公开(公告)号：US20070244003A1

公开(公告)日：2007-10-18

申请号：US11628874

申请日：2005-05-20

申请人： Masatoshi Majima ,  Kohei Shimoda ,  Kouji Yamaguchi

发明人： Masatoshi Majima ,  Kohei Shimoda ,  Kouji Yamaguchi

IPC分类号： B01J23/00

CPC分类号： H01M4/90 ,  B01J23/42 ,  B01J35/0013 ,  B01J35/006 ,  B01J37/16 ,  H01M4/9083 ,  H01M4/92 ,  H01M4/926

摘要： The present invention relates to a metal catalyst containing fine metal particles, characterized in that the fine metal particles have a particle diameter of 3 nm or less and also have a proportion of metallic bond state of 40% or more, which is ascribed by subjecting to waveform separation of a binding energy peak peculiar to the metal as measured by using an X-ray photoelectron spectrometer. The fine metal particles are preferably fine platinum particles. The fine metal particles are preferably supported on the surface of carrier particles by reducing ions of metal to be deposited through the action of a reducing agent in a reaction system of a liquid phase containing the carrier particles dispersed therein, thereby to deposit the metal on the surface of carrier particles in the form of fine particles. The proportion of metallic bond state of the fine metal particles is adjusted within the above range by reducing after deposition thereby to decrease the oxidation state.

摘要翻译： 本发明涉及含有金属微粒的金属催化剂，其特征在于，金属微粒的粒径为3nm以下，金属结合状态的比例为40％以上，这是通过使 通过使用X射线光电子能谱仪测量的金属特有的结合能峰的波形分离。 细金属颗粒优选为铂颗粒。 金属颗粒优选通过在含有分散在其中的载体颗粒的液相的反应体系中通过还原剂的作用还原待沉积的金属离子而负载在载体颗粒的表面上，从而将金属沉积在 载体颗粒表面呈细颗粒状。 通过在沉积后减少，将金属微粒的金属结合状态的比例调节在上述范围内，从而降低氧化态。

公开(公告)号：US20070074598A1

公开(公告)日：2007-04-05

申请号：US10575898

申请日：2004-06-24

申请人： Kohei Shimoda ,  Issei Okada ,  Masatoshi Majima

发明人： Kohei Shimoda ,  Issei Okada ,  Masatoshi Majima

IPC分类号： C22C1/05

CPC分类号： H01B1/22 ,  B01J13/0043 ,  B22F1/0096 ,  B22F2999/00 ,  B22F1/0018

摘要： When fine metal particles of a nano meter size are handled in a state of colloidal particles, it is difficult to handle them and the range of the selection of the solvent to be used is limited. The invention offers a granular metal powder that is produced by the steps of (a) preparing a suspension liquid comprising (a1) water, an organic solvent, or a mixture thereof, (a2) metal particles having an average particle diameter of at least 1 nm and at most 100 nm, and (a3) an organic compound capable of being adsorbed on the surface of the metal particles and (b) removing the water, organic solvent, or mixture thereof by drying the suspension liquid and that has an apparent density of at least 1.0 g/ml and at most 5.0 g/ml. The granular metal powder can be handled as a dry metal powder and is readily redispersed in a solvent.

摘要翻译： 当以胶体颗粒的状态处理纳米尺寸的细金属颗粒时，难以处理它们，并且所使用的溶剂的选择范围受到限制。 本发明提供一种颗粒状金属粉末，其通过以下步骤制备：（a）制备悬浮液体，所述悬浮液体包含（a1）水，有机溶剂或其混合物，（a2）平均粒径至少为1的金属颗粒 nm和至多100nm，和（a3）能够吸附在金属颗粒表面上的有机化合物和（b）通过干燥悬浮液除去水，有机溶剂或其混合物，并且具有表观密度 至少1.0μg/ ml至多5.0μg/ ml。 粒状金属粉末可以作为干金属粉末处理，并且容易地再分散在溶剂中。

公开(公告)号：US09325024B2

公开(公告)日：2016-04-26

申请号：US13990184

申请日：2011-11-29

申请人： Chihiro Hiraiwa ,  Masatoshi Majima ,  Tetsuya Kuwabara ,  Tomoyuki Awazu ,  Naho Mizuhara ,  Toshio Ueda ,  Hideyuki Doi ,  Toshiyuki Kuramoto

发明人： Chihiro Hiraiwa ,  Masatoshi Majima ,  Tetsuya Kuwabara ,  Tomoyuki Awazu ,  Naho Mizuhara ,  Toshio Ueda ,  Hideyuki Doi ,  Toshiyuki Kuramoto

IPC分类号： H01M8/10 ,  B01D53/32 ,  H01M8/00 ,  H01M8/06 ,  H01M8/22 ,  H01M4/88 ,  H01M8/02 ,  H01M8/08 ,  H01M8/12 ,  H01M8/14

CPC分类号： H01M8/1007 ,  B01D53/32 ,  B01D2257/406 ,  B01D2258/0216 ,  H01M4/8885 ,  H01M8/004 ,  H01M8/0232 ,  H01M8/0245 ,  H01M8/0247 ,  H01M8/0637 ,  H01M8/086 ,  H01M8/1006 ,  H01M8/124 ,  H01M8/222 ,  H01M2008/1095 ,  H01M2008/1293 ,  H01M2008/147 ,  Y02E60/521 ,  Y02E60/525 ,  Y02E60/526 ,  Y02E60/566 ,  Y02P70/56

摘要： Provided are a gas decomposition component, a method for producing a gas decomposition component, and a power generation apparatus. A gas decomposition component 10 includes a cylindrical-body MEA 7 including a first electrode 2 disposed on an inner-surface side, a second electrode 5 disposed on an outer-surface side, and a solid electrolyte 1 sandwiched between the first electrode and the second electrode; and a porous metal body 11s inserted on the inner-surface side of the cylindrical-body MEA and electrically connected to the first electrode, wherein the gas decomposition component further includes a porous conductive-paste-coated layer 11g formed on an inner circumferential surface of the first electrode, and a metal mesh sheet 11a disposed on an inner circumferential side of the conductive-paste-coated layer, and an electrical connection between the first electrode and the porous metal body is established through the conductive-paste-coated layer and the metal mesh sheet.

摘要翻译： 提供气体分解成分，气体分解成分的制造方法以及发电装置。 气体分解成分10包括：圆筒体MEA7，其包括设置在内表面侧的第一电极2，设置在外表面侧的第二电极5和夹在第一电极和第二电极之间的固体电解质1 电极; 以及插入在圆筒体MEA的内表面侧并与第一电极电连接的多孔金属体11s，其中气体分解成分还包括形成在第一电极的内周面上的多孔导电浆糊涂层11g 第一电极和设置在导电糊涂层的内周侧上的金属网片11a，并且通过导电糊涂层和第一电极建立第一电极和多孔金属体之间的电连接 金属网片。

公开(公告)号：US07803734B2

公开(公告)日：2010-09-28

申请号：US11628874

申请日：2005-05-20

申请人： Masatoshi Majima ,  Kohei Shimoda ,  Kouji Yamaguchi

发明人： Masatoshi Majima ,  Kohei Shimoda ,  Kouji Yamaguchi

IPC分类号： B01J23/00 ,  B01J23/40 ,  B01J21/00 ,  B01J20/00 ,  B01J29/00 ,  B01J37/00

CPC分类号： H01M4/90 ,  B01J23/42 ,  B01J35/0013 ,  B01J35/006 ,  B01J37/16 ,  H01M4/9083 ,  H01M4/92 ,  H01M4/926

摘要： The present invention relates to a metal catalyst containing fine metal particles, characterized in that the fine metal particles have a particle diameter of 3 nm or less and also have a proportion of metallic bond state of 40% or more, which is ascribed by subjecting to waveform separation of a binding energy peak peculiar to the metal as measured by using an X-ray photoelectron spectrometer. The fine metal particles are preferably fine platinum particles. The fine metal particles are preferably supported on the surface of carrier particles by reducing ions of metal to be deposited through the action of a reducing agent in a reaction system of a liquid phase containing the carrier particles dispersed therein, thereby to deposit the metal on the surface of carrier particles in the form of fine particles. The proportion of metallic bond state of the fine metal particles is adjusted within the above range by reducing after deposition thereby to decrease the oxidation state.

摘要翻译： 本发明涉及含有金属微粒的金属催化剂，其特征在于，金属微粒的粒径为3nm以下，金属结合状态的比例为40％以上，这是通过使 通过使用X射线光电子能谱仪测量的金属特有的结合能峰的波形分离。 细金属颗粒优选为铂颗粒。 金属颗粒优选通过在含有分散在其中的载体颗粒的液相的反应体系中通过还原剂的作用还原待沉积的金属离子而负载在载体颗粒的表面上，从而将金属沉积在 载体颗粒表面呈细颗粒状。 通过在沉积后减少，将金属微粒的金属结合状态的比例调节在上述范围内，从而降低氧化态。

公开(公告)号：US08865367B2

公开(公告)日：2014-10-21

申请号：US13702246

申请日：2011-06-06

申请人： Chihiro Hiraiwa ,  Masatoshi Majima ,  Tetsuya Kuwabara ,  Tomoyuki Awazu ,  Toshio Ueda ,  Toshiyuki Kuramoto

发明人： Chihiro Hiraiwa ,  Masatoshi Majima ,  Tetsuya Kuwabara ,  Tomoyuki Awazu ,  Toshio Ueda ,  Toshiyuki Kuramoto

IPC分类号： H01M8/12 ,  H01M8/02 ,  C25B9/00 ,  B01D53/32 ,  C25B1/00

CPC分类号： H01M8/122 ,  B01D53/326 ,  B01D2255/104 ,  B01D2255/20707 ,  B01D2255/20738 ,  B01D2255/20753 ,  B01D2257/404 ,  B01D2257/406 ,  B01D2257/708 ,  B01D2258/0216 ,  C25B1/00 ,  C25B9/00 ,  H01M8/0258 ,  H01M8/0267 ,  H01M8/1213 ,  H01M8/1231 ,  H01M8/241 ,  Y02E60/521 ,  Y02E60/525

摘要： Provided is a gas decomposition component that employs an electrochemical reaction and can have high treatment performance, in particular, an ammonia decomposition component. The gas decomposition component includes a MEA 7 including a solid electrolyte 1 and an anode 2 and a cathode 5 that are disposed so as to sandwich the solid electrolyte; Celmets 11s electrically connected to the anode 2; a heater 41 that heats the MEA; and an inlet 17 through which a gaseous fluid containing a gas is introduced into the MEA, an outlet 19 through which the gaseous fluid having passed through the MEA is discharged, and a passage P extending between the inlet and the outlet, wherein the Celmets 11s are discontinuously disposed along the passage P and, with respect to a middle position 15 of the passage, the length of the Celmets disposed is larger on the side of the outlet than on the side of the inlet.

摘要翻译： 提供了采用电化学反应并且可以具有高处理性能的气体分解成分，特别是氨分解成分。 气体分解成分包括MEA7，MEA7包括固体电解质1和阳极2和阴极5，其被设置为夹着固体电解质; 电连接到阳极2的硅片11; 加热MEA的加热器41; 以及入口17，含有气体的气态流体通过该入口被引入到MEA中，通过MEA流出的气态流体排出出口19以及在入口和出口之间延伸的通道P，其中Celmets 11s 沿着通道P不连续地设置，并且相对于通道的中间位置15，所设置的塞子的长度在出口侧比在入口侧更大。

公开(公告)号：US20130084514A1

公开(公告)日：2013-04-04

申请号：US13702221

申请日：2011-06-06

申请人： Chihiro Hiraiwa ,  Masatoshi Majima ,  Tetsuya Kuwabara ,  Tomoyuki Awazu ,  Toshio Ueda ,  Toshiyuki Kuramoto

发明人： Chihiro Hiraiwa ,  Masatoshi Majima ,  Tetsuya Kuwabara ,  Tomoyuki Awazu ,  Toshio Ueda ,  Toshiyuki Kuramoto

IPC分类号： H01M8/12 ,  C25B9/00 ,  C25B13/02 ,  C25B1/00 ,  C25B11/02

CPC分类号： H01M8/122 ,  B01D53/326 ,  B01D2255/104 ,  B01D2255/20707 ,  B01D2255/20738 ,  B01D2255/20753 ,  B01D2257/404 ,  B01D2257/406 ,  B01D2257/708 ,  B01D2258/0216 ,  C25B1/00 ,  C25B9/00 ,  C25B9/10 ,  C25B11/02 ,  C25B13/02 ,  H01M8/0252 ,  H01M8/1213 ,  H01M8/124 ,  Y02E60/521 ,  Y02E60/525 ,  Y02P70/56 ,  Y10T29/49108

摘要： Provided are a gas decomposition component in which an electrochemical reaction is used to reduce the running cost and high treatment performance can be achieved; and a method for producing the gas decomposition component. The gas decomposition component includes a cylindrical MEA 7 including an anode 2 on an inner-surface side, a cathode 5 on an outer-surface side, and a solid electrolyte 1 sandwiched between the anode and the cathode; a porous metal body 11s that is inserted on the inner-surface side of the cylindrical MEA and is in contact with the first electrode; and a central conductive rod 11k inserted so as to serve as an electrically conductive shaft of the porous metal body 11s.

摘要翻译： 提供使用电化学反应来降低运行成本并且可以实现高处理性能的气体分解成分; 以及气体分解成分的制造方法。 气体分解成分包括在内表面侧具有阳极2，外表面侧的阴极5和夹在阳极和阴极之间的固体电解质1的圆筒状MEA7。 多孔金属体11s，其插入在圆筒状MEA的内表面侧并与第一电极接触; 以及插入以用作多孔金属体11s的导电轴的中心导电杆11k。

公开(公告)号：US08377567B2

公开(公告)日：2013-02-19

申请号：US13111488

申请日：2011-05-19

申请人： Kazuki Okuno ,  Masahiro Kato ,  Tomoyuki Awazu ,  Masatoshi Majima ,  Hidetoshi Saito ,  Keiji Shiraishi ,  Hitoshi Tsuchida ,  Junichi Nishimura

发明人： Kazuki Okuno ,  Masahiro Kato ,  Tomoyuki Awazu ,  Masatoshi Majima ,  Hidetoshi Saito ,  Keiji Shiraishi ,  Hitoshi Tsuchida ,  Junichi Nishimura

IPC分类号： B32B5/18 ,  B32B15/04

CPC分类号： H01M4/661 ,  H01G9/008 ,  H01M4/808 ,  H01M10/052 ,  Y10T428/12479 ,  Y10T428/12944

摘要： A porous metal member composed of an alloy at least containing nickel and tungsten is provided. The alloy may contain 50 to 80 wt % of nickel and 20 to 50 wt % of tungsten and may further contain 10 wt % or less of phosphorus and/or 10 wt % or less of boron. Such a porous metal member can be produced by, for example, making a porous base such as a urethane foam be electrically conductive, forming an alloy film containing nickel and tungsten, then removing the porous base from the alloy film, and subsequently reducing the alloy.

摘要翻译： 提供由至少包含镍和钨的合金构成的多孔金属构件。 该合金可以含有50〜80重量％的镍和20〜50重量％的钨，还可以含有10重量％以下的磷和/或10重量％以下的硼。 这样的多孔金属构件可以通过例如使聚氨酯泡沫等多孔质基体导电，形成含有镍和钨的合金膜，然后从合金膜除去多孔质基底，然后还原合金 。