公开(公告)号：US09406930B2

公开(公告)日：2016-08-02

申请号：US14366871

申请日：2012-12-20

Applicant: SUMITOMO METAL MINING CO., LTD.

Inventor： Atsushi Fukui ,  Hiroyuki Toya

IPC: H01M4/00 ,  H01M4/36 ,  H01M4/505 ,  H01M4/525 ,  C01G53/00 ,  H01M4/04 ,  H01M4/1391 ,  H01M10/0525

CPC classification number: H01M4/364 ,  C01G53/006 ,  C01G53/42 ,  C01G53/44 ,  C01G53/50 ,  C01P2004/32 ,  C01P2004/45 ,  C01P2004/51 ,  C01P2004/61 ,  C01P2004/84 ,  C01P2006/12 ,  H01M4/0471 ,  H01M4/0497 ,  H01M4/1391 ,  H01M4/505 ,  H01M4/525 ,  H01M10/0525 ,  Y02E60/122 ,  Y02P70/54

Abstract: Provided is a lithium composite oxide having a uniform and suitable particle size and high specific surface area due to a hollow structure that can be produced on an industrial scale. A nickel composite hydroxide as a raw material thereof is obtained controlling the particle size distribution of the nickel composite hydroxide, the nickel composite hydroxide having a structure comprising a center section that comprises minute primary particles, and an outer-shell section that exists on the outside of the center section and comprises plate shaped primary particles that are larger than the primary particles of the center section, by a nucleation process and a particle growth process that are separated by controlling the pH during crystallization, and by controlling the reaction atmosphere in each process and the manganese content in a metal compound that is supplied in each process.

Abstract translation: 本发明提供一种锂复合氧化物，其具有均匀且适当的粒径和比表面积，由于可以工业规模生产的中空结构。 获得镍复合氢氧化物作为其原料，其控制镍复合氢氧化物的粒度分布，镍复合氢氧化物具有包括微小初级颗粒的中心部分的结构和存在于外部的外壳部分 的中心部分，并且通过成核过程和通过控制结晶期间的pH分离的成核过程和颗粒生长过程，并且通过控制每个过程中的反应气氛，包括大于中心部分的初级颗粒的板状初级颗粒 以及在各工序中供给的金属化合物中的锰含量。

公开(公告)号：US09406928B2

公开(公告)日：2016-08-02

申请号：US14696745

申请日：2015-04-27

Applicant: Sumitomo Metal Mining Co., Ltd.

Inventor： Rei Kokado ,  Kensaku Mori

IPC: H01M4/131 ,  H01M4/36 ,  H01M4/505 ,  H01M4/525 ,  B82Y30/00 ,  C01G53/00 ,  H01M4/485 ,  H01M10/0525 ,  H01M4/02

CPC classification number: H01M4/131 ,  B82Y30/00 ,  C01G53/42 ,  C01G53/50 ,  C01P2002/52 ,  C01P2002/54 ,  C01P2004/03 ,  C01P2004/45 ,  C01P2004/61 ,  C01P2004/64 ,  C01P2006/12 ,  H01M4/366 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M10/0525 ,  H01M2004/028 ,  Y02E60/122 ,  Y02P70/54 ,  Y02T10/7011

Abstract: Provided is a method for manufacturing the positive electrode active material for nonaqueous electrolyte secondary batteries, the method comprising: a first step, wherein an alkaline solution with a tungsten compound dissolved therein is added to and mixed with a lithium metal composite oxide powder represented by a general formula LizNi1—x—yCoxMyO2 (wherein, 0.10≦x≦0.35, 0≦y≦0.35, 0.97≦Z≦1.20, and M is at least one element selected from Mn, V, Mg, Mo, Nb, Ti, and Al), including primary particles and secondary particles composed of aggregation of the primary particles, and thereby W is dispersed on a surface of the primary particles; and a second step, wherein, by heat treating the mixture of the alkaline solution with the tungsten compound dissolved therein and the lithium metal composite oxide powder, fine particles containing W and Li are formed on a surface of the primary particles.

Abstract translation: 本发明提供一种非水电解质二次电池用正极活性物质的制造方法，其特征在于，包括：第一工序，将其中溶解有钨化合物的碱性溶液加入并与其混合，所述锂金属复合氧化物粉末由 通式LizNi1-x-yCoxMyO2（其中，0.10≤x≤0.35,0≤y≤0.35,0.97≤Z≤1.20，M是选自Mn，V，Mg，Mo，Nb，Ti和 Al），包括由一次粒子的聚集构成的一次粒子和二次粒子，由此将W分散在一次粒子的表面上; 和第二步骤，其中通过将溶解的钨化合物的碱溶液与锂金属复合氧化物粉末进行热处理，在一次颗粒的表面上形成含有W和Li的微粒。

公开(公告)号：US20160111725A1

公开(公告)日：2016-04-21

申请号：US14979629

申请日：2015-12-28

Applicant: TODA KOGYO CORPORATION

Inventor： Manabu Yamamoto ,  Daisuke Nishikawa ,  Kazutoshi Ishizaki ,  Osamu Sasaki ,  Hideaki Sadamura

IPC: H01M4/58 ,  H01M10/0525

CPC classification number: H01M4/5815 ,  C01G53/006 ,  C01G53/54 ,  C01P2002/52 ,  C01P2002/72 ,  C01P2004/03 ,  C01P2004/45 ,  C01P2004/51 ,  C01P2004/61 ,  C01P2006/12 ,  C01P2006/40 ,  H01M4/505 ,  H01M4/525 ,  H01M10/0525 ,  H01M2004/021 ,  H01M2004/028 ,  H01M2220/30

Abstract: The present invention relates to positive electrode active substance particles comprising a compound having a spinel type structure comprising at least Li, Ni and Mn, and having an Li content which is controlled such that a molar ratio of Li(Ni+Mn) therein is 0.3 to 0.65, an Ni content of 5 to 25% by weight, an Na content of 0.05 to 1.9% by weight and an S content of 0.0005 to 0.16% by weight, a sum of the Na content and the S content being 0.09 to 1.9005% by weight. The positive electrode active substance particles according to the present invention can be suitably used as positive electrode active substance particles for non-aqueous electrolyte secondary batteries which can exhibit a high discharge voltage and an excellent discharge capacity.

公开(公告)号：US20160089334A1

公开(公告)日：2016-03-31

申请号：US14892385

申请日：2014-05-14

Applicant: MITSUI CHEMICALS, INC.

Inventor： Norio NAKAYAMA ,  Hongbo WANG ,  Haruyuki MAKIO

IPC: A61K9/14 ,  F16L59/02 ,  C08K7/26 ,  C01B33/12

CPC classification number: A61K9/14 ,  C01B13/32 ,  C01B33/12 ,  C01B37/02 ,  C01P2004/04 ,  C01P2004/32 ,  C01P2004/45 ,  C01P2004/52 ,  C01P2004/62 ,  C01P2004/64 ,  C01P2006/12 ,  C01P2006/16 ,  C01P2006/17 ,  C08K7/24 ,  C08K7/26 ,  C08L101/00 ,  C09D7/40 ,  C09D7/61 ,  C09D7/66 ,  C09D11/00 ,  C09D11/037 ,  C09D201/00 ,  F16L59/028

Abstract: Provided are porous metal oxide particles, in which 50% mean particle size by volume is equal to or larger than 50 nm and equal to or smaller than 300 nm, ratio of 90% mean particle size by volume to 50% mean particle size by volume (D90/D50) is equal to or lower than 2.0, the particles have mesopores having a pore size determined by BJH method of equal to or larger than 5 nm and equal to or smaller than 30 nm, and the structure of the pores is a three-dimensional cubic phase structure.

Abstract translation: 提供的是多孔金属氧化物颗粒，其中平均粒径为50％的平均粒径等于或大于50nm且等于或小于300nm，平均粒径为90体积％至平均粒径的50％ （D90 / D50）等于或低于2.0，颗粒具有通过BJH方法确定的孔径等于或大于5nm且等于或小于30nm的中孔，并且孔的结构为 三维立方相结构。

公开(公告)号：US20160009567A1

公开(公告)日：2016-01-14

申请号：US14812125

申请日：2015-07-29

Applicant: ISHIHARA SANGYO KAISHA, LTD.

Inventor： Nariaki MORIYAMA ,  Masatoshi HONMA ,  Kazuyoshi TAKESHIMA ,  Yusuke OKUDA ,  Naoya NAGAHASHI

IPC: C01G23/00 ,  H01M4/62 ,  H01M4/485

CPC classification number: C01G23/005 ,  C01P2004/45 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/16 ,  C01P2006/40 ,  H01M4/131 ,  H01M4/485 ,  H01M4/625 ,  Y02E60/122 ,  Y02P70/54

Abstract: Disclosed is lithium titanate having excellent rate properties and useful for electricity storage devices, which is produced by preparing lithium titanate secondary particles that are aggregates of lithium titanate primary particles and forming at least macro-pores on the surfaces of the secondary particles. The lithium titanate can be produced by a process which comprises drying and granulating a slurry comprising crystalline titan oxide, a titanic acid compound and a lithium compound and firing the granulated product to thereby produce lithium titanate secondary particles, wherein (1) the crystalline titan oxide to be used comprises at least two types of crystalline titan oxide particles having different average particle diameters from each other, and/or (2) the crystalline titan oxide is used in an amount at least four-fold larger than that of the titanic acid compound in terms of TiO2 content by weight. The lithium titanate can achieve a satisfactory level of charge-discharge capacity for practical uses when used in a electricity storage device without requiring the use of a carbon-containing substance, such as carbon black, acethylene black or Ketjen black, as an electrically conductive material in combination, in spite of a fact that lithium titanate has an electrically insulating properties by nature.

Abstract translation: 公开了通过制备钛酸锂一次粒子的聚集体并在二次粒子的表面上形成至少大孔的钛酸锂二次粒子制造的，具有优异的速率性能并且可用于蓄电装置的钛酸锂。 钛酸锂可以通过包括干燥和造粒包含结晶氧化钛，钛酸化合物和锂化合物的浆料并焙烧该造粒产物从而制备钛酸锂二次颗粒的方法制备，其中（1）结晶氧化钛 所使用的结晶氧化钛粒子的平均粒径至少为2种以上，和/或（2）结晶性氧化钛的使用量比钛酸化合物的至少4倍 以TiO 2重量比计。 钛酸锂在用于蓄电装置时可以实现满足实际使用的充放电能力，而不需要使用碳黑，丙烯黑或科琴黑等含碳物质作为导电材料 尽管钛酸锂本质上具有电绝缘性，但是它们组合在一起。

公开(公告)号：US20150311519A1

公开(公告)日：2015-10-29

申请号：US14693200

申请日：2015-04-22

Applicant: TDK CORPORATION

Inventor： Yasuyuki KAWANAKA ,  Tomohiko KATO ,  Atsushi SANO

IPC: H01M4/48 ,  C01G49/06 ,  H01M10/052

CPC classification number: C01G49/06 ,  C01P2004/04 ,  C01P2004/45 ,  C01P2006/40 ,  H01M2/16 ,  H01M4/0404 ,  H01M4/0471 ,  H01M4/131 ,  H01M4/1391 ,  H01M4/525 ,  H01M4/622 ,  H01M4/625 ,  H01M10/052 ,  H01M10/0525 ,  H01M10/0568 ,  H01M10/0569 ,  H01M2004/021 ,  H01M2004/027 ,  Y02E60/122

Abstract: A negative electrode active material for a lithium ion secondary battery includes secondary particles formed by primary particles containing iron oxide that are linked in a chain.

Abstract translation: 用于锂离子二次电池的负极活性材料包括由连接在链中的含有氧化铁的一次粒子形成的二次粒子。

公开(公告)号：US09077034B2

公开(公告)日：2015-07-07

申请号：US13138944

申请日：2009-12-27

Applicant: Qianxin Xiang ,  Xiaolian Zhao

Inventor： Qianxin Xiang ,  Xiaolian Zhao

IPC: H01M4/13 ,  H01M4/505 ,  H01M4/525 ,  C01G45/12 ,  C01G51/00 ,  C01G53/00 ,  H01M4/36 ,  H01M4/131 ,  H01M10/0525

CPC classification number: H01M4/505 ,  C01G45/1242 ,  C01G51/42 ,  C01G53/42 ,  C01G53/44 ,  C01P2002/54 ,  C01P2002/72 ,  C01P2004/03 ,  C01P2004/45 ,  C01P2004/51 ,  C01P2004/61 ,  C01P2004/62 ,  C01P2004/80 ,  C01P2006/12 ,  C01P2006/40 ,  H01M4/131 ,  H01M4/364 ,  H01M4/525 ,  H01M10/0525 ,  Y02E60/122

Abstract: Provided are a high manganese polycrystalline anode material, preparation method thereof and dynamic lithium ion battery. The general formula of the high manganese polycrystalline anode material is LiwMnx(CoNi)yOz, wherein x=0.4-2.0, y=0.1-0.6, x+y

Abstract translation: 提供一种高锰多晶阳极材料及其制备方法和动态锂离子电池。 高锰多晶阳极材料的通式为LiwMnx（CoNi）yOz，其中x = 0.4-2.0，y = 0.1-0.6，x + y <2，z≥2，w≥1。 Mn的重量不小于LiwMnx（CoNi）yOz的重量的40％，其粒径为7-20微米。 高锰多晶阳极材料具有选自LiMn2O4，LiCOn（NiMn）1-nO2，LiNi0.8Co0.2O2，LiCoO2，LiNinMn1-nO2，LiMn2nNi2（1-n）O4和LiNiO2）中的两种以上晶格结构，它们是混合的 状态或共生状态，其中n <1。 阳极材料的比能大于155Wh / K，当充放电倍增动力为1C和55℃时500次充放电后的容量保持率不低于80％， 在25℃，循环寿命不低于1000次，保存率超过80％。 阳极材料的加工性良好。

公开(公告)号：US20150158728A1

公开(公告)日：2015-06-11

申请号：US14567220

申请日：2014-12-11

Applicant: CLARIANT (CANADA) INC.

Inventor： Guoxian LIANG ,  Patrick CHAREST ,  Michel GAUTHIER ,  Abdelbast GUERFI ,  Christophe MICHOT ,  Karim ZAGHIB

IPC: C01B25/45 ,  H01M4/62 ,  H01M4/58

CPC classification number: C01B25/45 ,  B82Y30/00 ,  C01P2002/32 ,  C01P2002/72 ,  C01P2004/03 ,  C01P2004/04 ,  C01P2004/45 ,  C01P2004/50 ,  C01P2004/51 ,  C01P2004/52 ,  C01P2004/53 ,  C01P2004/61 ,  C01P2004/62 ,  C01P2004/64 ,  C09C1/00 ,  C09C1/22 ,  C09C3/08 ,  H01M4/136 ,  H01M4/5825 ,  H01M4/625 ,  H01M2004/021

Abstract: A method for preparing an electrode material, said material comprising complex oxide particles having a non-powdery conductive carbon deposit on at least part of their surface, said method comprising: grinding into nanometer size complex oxide particles or particles of complex oxide precursors, wherein the grinding is performed in a bead mill on particles dispersed in a carrier solvent, adding an organic carbon precursor to the oxide particles or oxide precursor particles before, during or after said grinding, and pyrolysing the mixture thus obtained, selecting the size of the particles to grind, the size of the beads used to grind, and the size of the resulting particles such that: 0.004

Abstract translation: 一种制备电极材料的方法，所述材料包括在其表面的至少一部分上具有非粉末状导电碳沉积物的复合氧化物颗粒，所述方法包括：研磨成纳米尺寸的复合氧化物颗粒或复合氧化物前体的颗粒，其中 在珠磨机中在分散在载体溶剂中的颗粒上进行研磨，在所述研磨之前，期间或之后向氧化物颗粒或氧化物前体颗粒加入有机碳前体，并热解所得到的混合物，将颗粒的尺寸选择为 研磨，用于研磨的珠的尺寸和所得颗粒的尺寸，使得：0.004

公开(公告)号：US20150137026A1

公开(公告)日：2015-05-21

申请号：US14399664

申请日：2013-03-19

Applicant: Martin Engler ,  Krishna B. Uibel

Inventor： Martin Engler ,  Krishna B. Uibel

IPC: C09C1/00 ,  C08K3/38

CPC classification number: C09C1/00 ,  C01B21/064 ,  C01B21/0648 ,  C01P2004/03 ,  C01P2004/45 ,  C01P2004/61 ,  C04B35/581 ,  C04B35/583 ,  C04B35/62675 ,  C04B35/6303 ,  C04B35/65 ,  C04B2235/3206 ,  C04B2235/3208 ,  C04B2235/3217 ,  C04B2235/3224 ,  C04B2235/3225 ,  C04B2235/3232 ,  C04B2235/3409 ,  C04B2235/3418 ,  C04B2235/3813 ,  C04B2235/386 ,  C04B2235/3865 ,  C04B2235/3869 ,  C04B2235/3873 ,  C04B2235/3886 ,  C04B2235/402 ,  C04B2235/404 ,  C04B2235/428 ,  C04B2235/46 ,  C04B2235/465 ,  C04B2235/5427 ,  C04B2235/5436 ,  C04B2235/5445 ,  C04B2235/80 ,  C08K3/38 ,  C08K2003/385 ,  Y10T428/2982

Abstract: The invention relates to boron nitride agglomerates, comprising hexagonal boron nitride primary particles, wherein the hexagonal boron nitride primary particles are connected to one another by means of an inorganic binding phase comprising at least one nitride and/or oxynitride. The invention also relates to a method for producing such boron nitride agglomerates, wherein boron nitride starting powder in the form of boron nitride primary particles is mixed with binding-phase raw materials, processed into granules or moulded bodies and these are then subjected to a temperature treatment at a temperature of at least 1000° C. in a nitriding atmosphere, and the obtained granules or moulded bodies are comminuted and/or fractionated if necessary. The boron nitride agglomerates according to the invention are suitable as a filler for polymers to be used for producing polymer-boron nitride composite materials.

Abstract translation: 本发明涉及包含六方氮化硼一次粒子的氮化硼附聚物，其中六方氮化硼一次粒子通过包含至少一种氮化物和/或氮氧化物的无机结合相彼此连接。 本发明还涉及一种生产这种氮化硼附聚物的方法，其中氮化硼一次粒子形式的氮化硼起始粉末与结合相原料混合，加工成颗粒或模制体，然后将其经受温度 在氮化气氛中在至少1000℃的温度下进行处理，如果需要，将得到的颗粒或成型体粉碎和/或分级。 根据本发明的氮化硼附聚物适用作用于生产聚合物 - 氮化硼复合材料的聚合物的填料。

公开(公告)号：US20150044469A1

公开(公告)日：2015-02-12

申请号：US14385897

申请日：2013-03-22

Applicant: S.A. Lhoist Recherche et Developpement

Inventor： Marion Lorgouilloux ,  Robert Sebastian Gartner ,  Marc Pelletier ,  Thierry Chopin

IPC: C09K21/02

CPC classification number: C09K21/02 ,  C01F5/24 ,  C01F11/18 ,  C01F11/181 ,  C01P2004/03 ,  C01P2004/20 ,  C01P2004/45 ,  C01P2004/61 ,  C01P2006/11 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/32 ,  C01P2006/82 ,  C04B2/10 ,  C04B2/102 ,  C04B14/26 ,  C04B18/027 ,  C04B28/10 ,  C04B28/105 ,  C04B2111/28 ,  Y10T428/2982 ,  C04B14/28 ,  C04B40/0231 ,  C04B40/0263

Abstract: A mineral composition made from a mixed solid phase of calcium and magnesium carbonates, method of preparing same and use thereof. A mineral composition made from a mixed solid phase of calcium and magnesium carbonates, formed from a crystallised calcium portion and a crystallised magnesium portion in the form of platelets, the crystals of the calcium portion and those of the magnesium portion being aggregated in the form of composite aggregates, said aggregates themselves being at least partially agglomerated, said calcium portion comprising at least one carbonate chosen from the group consisting of calcite, aragonite and the mixtures thereof, said magnesium portion comprising hydromagnesite in platelet form, said mixed solid phase having a bulk density less than or equal to 250 kg/m3, and greater than or equal to 80 kg/m3, measured according to standard EN 459.2.

Abstract translation: 由碳酸钙和镁的混合固相制备的矿物组合物，其制备方法及其用途。 由结晶的钙部分形成的钙和镁碳酸盐的混合固相制成的矿物组合物和以血小板形式的结晶的镁部分，钙部分的晶体和镁部分的晶体以 所述聚集体本身至少部分凝聚，所述钙部分包含至少一种选自方解石，霰石及其混合物的碳酸盐，所述镁部分包含片状形式的水镁石，所述混合固相具有块状 密度小于或等于250kg / m 3，并且大于或等于80kg / m 3，根据标准EN 459.2测量。