Abstract:
A system and method for fast charging of a lithium-ion battery, including: continuously monitoring a state of charge (SOC) of the lithium-ion battery; during a normal mode of operation and upon detecting that the battery is at the predetermined low charge level, discontinuing the discharge; upon detecting that the battery is connected to a charger, providing charging rate of at least 4 C for at least part of charging; and upon detecting that the battery, while connected to the charger is at the predetermined high charge level, discontinue the charging, wherein the predetermined low charge level and the predetermined high charge level define a consumable capacity of the battery, wherein the consumable capacity is below 50% of the full capacity of the battery.
Abstract:
An anode material for a lithium ion device includes an active material including germanium and boron. The weight percentage of the germanium is between about 45 to 80 weight % of the total weight of the anode material and the weight percentage of the boron is between about 2 to 20 weight % of the total weight of the anode material. The active material may include carbon at a weight percentage of between 0.5 to about 5 weight % of the total weight of the anode material. Additional materials, methods of making and devices are taught.
Abstract:
A system and method for fast charging of a lithium-ion battery, including: continuously monitoring a state of charge (SOC) of the lithium-ion battery; during a normal mode of operation and upon detecting that the battery is at the predetermined low charge level, discontinuing the discharge; upon detecting that the battery is connected to a charger, providing charging rate of at least 4C for at least part of charging; and upon detecting that the battery, while connected to the charger is at the predetermined high charge level, discontinue the charging, wherein the predetermined low charge level and the predetermined high charge level define a consumable capacity of the battery, wherein the consumable capacity is below 50% of the full capacity of the battery.
Abstract:
A method for cooling a battery unit of an electric vehicle, the method includes fluidly coupling a daytime passive radiative cooling (DPRC) based cooling unit to a battery unit cooling element that is in fluid communication with the battery unit; and cooling the battery unit cooling element by the DPRC based cooling unit.
Abstract:
Rechargeable battery cells and methods for extreme fast charging are disclosed. For example, such a rechargeable battery cell might be chargeable to at least 70% of usable capacity within 15 minutes. Such a rechargeable battery cell may include an anode containing a Si—C composite within a porous structure, a metal oxide-based cathode configured as a source of Li ions, an electrolyte capable of carrying Li-ions between the anode and the cathode, and a separator between the anode and the cathode. The rechargeable battery may have an interface between the anode and the cathode that is pressurized in an amount sufficient to manage volumetric changes during charging and discharging processes.
Abstract:
Rechargeable battery cells and methods for extreme fast charging are disclosed. For example, such a rechargeable battery cell might be chargeable to at least 70% of usable capacity within 15 minutes. Such a rechargeable battery cell may include an anode having at least one surface with a reversible areal capacity, after formation, up to 8.0 mAh/cm2, containing a Si—C composite within a porous structure and including a carbon-based conductive additive, wherein the Si—C composite is at least 30% Si by weight, and the material is at least 85% Si—C composite. The rechargeable battery cell may also include a cathode having at least one surface with a reversible areal capacity, after formation, up to 6 mAh/cm2, wherein a ratio of areal capacity of the at least one surface of the anode to the at least one surface of the cathode is between 1.15 to 1.45.
Abstract:
Lithium ion batteries and electrolytes therefor are provided, which include electrolyte additives having dithioester functional group(s) that stabilize the SEI (solid-electrolyte interface) at the surfaces of the anode material particles, and/or stabilize the CEI (cathode electrolyte interface) at the surfaces of the cathode material particles, and/or act as oxygen scavengers to prevent cell degradation. The electrolyte additives having dithioester functional group(s) may function as polymerization controlling and/or chain transfer agents that regulate the level of polymerization of other electrolyte components, such as VC (vinyl carbonate) and improve the formation and operation of the batteries. The lithium ion batteries may have metalloid-based anodes—including mostly Si, Ge and/or Sn as anode active material particles.
Abstract:
Core-shell particles, composite anode material, anodes made therefrom, lithium ion cells and methods are provided, which enable production of fast charging lithium ion batteries. The composite anode material has core-shell particles which are configured to receive and release lithium ions at their cores and to have shells that are configured to allow for core expansion upon lithiation. The cores of the core-shell particles are connected to the respective shells by conductive material such as carbon fibers, which may form a network throughout the anode material and possibly interconnect cores of many core-shell particles to enhance the electrical conductivity of the anode. Ionic conductive material and possibly mechanical elements may be incorporated in the core-shell particles to enhance ionic conductivity and mechanical robustness toward expansion and contraction of the cores during lithiation and de-lithiation.
Abstract:
Lithium ion batteries and electrolytes therefor are provided, which include electrolyte additives having dithioester functional group(s) that stabilize the SEI (solid-electrolyte interface) at the surfaces of the anode material particles, and/or stabilize the CEI (cathode electrolyte interface) at the surfaces of the cathode material particles, and/or act as oxygen scavengers to prevent cell degradation. The electrolyte additives having dithioester functional group(s) may function as polymerization controlling and/or chain transfer agents that regulate the level of polymerization of other electrolyte components, such as VC (vinyl carbonate) and improve the formation and operation of the batteries. The lithium ion batteries may have metalloid-based anodes including mostly Si, Ge and/or Sn as anode active material particles.
Abstract:
Methods of preparing Si-based anode slurries and anode made thereof are provided. Methods comprise coating silicon particles within a size range of 300-700 nm by silver and/or tin particles within a size range of 20-500 nm, mixing the coated silicon particles with conductive additives and binders in a solvent to form anode slurry, and preparing an anode from the anode slurry. Alternatively or complementarily, silicon particles may be milled in an organic solvent, and, in the same organic solvent, coating agent(s), conductive additive(s) and binder(s) may be added to the milled silicon particles—to form the Si-based anode slurry. Alternatively or complementarily, milled silicon particles may be mixed, in a first organic solvent, with coating agent(s), conductive additive(s) and binder(s)—to form the Si-based anode slurry. Disclosed methods simplify the anode production process and provide equivalent or superior anodes.