摘要:
Process for the preparation of heat-stable, antimony-free polyesters of neutral color and the products which can be prepared by this process A process for the preparation of heat-stable, antimony-free polyesters of neutral color by esterification of aromatic dicarboxylic acids or transesterification of lower aliphatic esters of aromatic dicarboxylic acids with aliphatic diols and subsequent polycondensation in which a possible transesterification is carried out in the presence of 20 to 120 ppm, based on the catalyst metal, of a transesterification catalyst, after the esterification or transesterification has ended, phosphoric acid, phosphorous acid and/or phosphonic acids or a derivative thereof are added to the esterification or transesterification batch as a completing agent in an amount which is 100% of the amount equivalent to the transesterification catalyst employed and up to 99% of the amount equivalent to the cobalt to be employed, up to 80 ppm of cobalt in the form of a cobalt compound are then added to the batch, and the polycondensation is carried out without the addition of antimony, in the presence of 1 to 10 ppm of titanium, which is added in the form of a titanium compound, and if appropriate in the presence of up to 1000 ppm of organic compounds which donate crosslinking structural groups (pentaerythritol) and if appropriate up to 50 ppm of an optical brightener, is described. The polyester obtainable by this process is furthermore described.
摘要:
An apparatus is provided for dissipating heat from an electronic component, such as a processor, that is mounted in a conductive enclosure and for shielding electromagnetic radiation generated by the electronic component. The apparatus includes a heat sink that is configured to be mounted to a surface of the electronic component. The apparatus also includes a conductor connected to the heat sink. The conductor is configured to provide electrical contact between the heat sink and a surface of the conductive enclosure. Accordingly, the apparatus at least partially shields the electromagnetic radiation generated by the electronic component. A corresponding method is also provided.
摘要:
A portable scale is provided that includes a fulcrum, a balance beam pivotally mounted on the fulcrum, the balance beam supporting a load pan on one end and including an elongated portion having a measurement strip extending along the elongated portion of the balance beam. The portable scale includes a dynamic weight movable along the elongated portion of the balance beam. The dynamic weight includes a display unit on the elongated portion of the balance beam for detecting the location of the dynamic weight along the measurement strip, for electrically converting the location to a weight measurement, and for displaying the weight measurement. The portable scale may include luminescent material.
摘要:
A method for adjusting an internal combustion engine with variable valve timing wherein the current position of the accelerator pedal is associated with a set air mass and a set pressure. The set pressure is compared with a reference pressure and control of the set air mass takes place via the throttling device in the intake pipe when the pressure falls below the reference pressure, and control of the set air mass is carried out via the engine valves when the pressure exceeds the reference pressure.
摘要:
The ultrasound imaging system and method of the present invention defines the gray-scale value and other parameters for each of a plurality of image elements in an output volume by determining all of the image information in the scanning planes that is contained within a defined portion of the output volume (which contains the image element) and thereafter simultaneously analyzing the selected image information. These steps are repeated for each of the image elements in the output volume.
摘要:
Polyesters are disclosed containing at least 0.1 mol % of the structural repeat units of the formula I and optionally up to 99.9 mol % of the structural repeat units of the formula II --O--OC--Ar.sup.1 --CO--O--R.sup.1 -- (I) --O--OC--Ar.sup.2 --CO--O--R.sup.2 -- (II) where Ar.sup.1 is a radical of the formula III and/or of the formula IV and/or of the formula V ##STR1## Ar.sup.2 is a bivalent mono- or polycyclic aromatic radical which differs from the radicals of the formulae III, IV and V, R.sup.1 and R.sup.2 are independently of each other a bivalent cycloaliphatic radical derived from cyclohexanedimethanol, a radical of the formula --.sub.n H.sub.2n -- and/or a radical of the formula --�C.sub.m H.sub.2m --O--!.sub.x --C.sub.m H.sub.2m --, where n is an integer between 2 and 10, m is an integer between 2 and 10, and x is an integer from 1 to 20, Y is a direct C--C bond, --NR.sup.3 --, --S-- or --O--, Z is a direct C--C bond or a bridging group --O--, --C.sub.q H.sub.2q --, --S--, --CO-- or --SO.sub.2 --, q is an integer from 1 to 10, R.sup.3 is a univalent aliphatic, cycloaliphatic, aromatic or araliphatic radical, preferably methyl, R.sup.4 is a radical of the formula --C.sub.o H.sub.2o+1 and/or a radical of the formula --�C.sub.p H.sub.2p --O--!.sub.z --R.sup.5, R.sup.5 is a univalent aliphatic, cycloaliphatic, aromatic or araliphatic radical, preferably methyl, o is an integer from 6 to 30, p is an integer from 2 to 10, y is an integer from 1 to 4, and z is an integer from 1 to 10. The polyesters are notable for a low viscosity and are advantageous to process into shaped structures.
摘要:
The invention relates to a process for preparing phosphorus-containing compounds of the formula I ##STR1## in which R.sup.1 and R.sup.2 are an alkyl radical having 1 to 8 carbon atoms, a cyclohexyl radical, a cyclopentyl radical, an aryl radical or a halogen-, alkyl- or alkoxy-substituted aryl radical, where R.sup.1 and R.sup.2 together with the phosphorus atom can also form a ring, n and m=0 or 1 and R.sup.3 and R.sup.4 are alkyl radicals having 1 to 4 carbon atoms or n=0, m=0 or 1 and R.sup.3 and R.sup.4 are H, by adding compounds of the formula II ##STR2## into dialkyl esters of fumaric acid or of maleic acid of the formula (III) or dialkyl esters of itaconic acid of the formula (IV) ##STR3## in which R.sup.3 and R.sup.4 have the meaning given above, and, optionally reacting an alkyl ester of a phosphorus-containing dicarboxylic acid of the formula (I), where n=0, with water in the presence of catalytic amounts of an acid to give the phosphorus-containing dicarboxylic acid.
摘要:
A process for producing mass-colored fiber or film, comprises the steps of:a) preparing a premix by grinding a composition comprising a polar aprotic organic solvent, 5 to 30% by weight of an aromatic polyamide and 0.5 to 5% by weight of a color-conferring solid component so that the color-conferring solid component has particles with an average diameter of less than 200 nm,b) preparing a forming solution by mixing the premix produced in step a) with a solution comprising a polar aprotic organic solvent and an aromatic polyamide which corresponds to the aromatic polyamide used in step a), just upstream of a forming die,c) extruding the forming solution through the forming die which comprises orifices in a predetermined number and shape to produce primary fiber or film,d) removing the polar aprotic organic solvent in a conventional manner to leave solvent-leaner or-free fiber or film of sufficient mechanical stability and nontackiness for further processing, ande) optionally orienting the resulting fiber or film in a convention manner.
摘要:
A process is described for preparing directly spinnable polymer solutions containing as fiber-forming substance polymers containing at least 95 mol %, based on the polymer, of the recurring structural unit of the formula I[--CO--R.sup.1 --CO--NH--R.sup.2 --NH--] (I)and up to 5 mol % of structural units as formed in the conversion/reaction of aromatic, aliphatic or cycloaliphatic dicarbonyl dichlorides and/or diamines. R.sup.1 and R.sup.2 are independently of each other 1,6-naphthylene, 1,7-naphthylene, 2,7-naphthylene, 3,4'-biphenyldiyl or 1,3-phenylene. The polymers prepared by reacting diamines of the formula (II) with dicarbonyl dichlorides of the formula (III) in solutionH.sub.2 N--R.sup.2 --NH.sub.2 (II)ClOC--R.sup.1 --COCl (III)The process contains the steps ofa) presenting the diamines as initial charge in the form of a solution in N-methylpyrrolidone,b) adding the dicarbonyl dichlorides to this solution,c) using starting monomers having a purity of greater than 99.9% and a water content of less than 70 ppm, measured by the method of Karl Fischer,d) polycondensing at temperatures between -20.degree. and 100.degree. C. with forced circulation of the reaction solution,e) terminating the polycondensation at a certain inherent viscosity of the polymer of at least 1.5 dl/g, measured on a 0.5% strength polymer solution in concentrated H.sub.2 SO.sub.4 at 25.degree. C., by neutralizating of the reaction solution by addition of basic alkali metal and/or alkaline earth metal salts.
摘要:
Aromatic copolyamides are described which are soluble in organic polyamide solvents and which essentially consist of the recurring structural units of the formulae Ia, Ib and Ic ##STR1## wherein R.sup.1 and R.sup.4 are divalent aromatic radicals, the valency bonds of which are in the para position or in a comparable coaxial or parallel position relative to one another, R.sup.2 is a radical of the formula III ##STR2## and R.sup.3 is a radical of the formula IV ##STR3## The mole fractions of the individual structural features in the copolyamides are fixed within selected limits. Fibers composed of the copolyamides claimed are distinguished by a high stretchability.
摘要翻译:描述了芳族共聚酰胺,其可溶于有机聚酰胺溶剂,并且其基本上由式Ia,Ib和Ic [OCR1CONHR2NH],(Ia)[OCR1CONHR3NH],(Ib)[OCR1CONHR3NH],(Ib)[OCR1CONHR4NH],(Ic)的重复结构单元组成 R 1和R 4是二价芳族基团,其价键位于相对于彼此的对位或相当的同轴或平行位置,R 2是式III的基团(III),并且R 3是基团 (IV)共聚酰胺中各个结构特征的摩尔分数固定在选定的范围内。 由所要求的共聚酰胺组成的纤维具有高的拉伸性。