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704 条记录 (耗时 0.025 秒)

    Catalyst comprising n-substituted cylic imides and processes for preparing organic compounds with the catalyst
    61.
    发明申请
    Catalyst comprising n-substituted cylic imides and processes for preparing organic compounds with the catalyst 失效
    包含n-取代的酰亚胺的催化剂和用催化剂制备有机化合物的方法

    公开(公告)号：US20030013603A1

    公开(公告)日：2003-01-16

    申请号：US10181239

    申请日：2002-07-15

    发明人： Yasutaka Ishii ,  Tatsuya Nakano ,  Takahiro Iwahama ,  Naruhisa Hirai

    IPC分类号： B01J031/00

    CPC分类号： C07C45/34 ,  B01J23/34 ,  B01J23/75 ,  B01J31/0247 ,  B01J31/2208 ,  B01J2231/348 ,  B01J2231/42 ,  B01J2531/72 ,  B01J2531/845 ,  C07C45/00 ,  C07C45/33 ,  C07C45/36 ,  C07C51/265 ,  C07C51/313 ,  C07D207/46 ,  C07D209/48 ,  C07D215/54 ,  Y02P20/55 ,  C07C49/403 ,  C07C49/78 ,  C07C65/32 ,  C07C63/26 ,  C07C63/04 ,  C07C55/14

    摘要： A catalyst of the invention includes an imide compound having a N-substituted cyclic imide skeleton represented by following Formula (I): 1 wherein R is a hydroxyl-protecting group. Preferred R is a hydrolyzable protecting group. R may be a group obtained from an acid by eliminating an OH group therefrom. Such acids include, for example, carboxylic acids, sulfonic acids, carbonic acid, carbamic acid, sulfuric acid, nitric acid, phosphoric acids and boric acids. The catalyst may include the imide compound and a metallic compound in combination. In the presence of the catalyst, (A) a compound capable of forming a radical is allowed to react with (B) a radical scavenging compound and thereby yields an addition or substitution reaction product of the compound (A) and the compound (B) or a derivative thereof. This catalyst can produce an organic compound with a high selectivity in a high yield as a result of, for example, an addition or substitution reaction under mild conditions.

    摘要翻译： 本发明的催化剂包括具有由下式（I）表示的N-取代的环状酰亚胺骨架的酰亚胺化合物：其中R是羟基保护基。 优选的R是可水解的保护基团。 R可以是从酸中除去OH基团而获得的基团。 这些酸包括例如羧酸，磺酸，碳酸，氨基甲酸，硫酸，硝酸，磷酸和硼酸。 催化剂可以组合包括酰亚胺化合物和金属化合物。 在催化剂存在下，使（A）能够形成自由基的化合物与（B）自由基清除化合物反应，从而得到化合物（A）和化合物（B）的加成或取代反应产物， 或其衍生物。 作为例如在温和条件下的添加或取代反应的结果，该催化剂可以以高产率生产高选择性的有机化合物。

    Process for the preparation of organic compounds with manganese cataylsts or the like
    62.
    发明申请
    Process for the preparation of organic compounds with manganese cataylsts or the like 失效
    用锰催化剂等制备有机化合物的方法

    公开(公告)号：US20020165416A1

    公开(公告)日：2002-11-07

    申请号：US09959843

    申请日：2001-11-09

    发明人： Yasutaka Ishii ,  Takahiro Iwahama ,  Satoshi Sakaguchi ,  Tatsuya Nakano

    IPC分类号： C07D37/20 ,  C07C045/28 ,  C07C027/10

    CPC分类号： C07C403/02 ,  C07C45/33 ,  C07C45/69 ,  C07C51/56 ,  C07C67/347 ,  C07C253/30 ,  C07C2601/14 ,  C07D307/20 ,  C07D307/33 ,  C07D307/83 ,  C07D313/04 ,  C07C49/413 ,  C07C49/403 ,  C07C49/395 ,  C07C49/82 ,  C07C49/683 ,  C07C49/04 ,  C07C55/21 ,  C07C69/708 ,  C07C69/34 ,  C07C69/716 ,  C07C255/04

    摘要： A process of the present invention produces an organic compound by allowing a compound containing an electron attractive group of following Formula (1): 1 wherein Y is an electron attractive group; and Rb and Rc are each a hydrogen atom or an organic group, where Y, Rb and Rc may respectively be combined with each other to form a ring with an adjacent carbon atom, to react with a compound containing an unsaturated carbon-carbon bond of following Formula (2) or 2 wherein Rd, Re, Rf, Rg, Ri and Rj are each a hydrogen atom or an organic group, where Rd, Re, Rf and Rg may respectively be combined to form a ring with one or two adjacent carbon atoms, and Ri and Rj may be combined to form a ring with adjacent two carbon atoms, in the presence of oxygen and a catalytic compound of a Group 5, 6, 7, 8 or 9 element of the Periodic Table of Elements to yield a compound of following Formula (3) or (8): 3 wherein Z is a hydrogen atom or a hydroxyl group; and Y, Rb, Rc, Rd, Re, Rf, Rg, Ri and Rj have the same meanings as defined above. This process can efficiently produce a compound having an alkyl group or alkenyl group bonded at the alpha position of an electron attractive group, or a derivative thereof, by catalytic radical addition reaction.

    摘要翻译： 本发明的方法通过使含有下式（1）的吸电子基团的化合物，其中Y为吸电子基团，生成有机化合物; R b和R c各自为氢原子或有机基团，其中Y，Rb和Rc可以分别彼此结合形成具有相邻碳原子的环，与含有不饱和碳 - 碳键的化合物反应 下式（2）或其中R d，R e，R f，R g，R i和R j各自为氢原子或有机基团，其中R d，R e，R f和R g可以分别结合形成具有一个或两个相邻碳原子的环 原子，并且R 1和R 1可以在氧的存在下和元素周期表第5,6,7,8或9族元素的催化化合物的存在下结合形成具有相邻的两个碳原子的环，得到 下式（3）或（8）的化合物：其中Z是氢原子或羟基; Y，Rb，Rc，Rd，Re，Rf，Rg，R 1和R j具有与上述相同的含义。 该方法可以通过催化自由基加成反应有效地制备具有在吸电子基团的α位上键合的烷基或烯基的化合物或其衍生物。

    Catalysts for oxidative dehydrogenation
    64.
    发明授权
    Catalysts for oxidative dehydrogenation 有权
    催化剂用于氧化脱氢

    公开(公告)号：US06436871B1

    公开(公告)日：2002-08-20

    申请号：US09255384

    申请日：1999-02-22

    申请人： Yumin Liu

    发明人： Yumin Liu

    IPC分类号： B01J2300

    CPC分类号： C07C45/34 ,  B01J23/76 ,  B01J23/80 ,  B01J23/83 ,  C07C5/48 ,  C07C45/33 ,  C07C45/35 ,  C07C2523/755 ,  C07C11/02 ,  C07C47/22 ,  C07C49/205 ,  C07C49/10 ,  C07C47/21 ,  C07C49/08

    摘要： Catalysts for oxidative dehydrogenation of alkane to one or more olefins, exemplified by ethane to ethylene, are disclosed. The catalyst comprises a mixture of metal oxides having as an important component nickel oxide (NiO) and gives high conversion and selectivity. For example, the catalyst can be used to make ethylene by contacting it with a gas mixture containing ethane and oxygen. The gas mixture may optionally contain ethylene, an inert diluent such as nitrogen, or both ethylene and an inert diluent.

    摘要翻译： 公开了将烷烃氧化脱氢成一种或多种烯烃的催化剂，例如乙烷至乙烯。 该催化剂包含具有作为重要组分氧化镍（NiO）的金属氧化物的混合物，并且具有高的转化率和选择性。 例如，催化剂可用于通过使乙烯与含有乙烷和氧气的气体混合物接触来制备乙烯。 气体混合物可任选地含有乙烯，惰性稀释剂如氮气，或乙烯和惰性稀释剂。

    LOWER ALKANE OXIDATIVE DEHYDROGENATION CATALYSTS AND A PROCESS FOR PRODUCING OLEFINS
    70.
    发明申请
    LOWER ALKANE OXIDATIVE DEHYDROGENATION CATALYSTS AND A PROCESS FOR PRODUCING OLEFINS 无效
    低碱性氧化脱氢催化剂和生产烯烃的方法

    公开(公告)号：US20010008623A1

    公开(公告)日：2001-07-19

    申请号：US09313652

    申请日：1999-05-18

    发明人： NOBUJI KISHIMOTO ,  ETSUSHIGE MATSUNAMI

    IPC分类号： B01J023/32 ,  C01G045/12 ,  C07C027/10

    CPC分类号： C07C45/35 ,  B01J23/002 ,  B01J23/34 ,  B01J2523/00 ,  C07C5/48 ,  C07C45/33 ,  C07C45/34 ,  C07C51/252 ,  C07C2523/34 ,  Y02P20/52 ,  C07C11/02 ,  C07C47/22 ,  C07C57/04 ,  B01J2523/53 ,  B01J2523/72 ,  B01J2523/842 ,  B01J2523/51 ,  B01J2523/67 ,  B01J2523/56 ,  B01J2523/69 ,  B01J2523/17 ,  B01J2523/3712 ,  B01J2523/305 ,  B01J2523/12 ,  B01J2523/22 ,  B01J2523/62 ,  B01J2523/74 ,  B01J2523/55 ,  B01J2523/68 ,  B01J2523/13 ,  B01J2523/41 ,  B01J2523/54 ,  B01J2523/845

    摘要： The invention provides catalysts for oxidative dehydrogenation of lower alkanes, said catalysts being suitable for use in vapor phase oxidative dehydrogenation of C2-C5 lower alkanes in the presence of molecular oxygen to produce corresponding olefins and characterized by having a composition expressed by a general formula (I) below: MnnullE1nullE2nullOxnullnull(I) (in which Mn denotes manganese, and O, oxygen; E1 is at least one element selected from the group consisting of P, As, Sb, B, S, Se, Te, F, Cl, Br, I, Nb, Ta, W, Re and Cu; E2 is at least one element selected from the group consisting of Cr, Fe, Co, Ni, Ag, Au, Zn, Tl, Sn, Pb, Bi, Li, Na, K, Rb, Cs, Mg, Ca, Sr, Ba, Y, La, Ce, Nd and Sm; and null, null, null and x denote atomic numbers of Mn, E1, E2 and oxygen, respectively, where when nullnull1, nullnull0.01-10, nullnull0-5, and x is a numerical value determined by the state of oxidation of those elements other than oxygen). When these catalysts are used in reactions for oxidizing and dehydrogenating C2-C5 alkanes with molecular oxygen at vapor phase, corresponding olefins can be produced at high yield.

    摘要翻译： 本发明提供了用于低级烷烃的氧化脱氢的催化剂，所述催化剂适用于在分子氧存在下C2-C5低级烷烃的气相氧化脱氢以产生相应的烯烃，其特征在于具有由通式（ I）：<段落lvl =“0”> MnalphaE1betaE2gammaOx（I）（其中Mn表示锰，O，氧; E1是至少一种元素选择 由P，As，Sb，B，S，Se，Te，F，Cl，Br，I，Nb，Ta，W，Re和Cu组成的组中的至少一种元素; E2是选自Cr ，Fe，Co，Ni，Ag，Au，Zn，Tl，Sn，Pb，Bi，Li，Na，K，Rb，Cs，Mg，Ca，Sr，Ba，Y，La，Ce，Nd和Sm; α，β，γ和x分别表示Mn，E1，E2和氧的原子序数，其中当α= 1时，β= 0.01-10，γ= 0-5，x为由 除了氧以外的那些元素的氧化）。 当这些催化剂用于在气相下用分子氧氧化和脱氢C2-C5烷烃的反应中时，可以高产率生产相应的烯烃。