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公开(公告)号:US20240060205A1
公开(公告)日:2024-02-22
申请号:US18125908
申请日:2023-03-24
发明人: Yu Bao
CPC分类号: C25D5/02 , C25D7/123 , C25D3/38 , C25D3/58 , C25D21/14 , H01L21/76873 , H01L21/76879 , H01L21/76883
摘要: The present application provides a method for improving a copper alloy electroplating filling process, forming a groove on a semiconductor structure; forming a barrier layer on the surface of the groove, and then covering the barrier layer with a seed layer; electroplating the seed layer in the groove with copper, until an upper surface of the copper in the groove is close to an opening of the groove; adding impurity metal ions into an electroplating solution for copper electroplating to continue the electroplating, wherein during an electroplating process, the impurity metal ions are fully consumed quickly, forming an alloy layer on the surface of the copper; continuing the copper electroplating on the alloy layer in the groove; repeating steps 4 and 5 until the groove is fully filled; and performing chemical mechanical polishing, the polishing ending at the opening of the groove.
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公开(公告)号:US11512405B2
公开(公告)日:2022-11-29
申请号:US16961940
申请日:2018-12-14
发明人: Angela Llavona-Serrano , Timo Bangerter , Olivier Mann , Pamela Cebulla , Stefanie Ackermann , Heiko Brunner , Kinga Haubner , Bernd Froese
摘要: The present invention concerns a metal or metal alloy deposition composition, particularly a copper or copper alloy deposition composition, for electrolytic deposition of a metal or metal alloy layer, particularly for electrolytic deposition of a copper or copper alloy layer, comprising at least one type of metal ions to be deposited, preferably copper ions, and at least one imidazole based plating compound. The present invention further concerns a method for preparation of the plating compound, the plating compound itself and its use in a metal or metal alloy deposition composition. The inventive metal or metal alloy deposition composition can be preferably used for filling recessed structures, in particular those having higher diameter to depth aspect ratios.
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公开(公告)号:US20220090283A1
公开(公告)日:2022-03-24
申请号:US17429470
申请日:2020-02-06
申请人: aveni
摘要: Electrodeposition of a cobalt or copper alloy, and use in microelectronics The present invention relates to a process for fabricating cobalt or copper interconnects, and to an electrolyte enabling implementation of said process. The electrolyte, with a pH of less than 4.0, comprises cobalt or copper ions, chloride ions, manganese or zinc ions, and at most two organic additives of low molecular mass. One of these additives may be an alpha-hydroxy carboxylic acid.
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公开(公告)号:US20200098619A1
公开(公告)日:2020-03-26
申请号:US16141522
申请日:2018-09-25
申请人: INTEL CORPORATION
发明人: Thomas Marieb , Zhiyong Ma , Miriam R. Reshotko , Christopher Jezewski , Flavio Griggio , Rahim Kasim , Nikholas G. Toledo
IPC分类号: H01L21/768 , H01L23/532 , C23C18/48 , C25D3/58
摘要: Techniques are disclosed for providing cladded metal interconnects. Given an interconnect trench, a barrier layer is conformally deposited onto the bottom and sidewalls of the trench. A first layer of a bilayer adhesion liner is selectively deposited on the barrier layer, and a second layer of the bilayer adhesion liner is selectively deposited on the first layer. An interconnect metal is deposited into the trench above the bilayer adhesion liner. Any excess interconnect metal is recessed to get the top surface of the interconnect metal to a proper plane. Recessing the excess interconnect metal may include recessing previously deposited excess adhesion liner and barrier layer materials. The exposed top surface of the interconnect metal in the trench is then capped with the bilayer adhesion liner materials to provide a cladded metal interconnect core. In some embodiments, the adhesion liner is a single layer adhesion liner.
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公开(公告)号:US20200031818A1
公开(公告)日:2020-01-30
申请号:US16603319
申请日:2015-04-28
IPC分类号: C07D413/12 , C09D179/08 , C08G73/02 , C09D179/02 , C08G73/10 , C25D3/58 , C25D3/60 , C25D3/32 , C25D3/38 , C07D241/04 , C07D265/33 , C07D413/06 , C07D413/10 , C25D3/30
摘要: A method of providing spatial diversity for critical data delivery in a beamformed mmWave small cell is proposed. The proposed spatial diversity scheme offers duplicate or incremental data/signal transmission and reception by using multiple different beams for the same source and destination. The proposed spatial diversity scheme can be combined with other diversity schemes in time, frequency, and code, etc. for the same purpose. In addition, the proposed spatial diversity scheme combines the physical-layer resources associated with the beams with other resources of the same or different protocol layers. By spatial signaling repetition to avoid Radio Link Failure (RLF) and Handover Failure (HOF), mobility robustness can be enhanced. Mission-critical and/or time-critical data delivery can also be achieved without relying on retransmission.
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公开(公告)号:US10538850B2
公开(公告)日:2020-01-21
申请号:US15567637
申请日:2016-04-20
发明人: Heiko Brunner , Dirk Rohde , Manuel Pölleth , Sven Rückbrod , Desthree Darwin , Sandra Niemann , Gerhard Steinberger
摘要: The present invention relates to aqueous acidic plating baths for copper and copper alloy deposition in the manufacture of printed circuit boards, IC substrates, semiconducting and glass devices for electronic applications. The plating bath according to the present invention comprises at least one source of copper ions, at least one acid and at least one guanidine compound. The plating bath is particularly useful for plating recessed structures with copper and build-up of copper pillar bump structures.
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公开(公告)号:US10472728B2
公开(公告)日:2019-11-12
申请号:US15178620
申请日:2016-06-10
发明人: Hideta Arai , Atsushi Miki
IPC分类号: C23C28/00 , C25D15/00 , C25D7/06 , C25D5/10 , C25D5/12 , H05K3/38 , C25D5/16 , H05K1/09 , H05K3/20 , C25D1/04 , C25D3/38 , C25D3/56 , C25D3/58 , C25D9/04
摘要: A copper foil for printed circuits is prepared by forming a primary particle layer of copper on a surface of a copper foil, and then forming a secondary particle layer based on ternary alloy composed of copper, cobalt and nickel on the primary particle layer. The average particle size of the primary particle layer is 0.25 to 0.45 μm, and the average particle size of the secondary particles layer based on ternary alloy composed of copper, cobalt and nickel is 0.05 to 0.25 μm. Provided is a copper foil for printed circuits, in which powder fall from the copper foil can be reduced and the peeling strength and heat resistance can be improved by forming a primary particle layer of copper on a surface of a copper foil, and then forming a secondary particle layer based on copper-cobalt-nickel alloy plating on the primary particle layer.
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公开(公告)号:US20190338435A1
公开(公告)日:2019-11-07
申请号:US16462257
申请日:2017-10-25
发明人: Xiang LIU , Ziming HU , Haidong YAO
IPC分类号: C25D5/50 , C21D9/52 , C21D8/06 , C22C9/04 , C25D7/06 , C23F17/00 , B29B15/08 , B60C9/00 , C25D5/12 , C25D3/58 , D07B1/06 , B21C37/04
摘要: Disclosed are a metal wire, a manufacturing method therefor, and a tire. The metal wire is made by twisting a filament; an outer peripheral surface of the filament is covered with a Cu—M—Zn alloy coating; the outer peripheral surface of the filament is also covered with a Cu—Zn alloy coating; the metal wire is made of at least one filament; an area covered by the Cu—M—Zn alloy coating is 10%-90% of an area of the outer peripheral surface of the filament, and the rest is the Cu—Zn alloy coating; M in the Cu—M—Zn alloy coating is selected from one or two of Co, Ni, Mn, or Mo; the mass fraction of Cu in the Cu—M—Zn alloy coating is 58%-72%, the mass fraction of M in the Cu—M—Zn alloy coating is 0.5%-5%, and the balance in the Cu—M—Zn alloy coating is Zn and inevitable impurities.
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公开(公告)号:US10383222B2
公开(公告)日:2019-08-13
申请号:US15398126
申请日:2017-01-04
发明人: Atsushi Miki , Ryo Fukuchi , Hideta Arai
IPC分类号: H05K1/09 , C22C9/00 , C22C30/02 , C25F1/00 , C25D3/38 , C25D3/12 , C25D11/38 , C25D7/06 , C22F1/08 , H05K3/38 , C25D5/12 , C25D3/56 , C25D3/58
摘要: To provide a surface-treated copper foil that is excellent in adhesiveness to an insulating substrate at ordinary temperature, and is capable of suppressing the formation of blister on application of a thermal load of reflow soldering to a copper-clad laminate board constituted by the copper foil. A surface-treated copper foil having a surface-treated surface, the surface-treated copper foil satisfying one or more of the following conditions (1) to (3): by an XPS measurement at a depth after sputtering from the surface-treated surface for 0.5 min at a rate of 1.1 nm/min (SiO2 conversion), (1) the N concentration is from 1.5 to 7.5 atomic %; (2) the C concentration is from 12 to 30 atomic %; and (3) the Si concentration is 3.1 atomic % or more and the O concentration is from 40 to 48 atomic %.
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70.
公开(公告)号:US10329681B2
公开(公告)日:2019-06-25
申请号:US15801496
申请日:2017-11-02
发明人: Chi-Haw Chiang , Liang-Huei Jiang , Ren-Ruey Fang , Chien-Liang Chang , Yu-Ping Wang , Ming-Ta Hsieh
IPC分类号: C25D3/58 , C25D3/64 , H01L21/768
摘要: A copper-silver dual-component metal electroplating solution includes copper methanesulfonate, silver methanesulfonate, methanesulfonic acid, chlorine ions, and water. An electroplating method for forming a copper-silver dual-component metal by using such an electroplating solution, the steps of which includes (a) contacting the copper-silver dual-component metal electroplating solution with a substrate; (b) applying an operating voltage, the current density of which is controlled to be between 0.1 and 2 ASD in order to carry out electroplating on the substrate. Therefore, the electroplating solution has environmental characteristics, such as less poisoning hazards, through the design of methanesulfonic acid and methanesulfonate electroplating solution. Also, the potential and the current are adjusted during the electroplating in order to obtain a copper-silver dual-component metal plating layer with a specific silver content.
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