公开(公告)号：US20050233150A1

公开(公告)日：2005-10-20

申请号：US10903832

申请日：2004-07-30

Applicant: Naiyong Jing ,  George Tiers ,  Mark Muggli ,  Kathryn Spurgeon

Inventor： Naiyong Jing ,  George Tiers ,  Mark Muggli ,  Kathryn Spurgeon

IPC: B32B9/04 ,  B32B27/08 ,  C08F8/42

CPC classification number: B32B27/08 ,  B32B7/12 ,  B32B27/283 ,  B32B27/304 ,  B32B27/322 ,  B32B27/36 ,  B32B2250/24 ,  B32B2270/00 ,  B32B2274/00 ,  B32B2307/204 ,  B32B2307/308 ,  B32B2307/546 ,  B32B2307/714 ,  B32B2307/7265 ,  B32B2439/00 ,  B32B2439/40 ,  B32B2597/00 ,  C08F8/42 ,  C08G18/837 ,  C08G63/6854 ,  C08G63/6954 ,  C08G63/914 ,  C08G64/085 ,  C08G64/12 ,  C08G64/42 ,  C08G69/48 ,  C08K5/544 ,  C09J175/04 ,  C09J177/00 ,  Y10T428/3154 ,  Y10T428/31663 ,  C08F210/02

Abstract: Polymer bonding compositions having greater than about 1 milliequivalent primary amine/100 grams of the polymer, more preferably greater than about 3 milliequivalent non-tertiary amine/100 grams of the polymer. Preferably the polymer is not significantly crosslinked. These bonding compositions may be especially useful for bonding fluropolymers. Processes for making the novel polymers and the resulting multilayer bonded articles are described. The polymers include polymer-bonded ZNHLSi(OP)a(X)3-a-b(Y)b units. The bonding composition may be used for making multi-layer polymer laminates such as tubes and films and containers.

Abstract translation: 具有大于约1毫当量伯胺/ 100克聚合物，更优选大于约3毫当量非叔胺/ 100克聚合物的聚合物粘合组合物。 优选地，聚合物不是显着交联的。 这些粘合组合物可特别用于粘合氟聚合物。 描述了制备新型聚合物和所得多层粘合制品的方法。 聚合物包括聚合物键合的ZNHLSi（OP）a（X）3-a-b（Y）B单元。 粘合组合物可以用于制造多层聚合物层压材料，例如管，薄膜和容器。

公开(公告)号：US20050119417A1

公开(公告)日：2005-06-02

申请号：US10984031

申请日：2004-11-09

Applicant: Steven Hamrock ,  Naiyong Jing ,  Shane Mao ,  L. Hardy

Inventor： Steven Hamrock ,  Naiyong Jing ,  Shane Mao ,  L. Hardy

IPC: C08F8/26 ,  C08F8/36 ,  C08J5/22 ,  C08L27/16 ,  C08L27/22 ,  H01B1/06 ,  H01B13/00 ,  H01M8/02 ,  H01M8/10 ,  C08F14/18

CPC classification number: C08L27/22 ,  C08F8/26 ,  C08J5/225 ,  C08L27/16 ,  C08L2205/02 ,  H01M8/1023 ,  H01M8/1039 ,  H01M8/1072 ,  Y02P70/56 ,  C08F14/18 ,  C08L2666/04

Abstract: Methods are provided to make acid functional fluoropolymers by: a) dehydrofluorinating a starting fluoropolymer with a dehydrofluorinating agent to form an unsaturated fluoropolymer; b) adding an acidifiable nucleophilic functionalizing agent to a double bond of the unsaturated fluoropolymer; and c) acidifying the added acidifiable function. Acid functional fluoropolymers and ion conducting membranes thereof are also provided, including acid functional fluoropolymer having pendent groups according to the formula: —X—Ar-An, wherein X is selected from O, S or NR, where R is selected from H and C1-C30 alkyl or aryl, which are optionally substituted, wherein Ar is a C6-C30 aromatic group, which is optionally substituted, wherein A is an acidic function or salt thereof, wherein a can be independently chosen to be 1, 2 or 3.

Abstract translation: 提供通过以下方式制备酸官能含氟聚合物的方法：a）用脱氟化氢剂使起始含氟聚合物脱氟化氢以形成不饱和含氟聚合物; b）将可酸化的亲核官能化剂加入到不饱和含氟聚合物的双键中; 和c）酸化所添加的酸化功能。 还提供了酸官能含氟聚合物及其离子传导膜，包括具有下式的侧基的酸官能含氟聚合物：-X-Ar-A N，其中X选自O，S或NR， 其中R选自H和任选取代的C 1 -C 30烷基或芳基，其中Ar是任选取代的C 6 -C 30芳族基团，其中A是酸性官能团或其盐，其中a可以独立地选自 为1,2或3。

公开(公告)号：US20050107490A1

公开(公告)日：2005-05-19

申请号：US10712590

申请日：2003-11-13

Applicant: Michael Yandrasits ,  Steven Hamrock ,  Klaus Hintzer ,  Arne Thaler ,  Tatsuo Fukushi ,  Naiyong Jing ,  Kai Lochhaas

Inventor： Michael Yandrasits ,  Steven Hamrock ,  Klaus Hintzer ,  Arne Thaler ,  Tatsuo Fukushi ,  Naiyong Jing ,  Kai Lochhaas

IPC: B01D67/00 ,  B01D71/32 ,  B01D71/36 ,  B01D71/82 ,  C08F114/26 ,  C08F214/26 ,  C08J3/28 ,  C08J5/22 ,  H01M8/10 ,  C08G2/00

CPC classification number: C08J5/225 ,  B01D67/009 ,  B01D71/32 ,  B01D71/82 ,  C08F114/26 ,  C08J3/28 ,  C08J2327/18 ,  H01M8/1023 ,  H01M8/1039 ,  H01M8/1072 ,  H01M8/1088 ,  H01M2300/0082 ,  Y02P70/56

Abstract: A method is provided for making a crosslinked polymer electrolyte, typically in the form of a membrane for use as a polymer electrolyte membrane in an electrolytic cell such as a fuel cell, as well as the polymer so made, the method comprising application of electron beam radiation to a highly fluorinated fluoropolymer comprising: a backbone derived in part from tetrafluoro-ethylene monomer, first pendent groups which include a group according to the formula —SO2X, where X is F, Cl, Br, OH or —O−M+, where M+ is a monovalent cation, and second pendent groups which include Br, Cl or I. Typically, the membrane has a thickness of 90 microns or less, more typically 60 or less, and most typically 30 microns or less.

Abstract translation: 提供了一种用于制造交联聚合物电解质的方法，该电解质通常是在诸如燃料电池的电解槽中用作聚合物电解质膜的膜形式，以及如此制备的聚合物，该方法包括施加电子束 辐射到高度氟化的含氟聚合物，其包含：部分由四氟乙烯单体衍生的主链，第一侧基，其包括根据式-SO 2 X的基团，其中X是F，Cl，Br ，OH或-O - ，其中M +是单价阳离子，第二侧基包括Br，Cl或I. 通常，膜具有90微米或更小，更通常为60或更小，最通常为30微米或更小的厚度。

公开(公告)号：US20050107489A1

公开(公告)日：2005-05-19

申请号：US10712589

申请日：2003-11-13

Applicant: Michael Yandrasits ,  Steven Hamrock ,  Werner Grootaert ,  Miguel Guerra ,  Naiyong Jing

Inventor： Michael Yandrasits ,  Steven Hamrock ,  Werner Grootaert ,  Miguel Guerra ,  Naiyong Jing

IPC: C08J5/22 ,  C08G2/00

CPC classification number: C08J5/225 ,  C08J2327/12

Abstract: A method is provided for making a crosslinked polymer electrolyte, typically in the form of a membrane for use as a polymer electrolyte membrane in an electrolytic cell such as a fuel cell, by trimerization of nitrile groups contained on groups pendant from the polymer. The resulting polymer electrolyte membrane comprises a highly fluorinated polymer comprising: a perfluorinated backbone, first pendent groups which comprise sulfonic acid groups, and crosslinks comprising trivalent groups according to the formula: The first pendent groups are typically according to the formula: —R1—SO3H, where R1 is a branched or unbranched perfluoroalkyl or perfluoroether group comprising 1-15 carbon atoms and 0-4 oxygen atoms, most typically —O—CF2—CF2—CF2—CF2—SO3H or —O—CF2—CF(CF3)—O—CF2—CF2—SO3H.

Abstract translation: 提供了一种制备交联聚合物电解质的方法，通常是通过聚合物悬浮在基团上的腈基的三聚作用，在电解池如燃料电池中用作聚合物电解质膜的膜形式。 所得聚合物电解质膜包括高度氟化的聚合物，其包含：全氟化骨架，包含磺酸基团的第一侧基和包含根据下式的三价基团的交联：第一侧基通常根据下式：-R

公开(公告)号：US06767948B1

公开(公告)日：2004-07-27

申请号：US09470155

申请日：1999-12-22

Applicant: Naiyong Jing

Inventor： Naiyong Jing

IPC: B32B2704

CPC classification number: B32B27/08 ,  B32B1/08 ,  B32B27/18 ,  B32B2439/00 ,  B32B2597/00 ,  C08J5/128 ,  C09J11/06 ,  Y10T428/2878 ,  Y10T428/2891 ,  Y10T428/2896 ,  Y10T428/3154 ,  Y10T428/31544 ,  Y10T428/31551 ,  Y10T428/31573 ,  Y10T428/3158 ,  Y10T428/31721 ,  Y10T428/31725 ,  Y10T428/3175 ,  Y10T428/31797 ,  Y10T428/31855 ,  Y10T428/31909 ,  Y10T428/31913 ,  Y10T428/3192 ,  Y10T428/31928 ,  Y10T428/31935 ,  Y10T428/31938

Abstract: The invention relates to compositions useful for bonding fluoropolymer to substantially non-fluorinated polymer. The compositions of the invention comprise a substantially non-fluorinated polymer or a mixture of said polymers, a base, and a crown ether catalyst. Another aspect of the invention is an article comprising the above composition adhered to a fluoropolymer and methods of making said article.

Abstract translation: 本发明涉及用于将氟聚合物粘合到基本上非氟化聚合物上的组合物。 本发明的组合物包含基本上非氟化的聚合物或所述聚合物，碱和冠醚催化剂的混合物。 本发明的另一方面是包含粘附在含氟聚合物上的组合物和制备所述制品的方法的制品。

公开(公告)号：US06752894B2

公开(公告)日：2004-06-22

申请号：US10022761

申请日：2001-12-14

Applicant: Naiyong Jing ,  George Van Dyke Tiers

Inventor： Naiyong Jing ,  George Van Dyke Tiers

IPC: C08J704

CPC classification number: C08J5/124 ,  C08J7/12 ,  Y10T428/31504 ,  Y10T428/31507 ,  Y10T428/3154 ,  Y10T428/31721 ,  Y10T428/31725 ,  Y10T428/31728 ,  Y10T428/31736 ,  Y10T428/31786

Abstract: This invention concerns a process for modifying a polymeric substrate by contacting the surface with a photoreactive solution of an inorganic photochemical electron donor while irradiating the surface with actinic radiation. Patterns of modified and unmodified surfaces can be produced. Polymeric substrates with modified surfaces may be effectively bonded to polymer films to form composite articles. The process has particular applicability to the surface modification of fluorinated polymers.

Abstract translation: 本发明涉及一种通过使表面与无机光化学电子给体的光反应溶液接触，同时用光化辐射照射表面来改性聚合物基材的方法。 可以生产修饰和未改性表面的图案。 具有改性表面的聚合物基材可以有效地结合到聚合物膜上以形成复合制品。 该方法特别适用于氟化聚合物的表面改性。

公开(公告)号：US06734227B2

公开(公告)日：2004-05-11

申请号：US09961669

申请日：2001-09-24

Applicant: Naiyong Jing ,  George Van Dyke Tiers ,  Mark J. Pellerite

Inventor： Naiyong Jing ,  George Van Dyke Tiers ,  Mark J. Pellerite

IPC: C08K904

CPC classification number: C03C17/007 ,  C03C17/32 ,  Y10T428/24364 ,  Y10T428/2438 ,  Y10T428/2998 ,  Y10T428/3154

Abstract: The present invention relates to optical elements comprising fluorochemical surface treatments. The invention further relates to articles such as retroreflective sheetings, pavement markings and beaded projection screens comprising a binder and the surface treated optical elements. The surface treatment comprises at least one fluoropolymer selected from a) fluoropolymers comprising a fluorinated hydrocarbon backbone and side chains comprising at least one of fluoroalkyl, fluoroether alkyl, fluoroalkoxy and mixtures thereof; and b) fluoropolymers comprising a hydrocarbon backbone and side chains comprising at least one of fluoroether alkyl, fluoroalkoxy and mixtures thereof.

Abstract translation: 本发明涉及包含含氟表面处理的光学元件。 本发明还涉及诸如逆反射片材，路面标记和包括粘合剂和经表面处理的光学元件的串珠投影屏幕的制品。 表面处理包括至少一种含氟聚合物，其选自：a）包含氟化烃主链的含氟聚合物和包含氟代烷基，氟醚烷基，氟代烷氧基及其混合物中的至少一种的侧链; 和b）包含烃骨架和包含氟醚烷基，氟代烷氧基及其混合物中的至少一种的侧链的含氟聚合物。

公开(公告)号：US06649005B1

公开(公告)日：2003-11-18

申请号：US09676196

申请日：2000-09-28

Applicant: Naiyong Jing ,  Sehyun Nam ,  Trang Pham

Inventor： Naiyong Jing ,  Sehyun Nam ,  Trang Pham

IPC: C09J502

CPC classification number: C08J5/121 ,  B32B27/08 ,  C08J2327/12 ,  C08J2375/04 ,  C08J2377/00 ,  Y10T428/1352 ,  Y10T428/24802 ,  Y10T428/2848 ,  Y10T428/3154 ,  Y10T428/31544

Abstract: This invention provides a method of bonding substantially non-fluorinated polymeric material to dissimilar polymers, particularly fluoropolymer materials, utilizing a bonding composition comprising base-treated amine group-containing substantially non-fluorinated polymer. Multi-layer articles and composite constructions, including retroreflective sheeting, fuel line hoses, and adhesive articles made of a fluoropolymer layer and a substantially non-fluorinated layer are also provided.

Abstract translation: 本发明提供了使用包含碱处理的含胺基的基本上非氟化聚合物的粘合组合物将基本上非氟化聚合物材料粘合到不同聚合物，特别是含氟聚合物材料的方法。 还提供了由氟聚合物层和基本上非氟化层制成的多层制品和复合结构，包括回射片材，燃料管线和粘合剂制品。

公开(公告)号：US06582759B1

公开(公告)日：2003-06-24

申请号：US10132942

申请日：2002-04-26

Applicant: Zai-Ming Qiu ,  Naiyong Jing

Inventor： Zai-Ming Qiu ,  Naiyong Jing

IPC: G02B110

CPC classification number: C03C17/322 ,  C08G18/0823 ,  C08G18/2815 ,  C08G18/2885 ,  C08G18/289 ,  C08G18/3812 ,  C08G18/3872 ,  C08G18/4833 ,  C08G18/792 ,  C08G18/798 ,  Y10T428/252 ,  Y10T428/254 ,  Y10T428/2996 ,  Y10T428/2998 ,  Y10T428/3154 ,  Y10T428/31551 ,  Y10T428/31736 ,  Y10T428/31786

Abstract: The present invention relates to optical elements comprising fluorochemical surface treatments. The invention further relates to materials such as retroreflective sheetings, pavement markings and beaded projection screens comprising a binder and the surface treated optical elements.

Abstract translation: 本发明涉及包含含氟表面处理的光学元件。 本发明还涉及诸如逆反射片，路面标记和包括粘合剂和表面处理的光学元件的串珠投影屏幕的材料。

公开(公告)号：US06566455B2

公开(公告)日：2003-05-20

申请号：US10033483

申请日：2001-12-28

Applicant: Naiyong Jing ,  Brant U. Kolb ,  Robert E. Kolb

Inventor： Naiyong Jing ,  Brant U. Kolb ,  Robert E. Kolb

IPC: C08L2722

CPC classification number: C07C69/63 ,  C07C69/36 ,  C08K5/09 ,  C08L75/00

Abstract: In one aspect, the invention provides curable fluoropolymer compositions comprising fluoropolymer, onium, and alkyl or aryl oxalate-blocked compound and carbonate-blocked compound as crosslinking agents. In other aspects, the invention provides methods of making curable fluoropolymer compositions and provides alkyl or aryl oxalate-blocked and carbonate-blocked compounds.