公开(公告)号：US20080107581A1

公开(公告)日：2008-05-08

申请号：US11628826

申请日：2005-06-20

申请人： Christopher W. Sparling ,  P. Scott Northrop ,  Johnny E. Johnson ,  Jagannathan N. Iyengar ,  Barry M. Friedman

发明人： Christopher W. Sparling ,  P. Scott Northrop ,  Johnny E. Johnson ,  Jagannathan N. Iyengar ,  Barry M. Friedman

IPC分类号： B01D53/48 ,  B01D53/14

CPC分类号： B01D53/1462 ,  B01D53/501 ,  B01D53/75 ,  C01B17/0404 ,  C01B17/0408 ,  C01B17/167 ,  C10L3/10 ,  C10L3/102 ,  Y02C10/06 ,  Y02P20/152

摘要： A method for removing sulfur-containing compounds is provided. In one embodiment, the method includes selectively separating a feed stream (118) comprising carbon dioxide and one or more sulfur-containing compounds, including hydrogen sulfide, at conditions sufficient to produce a first stream (122) comprising carbon dioxide and hydrogen sulfide and a second stream (124) comprising carbon dioxide and hydrogen sulfide. A molar ratio of carbon dioxide to hydrogen sulfide in the first stream is greater than a molar ratio of carbon dioxide to hydrogen sulfide in the second stream, and a molar ratio of hydrogen sulfide in the first stream to hydrogen sulfide in the second stream is about 0.005 or more.

摘要翻译： 提供了一种去除含硫化合物的方法。 在一个实施方案中，该方法包括在足以产生包含二氧化碳和硫化氢的第一物流（122）的条件下选择性地分离包含二氧化碳和一种或多种含硫化合物（包括硫化氢）的进料流（118） 包含二氧化碳和硫化氢的第二物流（124）。 第一流中二氧化碳与硫化氢的摩尔比大于第二流中二氧化碳与硫化氢的摩尔比，第二流中第一流中的硫化氢与硫化氢的摩尔比约为 0.005以上。

公开(公告)号：US20070180802A1

公开(公告)日：2007-08-09

申请号：US11350358

申请日：2006-02-08

申请人： Richard Parker ,  Eric Davis ,  Roop Jain

发明人： Richard Parker ,  Eric Davis ,  Roop Jain

IPC分类号： B01D50/00 ,  B01D53/48 ,  B01D59/50

CPC分类号： B01D53/84 ,  B01D2257/30 ,  B01D2257/304 ,  B01D2257/40 ,  B01D2257/406 ,  Y02A50/2358 ,  Y10S423/05 ,  Y10S423/17

摘要： A system and method for the purification and biodeodorizing of a gas are disclosed. The system is highly adaptable and capable of operating in a variety of modes to tailor performance of the system to specific odor control applications. The scrubber stages of the system may each be maintained at different conditions to selectively promote bacterial activity that targets a variety of odorous constituents. The pH level of the irrigation fluid provided to each scrubber stage may be controlled.

摘要翻译： 公开了一种用于气体净化和生物除臭的系统和方法。 该系统具有高度适应性，能够以各种模式操作，以将系统的性能定制到特定的气味控制应用。 系统的洗涤器阶段可以各自保持在不同的条件下，以选择性地促进针对各种恶臭成分的细菌活性。 可以控制提供给每个洗涤器阶段的冲洗流体的pH值。

公开(公告)号：US07241430B2

公开(公告)日：2007-07-10

申请号：US11392169

申请日：2006-03-29

申请人： James Richard Graham ,  Jianyuan Cheng

发明人： James Richard Graham ,  Jianyuan Cheng

IPC分类号： B01D53/48 ,  B01D53/52 ,  B01J21/10 ,  B01J21/18 ,  B01J23/02 ,  C01B31/08 ,  C01B31/10

CPC分类号： B01J20/3042 ,  A61L9/014 ,  B01D53/02 ,  B01D53/8668 ,  B01D2251/40 ,  B01D2253/10 ,  B01D2253/102 ,  B01D2253/112 ,  B01D2257/304 ,  B01D2257/708 ,  B01D2257/90 ,  B01D2258/00 ,  B01J20/041 ,  B01J20/20 ,  B01J20/28026 ,  B01J20/2803 ,  B01J20/3007 ,  B01J20/3021 ,  B01J20/3078 ,  B01J21/18 ,  B01J23/02 ,  B01J37/0201 ,  B01J37/04 ,  B01J37/14 ,  B01J2220/42 ,  C01B32/30 ,  C01B32/336 ,  Y10T428/30

摘要： An activated carbon-metal oxide matrix is disclosed. The activated carbon-metal oxide matrix may be obtained by a method including the steps of: preoxidizing a carbon material, grinding the preoxidized carbon material; mixing the ground preoxidized material with a metal oxide to form a carbon mixture; extruding the carbon mixture; carbonizing and activating the extrudate. The activated carbon-metal oxide matrix may be used to remove odorous compounds, acidic gases, and volatile organic compounds from a gas.

摘要翻译： 公开了一种活性炭 - 金属氧化物基质。 活性炭 - 金属氧化物基质可以通过包括以下步骤的方法获得：将碳材料预氧化，研磨预氧化碳材料; 将地面预氧化材料与金属氧化物混合以形成碳混合物; 挤出碳混合物; 碳化和活化挤出物。 活性炭 - 金属氧化物基质可用于从气体中除去有气味的化合物，酸性气体和挥发性有机化合物。

公开(公告)号：US20050191237A1

公开(公告)日：2005-09-01

申请号：US10790530

申请日：2004-03-01

申请人： Richard Selinger ,  Brian Thicke

发明人： Richard Selinger ,  Brian Thicke

IPC分类号： B01D53/18 ,  B01D53/22 ,  B01D53/48 ,  C01B3/02 ,  C01B3/04 ,  C01B3/50 ,  C01B17/04

CPC分类号： C01B3/04 ,  C01B17/0495 ,  Y02E60/364 ,  Y10S423/10

摘要： A process and an apparatus for obtaining a hydrogen product and a sulfur product from a feed gas. The feed gas is comprised of hydrogen sulfide, the hydrogen product is comprised of elemental hydrogen and the sulfur product is comprised of elemental sulfur. In the process, a first separating step separates the feed gas to obtain a first purified hydrogen sulfide fraction comprised of at least about 90 percent hydrogen sulfide by volume. A dissociating step dissociates hydrogen sulfide present in the first purified hydrogen sulfide fraction to convert it into a dissociated first purified hydrogen sulfide fraction comprised of elemental hydrogen and sulfur. A second separating step separates the dissociated first purified hydrogen sulfide fraction to obtain a hydrogen rich fraction comprised of elemental hydrogen. The sulfur product may also be obtained from the dissociated first purified hydrogen sulfide fraction. Finally, the hydrogen product is obtained from the hydrogen rich fraction. The apparatus is provided for performing the process.

摘要翻译： 从进料气体获得氢产物和硫产物的方法和装置。 进料气体由硫化氢组成，氢气产物由元素氢组成，硫产物由元素硫组成。 在该过程中，第一分离步骤分离进料气体以获得由体积含有至少约90％硫化氢的第一纯化硫化氢级分。 解离步骤解离存在于第一纯化硫化氢级分中的硫化氢以将其转化成由元素氢和硫组成的解离的第一纯化硫化氢级分。 第二分离步骤分离解离的第一纯化硫化氢级分以获得由元素氢组成的富氢馏分。 硫产物也可以从解离的第一纯化硫化氢级分获得。 最后，从富氢馏分获得氢产物。 该装置用于执行该过程。

公开(公告)号：US06855305B2

公开(公告)日：2005-02-15

申请号：US10677961

申请日：2003-10-03

申请人： Shuichi Kanno ,  Toshiaki Arato ,  Shinzo Ikeda ,  Ken Yasuda ,  Hisao Yamashita ,  Shigeru Azuhata ,  Shin Tamata ,  Kazuyoshi Irie

发明人： Shuichi Kanno ,  Toshiaki Arato ,  Shinzo Ikeda ,  Ken Yasuda ,  Hisao Yamashita ,  Shigeru Azuhata ,  Shin Tamata ,  Kazuyoshi Irie

IPC分类号： A62D3/00 ,  A62D3/20 ,  A62D101/22 ,  A62D101/49 ,  B01D53/86 ,  B01D53/48 ,  B01D53/68

CPC分类号： A62D3/20 ,  A62D2101/22 ,  A62D2101/49 ,  B01D53/8659 ,  B01D53/8662 ,  B01D53/8671 ,  B01D2255/2092 ,  B01D2257/204 ,  B01D2258/0216 ,  C01B7/191 ,  Y02C20/30

摘要： A gas stream containing at least one fluorine compound selected from the group consisting of compounds of carbon and fluorine, compounds of carbon, hydrogen and fluorine, compounds of sulfur and fluorine, compounds of nitrogen and fluorine and compounds of carbon, hydrogen, oxygen and fluorine is contacted with a catalyst comprising at least one of alumina, titania, zirconia and silica, preferably a catalyst comprising alumina and at least one of nickel oxide, zinc oxide and titania in the presence of steam, thereby hydrolyzing the fluorine compound at a relatively low temperature, e.g. 200°-800° C., to convert the fluorine of the fluorine compound to hydrogen fluoride.

公开(公告)号：US20050013757A1

公开(公告)日：2005-01-20

申请号：US10654654

申请日：2003-09-03

申请人： Franz Windschmitt ,  Gebhard Bandel

发明人： Franz Windschmitt ,  Gebhard Bandel

IPC分类号： B01D53/48 ,  B01D53/50 ,  F23J15/04

CPC分类号： F23J15/04 ,  B01D53/48 ,  B01D53/504 ,  F23J2215/20 ,  F23J2217/102

摘要： A method and system for removing sulfur and dust from waste gases, particularly refinery waste gases, wherein the waste gas to be cleaned is passed to a scrubbing tower above a scrubber sump and, in order to remove SO2 and acidic gases, scrubbed in a scrubbing zone of the scrubbing tower, in counter-current with a scrubbing fluid that is drawn from the scrubber sump and passed to spray nozzles at the upper end of the scrubbing zone. Sulfites contained in the scrubber sump are oxidized to form sulfates, by means of gasification with air in the scrubber sump or in an external device assigned to the scrubber sump. A suspension stream is drawn from the scrubber sump. The gas that leaves the scrubbing zone flows through a wet electrofilter arranged above the scrubbing zone in the scrubbing tower, whereby dust particles and aerosols and entrained droplets are collected on precipitation electrodes of the wet electrofilter. The precipitation electrodes are periodically flushed with a partial stream of the scrubbing fluid, which is taken from the scrubber sump, applied at the head of the wet electrofilter and then enters the scrubber sump.

摘要翻译： 一种用于从废气，特别是炼油废气中除去硫和灰尘的方法和系统，其中待清洁的废气被传送到洗涤池上方的洗涤塔，并且为了除去SO 2和酸性气体，在洗涤中洗涤 洗涤塔的区域与从洗涤池抽出的洗涤流体逆流并且在洗涤区的上端传递到喷嘴。 包含在洗涤池中的亚硫酸盐被氧化以形成硫酸盐，通过在洗涤池中的空气或分配给洗涤池的外部装置气化。 从洗涤池抽出悬浮液流。 离开洗涤区的气体流过布置在洗涤塔中的洗涤区上方的湿电滤器，由此灰尘颗粒和气溶胶以及夹带的液滴被收集在湿电滤器的沉淀电极上。 定时将沉淀电极用洗涤液池的部分流进行清洗，该清洗液是从洗涤器槽中取出的，施加在湿式电滤器的头部，然后进入洗涤池。

公开(公告)号：US6126911A

公开(公告)日：2000-10-03

申请号：US873315

申请日：1997-06-11

申请人： Delbert C. Scranton, Jr.

发明人： Delbert C. Scranton, Jr.

IPC分类号： B01J23/745 ,  B01J37/00 ,  B01J37/02 ,  C10L3/10 ,  B01D53/48 ,  B01D53/54

CPC分类号： C10L3/10 ,  B01J23/745 ,  B01J37/0072 ,  B01J37/0203 ,  B01D2257/30 ,  B01D2257/304

摘要： The present invention relates to the use of metal oxide particles held on carrier particles and moistened with a hygroscopic moistening agent, preferably glycol, with the moistened metal oxide particles used in a system designed to remove sulfur from dehydrated and water under-saturated gas compounds.

摘要翻译： 本发明涉及保护在载体颗粒上并用吸湿润湿剂（优选二醇）润湿的金属氧化物颗粒在湿脱金属氧化物颗粒中的用途，该系统设计用于从脱水和水不足饱和气体化合物中除去硫。

公开(公告)号：US06068822A

公开(公告)日：2000-05-30

申请号：US934211

申请日：1997-09-19

申请人： Shinichiro Kotake ,  Atsushi Tatani

发明人： Shinichiro Kotake ,  Atsushi Tatani

IPC分类号： B01D53/50 ,  B01D53/52 ,  C01D5/00 ,  F03G7/04 ,  B01D53/48

CPC分类号： C01D5/00 ,  B01D53/504 ,  B01D53/52 ,  F03G7/04 ,  Y02E10/10 ,  Y10S423/19

摘要： An uncondensed gas in steam discharged from a turbine in a geothermal power plant and separated from water with a condenser is treated by a desulfurization method comprising the combustion step of combusting the uncondensed gas in the steam to convert hydrogen sulfide in the uncondensed gas to a sulfurous acid gas and the absorption reaction step of bringing a combustion gas coming from the combustion step into gas-liquid contact with an absorbent slurry and further bringing air into air-liquid contact with the absorbent slurry to allow the absorbent slurry to absorb the sulfurous acid gas and undergo oxidation and neutralization to exhaust desulfurized gas and to convert the absorbent slurry to a sulfate slurry, whereby detrimental hydrogen sulfide is removed from the steam exhausted after the use of the steam for power generation in the geothermal power plant.

摘要翻译： 在来自地热发电厂的涡轮机中并且与冷凝器分离的蒸汽中的未蒸发气体通过脱硫方法处理，所述脱硫方法包括燃烧步骤，在蒸汽中燃烧未冷凝的气体，将未冷凝气体中的硫化氢转化为亚硫酸盐 使来自燃烧步骤的燃烧气体与吸收剂浆料气液接触的吸收反应步骤，并且进一步使空气与吸收剂浆料气液接触，以使吸收剂浆料吸收亚硫酸气体 并进行氧化和中和以排出脱硫气体，并将吸收剂浆料转化为硫酸盐浆料，由此在使用用于在地热发电厂中发电的蒸汽之后排出的蒸汽中除去有害的硫化氢。

公开(公告)号：US6019953A

公开(公告)日：2000-02-01

申请号：US899368

申请日：1997-07-23

申请人： Peter John Van Den Brink ,  Hans Michiel Huisman ,  Inge Roos ,  Thoms Stanley Vermeulen

发明人： Peter John Van Den Brink ,  Hans Michiel Huisman ,  Inge Roos ,  Thoms Stanley Vermeulen

IPC分类号： B01J27/19 ,  B01D53/52 ,  B01D53/86 ,  B01J23/18 ,  B01J23/24 ,  B01J23/843 ,  B01D53/48

CPC分类号： B01D53/8612 ,  B01J23/18 ,  B01J23/24

摘要： There is provided a process for the incineration of gases containing sulphur compounds by contacting these gases with an oxygen-containing gas in the presence of a catalyst composition comprising (i) a metal selected from bismuth, molybdenum and chromium as a first metal component and (ii) at least one Group IIA metal as a second metal component, supported on a refractory oxide carrier not being a carrier comprising both aluminum and phosphorus.

摘要翻译： 提供了一种通过在含有（i）选自铋，钼和铬的金属作为第一金属组分的催化剂组合物存在下使这些气体与含氧气体接触来焚烧含硫化合物的方法， ii）至少一种IIA族金属作为第二金属组分，负载在不是包含铝和磷的载体的难熔氧化物载体上。

公开(公告)号：US5980846A

公开(公告)日：1999-11-09

申请号：US74033

申请日：1998-05-06

申请人： Atsushi Tatani ,  Kazuaki Kimura ,  Makoto Susaki ,  Toshikuni Sera ,  Kenji Inoue

发明人： Atsushi Tatani ,  Kazuaki Kimura ,  Makoto Susaki ,  Toshikuni Sera ,  Kenji Inoue

IPC分类号： B01D53/52 ,  B01D53/04 ,  C10J3/46 ,  C10K1/26 ,  C10L3/10 ,  B01D53/48 ,  B01D53/34

CPC分类号： C10K1/26

摘要： This invention relates to a gas refining system wherein a high-temperature and high-pressure reducing gas is introduced into a fixed-bed desulfurizer packed with an adsorbent by which sulfur compounds contained in the high-temperature and high-pressure reducing gas are adsorbed and removed in the form of a sulfide, and the adsorbent having the sulfide adsorbed thereon is regenerated by roasting it with a regenerating gas containing oxygen, characterized in that the gas refining system is equipped with oxygen concentration control means for controlling the oxygen concentration in the regenerating gas introduced into the desulfurizer so as to keep the internal temperature of the desulfurizer during the regeneration reaction within the allowable temperature range of the adsorbent. This invention includes an embodiment in which the exhaust gas obtained after the regeneration reaction gas is brought into contact with a calcium compound-containing slurry to recover gypsum is recycled to the desulfurizer for use as the regenerating gas for the adsorbent. Thus, the adverse effect of the heat of regeneration reaction on the adsorbent used in the fixed-bed desulfurizer can be avoided positively and easily.

摘要翻译： 本发明涉及一种气体精炼系统，其中将高温高压还原气体引入填充有吸附剂的固定床脱硫器中，通过该吸附剂吸附高温高压还原气体中所含的硫化合物， 以硫化物的形式除去，吸附有硫化物的吸附剂通过用含氧的再生气体焙烧而再生，其特征在于，气体精炼系统配备有氧浓度控制装置，用于控制再生中的氧浓度 将气体引入脱硫器中，以便在再生反应期间将脱硫剂的内部温度保持在吸附剂的允许温度范围内。 本发明包括将再生反应气体与含钙化合物的浆料接触以回收石膏后获得的废气再循环至脱硫器，用作吸附剂的再生气体。 因此，可以积极且容易地避免再生反应的热量对固定床脱硫剂中使用的吸附剂的不良影响。