摘要:
A process for producing multicoat color and/or effect finishes on motor vehicle bodies or parts thereof (substrates), in which (I) a pigmented powder coating material is applied to the substrates, (II) the resulting powder coating film is partly or fully cured, (III) the powder coating film or powder coating is overcoated with a solid-color topcoat, with a basecoat and a clearcoat, or with a clearcoat, after which (IV) the resulting films are cured in each case individually or together with other films (wet-on-wet technique), wherein said powder coating material (A) comprises at least one carboxyl-containing polyester and (B) comprises at least one glycidyl ester of an aromatic or of a saturated or unsaturated cycloaliphatic dicarboxylic acid and/or at least one N,N,Nnull,Nnull-tetrakis(beta-hydroxyalkyl)alkanedicarboxamide, or (A) comprises at least one hydroxyl-containing polyester and (B) comprises at least one internally blocked uretdione of a diisocyanate.
摘要:
The present invention provides a method of forming a multilayer coating film comprising the step (I) of coating an article to be coated with an electrodeposition coating containing two resin components incompatible with each other followed by curing by heating to form an electrodeposited coating film, the step (II) of applying a water-borne intermediate coating onto the electrodeposited coating film to form an uncured intermediate coating film, the step (III) of applying a water-borne base coating onto the intermediate coating film to form an uncured base coating film, the step (IV) of applying a clear coating onto the base coating film to form an uncured clear coating film and the step (V) of curing the intermediate coating film, the base coating film and the clear coating film simultaneously by heating to thereby obtain a multilayer coating film.
摘要:
Disclosed is an acid-epoxy curing type powder coating composition which forms a coated film having excellent yellow resistance and appearance. The powder coating composition comprises: (A) an epoxy group-containing acrylic resin prepared by polymerizing the monomer mixture which comprises, (a) 35 to 65% by weight of an epoxy group-containing ethylenically unsaturated monomer, and (b) remainder amount of an ethylenically unsaturated monomer which is different from the epoxy group-containing ethylenically unsaturated monomer; (B) a polycarboxylic acid; and (C) an antioxidant having a melting point of from 50.degree. to 140.degree. C.
摘要:
The present invention provides a method for film formation, which comprises applying onto a substrate an electrocoating (A) and an intermediate coating (B) in this order, heat-curing the formed films of the coatings (A) and (B), applying thereon a liquid deep color coating (C) which comprises 100 parts by weight of a thermosetting resin composition, 0.1-30 parts by weight of an aluminum powder having an average particle diameter of 10.mu. or less, 1-100 parts by weight of a titanium oxide pigment and 0.1-10 parts by weight of a carbon black pigment and which shows a film hiding power of 25.mu. or less and a film elongation ratio of 10-50% at 20.degree. C., a liquid color clear coating (D) which comprises a thermosetting resin composition and a color pigment as the main components and which shows a film hiding power of 50.mu. or more and a film elongation ratio of 10% or less at 20.degree. C., and a clear coating (E) in this order on a wet-on-wet basis, and heating the formed films of the coatings (C), (D) and (E) to crosslink and cure the three films simultaneously. According to the method, part of the heat-curing steps employed in multilayer film formation can be eliminated and a multilayer film of smaller thickness and improved properties (e.g. improved surface smoothness and chipping resistance) can be obtained.
摘要:
The invention provides a method of forming a coating film by forming in sequence a pigmented base coat and a clear top coat on a substrate followed by finishing by the two-coat one-bake technique, the method being characterized by using, as a coating composition for pigmented base coat formation, a composition comprising, as essential components thereof,(1) an OH-containing resin,(2) an amino resin,(3) a polyorganosiloxane which has, on an average, at least two groups, per molecule, each selected from the class consisting of a silanol group and an alkoxysilane group and has a number average molecular weight of at least 1,000,(4) a metal chelate compound(5) a flaky metal powder and/or a mica powder, and(6) an organic solvent,and using, as a coating composition for clear top coat formation, a composition comprising, as essential components thereof,(1) an OH- and epoxy-containing base resin which further contains at least one group selected from the group consisting of a silanol group and a hydrolyzable group bound directly to a silicon atom,(2) a curing catalyst, and(3) an organic solvent.
摘要:
The present invention provides a method for forming a coating film, comprising the steps of:(a) coating a metal panel with a cationic electrophoretic coating composition and heating the composition to form an electrophoretic coating,(b) applying to the electrophoretic coating an aqueous primer containing a polyurethane emulsion prepared by subjecting a carboxyl-containing urethane prepolymer to chain extension by water,(c) applying an intermediate coating composition to the primer surface,(d) baking the aqueous primer and the intermediate coating composition at the same time, and(e) applying a top coating composition to the cured coating and baking the composition.
摘要:
A method for improving the properties of a coated reinforced thermoplastic substrate which forms surface irregularities when cooled after being heated to elevated temperatures is disclosed. The method comprises coating the substrate with primer coating compositions, wet-on-wet, comprising first applying a rigid primer composition followed by applying a flexible primer composition, curing the composite primer coating and thereafter applying a topcoating. The coated substrates exhibit improved properties, especially distinctness of image (DOI).
摘要:
The invention relates to a process for coating an electrically conductive substrate, the said substrate being immersed in an aqueous bath based on a cationic synthetic resin binder which is at least in part neutralized with acids and contains amino and/or hydroxyl groups. The said bath contains a mixture of crosslinking agents as well as pigments, fillers, corrosion inhibitors, paint auxiliary substances, and, if appropriate, catalysts, as well as organic solvents in an amount of up to 15% by weight based on the total weight of the coating, the said substrate being cathodically connected. By the action of direct current, a film is deposited on the substrate, after which the said substrate is removed from the bath and the film is cured by stoving, the mixture of crosslinking agents comprising at least two crosslinking agents of different reactivities based on activated esters and/or polyisocyanates blocked by different blocking agents. The expression "different reactivities" means that the crosslinking reaction commences by heating to temperatures which are separated by at least 10.degree. C. and that crosslinking agent which is first to react is present in an amount of 15 to 60 mol %, based on the mixture of the crosslinking agents. This first coat is rinsed and one or more further cathodic coats are deposited before stoving. After each coat has been rinsed, all the coats are cured together.
摘要:
The present invention relates to a process for producing a multicoat paint system on a metallic substrate, by producing a basecoat film or two or more directly successive basecoat films directly on a metallic substrate coated with a cured electrocoat system, producing a clearcoat directly on the one or the topmost of the two or more basecoat films, and then jointly curing the one or the two or more basecoat films and the clearcoat film, and which comprises at least one basecoat material used in producing the basecoat films comprising at least one aqueous polyurethane-polyurea dispersion (PD) comprising polyurethane-polyurea particles, with the polyurethane-polyurea particles present in the dispersion (PD) comprising anionic groups and/or groups which can be converted into anionic groups, and having an average particle size of 40 to 2000 nm and also a gel fraction of at least 50%.
摘要:
A coating method includes coating a first coating composition including a heterogeneous photoinitiator having a first photoinitiator and a second photoinitiator on a substrate, irradiating ultraviolet rays having a first wavelength into the first coating composition to form a first coating layer and cure the first photoinitiator, coating a second coating composition on the first coating layer, and irradiating ultraviolet rays having a second wavelength different than the first wavelength into the second coating composition to form a second coating layer.