Methods for determining temperature value indicative of resin stickiness from data generated by polymerization reaction monitoring
    61.
    发明授权
    Methods for determining temperature value indicative of resin stickiness from data generated by polymerization reaction monitoring 有权
    用于通过聚合反应监测产生的数据确定指示树脂粘性的温度值的方法

    公开(公告)号:US08273834B2

    公开(公告)日:2012-09-25

    申请号:US12310723

    申请日:2007-08-09

    摘要: In some embodiments, a method including the steps of monitoring a polymerization reaction which produces a polymer resin in a fluid bed reactor, where a dry melt reference temperature is characteristic of melting behavior of a dry version of the resin, and in response to data indicative of at least one monitored parameter of the reaction, determining in on-line fashion a reduced melt reference temperature that is at least substantially equal to the difference between the dry melt reference temperature and a temperature by which the dry melt reference temperature is depressed by the presence of condensable diluent gas with the resin in the reactor. Optionally, the method also includes the step of controlling the reaction in response to the reduced melt reference temperature or a stickiness parameter determined from the reduced melt reference temperature.

    摘要翻译: 在一些实施方案中,一种方法包括以下步骤:监测在流化床反应器中产生聚合物树脂的聚合反应,其中干燥熔体参考温度是干燥形式的树脂的熔融特性的特征,并且响应于数据指示 的反应的至少一个监测参数,以在线方式确定降低的熔融参考温度,其至少基本上等于干熔体参考温度与干熔体参考温度被压下的温度之间的差异 在反应器中存在可冷凝稀释气体与树脂。 任选地,该方法还包括响应于降低的熔融参考温度或从降低的熔融参考温度确定的粘性参数来控制反应的步骤。

    Method for seed bed treatment before a polymerization reaction
    67.
    发明授权
    Method for seed bed treatment before a polymerization reaction 有权
    聚合反应前种子床处理方法

    公开(公告)号:US08039562B2

    公开(公告)日:2011-10-18

    申请号:US12322143

    申请日:2009-01-29

    IPC分类号: C08F2/00 C08F210/00

    摘要: In some embodiments, a method in which at least one continuity additive (“CA”) and a seed bed are pre-loaded into a reactor, and a polymerization reaction is optionally then performed in the reactor. In other embodiments, at least one flow improver, at least one CA, and a seed bed are pre-loaded into a reactor. Pre-loading of a reactor with a CA can significantly improve continuity of a subsequent polymerization reaction in the reactor during its initial stages, including by reducing sheeting and fouling. The CA can be pre-loaded in dry form (e.g., as a powder), or in liquid or slurry form (e.g., as an oil slurry). To aid delivery of a dry CA to the reactor and combination of the dry CA with a seed bed in the reactor, the dry CA can be combined with a flow improver and the combination of CA and flow improver then loaded into the reactor. Alternatively, the CA and flow improver can be sequentially loaded into the reactor, and then mixed together (and mixed with a seed bed) in the reactor after both the CA and flow improver have been separately loaded into the reactor.

    摘要翻译: 在一些实施方案中,将至少一种连续性添加剂(“CA”)和种子床预加载到反应器中的方法,然后任选地在反应器中进行聚合反应。 在其它实施方案中,将至少一种流动改进剂,至少一种CA和种子床预加载到反应器中。 具有CA的反应器的预装载可以显着改善反应器在其初始阶段期间的后续聚合反应的连续性,包括通过减少薄片和结垢。 CA可以预干燥形式(例如,作为粉末),或以液体或浆液形式(例如,作为油浆)预加载。 为了帮助将干燥的CA输送到反应器中,并且干燥的CA与反应器中的种子床的组合,干燥的CA可与流动改进剂组合,然后将CA和流动改进剂的组合装入反应器中。 或者,CA和流动改进剂可以顺序地加载到反应器中,然后在CA和流动改进剂已经分别装载到反应器中之后混合在一起(并与种子床混合)在反应器中。

    Slurry Catalyst Flow Splitters and Methods of Using the Same

    公开(公告)号:US20110232768A1

    公开(公告)日:2011-09-29

    申请号:US13156411

    申请日:2011-06-09

    申请人: Timothy R. Lynn

    发明人: Timothy R. Lynn

    IPC分类号: F17D3/00

    摘要: A system for feeding a slurry catalyst composition including: a primary slurry feed system comprising a primary slurry flow meter and a primary catalyst injection device, wherein the primary slurry flow meter measures a primary slurry catalyst composition flow rate to the primary catalyst injection device; and a secondary slurry feed system comprising a secondary slurry flow meter, a secondary carrier liquid, a secondary carrier liquid control device, and a secondary catalyst injection device, wherein the secondary slurry flow meter measures a secondary slurry catalyst composition flow rate to the secondary catalyst injection device, wherein the secondary carrier liquid control device controls a process parameter of the secondary slurry feed system based a ratio of the primary slurry catalyst composition flow rate to the secondary slurry catalyst composition flow rate.

    Processes for the Preparation of Arylamine Compounds
    69.
    发明申请
    Processes for the Preparation of Arylamine Compounds 失效
    制备芳胺化合物的方法

    公开(公告)号:US20110207599A1

    公开(公告)日:2011-08-25

    申请号:US13126202

    申请日:2009-10-21

    申请人: Adam M. Johns

    发明人: Adam M. Johns

    摘要: A process for the preparation of N-arylamine compounds, the process including: reacting a compound having an amino group with an acylating compound in the presence of a base and a transition metal catalyst under reaction conditions effective to form an N-arylamine compound; wherein the transition metal catalyst comprises a complex of a Group 8-10 metal and at least one chelating ligand comprising (R)-(−)-1-[(S)-2-dicyclohexylphosphino]-ferrocenyl]ethyldi-t-butylphosphine.

    摘要翻译: 一种制备N-芳基胺化合物的方法,该方法包括:在有效形成N-芳基胺化合物的反应条件下,在碱和过渡金属催化剂的存在下使具有氨基的化合物与酰化化合物反应; 其中所述过渡金属催化剂包含第8-10族金属和至少一种包含(R) - ( - ) - 1 - [(S)-2-二环己基膦基] - 二氢呋喃基]乙基二叔丁基膦的螯合配体的络合物。