摘要:
A novel flexible biregional carbonaceous fiber is disclosed comprising an inner core region of a thermoplastic polymeric material and an outer region of a carbonaceous sheath. The flexible biregional carbonaceous fibers are particularly characterized by having a ratio of the radius of the core region with respect to the total radius of the fiber (r:R) of from about 1:4 to about 1:1.05, a density of from about 1.45 to about 1.87 g/cm.sup.3, and a bending strain value of from greater than 0.01 to less than 50%. In a further embodiment of the invention, a biregional precursor fiber is disclosed having an inner core region of a thermoplastic polymeric material and an outer sheath region of a oxidation stabilized, thermoset polymeric material. The oxidation stabilized precursor fiber is characterized by having a density of from about 1.20 to about 1.32 g/cm.sup.3 The invention further resides in methods of making the biregional fibers. Preferred end uses for the biregional fibers are disclosed including thermal insulation; flame resistant and fire blocking insulation; blends of the biregional carbonaceous fibers with other natural or polymeric fibers; coated fibers, composites composed of a polymeric matrix reinforced with the biregional carbonaceous fibers of the invention, electron conductive fibers for battery electrodes, and the like.
摘要翻译:公开了一种新颖的柔性双向碳质纤维,其包括热塑性聚合材料的内核区域和含碳护套的外部区域。 柔性双向碳质纤维的特征在于,芯部区域的半径相对于纤维的总半径(r:R)为约1:4至约1:1.05,密度为约 1.45至约1.87g / cm 3,弯曲应变值大于0.01至小于50%。 在本发明的又一实施例中,公开了一种双向前体纤维,其具有热塑性聚合材料的内芯区域和氧化稳定的热固性聚合物材料的外护套区域。 氧化稳定的前体纤维的特征在于具有约1.20至约1.32g / cm 3的密度。本发明还涉及制备双向纤维的方法。 公开了用于双向纤维的优选最终用途,包括绝热; 阻燃和防火隔热; 双向碳质纤维与其它天然或聚合物纤维的共混物; 涂覆纤维,由本发明的双向碳质纤维增强的聚合物基质,电池电极用电子导电纤维等构成的复合体。
摘要:
A flexible, composite, thermoplastic filament, which contains continuous fibers, and which filament contains a flexible sheath of a thermoplastic polymer which coats a fiber bundle of fibers, which fiber bundle is impregnated with a thermoplastic powder, which is made of the same thermoplastic polymer coating the fiber bundle, wherein the filament has a substantially elliptical cross-section.
摘要:
Disclosed herein is a short carbon fiber bundling mass comprising not less than 90% by weight of short carbon fibers and carbonized materials derived from a resin as a sizing agent, and having not more than 0.5% of a weight loss of said short carbon fiber bundling mass when left in an inert atmosphere at a temperature of 400.degree. C.
摘要:
A process for preparing a composite, continuous-fiber-containing filament which entails:a) unwinding a continuous fiber bundle from a bobbin,b) loosening the fiber bundle, in order to separate the bundle substantially into individual fibers,c) impregnating the individual fibers with a thermoplastic polymer powder, andd) recompacting the fiber bundle and providing a flexible sheltering sheath around the bundle, whereby the fiber bundle is caused to have a substantially elliptical cross-section.
摘要:
Organic polymer surfaces are modified by contacting such surfaces with a haloester compound and a cationic compound of having a pK.sub.a >5. Preferably the organic polymer is selected from the group consisting of polyesters, aromatic polyamides, and graphitic polymers and the contacting is conducted at an elevated temperature.
摘要:
Processes for preparing a carbon product having an organic group attached to a carbon material. The carbon material is selected from graphite powder, a graphite fiber, a carbon fiber, a carbon cloth, a vitreous carbon product, and an activated carbon product. In one process at least one diazonium salt reacts with a carbon material in the absence of an externally applied electric current sufficient to reduce the diazonium salt. In another process at least one diazonium salt reacts with a carbon material in a protic reaction medium.
摘要:
A take-up apparatus is disclosed for tape type non-twisted carbon fiber bundles, in which a traverse guide unit consists of an introduction guide roller disposed so that an angle .theta..sub.1 between the introduction guide roller and the axial direction of the bobbin is substantially 90.degree., a final guide roller disposed so that an angle .theta..sub.e between it and the axial direction of the bobbin is -5.degree..+-.10.degree. (i.e., -15.degree. to +5.degree.), and at least one intermediate guide roller disposed between the introduction guide roller and final guide roller so that an angle difference between an intermediate guide roller and an adjacent guide roller is not more than 45.degree.. A take-up apparatus is also disclosed for tape type non-twisted carbon fiber bundles, in which a traverse guide unit has a helically continuing curved guide surface, an initial portion, i.e. an introduction surface portion of the curved guide surface extending at substantially right angles to the axial direction of a bobbin, and a final portion, i.e. discharge surface portion of the curved guide surface extending at an angle in the range of -5.degree..+-.10.degree. with respect to the axial direction of the bobbin.
摘要:
An improved flexible towpreg article and a method of production therefor. The improved flexible towpreg article comprises a prepreg which comprises reinforcing filaments and matrix forming material comprising recycled plastics; the reinforcing filaments being substantially wetout by the matrix forming material such that the towpreg plies have a low void content compared to the multiply towpreg. The method of production for the improved flexible towpreg article includes the steps of spreading the reinforcing filaments; coating the reinforcing filaments with the matrix forming material in a manner causing interfacial adhesion of the matrix forming material to the reinforcing filaments; forming the prepreg by heating the matrix forming material contacting the reinforcing filaments until the matrix forming material liquefies and coats the reinforcing filaments; and cooling the prepregs in a manner such that substantial cohesion between neighboring towpreg plies is prevented until the matrix forming material solidifies.
摘要:
A sizing agent for carbon fibers which comprises, as the indispensable ingredients, an epoxy resin having a viscosity of more than 1,000 P but up to 20,000 P at 50 .degree. C. and a urethane compound prepared from a polyol having an oxyalkylene unit with a polyisocyanate.
摘要:
The present invention is directed to fibers which are sized or coated on the surface with a polyamide-amic acid, an amide-imide polymer, an amide-imide copolymer or mixtures of these materials and to composites prepared from the sized fibers.