公开(公告)号：US07294315B1

公开(公告)日：2007-11-13

申请号：US09936426

申请日：1999-06-09

申请人： Shuichi Kanno ,  Akio Honji ,  Hisao Yamashita ,  Shigeru Azuhata ,  Shin Tamata ,  Kazuyoshi Irie

发明人： Shuichi Kanno ,  Akio Honji ,  Hisao Yamashita ,  Shigeru Azuhata ,  Shin Tamata ,  Kazuyoshi Irie

IPC分类号： B01D53/34

CPC分类号： B01J23/34 ,  B01D53/8659 ,  B01J23/38 ,  B01J23/63 ,  B01J23/70 ,  Y02C20/10 ,  Y02C20/30

摘要： Fluorine compounds such as C2F6, CF4, CHF3, SF6 and NF3, are made in contact with a fluorine compound decomposition catalyst and a catalyst the decomposition oft least one of CO, SO2F2 and N2O in the presence of water or in the presence of water and oxygen. The catalyst the decomposition oft least one of CO, SO2F2 and N2O preferably contains at least one selected from Pd, Pt, Cu, Mn, Fe, Co, Rh, Ir and Au in the form of a metal or an oxide. According to the invention, the fluorine compound can be converted to HF, which is liable to be absorbed by water or an alkaline aqueous solution, and a substance, such as CO, SO2F2 and N2O, formed by decomposition of the fluorine compound can also be decomposed.

摘要翻译： 氟化合物如C 2 F 6，CF 4，CH 3，SF 6， SUB＆gt;和NF 3 3与氟化合物分解催化剂和催化剂接触，分解为CO，SO 2/2 / 在水的存在下或在水和氧的存在下，将其与N 2 O 2 O反应。 CO，SO 2 H 2 N 2和N 2 O 2中的至少一种的分解催化剂优选含有选自Pd，Pt， Cu，Mn，Fe，Co，Rh，Ir和Au。 根据本发明，氟化合物可以转化成易于被水或碱性水溶液吸收的HF，以及CO，SO 2 F 2等物质 由氟化合物分解形成的N和N 2 O也可以分解。

公开(公告)号：US06942841B2

公开(公告)日：2005-09-13

申请号：US10215045

申请日：2002-08-09

申请人： Shuichi Kanno ,  Toshiaki Arato ,  Shinzo Ikeda ,  Ken Yasuda ,  Hisao Yamashita ,  Shigeru Azuhata ,  Shin Tamata ,  Kazuyoshi Irie

发明人： Shuichi Kanno ,  Toshiaki Arato ,  Shinzo Ikeda ,  Ken Yasuda ,  Hisao Yamashita ,  Shigeru Azuhata ,  Shin Tamata ,  Kazuyoshi Irie

IPC分类号： A62D3/00 ,  A62D3/20 ,  A62D101/22 ,  A62D101/49 ,  B01D53/86 ,  B01D53/48 ,  B01D53/68

CPC分类号： A62D3/20 ,  A62D2101/22 ,  A62D2101/49 ,  B01D53/8659 ,  B01D53/8662 ,  B01D53/8671 ,  B01D2255/2092 ,  B01D2257/204 ,  B01D2258/0216 ,  C01B7/191 ,  Y02C20/30

摘要： A gas stream containing at least one fluorine compound selected from the group consisting of compounds of carbon and fluorine, compounds of carbon, hydrogen and fluorine, compounds of sulfur and fluorine, compounds of nitrogen and fluorine and compounds of carbon, hydrogen, oxygen and fluorine is contacted with a catalyst comprising at least one of alumina, titania, zirconia and silica, preferably a catalyst comprising alumina and at least one of nickel oxide, zinc oxide and titania in the presence of steam, thereby hydrolyzing the fluorine compound at a relatively low temperature, e.g. 200°-800° C., to convert the fluorine of the fluorine compound to hydrogen fluoride.

摘要翻译： 含有选自碳和氟的化合物，碳，氢和氟的化合物，硫和氟的化合物，氮和氟的化合物，碳，氢，氧和氟的化合物的至少一种氟化合物的气流 与包含氧化铝，二氧化钛，氧化锆和二氧化硅中的至少一种的催化剂接触，优选在蒸汽存在下包含氧化铝和氧化镍，氧化锌和二氧化钛中的至少一种的催化剂，从而以相对低的水解水解氟化合物 温度，例如 200°-800℃，将氟化合物的氟转化成氟化氢。

公开(公告)号：US20050089461A1

公开(公告)日：2005-04-28

申请号：US10987156

申请日：2004-11-15

申请人： Shuichi Kanno ,  Akio Honji ,  Hisao Yamashita ,  Shigeru Azuhata ,  Shin Tamata ,  Kazuyoshi Irie

发明人： Shuichi Kanno ,  Akio Honji ,  Hisao Yamashita ,  Shigeru Azuhata ,  Shin Tamata ,  Kazuyoshi Irie

IPC分类号： B01J23/40 ,  B01J23/63 ,  B01J23/652 ,  B01J23/66 ,  B01J23/70 ,  C01B7/19 ,  C07C17/38 ,  C01B7/00

CPC分类号： B01J23/63 ,  B01J23/40 ,  B01J23/6527 ,  B01J23/66 ,  B01J23/70 ,  C01B7/191

摘要： Fluorine compounds such as C2F6, CF4, CHF3, SF6 and NF3, are made in contact with a fluorine compound decomposition catalyst and a catalyst the decomposition oft least one of CO, SO2F2 and N2O in the presence of water or in the presence of water and oxygen. The catalyst the decomposition oft least one of CO, SO2F2 and N2O preferably contains at least one selected from Pd, Pt, Cu, Mn, Fe, Co, Rh, Ir and Au in the form of a metal or an oxide. According to the invention, the fluorine compound can be converted to HF, which is liable to be absorbed by water or an alkaline aqueous solution, and a substance, such as CO, SO2F2 and N2O, formed by decomposition of the fluorine compound can also be decomposed.

摘要翻译： 氟化合物如C 2 F 6，CF 4，CH 3，SF 6， SUB＆gt;和NF 3 3与氟化合物分解催化剂和催化剂接触，分解为CO，SO 2/2 / 在水的存在下或在水和氧的存在下，将其与N 2 O 2 O反应。 CO，SO 2 H 2 N 2和N 2 O 2中的至少一种的分解催化剂优选含有选自Pd，Pt， Cu，Mn，Fe，Co，Rh，Ir和Au。 根据本发明，氟化合物可以转化成易于被水或碱性水溶液吸收的HF，以及CO，SO 2 F 2等物质 由氟化合物分解形成的N和N 2 O也可以分解。

公开(公告)号：US06596247B1

公开(公告)日：2003-07-22

申请号：US09348272

申请日：1999-07-07

申请人： Hidehiro Iizuka ,  Ryouta Doi ,  Hiroshi Hanaoka ,  Toshio Ogawa ,  Osamu Kuroda ,  Hisao Yamashita ,  Shigeru Azuhata ,  Yuichi Kitahara ,  Norihiro Shinotsuka

发明人： Hidehiro Iizuka ,  Ryouta Doi ,  Hiroshi Hanaoka ,  Toshio Ogawa ,  Osamu Kuroda ,  Hisao Yamashita ,  Shigeru Azuhata ,  Yuichi Kitahara ,  Norihiro Shinotsuka

IPC分类号： B01D5356

CPC分类号： B01D53/9422 ,  B01D2255/1021 ,  B01D2255/1023 ,  B01D2255/1025 ,  B01D2255/202 ,  B01D2255/2047 ,  B01D2255/2063 ,  B01D2255/2065 ,  B01D2255/20707 ,  B01J23/58 ,  B01J23/63

摘要： A catalyst being formed of a porous supporter supporting alkali metals, Ti and noble metal, or further supporting at least one of rare earth metal and magnesium, being disposed in a flow passage of the internal combustion engine, and being used to purify NOx contained in the exaust gas. The above catalyst has excellent NOx resistance not only to the exaust gas burnt with the stoichiometric air-to-fuel ratio or rich condition, but to the exhaust gas burnt with the lean condition, and furthermore has a high resistivity to poisoning of SOx slightly contained in the fuel.

摘要翻译： 催化剂由支撑碱金属，Ti和贵金属的多孔支撑体形成，或进一步支撑稀土金属和镁中的至少一种，设置在内燃机的流路中，用于净化含有 大气。 上述催化剂不仅具有优良的耐NOx燃烧性能，而且具有化学计量空燃比或浓度较高的燃烧气体，而且对贫燃料燃烧的废气具有优异的耐NOx性，而且还具有高电阻率， 在燃料中。

公开(公告)号：US06397582B1

公开(公告)日：2002-06-04

申请号：US09620650

申请日：2000-07-20

申请人： Hiroshi Hanaoka ,  Osamu Kuroda ,  Ryouta Doi ,  Hidehiro Iizuka ,  Toshio Ogawa ,  Hisao Yamashita ,  Shigeru Azuhata ,  Yuichi Kitahara ,  Toshifumi Hiratsuka ,  Kojiro Okude ,  Norihiro Shinotsuka ,  Toshio Manaka

发明人： Hiroshi Hanaoka ,  Osamu Kuroda ,  Ryouta Doi ,  Hidehiro Iizuka ,  Toshio Ogawa ,  Hisao Yamashita ,  Shigeru Azuhata ,  Yuichi Kitahara ,  Toshifumi Hiratsuka ,  Kojiro Okude ,  Norihiro Shinotsuka ,  Toshio Manaka

IPC分类号： F01N300

CPC分类号： F01N11/002 ,  B01D53/9422 ,  B01D53/9495 ,  B01D2255/1021 ,  B01D2255/1023 ,  B01D2255/1025 ,  B01D2255/2022 ,  B01D2255/2027 ,  B01D2255/2047 ,  B01D2255/2061 ,  B01D2255/2063 ,  B01D2255/2065 ,  B01D2255/91 ,  F01N3/0814 ,  F01N3/0842 ,  F01N3/0871 ,  F01N3/0878 ,  F01N13/009 ,  F01N2250/12 ,  F01N2430/06 ,  F01N2510/06 ,  F01N2570/04 ,  F01N2610/03 ,  F02D41/027 ,  F02D41/0275 ,  F02D41/1455 ,  F02D41/146 ,  F02D41/1462 ,  F02D41/1463 ,  F02D41/1465 ,  F02D2200/0806 ,  F02D2200/0814 ,  Y02A50/2324 ,  Y02T10/22 ,  Y02T10/47

摘要： An exhaust gas purification apparatus for use in an internal combustion engine comprises an exhaust gas duct connected to the engine through which the exhaust gas containing NOx gas passes and a catalyst so disposed in the exhaust gas duct that it contacts with the exhaust gas. The catalyst chemically adsorbs NOx under the condition that a stoichiometric amount of a gaseous oxidizing agent present in the exhaust gas is larger than that of a gaseous reducing agent present in the exhaust gas for reducing NOx, while NOx being adsorbed is catalytically reduced in the presence of the reducing agent under the condition that the stoichiometric amount of the oxidizing agent is not larger that of the reducing agent. Thereby, NOx the lean burn exhaust gas in the engine can be effectively made harmlessly.

摘要翻译： 在内燃机中使用的废气净化装置具备：与发动机连接的排气管道，通过该排气气体使含有NOx的废气通过，排气管与排气相接触的催化剂。 催化剂在排气中存在的化学计量的气态氧化剂大于存在于用于还原NOx的排气中的气态还原剂的化学计量量的条件下化学吸附NOx，而在存在下催化还原NOx 的还原剂在氧化剂的化学计量不大于还原剂的化学计量量的条件下进行。 因此，能够有效地使发动机中的贫燃废气的NOx成为无害化。

公开(公告)号：US6077482A

公开(公告)日：2000-06-20

申请号：US4981

申请日：1998-01-09

申请人： Shuichi Kanno ,  Hiroshi Kawagoshi ,  Akira Kato ,  Toshiaki Arato ,  Hisao Yamashita ,  Shigeru Azuhata ,  Shin Tamata

发明人： Shuichi Kanno ,  Hiroshi Kawagoshi ,  Akira Kato ,  Toshiaki Arato ,  Hisao Yamashita ,  Shigeru Azuhata ,  Shin Tamata

IPC分类号： A62D3/20 ,  A62D101/22 ,  B01D53/86 ,  B01J21/06 ,  B01J23/30 ,  B01J37/02 ,  B01D53/70 ,  B01J23/64

CPC分类号： A62D3/20 ,  B01D53/8662 ,  B01J23/30 ,  A62D2101/22 ,  B01J21/063 ,  B01J37/0201

摘要： A treating apparatus for decomposing organohalogen compounds such as chlorofluorocarbons (CFC's), trichloroethylene, methylbromide, halon, and the like, effectively, with a high activity of catalyst, is provided. The apparatus includes a reactor in which organohalogen compounds are decomposed by contact at a temperature in a range of 200.degree..about.500.degree. C. with a catalyst which comprises titania and tungsten oxide by an atomic ratio of Ti and W in a range from 20 mol % to 95 mol % Ti and from 5 mol % to 80 mol % W, with at least the surface of the titania being covered with a porous layer of the tungsten oxide. In accordance with the present invention, organic compounds containing any of fluorine, chlorine and bromine will be decomposed with a high efficiency, and the activity of the catalyst can be maintained for a long time.

摘要翻译： 提供了一种用于有效地分解具有高活性催化剂的有机卤素化合物如氯氟烃（CFC），三氯乙烯，甲基溴，哈芬等的处理装置。 该装置包括反应器，其中有机卤素化合物在200℃〜500℃的温度范围内与包含二氧化钛和氧化钨的催化剂在Ti和W的原子比为20摩尔的范围内接触分解 ％至95mol％的Ti和5mol％至80mol％的W，至少二氧化钛的表面被氧化钨的多孔层覆盖。 根据本发明，含有氟，氯和溴中的任何一种的有机化合物将被高效率地分解，催化剂的活性可长时间保持。

公开(公告)号：US5759504A

公开(公告)日：1998-06-02

申请号：US572878

申请日：1995-12-18

申请人： Shuichi Kanno ,  Hiroshi Kawagoshi ,  Akira Kato ,  Toshiaki Arato ,  Hisao Yamashita ,  Shigeru Azuhata ,  Shin Tamata

发明人： Shuichi Kanno ,  Hiroshi Kawagoshi ,  Akira Kato ,  Toshiaki Arato ,  Hisao Yamashita ,  Shigeru Azuhata ,  Shin Tamata

IPC分类号： A62D3/20 ,  A62D101/22 ,  B01D53/86 ,  B01J21/06 ,  B01J23/30 ,  B01J37/02 ,  C01B7/00

CPC分类号： A62D3/20 ,  B01D53/8662 ,  B01J23/30 ,  A62D2101/22 ,  B01J21/063 ,  B01J37/0201

摘要： A treating method for decomposing organohalogen compounds such as chlorofluorocarbons (CFC), trichloroethylene, methyl bromide, halon, and the like, effectively, with a high activity of catalyst is provided. Organohalogen compounds are decomposed by contacting at a temperature in a range of 200.degree..about.500.degree. C. with catalyst which comprises titania and tungsten oxide by an atomic ratio of Ti and W in a range from 20 mol % to 95 mol % Ti and from 5 mol % to 80 mol % W, and at least surface of the titania is covered with porous layer of tungsten oxide. In accordance with the present invention, organic compounds containing any of fluorine, chlorine, and bromine can be decomposed with a high efficiency, and the activity of the catalyst can be maintained for a long time.

摘要翻译： 提供了一种以高活性催化剂有效分解有机卤素化合物如氯氟烃（CFC），三氯乙烯，甲基溴，哈芬等的处理方法。 有机卤素化合物通过在200℃〜500℃的温度范围内与Ti和W的原子比在20摩尔％〜95摩尔％Ti的范围内与包含二氧化钛和氧化钨的催化剂接触而分解， 5摩尔％至80摩尔％W，并且二氧化钛的至少表面被多孔层氧化钨覆盖。 根据本发明，可以高效率地分解含有氟，氯和溴中的任何一种的有机化合物，并且可以长时间保持催化剂的活性。

公开(公告)号：US4653998A

公开(公告)日：1987-03-31

申请号：US694744

申请日：1985-01-25

申请人： Ken-ichi Sohma ,  Norio Arashi ,  Shigeru Azuhata ,  Kiyoshi Narato ,  Tooru Inada ,  Hironobu Kobayashi ,  Keizou Ohtsuka ,  Yukio Hishinuma

发明人： Ken-ichi Sohma ,  Norio Arashi ,  Shigeru Azuhata ,  Kiyoshi Narato ,  Tooru Inada ,  Hironobu Kobayashi ,  Keizou Ohtsuka ,  Yukio Hishinuma

IPC分类号： F23N5/00 ,  F23N5/08 ,  G01J1/42

CPC分类号： F23N5/082 ,  F23N5/006 ,  F23N2039/02 ,  Y02T50/677

摘要： A furnace system connected to a burner including a furnace for burning a fuel and air ejected from the burner into the furnace to produce a flame therein, and a combustion condition determining device for determining the conditions of combustion of the fuel in a zone of the flame extending along different strata thereof by collecting light in the flame at one point in the flame by moving such point. Signals outputted by the combustion condition determining device are utilized for monitoring or controlling the flame and controlling exhaust emission control devices for controlling exhaust emissions produced by the combustion of the fuel. Control of the conditions of combustion of the flame can be effected quickly with a high degree of precision by monitoring the flame.

摘要翻译： 一种连接到燃烧器的炉系统，包括用于燃烧燃料的炉和从燃烧器喷射到炉中以在其中产生火焰的燃烧空气;以及燃烧条件确定装置，用于确定燃料在火焰区域中的燃烧条件 通过移动这些点，在火焰的一个点处在火焰中收集光，沿不同的层延伸。 由燃烧条件确定装置输出的信号用于监视或控制火焰和控制废气排放控制装置，以控制由燃料燃烧产生的废气排放。 通过监视火焰可以高精度地快速实现对火焰燃烧条件的控制。

公开(公告)号：US07347980B2

公开(公告)日：2008-03-25

申请号：US10679297

申请日：2003-10-07

申请人： Shuichi Kanno ,  Toshiaki Arato ,  Shinzo Ikeda ,  Ken Yasuda ,  Hisao Yamashita ,  Shigeru Azuhata ,  Shin Tamata ,  Kazuyoshi Irie

发明人： Shuichi Kanno ,  Toshiaki Arato ,  Shinzo Ikeda ,  Ken Yasuda ,  Hisao Yamashita ,  Shigeru Azuhata ,  Shin Tamata ,  Kazuyoshi Irie

IPC分类号： A62D3/00 ,  B01D53/86

CPC分类号： A62D3/20 ,  A62D2101/22 ,  A62D2101/49 ,  B01D53/8659 ,  B01D53/8662 ,  B01D53/8671 ,  B01D2255/2092 ,  B01D2257/204 ,  B01D2258/0216 ,  C01B7/191 ,  Y02C20/30

摘要： A gas stream containing at least one fluorine compound selected from the group consisting of compounds of carbon and fluorine, compounds of carbon, hydrogen and fluorine, compounds of sulfur and fluorine, compounds of nitrogen and fluorine and compounds of carbon, hydrogen, oxygen and fluorine is contacted with a catalyst comprising at least one of alumina, titania, zirconia and silica, preferably a catalyst comprising alumina and at least one of nickel oxide, zinc oxide and titania in the presence of steam, thereby hydrolyzing the fluorine compound at a relatively low temperature, e.g. 200°–800° C., to convert the fluorine of the fluorine compound to hydrogen fluoride.

摘要翻译： 含有选自碳和氟的化合物，碳，氢和氟的化合物，硫和氟的化合物，氮和氟的化合物，碳，氢，氧和氟的化合物的至少一种氟化合物的气流 与包含氧化铝，二氧化钛，氧化锆和二氧化硅中的至少一种的催化剂接触，优选在蒸汽存在下包含氧化铝和氧化镍，氧化锌和二氧化钛中的至少一种的催化剂，从而以相对低的水解水解氟化合物 温度，例如 200°-800℃，将氟化合物的氟转化成氟化氢。

公开(公告)号：US06272848B1

公开(公告)日：2001-08-14

申请号：US09116708

申请日：1998-07-17

申请人： Kojiro Okude ,  Hidehiro Iizuka ,  Osamu Kuroda ,  Ryouta Doi ,  Toshio Ogawa ,  Hisao Yamashita ,  Shigeru Azuhata ,  Yuichi Kitahara ,  Toshifumi Hiratsuka ,  Norihiro Shinotsuka

发明人： Kojiro Okude ,  Hidehiro Iizuka ,  Osamu Kuroda ,  Ryouta Doi ,  Toshio Ogawa ,  Hisao Yamashita ,  Shigeru Azuhata ,  Yuichi Kitahara ,  Toshifumi Hiratsuka ,  Norihiro Shinotsuka

IPC分类号： F01N300

CPC分类号： F01N3/085 ,  B01D53/9495 ,  F01N3/0842 ,  F01N2570/04 ,  F02D41/0285 ,  F02D2041/288

摘要： An apparatus and method of highly efficiently purifying nitrogen oxides are provided. An NOx chemisorption reduction catalyst chemically absorbs NOx under a condition that an exhaust gas of an internal combustion engine is an oxidizing atmosphere and deoxidizes adsorbed NOx under a reducing atmosphere. An SOx absorbent absorbs SOx contained in the exhaust gas of the oxidizing atmosphere, and deoxidizes and release SOx absorbed in the reducing atmospheric exhaust gas. The catalyst and absorbent are arranged in the exhaust path to purify the exhaust gas while preventing or suppressing SOx-poisoning of the NOx chemisorption reduction catalyst.

摘要翻译： 提供了高效净化氮氧化物的装置和方法。 NOx化学吸附还原催化剂在内燃机的排气是氧化气氛并在还原气氛下脱氧吸附的NOx的条件下，化学吸收NOx。 SO x吸收剂吸收氧化气氛的废气中所含的SOx，并且还原和释放在还原气氛废气中吸收的SO x。 催化剂和吸收剂布置在排气路径中以净化废气，同时防止或抑制NOx化学吸附还原催化剂的SOx中毒。