公开(公告)号：US08399109B2

公开(公告)日：2013-03-19

申请号：US13624161

申请日：2012-09-21

Applicant: Azad M. Hassan ,  Mark E. Thompson

Inventor： Azad M. Hassan ,  Mark E. Thompson

IPC: H01L51/54

CPC classification number: H01L51/0072 ,  C07D209/48 ,  C07D403/08 ,  C07D403/10 ,  H01L51/0053 ,  H01L51/0081 ,  H01L51/0085 ,  H01L51/42 ,  H01L51/5012 ,  H01L51/5096 ,  H01L2251/308 ,  Y02E10/549

Abstract: Organic electronic devices comprising a phthalimide compound. The phthalimide compounds disclosed herein are electron transporters with large HOMO-LUMO gaps, high triplet energies, large reduction potentials, and/or thermal and chemical stability. As such, these phthalimide compounds are suitable for use in any of various organic electronic devices, such as OLEDs and solar cells. In an OLED, the phthalimide compounds may serve various functions, such as a host in the emissive layer, as a hole blocking material, or as an electron transport material. In a solar cell, the phthalimide compounds may serve various functions, such as an exciton blocking material. Various examples of phthalimide compounds which may be suitable for use in the present invention are disclosed.

公开(公告)号：US20120177813A1

公开(公告)日：2012-07-12

申请号：US13274875

申请日：2011-10-17

Applicant: Mark E. Thompson ,  Cong Trinh ,  Matthew T. Whited

Inventor： Mark E. Thompson ,  Cong Trinh ,  Matthew T. Whited

IPC: B05D3/10 ,  B05D5/12 ,  C23C16/44

CPC classification number: H01L51/002 ,  B82Y10/00 ,  C23C14/12 ,  C23C14/5846 ,  H01L51/0028 ,  H01L51/0046 ,  H01L51/0077 ,  H01L2251/308 ,  Y02E10/549

Abstract: There is disclosed a method of coordinating ligands, such as nitrogen-containing ligands to metal centers of metal-containing macrocyclic compounds, such as Magnesium Tetraphenyl Porphyrin (MgTPP) or Zinc Tetraphenyl Porphyrin (ZnTPP). The disclosed method comprises (a) forming an organic film comprising the disclosed metal-containing, macrocyclic compound; and (b) exposing the organic film to a vapor comprising at least one ligand for a time sufficient to coordinate the ligand to metal centers in the metal-containing, macrocyclic compound. There is also disclosed a method for preparing an organic photovoltaic device, such as a solar cell, comprising an ordered crystalline organic film made by the disclosed chemical annealing process.

Abstract translation: 公开了配位体如含金属的大环化合物如四苯基卟啉镁（MgTPP）或锌四苯基卟啉（ZnTPP）的金属中心的配体配位体的方法。 所公开的方法包括（a）形成包含所公开的含金属的大环化合物的有机膜; 和（b）将有机膜暴露于包含至少一种配体的蒸气足够长的时间以使该配体与含金属的大环化合物中的金属中心配位。 还公开了一种制备有机光伏器件的方法，例如太阳能电池，其包括通过公开的化学退火工艺制成的有序结晶有机膜。

公开(公告)号：US20120104378A1

公开(公告)日：2012-05-03

申请号：US13347945

申请日：2012-01-11

Applicant: Peter Djurovich ,  Jui-Yi Tsai ,  Chun Lin ,  Jason Brooks ,  Bert Alleyne ,  Mark E. Thompson ,  Peter B. MacKenzie ,  Bein Ma

Inventor： Peter Djurovich ,  Jui-Yi Tsai ,  Chun Lin ,  Jason Brooks ,  Bert Alleyne ,  Mark E. Thompson ,  Peter B. MacKenzie ,  Bein Ma

IPC: H01L51/54 ,  C07F15/00

CPC classification number: H01L51/0085 ,  C07F15/0033 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1029 ,  C09K2211/1044 ,  C09K2211/185 ,  H01L51/0067 ,  H01L51/0069 ,  H01L51/0072 ,  H01L51/0077 ,  H01L51/0079 ,  H01L51/0081 ,  H01L51/5016 ,  H01L51/5036 ,  H01L2251/308 ,  Y10S428/917

Abstract: An organic light emitting device having an anode, a cathode and an organic layer disposed between the anode and the cathode is provided. In one aspect, the organic layer comprises a compound having at least one zwitterionic carbon donor ligand. In another aspect, the organic layer comprises a carbene compound, including the following: In another aspect, the organic layer comprises a carbene compound, including: In another aspect, the organic layer comprises a carbene compound that includes a triazole ring and has the structure: In another aspect, the organic layer comprises a carbene compound that includes a tetrazole ring and has the structure:

Abstract translation: 提供一种具有设置在阳极和阴极之间的阳极，阴极和有机层的有机发光器件。 一方面，有机层包括具有至少一个两性离子碳供体配体的化合物。 另一方面，有机层包括卡宾化合物，其包括以下：另一方面，有机层包含卡宾化合物，其包括：另一方面，有机层包含含有三唑环的卡宾化合物，其结构 另一方面，有机层包含含有四唑环的卡宾化合物，其结构如下：

公开(公告)号：US20120045862A1

公开(公告)日：2012-02-23

申请号：US13193036

申请日：2011-07-28

Applicant: Mark E. Thompson ,  Zhiwei Liu ,  Chao Wu

Inventor： Mark E. Thompson ,  Zhiwei Liu ,  Chao Wu

IPC: H01L51/56

CPC classification number: C23C14/12 ,  C07F1/005 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1029 ,  C09K2211/1048 ,  C09K2211/188 ,  H01L51/001 ,  H01L51/0091 ,  H01L51/5016

Abstract: A method for fabricating an OLED by preparing phosphorescent metal complexes in situ is provided. In particular, the method simultaneously synthesizes and deposits copper (I) complexes in an organic light emitting device. Devices comprising such complexes may provide improved photoluminescent and electroluminescent properties.

Abstract translation: 提供了通过原位制备磷光金属络合物来制造OLED的方法。 特别地，该方法同时在有机发光器件中合成并沉积铜（I）配合物。 包含这种配合物的装置可以提供改进的光致发光和电致发光性质。

公开(公告)号：US08105700B2

公开(公告)日：2012-01-31

申请号：US11974020

申请日：2007-10-10

Applicant: Mark E. Thompson ,  Raymond Kwong ,  Yeh-Jiun Tung ,  Jason Brooks

Inventor： Mark E. Thompson ,  Raymond Kwong ,  Yeh-Jiun Tung ,  Jason Brooks

IPC: H01L51/54

CPC classification number: H01L51/5016 ,  C07C13/567 ,  C07C13/66 ,  C07C15/24 ,  C07C15/38 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1011 ,  H01L51/0034 ,  H01L51/0035 ,  H01L51/0039 ,  H01L51/005 ,  H01L51/0052 ,  H01L51/0054 ,  H01L51/0081 ,  H01L51/0085 ,  H01L51/5048 ,  H01L2251/308 ,  H05B33/14 ,  Y10S428/917

Abstract: A device is provided, having an anode, a cathode, and two adjacent organic layers disposed between the anode and the cathode. One organic layer is a phosphorescent emissive material. The other organic layer may comprise an aromatic hydrocarbon material, comprising an aromatic non-heterocyclic hydrocarbon core optionally substituted, and wherein the substituents are the same or different, and each is selected from the group consisting of alkyl, alkenyl, alkynyl, aryl, heteroalkyl, substituted aryl, substituted heteroaryl and heterocyclic groups. The second organic layer may comprise a material having a molecular dipole moment less than about 2.0 debyes, such that the device has an unmodified external quantum efficiency of at least about 3% and a lifetime of at least about 1000 hours at an initial luminance of about 100 to about 1000 cd m2.

Abstract translation: 提供一种具有阳极，阴极和设置在阳极和阴极之间的两个相邻有机层的器件。 一个有机层是磷光发光材料。 另一有机层可以包括芳族烃材料，其包含任选取代的芳族非杂环烃核心，并且其中取代基相同或不同，并且各自选自烷基，烯基，炔基，芳基，杂烷基 取代的芳基，取代的杂芳基和杂环基。 第二有机层可以包括具有小于约2.0德拜兹的分子偶极矩的材料，使得该器件在初始亮度约为约3％时具有至少约3％的未修饰的外量子效率和至少约1000小时的寿命 100至约1000cd m2。

公开(公告)号：US20120001155A1

公开(公告)日：2012-01-05

申请号：US12985439

申请日：2011-01-06

Applicant: Mark E. Thompson ,  Viacheslav Diev ,  Kenneth Hanson ,  Stephen R. Forrest

Inventor： Mark E. Thompson ,  Viacheslav Diev ,  Kenneth Hanson ,  Stephen R. Forrest

IPC: H01L51/46 ,  H01L51/48 ,  C07D487/22

CPC classification number: H01L51/0092 ,  C07D487/22 ,  C07D495/22 ,  C09B47/00 ,  C09K2211/1007 ,  C09K2211/1011 ,  C09K2211/1029 ,  C09K2211/188 ,  H01L51/0026 ,  H01L51/0072 ,  H01L51/0077 ,  H01L51/442 ,  H01L2251/308 ,  H05B33/10 ,  Y02E10/549

Abstract: A compound that can be used as a donor material in organic photovoltaic devices comprising a non-activated porphyrin fused with one or more non-activated polycyclic aromatic rings or one or more non-activated, heterocyclic rings can be obtained by a thermal fusion process. By heating the reaction mixture of non-activated porphyrins with non-activated polycyclic aromatic rings or heterocyclic rings to a fusion temperature and holding for a predetermined time, fusion of one or more polycyclic rings or heterocyclic rings to the non-activated porphyrin core in meso,β fashion is achieved, resulting in hybrid structures containing a distorted porphyrin ring with annulated aromatic rings. The porphyrin core can be olygoporphyrins.

Abstract translation: 可以通过热熔融方法获得可用作有机光伏器件中的供体材料的化合物，其包含与一种或多种未活化多环芳环或一个或多个未活化杂环稠合的未活化卟啉。 通过将非活化卟啉与非活化多环芳环或杂环的反应混合物加热至融合温度并保持预定时间，将一个或多个多环环或杂环与内消旋的非活化卟啉核心的融合 ，＆bgr 实现了时尚，导致包含具有环状芳环的扭曲的卟啉环的杂化结构。 卟啉核可以是o卟啉。

公开(公告)号：US20110275544A1

公开(公告)日：2011-11-10

申请号：US12680821

申请日：2008-10-01

Applicant: Chongwu Zhou ,  Mark E. Thompson ,  Richard James Cote ,  Emil P. Kartalov

Inventor： Chongwu Zhou ,  Mark E. Thompson ,  Richard James Cote ,  Emil P. Kartalov

IPC: C40B50/14 ,  C40B60/12

CPC classification number: C12Q1/6825 ,  B82Y15/00 ,  B82Y30/00 ,  C12Q1/6827 ,  C12Q1/6886 ,  C12Q2600/154 ,  C12Q2600/156 ,  G01N27/4146 ,  C12Q2565/607 ,  C12Q2565/519 ,  C12Q2537/164 ,  C12Q2522/101 ,  C12Q2522/10 ,  C12Q2523/125 ,  C12Q2563/155 ,  C12Q2565/631

Abstract: The present invention describes microfluidics being employed to achieve multiplex surface functionalization of nanosensor chips by selectively delivering probe molecules to individual nanosensors in an array, and microfluidics being employed to achieve delivery of a solution containing multiple analytes over individual nanosensors in an array, where each nanosensor was previously configured with a specific capture molecule.

Abstract translation: 本发明描述了微流体，用于通过选择性地将探针分子递送到阵列中的单个纳米传感器来实现纳米传感器芯片的多重表面官能化，并且微流体用于实现在阵列中的单个纳米传感器上递送含有多个分析物的溶液，其中每个纳米传感器 以前配置了特定的捕获分子。

公开(公告)号：US08043724B2

公开(公告)日：2011-10-25

申请号：US12069610

申请日：2008-02-11

Applicant: Mark E. Thompson ,  Arnold Tamayo ,  Peter Djurovich

Inventor： Mark E. Thompson ,  Arnold Tamayo ,  Peter Djurovich

IPC: H01L51/54 ,  C09K11/06

CPC classification number: H01L51/0085 ,  C07D231/12 ,  C07F15/0033 ,  C07F15/0046 ,  C09K11/06 ,  C09K2211/1029 ,  C09K2211/1044 ,  C09K2211/185 ,  H01L51/5016 ,  H01L2251/55 ,  H05B33/14 ,  Y10S428/917

Abstract: The invention provides emissive materials and organic light emitting devices using the emissive materials in an emissive layer disposed between and electrically connected to an anode and a cathode. The emissive materials include compounds with the following structure: wherein at least one of R8 to R14 is phenyl or substituted phenyl, and/or at least two of R8 to R14 that are adjacent are part of a fluorenyl group. The emissive materials have enhanced electroluminescent efficiency and improved lifetime when incorporated into light emitting devices.

Abstract translation: 本发明提供发射材料和使用发光材料的发光材料和设置在阳极和阴极之间并与之电连接的发光层。 发光材料包括具有以下结构的化合物：其中R 8至R 14中的至少一个为苯基或取代的苯基，和/或相邻的R 8至R 14中的至少两个为芴基的一部分。 发光材料在结合到发光器件中时具有增强的电致发光效率和改善的寿命。

公开(公告)号：US20110147727A1

公开(公告)日：2011-06-23

申请号：US13035051

申请日：2011-02-25

Applicant: Mark E. Thompson ,  Yujian You ,  Andrei Shoustikov ,  Scott Sibley ,  Paul E. Burrows ,  Stephen R. Forrest

Inventor： Mark E. Thompson ,  Yujian You ,  Andrei Shoustikov ,  Scott Sibley ,  Paul E. Burrows ,  Stephen R. Forrest

IPC: H01L51/54

CPC classification number: H01L51/0084 ,  C07D487/22 ,  C09K11/06 ,  C09K2211/10 ,  C09K2211/1003 ,  C09K2211/1007 ,  C09K2211/1018 ,  C09K2211/1029 ,  C09K2211/1033 ,  C09K2211/1074 ,  C09K2211/18 ,  C09K2211/185 ,  C09K2211/186 ,  H01L51/0053 ,  H01L51/0067 ,  H01L51/0077 ,  H01L51/0081 ,  H01L51/0087 ,  H01L51/5016 ,  H01L51/5221 ,  H01L51/5234 ,  H01L2251/308 ,  H01L2251/5323 ,  H05B33/14 ,  H05B33/28 ,  Y10S428/917 ,  Y10T428/24942

Abstract: Organic light emitting devices are disclosed which are comprised of a heterostructure for producing electroluminescence wherein the heterostructure is comprised of an emissive layer containing a phosphorescent dopant compound. For example, the phosphorescent dopant compound may be comprised of platinum octaethylporphine (PtOEP), which is a compound having the chemical structure with the formula:

Abstract translation: 公开了由用于产生电致发光的异质结构组成的有机发光器件，其中异质结构由含有磷光掺杂剂化合物的发射层组成。 例如，磷光掺杂剂化合物可以由具有以下化学结构的化合物的铂八乙基卟吩（PtOEP）组成：

公开(公告)号：US07901795B2

公开(公告)日：2011-03-08

申请号：US12489045

申请日：2009-06-22

Applicant: Mark E. Thompson ,  Yujian You ,  Andrei Shoustikov ,  Scott Sibley ,  Paul E. Burrows ,  Stephen R. Forrest

Inventor： Mark E. Thompson ,  Yujian You ,  Andrei Shoustikov ,  Scott Sibley ,  Paul E. Burrows ,  Stephen R. Forrest

IPC: H01L51/54

CPC classification number: H01L51/0084 ,  C07D487/22 ,  C09K11/06 ,  C09K2211/10 ,  C09K2211/1003 ,  C09K2211/1007 ,  C09K2211/1018 ,  C09K2211/1029 ,  C09K2211/1033 ,  C09K2211/1074 ,  C09K2211/18 ,  C09K2211/185 ,  C09K2211/186 ,  H01L51/0053 ,  H01L51/0067 ,  H01L51/0077 ,  H01L51/0081 ,  H01L51/0087 ,  H01L51/5016 ,  H01L51/5221 ,  H01L51/5234 ,  H01L2251/308 ,  H01L2251/5323 ,  H05B33/14 ,  H05B33/28 ,  Y10S428/917 ,  Y10T428/24942

Abstract: Organic light emitting devices are disclosed which are comprised of a heterostructure for producing electroluminescence wherein the heterostructure is comprised of an emissive layer containing a phosphorescent dopant compound. For example, the phosphorescent dopant compound may be comprised of platinum octaethylporphine (PtOEP), which is a compound having the chemical structure with the formula:

Abstract translation: 公开了由用于产生电致发光的异质结构组成的有机发光器件，其中异质结构由含有磷光掺杂剂化合物的发射层组成。 例如，磷光掺杂剂化合物可以由具有以下化学结构的化合物的铂八乙基卟吩（PtOEP）组成：