UZM-35 family of crystalline aluminosilicate zeolitic compositions represented by the empirical formula: Mmn+Rr+Al(1-x)ExSiyOz where M represents a combination of potassium and sodium exchangeable cations, R is a singly charged organoammonium cation such as the dimethyldipropylammonium cation and E is a framework element such as gallium. These UZM-35 zeolitic compositions are active and selective in the isomerization of xylenes and ethylbenzene.
摘要翻译： 二甲苯和乙苯异构化过程由经验式由Mmn + Rr + Al（1-x）ExSiyOz表示的结晶硅铝酸盐沸石组合的UZM-35族催化，其中M表示钾和钠可交换阳离子的组合，R是 单电荷的有机铵阳离子如二甲基二丙基铵阳离子，E是骨架元素如镓。 这些UZM-35沸石组合物在二甲苯和乙苯的异构化中是活性的和选择性的。
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公开(公告)号：US20110245565A1
公开(公告)日：2011-10-06
申请号：US12751720
申请日：2010-03-31
IPC分类号： C07C5/22
CPC分类号： C07C5/2737 , B01J29/70 , B01J29/74 , B01J2229/36 , B01J2229/42 , C01B39/48 , C07C5/2708 , C07C2529/70 , C07C2529/74 , Y02P20/52 , C07C15/08
摘要： Xylene and ethylbenzene isomerization process is catalyzed by the UZM-35 family of crystalline aluminosilicate zeolites represented by the empirical formula: Mmn+Rr+Al(1-x)ExSiyOz where M represents a combination of potassium and sodium exchangeable cations, R is a singly charged organoammonium cation such as the dimethyldipropylammonium cation and E is a framework element such as gallium. These UZM-35 zeolites are active and selective in the isomerization of xylenes and ethylbenzene.
摘要翻译： 二甲苯和乙苯异构化过程由经验式：Mmn + Rr + Al（1-x）ExSiyOz表示的结晶硅铝酸盐沸石的UZM-35族催化，其中M表示钾和钠可交换阳离子的组合，R是单 带电荷的有机铵阳离子如二甲基二丙基铵阳离子，E是骨架元素如镓。 这些UZM-35沸石在二甲苯和乙苯的异构化中是有活性和选择性的。
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