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144 条记录 (耗时 0.024 秒)

    IRON-COMPRISING HETEROGENEOUS CATALYST AND PROCESS FOR PREPARING OLEFINS BY REACTION OF CARBON MONOXIDE WITH HYDROGEN
    63.
    发明申请
    IRON-COMPRISING HETEROGENEOUS CATALYST AND PROCESS FOR PREPARING OLEFINS BY REACTION OF CARBON MONOXIDE WITH HYDROGEN 失效
    含有异构催化剂的铁和通过氢氧化碳反应制备烯烃的方法

    公开(公告)号：US20110112204A1

    公开(公告)日：2011-05-12

    申请号：US12939903

    申请日：2010-11-04

    申请人： JOCHEN STEINER ,  Kerem Bay ,  Ralf Böhling ,  Ekkehard Schwab

    发明人： JOCHEN STEINER ,  Kerem Bay ,  Ralf Böhling ,  Ekkehard Schwab

    IPC分类号： C07C1/20 ,  B01J37/08 ,  B01J23/78 ,  B01J37/02 ,  C21B15/04 ,  B22F9/22 ,  C22C38/00

    CPC分类号： B01J27/20 ,  B01J23/745 ,  B01J23/78 ,  B01J35/023 ,  B01J37/0201 ,  B01J37/086 ,  B01J37/18 ,  C10G2/332 ,  C10G2400/20

    摘要： Iron—comprising heterogeneous catalyst and a process for producing it, which comprises the following steps:I. thermal decomposition of gaseous iron pentacarbonyl to give carbonyl iron powder having spherical primary particles,II. treatment of carbonyl iron powder obtained in step I with hydrogen, resulting in the metallic spherical primary particles at least partially agglomerating,III. contacting of the agglomerates (=secondary particles) with iron pentacarbonyl,IV. thermal decomposition of the iron pentacarbonyl applied in step III to give at least predominantly pore- and void-free secondary particles.Process for preparing olefins by reaction of carbon monoxide with hydrogen in the presence of a catalyst, with the abovementioned iron-comprising heterogeneous catalyst being used as catalyst.

    摘要翻译： 含铁非均相催化剂及其制备方法，其包括以下步骤：I.气态铁五羰基热分解，得到具有球形初级颗粒的羰基铁粉末，II。 用氢气处理在步骤I中获得的羰基铁粉，导致金属球形初级粒子至少部分凝聚，III。 附聚物（=二次粒子）与五羰基铁的接触，IV。 在步骤III中施加五羰基铁的热分解以产生至少主要是无孔隙和无空隙的二次颗粒。 在催化剂存在下通过一氧化碳与氢气反应制备烯烃的方法，上述含铁非均相催化剂用作催化剂。

    Carbon-containing molybdenum and tungsten sulfide catalysts
    67.
    发明授权
    Carbon-containing molybdenum and tungsten sulfide catalysts 失效
    含碳钼和硫化钨催化剂

    公开(公告)号：US4826797A

    公开(公告)日：1989-05-02

    申请号：US929013

    申请日：1986-11-10

    申请人： Russell R. Chianelli ,  Theresa A. Pecoraro

    发明人： Russell R. Chianelli ,  Theresa A. Pecoraro

    IPC分类号： B01J27/20 ,  B01J27/24 ,  C10G45/04 ,  B01J27/049 ,  B01J27/047 ,  B01J27/051

    CPC分类号： B01J27/24 ,  B01J27/20 ,  C10G45/04

    摘要： Catalysts comprising a carbon-containing sulfide of molybdenum or tungsten are prepared by contacting, in the presence of sulfur, hydrogen and a hydrocarbon, ammonia and ammonium substituted molybdate, thiomolybdate, tungstate and thiotungstate salts at a temperature of from about 200.degree.-600.degree. C. These catalysts are useful for hydrotreating reactions. In a preferred embodiment, these catalysts will be promoted with certain transition metal sulfides, such as cobalt sulfide, which results in catalysts having greater activity than conventional catalysts such as cobalt-molybdate on alumina.

    摘要翻译： 包含钼或钨的含碳硫化物的催化剂通过在硫，氢和烃，氨和铵取代的钼酸盐，硫钼酸盐，钨酸盐和硫代钨酸盐的存在下，在约200-600℃的温度下接触来制备 这些催化剂可用于加氢处理反应。 在优选的实施方案中，这些催化剂将被某些过渡金属硫化物（例如硫化钴）促进，这导致催化剂比诸如氧化铝上的钼酸钼等常规催化剂具有更大的活性。

    Potassium carbonate with carbon supports and catalysts with elemental alkali metal
    68.
    发明授权
    Potassium carbonate with carbon supports and catalysts with elemental alkali metal 失效
    碳酸钾与碳载体和催化剂与元素碱金属

    公开(公告)号：US4656154A

    公开(公告)日：1987-04-07

    申请号：US825165

    申请日：1986-02-03

    申请人： Charles A. Drake

    发明人： Charles A. Drake

    IPC分类号： B01J23/04 ,  B01J27/20 ,  B01J27/232 ,  C07C2/24 ,  B01J23/02 ,  B01J23/72 ,  B01J23/74

    CPC分类号： B01J27/232 ,  B01J23/04 ,  B01J27/20 ,  C07C2/24 ,  C07C2521/18 ,  C07C2523/04 ,  C07C2527/232

    摘要： Catalyst supports, catalysts, method for the preparation thereof, and dimerization processes therewith are provided. Catalyst supports consist essentially of potassium carbonate with a crush strength of at least 5 pounds and at least one carbonaceous compound. Catalysts consist essentially of at least one elemental alkali metal deposited on the novel catalyst supports. Optionally, the catalysts further consist essentially of at least one promoter selected from the group consisting of elemental copper, elemental cobalt, and finely divided stainless steel.

    摘要翻译： 提供了催化剂载体，催化剂，其制备方法和二聚过程。 催化剂载体基本上由压碎强度至少为5磅的碳酸钾和至少一种含碳化合物组成。 催化剂基本上由沉积在新型催化剂载体上的至少一种元素碱金属组成。 任选地，催化剂还基本上由至少一种选自元素铜，元素钴和细碎不锈钢的助催化剂组成。