Four component anionic and non-ionic surfactant composition for single
bath and single stage dyeing of textile fibers
    63.
    发明授权
    Four component anionic and non-ionic surfactant composition for single bath and single stage dyeing of textile fibers 失效
    单组份单组分阴离子和非离子表面活性剂组合物,用于纺织纤维单层浴和单级染色

    公开(公告)号:US5152802A

    公开(公告)日:1992-10-06

    申请号:US741437

    申请日:1991-08-09

    IPC分类号: D06P1/613 D06P1/62 D06P1/651

    摘要: A dyeing aid composition containing 1 to 60% by weight of a surfactant selected from (a) C.sub.8-24 alkyl or alkenyl alcohol sulfate, C.sub.14-18 alkane sulfonate and C.sub.10-14 alkyl benzenesulfonate; (b) castor oil containing 20-50 mols ethylene oxide, alkoxylated C.sub.8-24 alkyl or alkenyl alcohols, and alkoxylated C.sub.8-12 alkylphenols; from about 1 to about 25% by weight of sulfated hydroxyalkyl alkylpolyalkylene glycol ether corresponding to formula I ##STR1## in which R is a C.sub.1-6 alkyl radical, R.sup.1 is a C.sub.6-8 alkyl radical, M is an alkali metal or, ammonium cation, n=2 or 3 and x is a number of about 2 to about 10; and from about 1 to about 30% by weight of C.sub.2-12 alkyl alcohol; with the proviso that the ratio by weight of surfactants (a) to surfactants (b) is from about 5:1 to about 1:5, the ratio by weight of surfactants (a) and (b) to sulfatized hydroxyalkyl alkylpolyalkylene glycol ether is from about 1:1 to about 4:1 and the ratio by weight of surfactants (a) and (b) and sulfatized hydroxyalkyl polyalkyene glycol ether to alkyl alcohol is from about 1:1 to about 5:1.

    摘要翻译: PCT No.PCT / EP90 / 00177 Sec。 371日期1991年8月9日 102(e)日期1991年8月9日PCT提交1990年2月1日PCT公布。 第WO90 / 09479号公报 日本1990年8月23日。一种染色助剂组合物,其含有1至60重量%的选自(a)C8-24烷基或链烯基醇硫酸盐,C14-18烷基磺酸盐和C10-14烷基苯磺酸盐的表面活性剂; (b)含有20-50摩尔环氧乙烷,烷氧基化C8-24烷基或烯基醇和烷氧基化C8-12烷基酚的蓖麻油; 约1至约25重量%的对应于式I的硫酸化羟烷基烷基聚亚烷基二醇醚(I)其中R是C 1-6烷基,R 1是C 6-8烷基,M是碱金属 或铵阳离子,n = 2或3,x为约2至约10的数; 和约1至约30重量%的C 12-12烷基醇; 表面活性剂(a)与表面活性剂(b)的重量比为约5:1至约1:5,表面活性剂(a)和(b)与硫酸化羟烷基烷基聚亚烷基二醇醚的重量比为 约1:1至约4:1,表面活性剂(a)和(b)的重量比和硫酸化羟烷基聚亚烷基二醇醚与烷基醇的比例为约1:1至约5:1。

    Composition and use thereof as dyeing or textile auxiliary
    65.
    发明授权
    Composition and use thereof as dyeing or textile auxiliary 失效
    作为染色或纺织助剂的组成和用途

    公开(公告)号:US4894183A

    公开(公告)日:1990-01-16

    申请号:US147093

    申请日:1988-01-20

    摘要: A composition suitable for use as dyeing or textile auxiliary and which comprises a mixture of acid esters of adducts of ethylene oxide and propylene oxide with fatty alcohols having not less than 6 carbon atoms, at least one component of which composition is an acid ester of the formula ##STR1## wherein s is 3 to 10, p is 5 to 15, R is an aliphatic radical of not less than 6 carbon atoms; one of Z.sub.1 and Z.sub.2 is methyl and the other is hydrogen, and X is the acid radical of a low molecular aliphatic dicarboxylic acid, in particular maleic acid. This composition is used in particular as low foaming wetting agent and padding auxliary for pretreating or dyeing cellulosic fibre materials.

    摘要翻译: 适合用作染色或纺织助剂的组合物,其包含环氧乙烷和环氧丙烷的加成酸的酸酯与不少于6个碳原子的脂肪醇的混合物,其组成为至少一种组分为 式(1)其中s为3至10,p为5至15,R为不少于6个碳原子的脂族基团; Z1和Z2之一是甲基,另一个是氢,X是低分子量脂族二羧酸,特别是马来酸的酸基。 该组合物特别用作低发泡润湿剂和用于预处理或染色纤维素纤维材料的填充辅助材料。

    Waterless dip dye composition and method of use thereof for synthetic
articles
    66.
    发明授权
    Waterless dip dye composition and method of use thereof for synthetic articles 失效
    无水浸渍染料组合物及其用于合成制品的方法

    公开(公告)号:US4661117A

    公开(公告)日:1987-04-28

    申请号:US669355

    申请日:1984-11-08

    摘要: A waterless dip dye composition for non-textile and general-utility articles comprises an aromatic ester of the formula ArCOOR.sub.2, ArCOO--R.sub.1 --OOCAr or (ArCOO).sub.z --R.sub.3, wherein R.sub.1 is alkylene of 2-8 carbon atoms or polyoxyalkylene of the formula --C.sub.r H.sub.2r (OC.sub.r H.sub.2r).sub.s, in which r is 2 or 3 and s is 1 to 15; R.sub.2 is substituted or unsubstituted alkyl or alkenyl of 8-30 carbon atoms; R.sub.3 is the residue of a polyhydric alcohol having z hydroxyl groups; Ar is substituted or unsubstituted mono- or bicyclic aryl of up to 15 carbon atoms and z is 3-6, admixed with at least 0.5% by weight of a dyeing assistant agent and an organic colorant.A process for coloring non-textile and general-utility articles, fabricated from polyester, polyamide, polyurethane, acrylic, halogenated polyolefin or epoxy plastic, comprises exposing an article to the foregoing compositions, maintained at a temperature from about 100.degree. C. to the temperature at which the plastic degrades, for a time adequate to achieve the desired degree of coloration.

    摘要翻译: 非纺织和一般用途制品的无水浸渍染料组合物包括式ArCOOR 2,ArCOO-R 1 -OOC Ar或(ArCOO)z -R 3的芳族酯,其中R 1是2-8个碳原子的亚烷基或聚氧亚烷基 式-CrH 2r(OCr H 2r)s,其中r为2或3,s为1至15; R2是取代或未取代的8-30个碳原子的烷基或链烯基; R3是具有z个羟基的多元醇的残基; Ar是至多15个碳原子的取代或未取代的单环或双环芳基,z是3-6,与至少0.5重量%的染色助剂和有机着色剂混合。 用于染色由聚酯,聚酰胺,聚氨酯,丙烯酸,卤化聚烯烃或环氧树脂制成的非纺织和通用型制品的方法包括将制品暴露于上述组合物中,保持在约100℃至 塑料降解的温度足以达到所需的着色程度。

    Propylene oxide polyadducts containing carboxyl groups and their salts
useful as dyeing assistants for dyeing wool fibers
    67.
    发明授权
    Propylene oxide polyadducts containing carboxyl groups and their salts useful as dyeing assistants for dyeing wool fibers 失效
    含有羧基的环氧丙烷加成物及其盐可用作染色羊毛纤维的染色助剂

    公开(公告)号:US4615837A

    公开(公告)日:1986-10-07

    申请号:US321850

    申请日:1981-11-16

    摘要: A propylene oxide polyadduct containing carboxyl groups, or a salt thereof, obtained from(a) an adduct of propylene oxide and an aliphatic alcohol having 3 to 10 carbon atoms which is at least trihydric,(b) an aliphatic dicarboxylic acid or the anhydride thereof having 2 to 10 carbon atoms or a mono- or di-lower alkylester of said dicarboxylic acids,(c) an aliphatic diol having an average molecular weight of at most 2,000,(d) a fatty acid having 8 to 22 carbon atoms and(e) an aromatic dicarboxylic acid or the anhydride thereof having 8 to 12 carbon atoms; it is in particular useful as dyeing assistant for the dyeing of fibrous material made of or containing wool with anionic dyes.

    摘要翻译: 由(a)环氧丙烷与3〜10个碳原子的脂肪族醇的加合物(a)至少三元得到的含有羧基的环氧丙烷聚合物或其盐,(b)脂肪族二羧酸或其酸酐 具有2至10个碳原子或所述二羧酸的单 - 或二 - 低级烷基酯,(c)平均分子量至多为2,000的脂族二醇,(d)具有8至22个碳原子的脂肪酸和( e)芳族二羧酸或其具有8至12个碳原子的酸酐; 它特别适用于用阴离子染料染色由羊毛制成或含有羊毛的纤维材料的染色助剂。

    Process for printing cellulose-containing textile material with
foam-containing reactive dyes and addition of (meth) acrylamide polymers
    68.
    发明授权
    Process for printing cellulose-containing textile material with foam-containing reactive dyes and addition of (meth) acrylamide polymers 失效
    用含泡沫的活性染料印刷含纤维素的纺织材料和加入(甲基)丙烯酰胺聚合物的方法

    公开(公告)号:US4604099A

    公开(公告)日:1986-08-05

    申请号:US694189

    申请日:1985-01-23

    摘要: Textile cellulose material is printed with a reactive dye by applying to the cellulose material a foamed aqueous preparation which, in addition to the dye, contains foaming agent and a homopolymer or copolymer of acrylamide or methacrylamide or preferably a graft polymer obtained from an adduct of an alkylene oxide, preferably propylene oxide, on an at least trihydric aliphatic alcohol, for example glycerol, and acrylamide or methacrylamide.The printed cellulose material is then subjected to a heat treatment, for example steaming, to fix the dye.This foamed printing color produces without the use of thickenings a deep, level and crisp print which also has excellent handle.

    摘要翻译: 纺织纤维素材料通过向纤维素材料施加泡沫水性制剂而印刷有活性染料,发泡水性制剂除了染料之外还含有发泡剂和丙烯酰胺或甲基丙烯酰胺的均聚物或共聚物,或优选由 环氧烷,优选环氧丙烷,至少三元脂肪醇,例如甘油,丙烯酰胺或甲基丙烯酰胺。 然后将印刷的纤维素材料进行热处理,例如蒸汽以固定染料。 这种泡沫印刷颜色产生而不使用增厚的深度,水平和清晰的印刷品,其也具有优异的手感。

    Dye composition and method of use thereof for coloring thermoplastic
articles
    69.
    发明授权
    Dye composition and method of use thereof for coloring thermoplastic articles 失效
    染料组合物及其用于着色热塑性物品的方法

    公开(公告)号:US4602916A

    公开(公告)日:1986-07-29

    申请号:US769612

    申请日:1985-08-26

    申请人: Robert B. Wilson

    发明人: Robert B. Wilson

    摘要: A waterless dye composition for apparel and other articles, made from thermoplastic materials, comprises an aliphatic polyester of a higher alkanoic acid and a polyol, of the formula (ACOO).sub.2-6 B, wherein A is alkyl of 8-22 carbon atoms and B is the residue of a polyhydric alcohol, other than glycerol, of 2-6 hydroxyl groups and an organic colorant. The compositions can further comprise an aromatic polyester of the formula C.sub.6 H.sub.z' --(COOR.sub.1).sub.z, wherein z is 3, 4, 5, or 6; z' is 6-z; and R.sub.1 is higher alkyl; and/or a cycloaliphatic diester of the formula ##STR1## wherein R is substituted or unsubstituted straight or branched chain alkyl of 4-20 carbon atoms, polyoxyalkylene of the formula HO(C.sub.x H.sub.y O).sub.n C.sub.x H.sub.y -- or phosphated polyoxyalkylene of the formula (HO).sub.2 P(.dbd.O)O(C.sub.x H.sub.2x O).sub.n C.sub.x H.sub.2x or a salt thereof, wherein (C.sub.x H.sub.2x O).sub.n is (CH.sub.2 CH.sub.2 O).sub.n, (C.sub.3 H.sub.6 O).sub.n or (CH.sub.2 CH.sub.2 O).sub.p (C.sub.3 H.sub.6 O).sub.q, n is 2-22, and the sum of p+q is n.A process for coloring apparel or other articles, fabricated from polyester, polyamide, polyurethane, acrylic, halogenated polyolefin or epoxy plastic, comprises exposing an article to the foregoing compositions, maintained at a temperature between 100.degree. C. and the temperature at which the plastic is degraded, for a time adequate to achieve the desired degree of coloration.The compositions may further be diluted with water and used for textile finishing processes or as dyeing assistants in aqueous baths.

    摘要翻译: 由热塑性材料制成的用于服装和其它制品的无水染料组合物包含式(ACOO)2-6B的高级链烷酸和多元醇的脂族聚酯,其中A是8-22个碳原子的烷基和B 是除了甘油以外的2-6个羟基的多元醇的残基和有机着色剂。 组合物还可以包含式C 6 H 6' - (COOR 1)z的芳族聚酯,其中z为3,4,5或6; z'为6-z; 且R1为高级烷基; 和/或下式的脂环族二酯其中R是取代或未取代的4-20个碳原子的直链或支链烷基,式HO(C x H y O)n C x H y - 或式(HO)2 P的磷酸化聚氧化烯的聚氧化烯 (= O)O(C x H x O)n C x H 2 x或其盐,其中(C x H 2 x O)n为(CH 2 CH 2 O)n,(C 3 H 6 O)n或(CH 2 CH 2 O)p(C 3 H 6 O)q,n为2-22, + q是n。 用于着色由聚酯,聚酰胺,聚氨酯,丙烯酸,卤化聚烯烃或环氧树脂制成的服装或其他制品的方法包括将制品暴露于前述组合物,保持在100℃至塑料的温度 在一段时间内降解,达到所需的着色程度。 组合物还可以用水稀释并用于纺织品整理过程或作为染色助剂在水浴中。

    Solid formulations of metal complex dyes
    70.
    发明授权
    Solid formulations of metal complex dyes 失效
    固体配方的金属络合染料

    公开(公告)号:US4525170A

    公开(公告)日:1985-06-25

    申请号:US496036

    申请日:1983-05-19

    申请人: Paolo Balliello

    发明人: Paolo Balliello

    摘要: The invention relates to solid formulations of metal complex dyes, which formulations are obtained by dissolving or suspending at least one metal complex dye in water with the addition of an anionic dispersant or mixture of dispersants, and 1 to 20% by weight, based on the final formulation, of a non-ionic ethylene oxide adduct having a molecular weight of 200 to 5000, and optionally further ingredients, subsequently mixing the components and spray drying the solution or suspension.Such formulations are readily wettable and have a cold water dispersibility of .gtoreq.30 g/l.

    摘要翻译: 本发明涉及金属络合物染料的固体制剂,该制剂是通过将至少一种金属络合物染料溶解或悬浮在水中,通过加入阴离子分散剂或分散剂混合物,以及1-20重量%,基于 最终制剂,分子量为200至5000的非离子环氧乙烷加合物,以及任选的其它成分,随后将组分混合并喷雾干燥溶液或悬浮液。 这些制剂易于润湿,并且具有≥30g/ l的冷水分散性。