公开(公告)号：US5391677A

公开(公告)日：1995-02-21

申请号：US105164

申请日：1993-08-12

申请人： Masatoshi Arai ,  Takafumi Sakamoto ,  Kazutoshi Fujioka

发明人： Masatoshi Arai ,  Takafumi Sakamoto ,  Kazutoshi Fujioka

IPC分类号： C07F7/08 ,  C08G77/20 ,  C08G77/40

CPC分类号： C07F7/0859 ,  C07F7/0852 ,  C08G77/20

摘要： A novel acrylic-functional organopolysiloxane is proposed which has a plural number of silicon-bonded (meth)acryloxyalkyl groups at each molecular chain end along with one or more of silicon-bonded alkoxy groups. The organopolysiloxane exhibits high curability by the irradiation with ultraviolet light or dual curability either by the ultraviolet irradiation or by the dealcoholation condensation reaction in a moisture-containing atmosphere. The acrylic-functional organopolysiloxane is prepared by the dealcoholation condensation reaction between a starting organopolysiloxane having a plural number of silicon-bonded alkoxy groups at each molecular chain end and a (meth)acryloxyalkyl dimethyl silanol compound in the presence of a specific condensation catalyst which is a divalent tin compound such as tin (II) dioctoate promoting the dealcoholation condensation but suppressing the silanol condensation reaction between the moleculaes of the (meth)acryloxyalkyl dimethyl silanol compound.

摘要翻译： 提出了一种新的丙烯酸官能的有机聚硅氧烷，其在每个分子链端具有多个硅键合的（甲基）丙烯酰氧基烷基以及一个或多个与硅键合的烷氧基。 有机聚硅氧烷通过紫外线照射或通过紫外线照射或通过在含水气氛中的脱醇缩合反应的双重固化性，显示出高的固化性。 丙烯酸官能的有机聚硅氧烷是通过在各分子链末端具有多个与硅键合的烷氧基的起始有机聚硅氧烷与（甲基）丙烯酰氧基烷基二甲基硅烷醇化合物在特定的缩合催化剂存在下的脱醇缩合反应来制备的， 二异辛基锡化合物如二辛酸锡（II），促进脱醇缩合，但抑制（甲基）丙烯酰氧基烷基二甲基硅烷醇化合物的分子之间的硅烷醇缩合反应。

公开(公告)号：US5357023A

公开(公告)日：1994-10-18

申请号：US83387

申请日：1993-06-29

申请人： Yoshio Inoue ,  Masatoshi Arai ,  Kazutoshi Fujioka ,  Tsuneo Kimura

发明人： Yoshio Inoue ,  Masatoshi Arai ,  Kazutoshi Fujioka ,  Tsuneo Kimura

IPC分类号： C08G77/50 ,  C08L83/14 ,  C08G77/20

CPC分类号： C08L83/14 ,  C08G77/50

摘要： A novel organopolysiloxane compound having, in a molecule, at least one silyl-substituted ethyl group of the general formula ##STR1## in which R.sup.1 is a hydrogen atom or a methyl group, R is a monovalent hydrocarbon group and the subscripts a is 2 or and b is 1, 2 or 3, or a linear organopolysiloxane having, at each molecular chain end, at least one of such a group, can be prepared by first reacting a vinyl-containing organopolysiloxane with a hydrogen chlorosilane compound to effect the hydrosilation reaction between the silicon-bonded vinyl groups and the silicon-bonded hydrogen atoms and then the silicon-bonded chlorine atoms are subjected to a dehydrochlorination reaction with a silanol compound of the general formula ##STR2## A composition comprising the organopolysiloxane and a photopolymerization initiator is highly sensitive to light and readily cured into a rubbery elastomer by irradiation with ultraviolet light.

摘要翻译： 一种新的有机聚硅氧烷化合物，其在分子中具有至少一个通式为“IMAGE”的甲硅烷基取代的乙基，其中R 1为氢原子或甲基，R为单价烃基，下标a为2或 并且b为1,2或3，或者在各分子链末端具有这种基团中的至少一个的线性有机聚硅氧烷可以通过首先使含乙烯基的有机聚硅氧烷与氢氯硅烷化合物反应来进行氢化硅烷化反应 硅键合的乙烯基和与硅键合的氢原子之间，然后与硅键合的氯原子与通式为的硅烷醇化合物进行脱氯化氢反应。包含有机聚硅氧烷和光聚合引发剂的组合物是高度的 对光敏感，并通过紫外线照射容易地固化成橡胶状弹性体。

公开(公告)号：US5117029A

公开(公告)日：1992-05-26

申请号：US741371

申请日：1991-08-07

申请人： Masatoshi Arai

发明人： Masatoshi Arai

IPC分类号： C07F7/08 ,  C08G77/04 ,  C08G77/18 ,  C08G77/22 ,  C08G77/38

CPC分类号： C08G77/18 ,  C07F7/0858 ,  C07F7/0874 ,  C08G77/045

摘要： Alkoxy-functional organopolysiloxanes can be prepared in high yields by reacting a hydroxy-containing organic silicon compound with an .alpha.-alkoxysilyl ester in the absence of a catalyst. The alkoxy-functional organopolysiloxanes are useful modifiers and surface treating agents a well as raw materials for silicone resins and rubbers.

公开(公告)号：US4845259A

公开(公告)日：1989-07-04

申请号：US144465

申请日：1988-01-19

申请人： Masatoshi Arai ,  Tsuneo Kimura

发明人： Masatoshi Arai ,  Tsuneo Kimura

IPC分类号： C07F7/08 ,  C08F30/08 ,  C08K5/5425

CPC分类号： C08F30/08 ,  C07F7/0836 ,  C08K5/5425

摘要： Novel organosilane compounds of the following general formula ##STR1## in which R.sup.1 is a hydrogen atom or a methyl group, R.sup.2 and R.sup.3 are independently an unsubstituted or substituted monovalent hydrocarbon group, and n is an integer of 1, 2 or 3. The compounds are reactive with other reactive group-bearing copounds and are effective for potting, sealing or coating of electric and electronic parts.

摘要翻译： 其中R 1为氢原子或甲基的下列通式为“IMAGE”的新型有机硅烷化合物，R 2和R 3独立地为未取代或取代的一价烃基，n为1,2或3的整数。化合物 与其他具有反应活性基团的组合物反应，对于电气和电子部件的灌封，密封或涂层是有效的。

公开(公告)号：US4737563A

公开(公告)日：1988-04-12

申请号：US944751

申请日：1986-12-22

申请人： Masatoshi Arai ,  Shinichi Sato

发明人： Masatoshi Arai ,  Shinichi Sato

IPC分类号： C07F7/18 ,  C07F7/08 ,  C08G77/06 ,  C08G77/12 ,  C08G77/22 ,  C08G77/38 ,  C08G77/02

CPC分类号： C08G77/12 ,  C07F7/0896

摘要： A novel method is proposed for the synthesis of an organopolysiloxane having two hydrogen atoms directly bonded to the same silicon atom at the molecular chain end. The method comprises mixing a dihydro isopropenyloxy silane with an organosilicon compound having at least one silanolic hydroxy group so that a condensation reaction takes place between the isopropenyloxy group of the former reactant and the silanol group of the latter reactant forming acetone as a by-product. The method is advantageous in respect of the absence of any acidic or basic by-product contained in the product as an impurity in the conventional methods.

摘要翻译： 提出了一种合成具有在分子链端直接键合到同一个硅原子上的两个氢原子的有机聚硅氧烷的新方法。 该方法包括将二氢异丙烯氧基硅烷与具有至少一个硅烷醇羟基的有机硅化合物混合，使得在前一反应物的异丙烯氧基与作为副产物形成丙酮的后者反应物的硅烷醇基之间发生缩合反应。 该方法在常规方法中不存在产物中包含的任何酸性或碱性副产物作为杂质是有利的。

公开(公告)号：US4721766A

公开(公告)日：1988-01-26

申请号：US894857

申请日：1986-08-08

申请人： Yoshio Inoue ,  Masatoshi Arai ,  Koji Yokoo

发明人： Yoshio Inoue ,  Masatoshi Arai ,  Koji Yokoo

IPC分类号： C08L83/00 ,  C08K5/5419 ,  C08K5/5425 ,  C08K5/5465 ,  C08L1/00 ,  C08L23/00 ,  C08L27/00 ,  C08L83/04 ,  C08L83/06 ,  C08L101/00 ,  C08G77/06

CPC分类号： C08K5/5465 ,  C08L83/04 ,  C08G77/16 ,  C08G77/18 ,  Y10S528/901

摘要： The room temperature-curable organopolysiloxane composition of the invention is imparted with greatly improved stability in prolonged storage without being affected in respect of the curability. The composition is formulated, in addition to the base ingredients of a silanol- or alkoxy-terminated diorganopolysiloxane and a filler, with an alkenyloxy-containing silane compound in an amount of at least equimolar to the silanol groups and water in the base ingredients and a guanidino-containing organosilane compound in a limited amount.

摘要翻译： 本发明的室温可固化的有机基聚硅氧烷组合物在长期保存中赋予了极大的改进的稳定性，而不会影响固化性。 除了硅烷醇或烷氧基封端的二有机聚硅氧烷和填料的基础成分之外，配合含有至少等摩尔量的含烯氧基的硅烷化合物与基础成分中的硅烷醇基和水，以及 含胍基的有机硅烷化合物。

公开(公告)号：US4695603A

公开(公告)日：1987-09-22

申请号：US739421

申请日：1985-05-30

申请人： Yoshio Inoue ,  Masatoshi Arai ,  Takeo Inoue

发明人： Yoshio Inoue ,  Masatoshi Arai ,  Takeo Inoue

IPC分类号： C09K3/10 ,  C08K3/00 ,  C08K5/00 ,  C08K5/54 ,  C08K5/5455 ,  C08K5/549 ,  C08L83/00 ,  C08L83/04 ,  C08L83/06 ,  C08L83/08

CPC分类号： C08K5/0008 ,  C08K5/5455

摘要： The room temperature curable silicone rubber composition of the invention is outstandingly free from the problem of surface stain when a cured elastomer thereof used, for example, in building works is prolongedly exposed to the atmosphere with very durable stain-preventing effect by the formulation of a surface active agent having at least one fluorine atom in a molecule and a specific organosilicon compound of the formula R.sup.1 --CO--NR.sup.2 --CH.sub.2).sub.b SiR.sup.3.sub.a O.sub.(3-a)/2, in which R.sup.1 and R.sup.2 are each a hydrogen atom or a monovalent hydrocarbon group, R.sup.3 is a hydrogen atom, or monovalent hydrocarbon group, a is 0-3 and b is a positive integer not larger than 10, in addition to the usual components of conventional room temperature curable silicone rubber compositions.

摘要翻译： 当本发明的室温可固化硅橡胶组合物在其用于例如建筑工程中的固化弹性体长期暴露于大气中时，其表面污渍的问题显着地不会受到非常耐用的防污染作用， 分子中具有至少一个氟原子的表面活性剂和式R 1 -CO-NR 2 -CH 2）b SiR 3 a O（3-a）/ 2的特定有机硅化合物，其中R 1和R 2各自为氢原子或 一价烃基，R3为氢原子或一价烃基，a为0-3，b为不大于10的正整数，除常规的室温可固化硅橡胶组合物的组分外。

公开(公告)号：US4376192A

公开(公告)日：1983-03-08

申请号：US358296

申请日：1982-03-15

申请人： Toshio Takago ,  Masatoshi Arai ,  Takeo Inoue ,  Masami Terashima

发明人： Toshio Takago ,  Masatoshi Arai ,  Takeo Inoue ,  Masami Terashima

IPC分类号： C08L83/00 ,  C08K5/5455 ,  C08K5/5465 ,  C08L1/00 ,  C08L27/00 ,  C08L33/00 ,  C08L33/02 ,  C08L83/04 ,  C08G77/04

CPC分类号： C08K5/54 ,  C08G77/16 ,  C08G77/26 ,  Y10S528/901

摘要： The invention provides a novel room temperature-curable organopolysiloxane composition useful as an adhesive or a sealing material with remarkably extended workable time owing to the delayed surface filming. The base component in the composition is a conventional diorganopolysiloxane terminated with hydroxy groups at both molecular chain ends admixed with several known ingredients such as a cross linking agent, curing catalyst, filler and the like. The most characteristic ingredient in the composition effective to achieve the above mentioned desired property is a 1,1,1-trimethyl-3-hydrocarbyl-3,3-di(acylamino)disiloxane which belongs to a novel class of organopolysiloxane compounds and method is described for the preparation of these siloxane compounds.

摘要翻译： 本发明提供了一种用作粘合剂或密封材料的新颖的室温可固化的有机聚硅氧烷组合物，由于延迟的表面成膜而具有显着延长的可使用时间。 组合物中的基础组分是在两个分子链末端用羟基封端的常规二有机聚硅氧烷，其与若干已知成分如交联剂，固化催化剂，填料等混合。 有效实现上述所需性能的组合物中最具特色的成分是属于新一类有机聚硅氧烷化合物的1,1,1-三甲基-3-烃基-3,3-二（酰氨基）二硅氧烷，方法为 描述为制备这些硅氧烷化合物。

公开(公告)号：US4304920A

公开(公告)日：1981-12-08

申请号：US162533

申请日：1980-06-24

申请人： Masatoshi Arai ,  Koji Futatsumori

发明人： Masatoshi Arai ,  Koji Futatsumori

IPC分类号： C08K5/00 ,  C07F7/18 ,  C08K5/5425 ,  C08K9/06 ,  C07F7/04

CPC分类号： C07F7/1828 ,  C08K5/5425 ,  C08K9/06

摘要： The invention provides a novel class or organosilane compounds having a methacryloxy group and one or more of alkenyloxy groups bonded to the silicon atom as represented by the general formula ##STR1## in which R.sup.1 is a monovalent hydrocarbon group having from 1 to 8 carbon atoms, R.sup.2, R.sup.3 and R.sup.4 are each a hydrogen atom or a monovalent hydrocarbon group having from 1 to 8 carbon atoms, m is an integer of 3, 4 or 5 and n is a number of zero, 1 or 2. The organosilane compound, e.g. 3-methacryloxypropyl-containing alkenyloxysilanes can be readily prepared by the addition reaction of allyl methacrylate and a corresponding alkenyloxysilane having a hydrogen atom directly bonded to the silicon atom in the presence of a platinum catalyst. The organosilane compounds are useful as a coupling agent to increase adhesive bonding strength between inorganic and organic materials.

摘要翻译： 本发明提供了具有甲基丙烯酰氧基和一个或多个与硅原子键合的链烯氧基的新型或有机硅烷化合物，如通式“IMAGE”所示，其中R 1是具有1至8个碳原子的一价烃基， R2，R3和R4各自为氢原子或具有1至8个碳原子的一价烃基，m为3,4或5的整数，n为0,1或2的数。有机硅烷化合物，例如 含有甲基丙烯酰氧基丙基的烯基氧基硅烷可以容易地通过在铂催化剂存在下，通过甲基丙烯酸烯丙酯和具有直接与硅原子键合的氢原子的相应的烯基氧基硅烷的加成反应来制备。 有机硅烷化合物可用作偶联剂以增加无机和有机材料之间的粘合强度。

公开(公告)号：US4294975A

公开(公告)日：1981-10-13

申请号：US151696

申请日：1980-05-20

申请人： Toshio Takago ,  Masatoshi Arai ,  Koji Futatsumori

发明人： Toshio Takago ,  Masatoshi Arai ,  Koji Futatsumori

IPC分类号： C08K5/00 ,  C07F7/02 ,  C07F7/04 ,  C07F7/08 ,  C07F7/18 ,  C08K5/5425 ,  C08L83/04

CPC分类号： C07F7/1868 ,  C07F7/025 ,  C07F7/04 ,  C07F7/0896 ,  C08K5/54

摘要： The invention provides a novel class of organosilicon compounds which are hydrogenalkenyloxysilanes represented by the general formula ##STR1## in which R.sup.1 is a monovalent hydrocarbon group having from 1 to 8 carbon atoms, R.sup.2, R.sup.3 and R.sup.4 are each a hydrogen atom or a monovalent hydrocarbon group having from 1 to 8 carbon atoms and n is a number of zero, 1 or 2. The silane compounds are readily obtained by the dehydrochlorination reaction between a corresponding hydrogen-containing chlorosilane compound and an .alpha., .beta.-unsaturated aldehyde compound or a ketone compound in the presence of an acid acceptor. The compounds are useful as a modifying agent in the silicone technology and also serve as a curing agent.

摘要翻译： 本发明提供了一类新的有机硅化合物，它们是由通式“IMAGE”表示的氢链烷氧基硅烷，其中R 1是具有1至8个碳原子的一价烃基，R 2，R 3和R 4各自为氢原子或一价烃 具有1至8个碳原子的基团，n是0,1或2的数。硅烷化合物通过相应的含氢氯硅烷化合物和α，β-不饱和醛化合物或酮之间的脱氯化氢反应容易地获得 化合物在酸受体的存在下。 该化合物可用作硅氧烷技术中的改性剂，并且还用作固化剂。