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    Method for the production of formaldehyde
    64.
    发明授权
    Method for the production of formaldehyde 有权
    甲醛生产方法

    公开(公告)号：US07943102B2

    公开(公告)日：2011-05-17

    申请号：US11463388

    申请日：2006-08-09

    Applicant: Giancarlo Sioli

    Inventor： Giancarlo Sioli

    IPC: B01J8/04 ,  B01J19/30 ,  B01J8/18 ,  B01J8/00 ,  B01J10/00 ,  B01J19/00

    CPC classification number: B01J8/067 ,  B01J8/0403 ,  B01J8/0419 ,  B01J8/0446 ,  C07C45/38 ,  C07C47/04

    Abstract: A method for formaldehyde production through catalytic oxidation of methanol, comprising the steps of feeding to a first oxidation catalytic bed (2) a gas flow comprising methanol and oxygen at a predetermined crossing linear flow rate, obtaining at the outlet of said first catalytic bed (2) a flow of gaseous reaction products comprising unreacted methanol, and feeding the flow of gaseous products to a second oxidation catalytic bed (6) is distinguished by the fact that the flow of gaseous reaction products comprising unreacted methanol is fed to the second catalytic bed (6) with a crossing linear flow rate substantially equal to said predetermined first catalytic bed (2) feeding flow rate.

    Abstract translation: 一种通过甲醇的催化氧化生产甲醛的方法，包括以下步骤：以预定的交联线性流速向第一氧化催化床（2）供给包含甲醇和氧气的气流，在所述第一催化床的出口 2）包含未反应的甲醇的气态反应产物流并将气态产物流送入第二氧化催化剂床（6）的特征在于将包含未反应的甲醇的气态反应产物的流量送入第二催化床 （6），其交叉线性流速基本上等于所述预定的第一催化床（2）进料流量。

    Fuel processing system and improved feedstock therefor
    65.
    发明授权
    Fuel processing system and improved feedstock therefor 有权
    燃料加工系统和改进的原料

    公开(公告)号：US07201783B2

    公开(公告)日：2007-04-10

    申请号：US10016807

    申请日：2001-11-01

    Applicant: David J. Edlund

    Inventor： David J. Edlund

    IPC: C01B3/32 ,  B01D53/22 ,  C01B3/50

    CPC classification number: B01J19/002 ,  B01J8/009 ,  B01J8/0403 ,  B01J2219/00268 ,  C01B3/323 ,  C01B2203/0233 ,  C01B2203/0261 ,  C01B2203/0405 ,  C01B2203/042 ,  C01B2203/0445 ,  C01B2203/047 ,  C01B2203/066 ,  C01B2203/1205 ,  C01B2203/1223 ,  H01M8/0612 ,  H01M8/0662

    Abstract: An improved feedstock for fuel processing systems, and fuel processing systems incorporating the same. The fuel processing system includes a fuel processor adapted to produce a product hydrogen stream from a carbon-containing feedstock. The fuel processing system may also include a fuel cell stack adapted to produce an electric current from the product hydrogen stream. The feedstock is at least substantially formed of a hydrocarbon or alcohol. In an exemplary embodiment, the feedstock includes methanol. The feedstock also includes at least one odorant adapted to produce a strong and characteristic odor, even when present in only low concentrations. The odorant, or odorants, are selected to be free or at least sufficiently free from compounds that will poison the catalyst used in the fuel processor.

    Abstract translation: 用于燃料处理系统的改进的原料，以及包含该原料的燃料处理系统。 燃料处理系统包括适于产生来自含碳原料的产物氢气流的燃料处理器。 燃料处理系统还可以包括适于从产物氢流产生电流的燃料电池堆。 原料至少基本上由烃或醇形成。 在一个示例性实施方案中，原料包括甲醇。 原料还包括至少一种适于产生强烈和特征气味的气味剂，即使仅以低浓度存在。 气味剂或气味剂被选择为游离或至少充分地不含将会燃烧在燃料处理器中使用的催化剂的化合物。

    Fuel processing system and improved feedstock therefor
    67.
    发明申请
    Fuel processing system and improved feedstock therefor 有权
    燃料加工系统和改进的原料

    公开(公告)号：US20020083645A1

    公开(公告)日：2002-07-04

    申请号：US10016807

    申请日：2001-11-01

    Inventor： David J. Edlund

    IPC: C10J001/00 ,  C10J001/28 ,  C10L001/32

    CPC classification number: B01J19/002 ,  B01J8/009 ,  B01J8/0403 ,  B01J2219/00268 ,  C01B3/323 ,  C01B2203/0233 ,  C01B2203/0261 ,  C01B2203/0405 ,  C01B2203/042 ,  C01B2203/0445 ,  C01B2203/047 ,  C01B2203/066 ,  C01B2203/1205 ,  C01B2203/1223 ,  H01M8/0612 ,  H01M8/0662

    Abstract: An improved feedstock for fuel processing systems, and fuel processing systems incorporating the same. The fuel processing system includes a fuel processor adapted to produce a product hydrogen stream from a carbon-containing feedstock. The fuel processing system may also include a fuel cell stack adapted to produce an electric current from the product hydrogen stream. The feedstock is at least substantially formed of a hydrocarbon or alcohol. In an exemplary embodiment, the feedstock includes methanol. The feedstock also includes at least one odorant adapted to produce a strong and characteristic odor, even when present in only low concentrations. The odorant, or odorants, are selected to be free or at least sufficiently free from compounds that will poison the catalyst used in the fuel processor.

    Abstract translation: 用于燃料处理系统的改进的原料，以及包含该原料的燃料处理系统。 燃料处理系统包括适于产生来自含碳原料的产物氢气流的燃料处理器。 燃料处理系统还可以包括适于从产物氢流产生电流的燃料电池堆。 原料至少基本上由烃或醇形成。 在一个示例性实施方案中，原料包括甲醇。 原料还包括至少一种适于产生强烈和特征气味的气味剂，即使仅以低浓度存在。 气味剂或气味剂被选择为游离或至少充分地不含将会燃烧在燃料处理器中使用的催化剂的化合物。

    Apparatus for performing chemical reactions under pressure in a multi-stage reaction zone with external intermediary thermal conditioning
    69.
    发明授权
    Apparatus for performing chemical reactions under pressure in a multi-stage reaction zone with external intermediary thermal conditioning 失效
    用于在具有外部中间热调节的多级反应区中进行压力下的化学反应的装置

    公开(公告)号：US5192512A

    公开(公告)日：1993-03-09

    申请号：US709932

    申请日：1991-06-04

    Applicant: Dang V. Quang ,  Pierre Ham ,  Daniel Gelas ,  Christian Legrand

    Inventor： Dang V. Quang ,  Pierre Ham ,  Daniel Gelas ,  Christian Legrand

    IPC: B01J8/00 ,  B01J8/04 ,  C01C1/04 ,  C07C29/152

    CPC classification number: C01C1/0423 ,  B01J8/0005 ,  B01J8/0403 ,  C07C29/152 ,  Y02P20/52

    Abstract: The invention concerns a process and an apparatus for performing chemical reactions under pressure in the presence of a solid catalyst in a multi-stage reaction zone, after external intermediary thermal conditioning. This process may be used for the synthesis of ammonia or methanol or for gasoline reforming. It is characterized in that at least one reaction fluid is introduced into at least one compartment, a first reaction effluent is recovered, a heat exchange takes place, outside the reaction zone, between a first effluent and an external heat exchange medium, then the first effluent is introduced into at least one subsequent compartment and a second reaction effluent is recovered from the subsequent compartment. The reaction fluid or reaction effluent circulates cross-wise in the compartments substantially perpendicularly to the reaction zone, the compartments being tight and of elongate shape, each compartment being adjacent to one or two other compartments, each group of two adjacent compartments comprising a common partition wall, either substantially parallel to generatrix or substantially oblique with respect thereto.

    Abstract translation: 本发明涉及在外部中间热调节之后，在多级反应区中的固体催化剂存在下，在压力下进行化学反应的方法和装置。 该方法可用于氨或甲醇的合成或用于汽油重整。 其特征在于，将至少一个反应流体引入至少一个隔室中，回收第一反应流出物，在反应区外部，在第一流出物和外部热交换介质之间进行热交换，然后将第一反应流出物 将流出物引入至少一个随后的隔室中，并从随后的室回收第二反应流出物。 反应流体或反应流出物在基本上垂直于反应区的隔室中交叉循环，隔室是紧密和细长的形状，每个隔室与一个或两个其它隔室相邻，每组两个相邻隔室包括公共隔板 基本上平行于母线或相对于母线基本倾斜。

    System to reduce energy consumption in heterogeneous synthesis reactors and related reactors
    70.
    发明授权
    System to reduce energy consumption in heterogeneous synthesis reactors and related reactors 失效
    降低异质合成反应堆和相关反应堆能源消耗的系统

    公开(公告)号：US4946657A

    公开(公告)日：1990-08-07

    申请号：US110925

    申请日：1987-10-20

    Applicant: Umberto Zardi

    Inventor： Umberto Zardi

    IPC: B01J8/04 ,  C01C1/04

    CPC classification number: C01C1/0423 ,  B01J8/0403 ,  Y02P20/52

    Abstract: The system to reduce the energy consumption of heterogeneous synthesis reactors, particularly of ammonia reactors, f.i. the "Chemico"-type reactor, foresees the insertion of two cylindrical walls at least partially perforated in order to annularly delimit the catalytic beds; the first outer wall (Fe) having a diameter (Di) slightly smaller than diameter (Dc) of the cartridge (C), has a height (Hi) higher than (H'i) of the internal cylindrical wall (Fi) which has a diameter inferior to the above mentioned (Di), but superior to the external diameter (Dt) of the central feed pipe (T) of the quench gas (QG). The top (SO) of the internal cylindrical wall (Fi) is closed by a cover (CO) that has a distance from the bottom (FO) of the basket equal to the mentioned height (H'i) of the internal cylindrical wall. The catalytic bed is therefore annular in diameter (Di-D'i) on all of the said height (H'i), but is substantially cylindrical (of diameter Di) on the height (Hi-H'i).In the substantially annular zone (Q) between the cylindrical internal perforated wall (Fi) and the external face of the pipe (T), which is also at least partially perforated, the reacted and quench gases are collected.

    Abstract translation: 减少非均相合成反应堆，特别是氨反应堆f.i的能源消耗的系统。 “Chemico”型反应器预计将至少部分穿孔的两个圆柱形壁插入以环形地界定催化床; 具有比盒（C）的直径（Dc）略小的直径（Di）的第一外壁（Fe）的高度（Hi）高于内壁（Fi）的（H'i） 直径小于上述（Di），但优于骤冷气体（QG）的中心供给管（T）的外径（Dt）。 内部圆柱形壁（Fi）的顶部（SO）由盖（CO）封闭，盖（CO）与篮子底部（FO）的距离等于内圆柱壁的提到的高度（H'i）。 因此，催化床在所有高度（H'i）上都是环形直径（Di-D'i），但是在高度（Hi-H'i）上基本上是圆柱形（直径Di）。 在圆筒形内部多孔壁（Fi）和也至少部分穿孔的管道（T）的外表面之间的大致环形区域（Q）中，收集反应和骤冷气体。

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