公开(公告)号：US4697877A

公开(公告)日：1987-10-06

申请号：US709036

申请日：1985-03-06

Applicant: Yoshinori Hida ,  Noriyuki Meguriya ,  Akira Yoshida

Inventor： Yoshinori Hida ,  Noriyuki Meguriya ,  Akira Yoshida

IPC: C03C25/24 ,  C03C25/10 ,  C08G77/442 ,  C09D183/04 ,  C09D201/02 ,  G02B6/44 ,  G02B6/16

CPC classification number: C08G77/442 ,  C03C25/106 ,  Y10T428/2962

Abstract: The surface-coated optical fiber of the invention is composed of a fibrous body of a vitreous material, e.g. fused quartz glass, and a coating layer thereon formed of a coating composition comprising an organosiloxane-modified organic polymer, of which the backbone is formed of recurring organic units such as a polybutadiene, an acrylic polymer and the like having modifying pendant groups containing an organosiloxane unit. The workability of the coating composition in the coating application is excellent so that a high uniformity is obtained in the coating layer in comparison with a coating composition comprising an unmodified organic polymer. The coating layer thus formed has a remarkably improved mechanical strength over a coating layer formed of an organopolysiloxane resin alone.

Abstract translation: 本发明的表面被覆光纤由玻璃质材料的纤维体构成，例如， 熔融石英玻璃及其上的涂层由包含有机硅氧烷改性的有机聚合物的涂料组合物形成，所述有机硅氧烷改性的有机聚合物的主链由诸如聚丁二烯的重复有机单元形成，具有包含有机硅氧烷的改性侧基的丙烯酸类聚合物等 单元。 涂料组合物在涂布应用中的可加工性是优异的，因此与包含未改性的有机聚合物的涂料组合物相比，在涂层中获得高均匀性。 如此形成的涂层相对于仅由有机聚硅氧烷树脂形成的涂层而言具有显着提高的机械强度。

公开(公告)号：US4623697A

公开(公告)日：1986-11-18

申请号：US728966

申请日：1985-04-30

Applicant: Wen-Hsuan Chang ,  David T. McKeough

Inventor： Wen-Hsuan Chang ,  David T. McKeough

IPC: C08G59/00 ,  C08F8/42 ,  C08F16/00 ,  C08F16/02 ,  C08F16/06 ,  C08G59/14 ,  C08G63/00 ,  C08G63/91 ,  C08G65/48 ,  C08G69/00 ,  C08G69/48 ,  C08G77/50 ,  C08G85/00 ,  C09D157/06 ,  C09D183/00 ,  C09D183/05 ,  C09D201/02 ,  C08F8/00

CPC classification number: C09D201/02 ,  C08G77/50 ,  C08G85/004 ,  C09D157/06

Abstract: Disclosed is an ungelled resin composition comprising a compound having at least one group containing a silicon atom selected from: ##STR1## wherein Q represents the residue from an organic polyol selected from the group consisting of (1) simple diols, triols and higher hydric alcohols, (2) polyester polyols, (3) polyether polyols, (4) amide-containing polyols, (5) epoxy polyols and (6) polyhydric polyvinyl alcohols, and eachR independently is selected from the group of moieties consisting of hydrogen, and a C.sub.1 -C.sub.10 group joined to Si through an Si-C linkage, andY represents an easily hydrolyzable group.The ungelled resin composition contains an amount of easily hydrolyzable Y moieties directly bonded to silicon atoms such that the ratio of the number of grams of the ungelled resin composition to equivalents of easily hydrolyzable Y moieties in the ungelled resin composition is in a range of from 40 to 667. Preferred resin compositions of the invention can be cured in the presence of atmospheric moisture and a suitable catalyst at a temperature of less than or equal to 121 degrees Celsius within 3 hours.Disclosed is a method for producing the ungelled resin composition.Also disclosed is a nonaqueous composition, particularly a nonaqueous coating composition, containing an ungelled resin composition of the invention. Preferred coating compositions containing an ungelled resin composition of the invention can be cured in the presence of atmospheric moisture and a suitable catalyst at a temperature of less than or equal to 121 degrees C within 3 hours.

Abstract translation: 公开了一种无胶凝树脂组合物，其包含具有至少一个含有选自以下的硅原子的基团的化合物：其中Q表示选自（1）简单二醇， 三醇和高级醇，（2）聚酯多元醇，（3）聚醚多元醇，（4）含酰胺的多元醇，（5）环氧多元醇和（6）多元聚乙烯醇，并且每个R独立地选自部分 由氢组成的C1-C10基团和通过Si-C键与Si连接的C1-C10基团，Y表示易水解基团。 未凝胶化树脂组合物含有一定量的直接键合到硅原子上的易水解的Y部分，使得未凝胶化树脂组合物的克数与未凝胶化树脂组合物中容易水解的Y部分的当量之比在40 本发明优选的树脂组合物可在大气湿度和合适的催化剂存在下在3小时内在小于或等于121℃的温度下固化。 公开了一种无胶凝树脂组合物的制造方法。 还公开了含有本发明的未凝胶化树脂组合物的非水性组合物，特别是非水性涂料组合物。 含有本发明的未凝胶化树脂组合物的优选涂料组合物可在大气水分和合适的催化剂存在下在3小时内在小于或等于121℃的温度下固化。

公开(公告)号：US4552908A

公开(公告)日：1985-11-12

申请号：US641777

申请日：1984-08-17

Applicant: Peter F. Nicks ,  Gillian A. Young

Inventor： Peter F. Nicks ,  Gillian A. Young

IPC: C09D5/02 ,  C09D133/04 ,  C09D151/08 ,  C09D157/00 ,  C09D167/00 ,  C09D201/02 ,  C09D3/64 ,  C09D3/72

CPC classification number: C09D151/08 ,  C09D157/00 ,  C09D5/02

Abstract: Aqueous coating compositions comprise a polymer of defined molecular weight which contains either anionizable or cationizable groups and also certain defined non-ionizable water-soluble moieties (derived for example from polyethylene glycol), water, optionally an organic coupling solvent and optionally either base or acid. The presence of regularly distributed non-ionizable water-soluble moieties enables the selection of aqueous polymer solutions which, on dilution, show a regular relationship between viscosity and solids content. The polymer solutions are useful in the formulation of coating compositions, particularly paints.

Abstract translation: 水性涂​​料组合物包含具有限定分子量的聚合物，其含有可阴离子化或阳离子化基团以及某些限定的非电离水溶性部分（衍生自例如聚乙二醇），水，任选的有机偶联溶剂和任选的碱或酸 。 常规分布的非电离水溶性部分的存在使得能够选择在稀释时粘度和固体含量之间规则关系的聚合物水溶液。 聚合物溶液可用于涂料组合物，特别是涂料的配方中。

公开(公告)号：US4539385A

公开(公告)日：1985-09-03

申请号：US620767

申请日：1984-06-14

Applicant: Michael Geist ,  Gunther Ott

Inventor： Michael Geist ,  Gunther Ott

IPC: C08G59/00 ,  C08G59/50 ,  C08G59/52 ,  C08G59/58 ,  C08G59/62 ,  C09D5/44 ,  C09D17/00 ,  C09D163/00 ,  C09D201/02 ,  C09D201/06 ,  C08G59/14 ,  C08G59/16

CPC classification number: C08G59/625 ,  C08G59/58 ,  C09D163/00 ,  C09D17/00 ,  C09D5/4446 ,  C09D5/4488 ,  Y10T428/31529 ,  Y10T428/31681 ,  Y10T428/31699

Abstract: The invention relates to a self-crosslinking heat-curable binder, in particular for electrocoating finishes, based on an organic synthetic resin which contains primary and/or secondary hydroxyl groups, esterified carboxyl groups and quaternary ammonium groups and can be diluted with water as a result of partial or complete neutralization with acids. The esterified carboxyl groups are activated in the alcohol component by a substituent which has a negative inductive effect.

公开(公告)号：US4528363A

公开(公告)日：1985-07-09

申请号：US582595

申请日：1984-02-22

Applicant: Akira Tominaga

Inventor： Akira Tominaga

IPC: C08G59/00 ,  C08G59/14 ,  C08G59/42 ,  C08G59/56 ,  C08G85/00 ,  C09D5/44 ,  C09D163/00 ,  C09D201/02 ,  C09D201/06

CPC classification number: C08G85/004 ,  C08G59/4292 ,  C08G59/56 ,  C09D5/4488

Abstract: A heat-curable resin coating composition comprising as a resin binder a film-forming resin which contains at least two tertiary nitrogen atoms per molecule and may optionally contain primary or secondary amino groups, each of said tertiary nitrogen atoms having directly bonded thereto a functional group represented by the following formula ##STR1## wherein R.sub.1 represents a divalent saturated aliphatic hydrocarbon group having 1 to 18 carbon atoms which may be substituted by a hydroxyl group and/or may be interrupted by an ether linkage (--O--); R.sub.2 represents a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 6 carbon atoms, or a part of the main chain of the resin; and R.sub.3 represents a hydrogen atom or a hydrocarbon group having 1 to 12 carbon atoms which may be substituted by a hydroxyl group and/or may be interrupted by an ether linkage, and each of said tertiary nitrogen atoms optionally forming a member of a nitrogen-containing heterocyclic ring formed together with R.sub.1 and R.sub.2 in the above formula and the nitrogen atom to which they are bonded.

Abstract translation: 一种热固性树脂涂料组合物，其包含作为树脂粘合剂的每分子含有至少两个叔氮原子并且可以任选地含有伯或仲氨基的成膜树脂，所述叔氮原子中的每一个直接键合有官能团 由下式（I）表示，其中R1表示可被羟基取代的碳原子数1〜18的二价饱和脂肪族烃基和/或可被醚键（-O-）中断。 R2表示氢原子，取代或未取代的碳原子数1〜6的烷基或树脂的主链的一部分。 R3表示氢原子或可被羟基取代的碳原子数1〜12的烃基和/或可被醚键中断，所述叔氮原子任意形成氮原子， 与上述式中的R 1和R 2一起形成的含氮杂环和与它们键合的氮原子。

公开(公告)号：US4501863A

公开(公告)日：1985-02-26

申请号：US567313

申请日：1983-12-30

Applicant: Hirotoshi Umemoto ,  Hisaki Tanabe ,  Mitsuo Yamada ,  Shinji Nakano

Inventor： Hirotoshi Umemoto ,  Hisaki Tanabe ,  Mitsuo Yamada ,  Shinji Nakano

IPC: C08G63/00 ,  C08G18/08 ,  C08G63/12 ,  C08G63/78 ,  C08L33/04 ,  C08L61/20 ,  C08L61/28 ,  C09D133/04 ,  C09D161/20 ,  C09D161/28 ,  C09D167/00 ,  C09D167/02 ,  C09D175/04 ,  C09D201/00 ,  C09D201/02 ,  C09D201/08 ,  C08F283/00 ,  C08G63/76 ,  C08L61/00

CPC classification number: C09D201/08 ,  C08G18/0823 ,  C09D167/00

Abstract: A resinous composition for coating use comprising a resin having a resinous acid value derived from polycarboxylic acid whose titration midpoint potential in non-aqueous potentiometric titration is more than -300 mV under the state capable of developing resinous acid value of 2 to 50 and having a functional group reactive with a crosslinking agent, and preparation thereof.The composition is useful for the preparation of coating composition having improved curing property.

Abstract translation: 一种用于涂料的树脂组合物，其包含树脂，其树脂酸值源自多元羧酸，其在非水电位滴定中的滴定中点电位大于-300mV，在能够发挥树脂酸值为2-50的状态下，并具有 与交联剂反应的官能团及其制备。 该组合物可用于制备具有改进的固化性能的涂料组合物。

公开(公告)号：US4490417A

公开(公告)日：1984-12-25

申请号：US495731

申请日：1983-05-20

Applicant: Kenji Shindow ,  Akimitsu Uenaka ,  Takaharu Izumo ,  Teruyoshi Fujishima ,  Satoshi Yamamoto

Inventor： Kenji Shindow ,  Akimitsu Uenaka ,  Takaharu Izumo ,  Teruyoshi Fujishima ,  Satoshi Yamamoto

IPC: C08L57/00 ,  C08G18/00 ,  C08G18/42 ,  C08G18/62 ,  C08L33/00 ,  C08L33/02 ,  C08L61/20 ,  C08L61/32 ,  C08L67/00 ,  C09D131/04 ,  C09D133/06 ,  C09D161/02 ,  C09D161/20 ,  C09D167/00 ,  C09D175/00 ,  C09D201/02 ,  B05D3/02 ,  C08L61/28

CPC classification number: C09D133/066 ,  C08L61/32 ,  Y10T428/31688 ,  Y10T428/31862

Abstract: A coating composition which comprises (A) a vinylic monomer-copolymerized resin having a hydroxyl group and a carboxyl group and (B) an alkoxylated amine-formaldehyde condensate as a curing agent for the resin (A). When the coating composition is used as a base coating composition and/or as a clear coating composition in the two coat-one bake coating system, the resulting coating film shows excellent weather resistance with good appearance.

Abstract translation: 一种涂料组合物，其包含（A）具有羟基和羧基的乙烯基单体共聚树脂和（B）作为树脂（A）的固化剂的烷氧基化胺 - 甲醛缩合物。 当涂料组合物作为基底涂料组合物和/或作为透明涂料组合物用于两个涂料一烘烤涂料体系中时，所得涂膜显示出优异的耐候性和良好的外观。

公开(公告)号：US4484994A

公开(公告)日：1984-11-27

申请号：US581005

申请日：1984-02-17

Applicant: William Jacobs, III ,  Girish G. Parekh ,  Werner J. Blank

Inventor： William Jacobs, III ,  Girish G. Parekh ,  Werner J. Blank

IPC: C08G59/40 ,  C08G71/00 ,  C09D5/44 ,  C09D163/00 ,  C09D201/02 ,  C08L63/00 ,  C08G18/58

CPC classification number: C09D201/025 ,  C08G59/4057 ,  C08G71/00 ,  C09D163/00 ,  C09D5/443

Abstract: A cathodically electrodepositable, self-cross-linkable polymer is a hydroxyalkyl carbamate-containing resin having at least one tertiary amine and at least two hydroxyalkyl carbamate groups per molecule. The polymer is made by reacting an epoxy resin having an average epoxy equivalent weight of from about 300 to about 10,000 with one or more amines having at least one secondary amine group and at least one hydroxyalkyl carbamate group or precursor thereof. Hydrophobic amines may be co-reacted to enhance hydrophobicity of the polymer. An electrodeposition bath is made by acidifying the polymer to form an aqueous dispersion. A low temperature-curable coating is attained by utilization of the polymer with a suitable quaternary or ternary compound catalyst.

Abstract translation: 阴离子可电沉积的自交联聚合物是每分子具有至少一个叔胺和至少两个羟烷基氨基甲酸酯基团的含氨基甲酸羟烷基酯的树脂。 该聚合物通过使平均环氧当量为约300至约10,000的环氧树脂与一种或多种具有至少一个仲胺基团和至少一种氨基甲酸羟烷基酯基团或其前体的胺反应制备。 疏水胺可以共反应以增强聚合物的疏水性。 通过酸化聚合物以形成水分散体来制备电沉积浴。 通过使用合适的季铵或三元化合物催化剂的聚合物可获得低温可固化涂层。

公开(公告)号：US4477628A

公开(公告)日：1984-10-16

申请号：US405334

申请日：1982-08-05

Applicant: Yasushi Kato ,  Hisao Furukawa

Inventor： Yasushi Kato ,  Hisao Furukawa

IPC: C08L57/00 ,  C08F8/42 ,  C08F230/08 ,  C08G77/00 ,  C08G77/02 ,  C08K5/00 ,  C08L57/06 ,  C09D183/00 ,  C09D201/02 ,  C08F8/00

CPC classification number: C08F230/08 ,  C08F8/42 ,  C08K5/0025

Abstract: A composition consisting essentially of a homogeneous mixture of 0.01 to 10 parts by weight of a novel hardening catalyst and 100 parts by weight of a vinyl type resin containing at least one silyl radical, wherein the pot life of the vinyl type resin, when exposed to ambient atmosphere, is substantially improved. The composition is useful as a paint, coating, sealant or the like.

Abstract translation: 一种组合物，其基本上由0.01至10重量份的新型硬化催化剂和100重量份含有至少一个甲硅烷基的乙烯基类树脂的均匀混合物组成，其中乙烯基类树脂暴露于 环境气氛大大提高。 该组合物可用作油漆，涂料，密封胶等。

公开(公告)号：US4403065A

公开(公告)日：1983-09-06

申请号：US197322

申请日：1980-10-15

Applicant: Tamotsu Yoshioka ,  Ryuzo Mizuguchi ,  Shinichi Ishikura ,  Keizo Ishii

Inventor： Tamotsu Yoshioka ,  Ryuzo Mizuguchi ,  Shinichi Ishikura ,  Keizo Ishii

IPC: C08F12/00 ,  C08F16/00 ,  C08F16/14 ,  C08F212/14 ,  C08F216/14 ,  C08F246/00 ,  C08L7/00 ,  C08L21/00 ,  C08L23/00 ,  C08L25/00 ,  C08L29/00 ,  C08L29/10 ,  C08L33/00 ,  C08L33/02 ,  C08L101/00 ,  C09D129/00 ,  C09D129/10 ,  C09D201/02 ,  C08L39/00

CPC classification number: C08F216/1458 ,  C08F212/14 ,  C08F216/14 ,  C09D129/10

Abstract: An aqueous emulsion comprising a polymeric resin prepared by polymerizing (a) at least one amino acid of either one of the formula: ##STR1## and the formula: ##STR2## with (b) at least one other polymerizable monomer in an aqueous medium, the component (a) and at least a portion of the component (b) being introduced separately into the reaction system.

Abstract translation: 一种水乳液，其包含聚合物树脂，其通过使（a）至少一种下式的氨基酸与下式（Ia）和式（Ⅰb）与（b）至少一种其它可聚合的 单体在水性介质中，组分（a）和至少一部分组分（b）分别引入反应体系中。