公开(公告)号：US08460541B2

公开(公告)日：2013-06-11

申请号：US13008430

申请日：2011-01-18

申请人： Paul O'Connor ,  Dennis Stamires ,  Jacob Adriaan Moulijn

发明人： Paul O'Connor ,  Dennis Stamires ,  Jacob Adriaan Moulijn

IPC分类号： C10L3/00

CPC分类号： C10G1/086 ,  C10B49/20 ,  C10G1/08 ,  C10G11/18 ,  Y02E50/14

摘要： A process is disclosed process for converting a solid or highly viscous carbon-based energy carrier material to liquid and gaseous reaction products, said process comprising the steps of: a) contacting the carbon-based energy carrier material with a particulate catalyst material b) converting the carbon-based energy carrier material at a reaction temperature between 200° C. and 450° C., preferably between 250° C. and 350° C., thereby forming reaction products in the vapor phase. In a preferred embodiment the process comprises the additional step of: c) separating the vapor phase reaction products from the particulate catalyst material within 10 seconds after said reaction products are formed. In a further preferred embodiment step c) is followed by: d) quenching the reaction products to a temperature below 200° C.

摘要翻译： 公开了一种将固体或高粘度碳基能量载体材料转化为液体和气态反应产物的方法，所述方法包括以下步骤：a）使碳基能量载体材料与颗粒催化剂材料接触b）将 在200℃至450℃的反应温度下，优选250℃至350℃之间的碳基能量载体材料，从而在气相中形成反应产物。 在优选实施方案中，该方法包括以下附加步骤：c）在所述反应产物形成后10秒内从气态反应产物与颗粒状催化剂材料分离。 在另一优选实施方案中，步骤c）之后是：d）将反应产物淬灭至低于200℃的温度

公开(公告)号：US08088354B2

公开(公告)日：2012-01-03

申请号：US10579595

申请日：2004-11-19

申请人： Erik Jeroen Laheij ,  Paul O'Connor ,  Dennis Stamires ,  Edisson Morgado, Jr. ,  Marco Antonio Santos de Abreu ,  Márcio Fernandes ,  Michael Brady

发明人： Erik Jeroen Laheij ,  Paul O'Connor ,  Dennis Stamires ,  Edisson Morgado, Jr. ,  Marco Antonio Santos de Abreu ,  Márcio Fernandes ,  Michael Brady

IPC分类号： C01F7/02

CPC分类号： C04B35/6303 ,  B82Y30/00 ,  C01F7/02 ,  C01F7/34 ,  C01F7/448 ,  C01P2002/04 ,  C01P2002/70 ,  C01P2004/62 ,  C01P2004/64 ,  C04B35/62605 ,  C04B35/63 ,  C04B2235/3218 ,  C04B2235/5454 ,  C04B2235/549

摘要： Process for the preparation of quasi-crystalline boehmite comprising the steps of: (a) preparing an aqueous precursor mixture comprising a water-insoluble aluminum source; (b) decreasing the pH of the precursor mixture of step (a) by at least 2 units; (c) increasing the pH of the mixture of step (b) by at least 2 units, and (d) aging the mixture of step (c) under hydrothermal conditions to form a quasi-crystalline boehmite. This process provides for the hydrothermal preparation of quasi-crystalline boehmites with high peptizability. The invention therefore further relates to quasi-crystalline boehmites with a high peptizability, measured as the Z-average submicron particle size. This Z-average submicron particle size preferably is less than 500 nm, more preferably less than 300 nm, even more preferably less than 200 nm, and most preferably less than 100 nm.

摘要翻译： 制备准晶体勃姆石的方法，包括以下步骤：（a）制备包含水不溶性铝源的水性前体混合物; （b）将步骤（a）的前体混合物的pH降低至少2单位; （c）将步骤（b）的混合物的pH提高至少2单位，和（d）在水热条件下老化步骤（c）的混合物以形成准结晶勃姆石。 该方法提供了具有高可溶性性的准晶体沸石的水热制备。 因此，本发明进一步涉及具有高可溶性性的准晶体沸石，其测量为Z-平均亚微米粒度。 该Z平均亚微米粒径优选小于500nm，更优选小于300nm，甚至更优选小于200nm，最优选小于100nm。

公开(公告)号：US20110154720A1

公开(公告)日：2011-06-30

申请号：US12917988

申请日：2010-11-02

申请人： Robert Bartek ,  Michael Brady ,  Dennis Stamires ,  Steve Yanik ,  Paul O'Connor ,  Jacobus C. Rasser

发明人： Robert Bartek ,  Michael Brady ,  Dennis Stamires ,  Steve Yanik ,  Paul O'Connor ,  Jacobus C. Rasser

IPC分类号： C10L1/00 ,  B01J8/00

CPC分类号： C10G11/18 ,  C10G1/002 ,  C10G1/06 ,  C10G1/08 ,  C10G3/42 ,  C10G3/50 ,  C10G3/56 ,  C10G3/57 ,  C10G3/62 ,  C10G45/02 ,  C10G47/00 ,  C10G47/02 ,  C10G47/30 ,  C10G47/34 ,  C10G49/007 ,  C10G2300/1011 ,  C10G2300/1014 ,  C10G2300/107 ,  C10G2300/1074 ,  C10G2300/1077 ,  Y02P30/20

摘要： A process for producing fuel from biomass is disclosed herein. The process includes torrefying biomass material at a temperature between 80° C. to 400° C. to form particulated biomass having a mean average particle size between 1 μm and 1000 μm. The particulated biomass is mixed with a liquid hydrocarbon to form a suspension, wherein the suspension includes from 1 weight percent to 40 weight percent particulated biomass. The suspension is fed into a unit selected from the group consisting of a pyrolysis reactor, a fluid catalytic cracking unit, a delayed coker, a fluid coker, a hydroprocessing unit, and a hydrocracking unit, and then at least a portion of the particulated biomass of the suspension is converted into fuel.

摘要翻译： 本文公开了一种从生物质生产燃料的方法。 该方法包括在80℃至400℃的温度下焙烧生物质材料，以形成平均粒度为1μm至1000μm的颗粒状生物质。 将颗粒状生物质与液体烃混合以形成悬浮液，其中悬浮液包括1重量％至40重量％的颗粒生物质。 将悬浮液加入到选自热解反应器，流化催化裂化装置，延迟焦化器，流体焦化器，加氢处理装置和加氢裂化装置中的单元中，然后将至少一部分颗粒生物质 的悬浮液转化为燃料。

公开(公告)号：US20100228068A1

公开(公告)日：2010-09-09

申请号：US12377389

申请日：2007-08-15

申请人： Paul O'Connor ,  Avelino Corma Camos ,  Dennis Stamires

发明人： Paul O'Connor ,  Avelino Corma Camos ,  Dennis Stamires

IPC分类号： C07C1/20

CPC分类号： C10G3/50 ,  C10G3/46 ,  C10G2300/1011 ,  C10G2300/1014 ,  C10G2300/1059 ,  C10G2300/4012 ,  C10G2300/805 ,  C10G2400/04 ,  Y02P30/20

摘要： A process is disclosed for mild hydro-conversion of oxygenated hydrocarbon compounds. The oxygenated hydrocarbon compounds are contacted with a hydro-conversion catalyst material at a reaction pressure below 100 bar.Preferred oxygenated hydrocarbon compounds are those obtained by the liquefaction of biomass.In a specific embodiment the process is used for production of normal alkanes by hydrotreating mixtures of triglycerides (or compounds derived-from triglycerides, including free fatty acids) and vacuum gasoil.

摘要翻译： 公开了一种用于氧化烃化合物的轻度加氢转化的方法。 氧化烃化合物在低于100巴的反应压力下与水力转化催化剂材料接触。 优选的含氧烃化合物是通过液化生物质获得的化合物。 在一个具体实施方案中，该方法用于通过加氢处理甘油三酯（或衍生自甘油三酯，包括游离脂肪酸的化合物）和真空气体油的混合物来生产正烷烃。

公开(公告)号：US20100209965A1

公开(公告)日：2010-08-19

申请号：US12373748

申请日：2007-07-13

申请人： Paul O'Connor ,  Dennis Stamires

发明人： Paul O'Connor ,  Dennis Stamires

IPC分类号： C10B57/00 ,  C12P1/00 ,  C09K3/00

CPC分类号： C10G1/00 ,  C10B49/16 ,  C10B53/02 ,  C10G1/086 ,  C10G2300/1011 ,  C10L9/086 ,  Y02E50/14 ,  Y02P30/20

摘要： A process is disclosed for converting a particulate biomass material to a bioliquid. In the process the biomass material is mixed with a heat transfer medium and a catalytic material, and heated to a temperature in the range of from 150 to 600° C. The particle size of the solid biomass may be reduced by abrasion in admixture with inorganic particles under agitation by a gas. The biomass particles of reduced size obtained in the abrasion process may be converted to bioliquid in any of a number of conversion processes.

摘要翻译： 公开了将颗粒状生物质材料转化为生物液体的方法。 在该过程中，将生物质材料与传热介质和催化材料混合，并加热至150至600℃的温度。固体生物质的粒度可以通过与无机物的混合物的磨损而降低 颗粒在气体搅拌下。 在磨损过程中获得的尺寸减小的生物质颗粒可以以多种转化方法中的任何一种转化为生物液体。

公开(公告)号：US07598202B2

公开(公告)日：2009-10-06

申请号：US11313837

申请日：2005-12-20

申请人： Paul O'Connor ,  William Jones ,  Dennis Stamires

发明人： Paul O'Connor ,  William Jones ,  Dennis Stamires

IPC分类号： B01J29/06

CPC分类号： B01J23/002 ,  B01J23/007 ,  B01J23/06 ,  B01J27/232 ,  B01J2523/00 ,  C10G2/33 ,  C10G45/00 ,  C10G45/04 ,  C10G45/46 ,  Y10S208/95 ,  B01J2523/27 ,  B01J2523/31 ,  B01J2523/847 ,  B01J2523/17

摘要： Novel compositions of matter comprising a cationic layered material and a second compound. The second compound has a reflection in its XRD pattern at 18.5 degrees two-theta, and s second reflection at 29 degrees two-theta. The composition of matter may be used in hydrocarbon conversion, purification, and synthesis processes, such as fluid catalytic cracking and hydroprocessing. The materials are especially suitable for the reduction of SOx and NOx emissions and the reduction of the sulfur and nitrogen content in fuels like gasoline and diesel.

摘要翻译： 包含阳离子层状材料和第二化合物的新型组合物。 第二种化合物在其XRD图案上具有18.5度2θ的反射，在29度处具有第二反射2θ。 物质的组成可用于烃转化，纯化和合成过程，如流化催化裂化和加氢处理。 这些材料特别适用于减少SOx和NOx排放以及减少燃料如汽油和柴油中的硫和氮含量。

公开(公告)号：US20090149317A1

公开(公告)日：2009-06-11

申请号：US12093104

申请日：2006-11-07

申请人： Dennis Stamires ,  Paul O'Connor

发明人： Dennis Stamires ,  Paul O'Connor

IPC分类号： B01J21/16

CPC分类号： B01J35/0006 ,  B01J21/12 ,  B01J21/16 ,  B01J23/007 ,  B01J23/02 ,  B01J23/06 ,  B01J23/10 ,  B01J27/16 ,  B01J29/061 ,  B01J29/83 ,  B01J37/031 ,  B01J37/28 ,  C10G11/05

摘要： Process for the preparation of an aluminium phosphate-containing composition wherein an aluminium source is converted partly to aluminium phosphate using a phosphorus-containing compound and partly to (i) an anionic clay and/or a Al-MII mixed metal (hydr)oxide using a divalent metal (MII) source, (ii) an aluminosilicate using a silicon source, and/or (iii) a MII- aluminosilicate using both a divalent metal source and a silicon source.

摘要翻译： 制备含磷酸铝的组合物的方法，其中使用含磷化合物将铝源部分转化成磷酸铝，并且部分地使用（i）阴离子粘土和/或Al-MII混合金属（hydr）氧化物，使用 二价金属（MII）源，（ii）使用硅源的硅铝酸盐和/或（iii）使用二价金属源和硅源的MII-硅铝酸盐。

公开(公告)号：US20090048097A1

公开(公告)日：2009-02-19

申请号：US10582601

申请日：2004-12-06

申请人： William Jones ,  Dennis Stamires ,  Paul O'Connor ,  Michael Brady

发明人： William Jones ,  Dennis Stamires ,  Paul O'Connor ,  Michael Brady

IPC分类号： B01J27/232 ,  B01J27/14 ,  B01J23/00 ,  B01J27/24 ,  B01J23/34 ,  B01J23/745 ,  B01J23/75 ,  B01J23/72 ,  B01J23/06 ,  B01J23/02 ,  B01J21/02 ,  B01J23/26 ,  B01J23/22 ,  B01J23/28 ,  B01J23/30 ,  B01J23/10

CPC分类号： B01J23/002 ,  B01J23/02 ,  B01J23/06 ,  B01J23/10 ,  B01J23/22 ,  B01J23/24 ,  B01J23/78 ,  B01J23/83 ,  B01J23/868 ,  B01J23/8892 ,  B01J27/18 ,  B01J29/06 ,  B01J35/0006 ,  B01J35/002 ,  B01J37/03 ,  B01J37/04 ,  B01J2229/20 ,  B01J2229/42 ,  B01J2523/00 ,  C10G11/04 ,  C10G11/18 ,  B01J2523/22 ,  B01J2523/31 ,  B01J2523/3706

摘要： Process for the preparation of an oxidic catalyst composition consisting of one or more trivalent metals preferably aluminum, one or more divalent metals preferably magnesium and more than 18 wt % of one or more compounds selected from the group consisting of rare earth metal compounds, phosphorus compounds, and transition metal compounds, which process comprises the steps of preparing a precursor mixture consisting of (i) or more trivalent metal compounds, (ii) one or more divalent metal compounds, (iii) one or more compounds selected from the group consisting of rare earth metal compounds, and transition metal compounds, and (iv) optionally water, which precursor mixture is not a solution. The resulting oxidic catalyst composition is suitable as a metal trap and SOx sorbent FCC processes.

摘要翻译： 制备由一种或多种三价金属组成的氧化催化剂组合物的方法，优选铝，一种或多种二价金属，优选镁和大于18wt％的一种或多种选自稀土金属化合物，磷化合物 和过渡金属化合物，该方法包括制备由（i）或更多种三价金属化合物组成的前体混合物，（ii）一种或多种二价金属化合物，（iii）一种或多种选自以下的化合物的步骤： 稀土金属化合物和过渡金属化合物，和（iv）任选的水，该前体混合物不是溶液。 所得到的氧化催化剂组合物适合作为金属捕集剂和SOx吸附剂FCC方法。

公开(公告)号：US07473663B2

公开(公告)日：2009-01-06

申请号：US11587393

申请日：2005-04-26

申请人： William Jones ,  Dennis Stamires ,  Paul O'Connor ,  Michael F. Brady

发明人： William Jones ,  Dennis Stamires ,  Paul O'Connor ,  Michael F. Brady

IPC分类号： B01J20/06 ,  B01J20/08 ,  B01J23/00 ,  B01J21/02

CPC分类号： C01B13/322 ,  B01J20/06 ,  B01J20/08 ,  B01J23/002 ,  C01F7/005 ,  C01P2002/22 ,  C01P2002/50

摘要： Process for the preparation of an additive-containing anionic clay comprising the steps of (a) preparing a physical mixture of a divalent and a trivalent metal compound, (b) calcining the physical mixture at a temperature in the range 200-800° C. without performing a prior aging or shaping step, thereby forming a product containing at least 5 wt % of a rehydratable compound, and (c) rehydrating the calcined mixture in aqueous suspension containing an additive to form the additive-containing anionic clay.This process provides a simple and cost-effective way of preparing additive-containing anionic clays. The process does neither require aging or reaction steps before calcination, nor does it require precipitation of metal salts or the handling of inhomogeneous slurries.

摘要翻译： 制备含添加剂的阴离子粘土的方法包括以下步骤：（a）制备二价和三价金属化合物的物理混合物，（b）在200-800℃的温度下煅烧该物理混合物。 从而形成含有至少5重量％的可再水化合物的产品，和（c）将含有添加剂的含水悬浮液中的煅烧混合物再水合以形成含添加剂的阴离子粘土。 该方法提供了制备含添加剂的阴离子粘土的简单和成本有效的方法。 该方法既不需要煅烧前的老化或反应步骤，也不需要沉淀金属盐或处理不均匀的浆料。

公开(公告)号：US20080308456A1

公开(公告)日：2008-12-18

申请号：US11915704

申请日：2006-06-02

申请人： Dennis Stamires ,  Paul O'Connor ,  William Jones

发明人： Dennis Stamires ,  Paul O'Connor ,  William Jones

IPC分类号： C10G11/04 ,  C01F17/00 ,  C01G23/04 ,  C01G25/02 ,  C01F11/02 ,  C01B31/00 ,  B01J23/10 ,  B01J23/02 ,  B01J21/06

CPC分类号： B01J23/868 ,  B01J23/002 ,  B01J23/34 ,  B01J23/72 ,  B01J37/04 ,  B01J2523/00 ,  C10G11/04 ,  C10G11/05 ,  C10G11/18 ,  B01J2523/47 ,  B01J2523/67 ,  B01J2523/72 ,  B01J2523/48 ,  B01J2523/17 ,  B01J2523/31 ,  B01J2523/69 ,  B01J2523/22 ,  B01J2523/3712

摘要： Oxidic composition consisting essentially of oxidic forms of a first metal, a second metal, and optionally a third metal, the first metal being either Ca or Ba and being present in the composition in an amount of from about 5 to about 80 wt %, the second metal being Al and being present in the composition in an amount of from about 5 to about 80 wt %, the third metal being selected from the group consisting of La, Ti, and Zr, and being present in an amount of from 0 to about 17 wt %—all weight percentages calculated as oxides and based on the weight of the oxidic composition, the oxidic composition being obtainable by (a) preparing a physical mixture comprising solid compounds of the first, the second, and the optional third metal, (b) optionally aging the physical mixture, without anionic clay being formed, and (c) calcining the mixture. This composition is suitable for use in FCC processes for the passivation of metals with only minimal influence on the zeolite's hydrothermal stability.

摘要翻译： 基本上由第一金属，第二金属和任选的第三金属的氧化形式组成的氧化组合物，第一金属是Ca或Ba，并且以约5至约80wt％的量存在于组合物中， 第二金属为Al，并且以约5至约80重量％的量存在于组合物中，第三金属选自La，Ti和Zr，并且以0至 约17重量％的重量百分比计算为氧化物，并且基于氧化组合物的重量，氧化组合物可通过（a）制备包含第一，第二和任选的第三金属的固体化合物的物理混合物获得， （b）任选地老化物理混合物，而不形成阴离子粘土，和（c）煅烧该混合物。 该组合物适用于FCC工艺中钝化金属，对沸石的水热稳定性影响最小。