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公开(公告)号：US08058492B2
公开(公告)日：2011-11-15
申请号：US12402873
申请日：2009-03-12
IPC分类号： C10M171/00 , C07C4/00 , C10G1/00
CPC分类号： C10G45/58 , C01B2203/0233 , C01B2203/0244 , C01B2203/062 , C10G3/42 , C10G3/50 , C10G3/52 , C10G45/64 , C10G45/72 , C10G47/00 , C10G47/36 , C10G65/12 , C10G2300/1014 , C10G2300/1018 , C10G2300/1022 , C10G2300/1037 , C10G2300/4081 , C10G2300/80 , C10G2400/04 , C10G2400/08 , C10L1/08 , Y02E50/13 , Y02P30/20 , Y02T50/678
摘要： A process for controlling the concurrent production of both diesel range hydrocarbons and aviation range hydrocarbons from renewable feedstocks such as plant oils and animal oils. The process involves determining the required specification of the desired products and the desired relative yields of the product that still meet the required specifications. The necessary isomerization and selective hydrocracking zone conditions are determined in order to create a mixture of paraffins which meet the required product specifications and yields. The necessary fractionation zone conditions are determined to separate the desired products. A renewable feedstock is treated by hydrogenating and deoxygenating to provide an effluent comprising paraffins, isomerizing and selectively hydrogenating at least a portion of the paraffins at the predetermined conditions, and separating by fractionation at the predetermined fractionation conditions to generate a diesel range hydrocarbon product and an aviation range hydrocarbon product.
摘要翻译： 控制从可再生原料如植物油和动物油同时生产柴油范围碳氢化合物和航空范围烃的过程。 该过程包括确定所需产品的所需规格以及仍符合要求规格的产品所需的相对产量。 确定所需的异构化和选择性加氢裂化区条件以产生满足所需产物规格和产率的石蜡混合物。 确定所需的分馏区条件以分离所需的产物。 通过氢化和脱氧来处理可再生原料以提供包含链烷烃的流出物，在预定条件下异构化和选择性氢化至少一部分链烷烃，并通过在预定分馏条件下分级分离以产生柴油范围烃产物和 航空范围烃产品。
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72.发明申请公开(公告)号：US20110245551A1
公开(公告)日：2011-10-06
申请号：US12750057
申请日：2010-03-30
IPC分类号： C07C1/00
CPC分类号： C10G3/46 , C10G3/00 , C10G45/00 , C10G2300/1011 , C10G2300/1014 , C10G2300/202 , C10G2300/802 , C10L1/04 , Y02P30/20
摘要： The present invention involves a process for processing an acidic biorenewable feedstock comprising olefins, in which the acidic biorenewable feedstock is diluted with a deoxygenated feed to produce a diluted biorenewable feedstock and then is sent through a guard bed comprising a hydroprocessing catalyst to cause the olefins to be saturated with hydrogen and thereby to produce a treated biorenewable feedstock. This treated biorenewable feedstock can then be treated under standard hydroprocessing condition to produce an upgraded feedstock for transportation fuels.
摘要翻译： 本发明涉及一种用于处理包含烯烃的酸性生物可再生原料的方法，其中酸性生物可再生原料用脱氧原料稀释以产生稀释的生物可再生原料，然后通过包含加氢处理催化剂的保护床送入， 用氢饱和，从而产生经处理的生物可再生原料。 然后可以在标准加氢处理条件下处理经处理的生物可再生原料，以生产用于运输燃料的升级原料。
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73.发明申请公开(公告)号：US20110146145A1
公开(公告)日：2011-06-23
申请号：US12646327
申请日：2009-12-23
IPC分类号： C10L1/12
CPC分类号： B01J49/0069 , B01D15/20 , B01D15/203 , B01D15/362 , B01J49/06 , B01J49/53 , C10G2300/1011 , C10L1/02 , G01N30/50 , G01N30/96 , Y02P30/20
摘要： Methods for regenerating acidic ion-exchange resins and reusing regenerants in such methods are provided. A spent ion-exchange resin is contacted with an alcohol ion-exchange regenerant. The spent ion-exchange resin is thereafter contacted with an acidic ion-exchange regenerant to recharge the acidic ion-exchange resin to produce a regenerated acidic ion-exchange resin. Metal- and water-containing biomass-derived pyrolysis oil is then contacted with the regenerated acidic ion-exchange resin to produce low metal, water-containing biomass-derived pyrolysis oil. The regenerated acidic ion-exchange resin may be recycled. The spent alcohol and acid ion-exchange regenerants may be recovered and recycled.
摘要翻译： 提供了在这种方法中再生酸性离子交换树脂和再利用再生剂的方法。 将废弃的离子交换树脂与醇离子交换再生剂接触。 然后将废弃的离子交换树脂与酸性离子交换再生剂接触以对酸性离子交换树脂再充电以产生再生的酸性离子交换树脂。 然后将含金属和含水的生物质衍生的热解油与再生的酸性离子交换树脂接触以产生低金属，含水生物质的热解油。 再生的酸性离子交换树脂可以再循环。 废乙醇和酸离子交换再生剂可以回收和再循环。
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74.发明申请LOW WATER BIOMASS-DERIVED PYROLYSIS OIL AND PROCESSES FOR PREPARING THE SAME 审中-公开低水生物质衍生的热解油及其制备方法公开(公告)号：US20110146140A1
公开(公告)日：2011-06-23
申请号：US12646203
申请日：2009-12-23
IPC分类号： C10L1/18
摘要： Low water-containing biomass-derived pyrolysis oils and processes for preparing them are provided. Water-containing biomass-derived pyrolysis oil is distilled in the presence of an azeotrope-forming liquid to form an azeotrope. The azeotrope is removed at or above the boiling point of the azeotrope and low water biomass-derived pyrolysis oil is obtained.
摘要翻译： 提供了低含水生物质衍生的热解油及其制备方法。 在形成共沸物质的液体存在下蒸馏含水生物质的热解油，形成共沸物。 在共沸物的沸点以上沸腾除去共沸物，得到低水生物质衍生的热解油。
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75.发明申请Production of Blended Gasoline and Blended Aviation Fuel from Renewable Feedstocks 有权从可再生原料生产混合汽油和混合航空燃料公开(公告)号：US20090250376A1
公开(公告)日：2009-10-08
申请号：US12418994
申请日：2009-04-06
CPC分类号： C10G3/52 , C10G3/46 , C10G3/47 , C10G3/49 , C10G69/00 , C10G69/02 , C10G69/14 , C10G2300/1014 , C10G2300/1018 , C10G2300/1022 , C10G2300/1037 , C10G2300/4081 , C10G2300/80 , C10G2400/02 , C10G2400/04 , C10G2400/08 , Y02P30/20
摘要： A process for producing at least one blended fuel from a paraffin rich component and a cyclic rich component, where each of the components are generated from a renewable feedstock, is presented. The paraffin rich component is generated from glycerides and free fatty acids in feedstocks such as plant and animal oils. The cyclic rich component is generated from biomass derived pyrolysis oil. The source of the animal or plant oil and the biomass may be the same renewable source.
摘要翻译： 提出了一种从富含链烷烃的组分和富含氟的组分制备至少一种混合燃料的方法，其中每种组分由可再生原料生成。 富含石蜡的组分由原料如植物油和动物油中的甘油酯和游离脂肪酸产生。 循环富成分由生物质衍生的热解油产生。 动物或植物油和生物质的来源可能是相同的可再生能源。
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公开(公告)号：US07288684B1
公开(公告)日：2007-10-30
申请号：US11560960
申请日：2006-11-17
IPC分类号： C07C27/12
CPC分类号： C07C29/48 , C07C29/095 , C07C29/80 , C07C67/035 , C07C69/63 , C07C31/04
摘要： A process for the production of methanol from methane has been developed. The process involves reacting methane with an oxidant such as oxygen or a peroxide in the presence of a catalyst and a solvent in a reaction zone to produce an effluent stream comprising a methanol product. The effluent stream is next separated into a gaseous stream comprising unreacted methane and carbon dioxide and a liquid stream comprising the methanol product and solvent. Next the gaseous stream is further separated to provide a methane stream which is recycled to the reaction zone. Finally, a methanol stream is isolated and a solvent stream is recycled to the reaction zone.
摘要翻译： 已经开发了从甲烷生产甲醇的方法。 该方法包括在反应区中在催化剂和溶剂存在下使甲烷与氧化剂如氧或过氧化物反应，以产生包含甲醇产物的流出物流。 然后将流出物流分离成包含未反应的甲烷和二氧化碳的气流以及包含甲醇产物和溶剂的液体流。 接下来，进一步分离气流以提供甲烷流，其被再循环到反应区。 最后，分离甲醇流，将溶剂流再循环到反应区。
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公开(公告)号：US07038090B1
公开(公告)日：2006-05-02
申请号：US10816128
申请日：2004-04-01
IPC分类号： C07C409/00
CPC分类号： C10L1/1811 , B01J23/002 , B01J23/34 , B01J2523/00 , C07B41/14 , B01J2523/22 , B01J2523/72 , B01J2523/11 , B01J2523/12 , B01J2523/51 , B01J2523/48
摘要： A process and catalyst for preparing organic hydroperoxides by oxidizing hydrocarbon compounds in the presence of an oxygen-containing gas and a catalyst containing a transition metal on a solid support.
摘要翻译： 一种通过在含氧气体和含有过渡金属的催化剂存在下在固体载体上氧化烃化合物来制备有机氢过氧化物的方法和催化剂。
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公开(公告)号：US5760286A
公开(公告)日：1998-06-02
申请号：US832594
申请日：1997-04-02
申请人： Timothy A. Brandvold
发明人： Timothy A. Brandvold
CPC分类号： C07F9/5068 , C07F9/52
摘要： Tertiary phosphine sulfonic acids are important ligands for transition metals where the complex is effective in catalyzing the oligomerization of alpha-olefins. An improved method of preparation utilizes inverse addition of lithiated aryl sulfonate salts to dihalophosphines at a rate which maintains a homogeneous reaction mixture, then alkylating the product of this reaction--a monohalo secondary phosphine sulfonate--with an organometallic compound, such as a Grignard reagent or an organolithium species.
摘要翻译： 叔膦磺酸是过渡金属的重要配体，其中络合物有效催化α-烯烃的低聚。 改进的制备方法利用将卤代芳基磺酸盐以保持均匀的反应混合物的速率逆向加入二卤代膦，然后将该反应的产物 - 单卤代仲膦磺酸酯与有机金属化合物如格氏试剂或 有机锂物质。
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公开(公告)号：US5744679A
公开(公告)日：1998-04-28
申请号：US775051
申请日：1996-12-27
IPC分类号： B01J31/24 , C07B61/00 , C07C2/08 , C07C2/32 , C07C2/36 , C07C11/02 , C07C2/16 , C07C2/18 , C07C2/22
CPC分类号： C07C2/36 , C07C2531/24 , Y02P20/52
摘要： Ethylene is effectively oligomerized to linear alpha-olefins using catalyst systems based on transition metal compounds. It has been found that when the reaction is conducted in a polar organic liquid as solvent, incorporation of water into the solvent at levels of 1 to 10 weight percent increases alpha-olefin purity and also influences the Schulz-Flory distribution.
摘要翻译： 使用基于过渡金属化合物的催化剂体系，乙烯有效地低聚成线性α-烯烃。 已经发现，当反应在作为溶剂的极性有机液体中进行时，以1-10重量％的水平将水引入溶剂中增加了α-烯烃的纯度，并且也影响了Schulz-Flory分布。
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80.发明授权Process for forming acid functionalized organically-bridged polysilsesquioxanes 失效形成酸官能化有机桥连聚倍半硅氧烷的方法
公开(公告)号：US5371154A
公开(公告)日：1994-12-06
申请号：US149391
申请日：1993-11-09
IPC分类号： C08G77/52 , C08F283/00
CPC分类号： C08G77/52
摘要： A process for forming a solid acid catalyst where all of the add functionality is covalently bonded to the organic portion of an organically-bridged polysilsesquioxane framework has been developed. The process involves polymerizing a monomer through sol-gel processing to form an organically-bridged polysilsesquioxane, reacting an acid group onto the organic portion of the organically-bridged polysilsesquioxane, and recovering the acid functionalized product. The invention also includes the product acid functionalized organically-bridged polysilsesquioxane catalyst of the process described. The catalyst is unique in that the acid functionality is incorporated within an organic-inorganic hybrid framework as opposed to being attached to pendant organic groups.
摘要翻译： 已经开发了形成固体酸催化剂的方法，其中所有添加官能团共价键合到有机桥连聚倍半硅氧烷骨架的有机部分。 该方法包括通过溶胶 - 凝胶加工聚合单体以形成有机桥连聚倍半硅氧烷，将酸基团与有机桥连聚倍半硅氧烷的有机部分反应，并回收酸官能化产物。 本发明还包括所述方法的产物酸官能化有机桥联聚倍半硅氧烷催化剂。 催化剂是独特的，因为酸官能团被结合到有机 - 无机混合物框架内，而不是附着于有机基团上。
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