公开(公告)号：US20080161181A1

公开(公告)日：2008-07-03

申请号：US11648844

申请日：2006-12-29

申请人： Robert J. Schmidt ,  Deng-Yang Jan ,  Raelynn M. Miller ,  James A. Johnson

发明人： Robert J. Schmidt ,  Deng-Yang Jan ,  Raelynn M. Miller ,  James A. Johnson

IPC分类号： B01J21/00

CPC分类号： B01J29/7007 ,  B01J37/0221 ,  B01J37/0246 ,  C07C37/08 ,  C07C45/53 ,  Y02P20/52 ,  C07C49/08 ,  C07C39/04

摘要： The present invention provides a catalyst particle of an inner core, an outer layer surrounding and bonded to the inner core, the outer layer of a zeolite beta catalyst, and the outer layer having a volumetric fraction from about 0.17 to about 0.62 of the entire catalyst particle.

公开(公告)号：US20050137442A1

公开(公告)日：2005-06-23

申请号：US10740872

申请日：2003-12-19

申请人： Gregory Gajda ,  Guy Woodle ,  Deng-Yang Jan ,  Andrew Zarchy

发明人： Gregory Gajda ,  Guy Woodle ,  Deng-Yang Jan ,  Andrew Zarchy

IPC分类号： C07C7/12 ,  C07C7/13

CPC分类号： C07C7/13

摘要： At lower temperatures an acidic molecular sieve adsorbent preferentially adsorbs water and basic organic nitrogen compounds over weakly basic organic nitrogen compounds such as nitrites. Elevated temperatures improve the capacity of acidic molecular sieve adsorbents to adsorb nitrites in the presence of water.

摘要翻译： 在较低温度下，酸性分子筛吸附剂优先在弱碱性有机氮化合物如亚硝酸盐上吸附水和碱性有机氮化合物。 升高的温度提高了酸性分子筛吸附剂在水存在下吸附亚硝酸盐的能力。

公开(公告)号：US06388159B1

公开(公告)日：2002-05-14

申请号：US09705839

申请日：2000-11-03

申请人： Deng-Yang Jan ,  Gregory J. Lewis ,  Jaime G. Moscoso ,  Mark A. Miller ,  Qianjun Chen

发明人： Deng-Yang Jan ,  Gregory J. Lewis ,  Jaime G. Moscoso ,  Mark A. Miller ,  Qianjun Chen

IPC分类号： C07C522

CPC分类号： C07C5/2724 ,  B01J29/04 ,  B01J29/70 ,  B01J2229/26 ,  B01J2229/42 ,  C01B39/06 ,  C01B39/065 ,  C01B39/48 ,  C07C2/66 ,  C07C6/126 ,  C07C7/13 ,  C07C2529/70 ,  Y02P20/52 ,  C07C15/085 ,  C07C15/067 ,  C07C15/08

摘要： A process for isomerising xylene using a new family of related crystalline aluminosilicate zeolites has been developed. These zeolites are represented by the empirical formula: Mmn+Rrp+Al(1−x)ExSiyOz where M is an alkali or alkaline earth metal such as lithium and strontium, R is a nitrogen containing organic cation such as tetramethyl-ammonium and E is a framework element such as gallium.

摘要翻译： 已经开发了使用新的相关结晶硅铝酸盐沸石族异构化二甲苯的方法。 这些沸石由经验式表示：其中M是碱金属或碱土金属如锂和锶，R是含氮有机阳离子如四甲基铵，E是骨架元素如镓。

公开(公告)号：US06376730B1

公开(公告)日：2002-04-23

申请号：US09603769

申请日：2000-06-26

申请人： Deng-Yang Jan ,  James F. Mc Gehee ,  Guy B. Woodle ,  Masao Takayama ,  Raelynn M. Miller

发明人： Deng-Yang Jan ,  James F. Mc Gehee ,  Guy B. Woodle ,  Masao Takayama ,  Raelynn M. Miller

IPC分类号： C07C266

CPC分类号： B01J23/626 ,  B01J23/40 ,  B01J29/06 ,  B01J29/7007 ,  B01J37/0219 ,  B01J37/0242 ,  B01J37/0246 ,  Y10T428/2991 ,  Y10T428/2993

摘要： A layered catalyst composition is disclosed where the composition is prepared by bonding an outer layer comprising a bound zeolite (e.g. zeolite beta) to an inner core material (e.g. cordierite). The use of an organic bonding agent in the catalyst preparation procedure provides a composition that is sufficiently resistant to mechanical attrition to be used commercially in aromatic alkylation processes (e.g. benzene alkylation to ethylbenzene). Advantages associated with the use of layered compositions include a significant reduction in the amount of zeolite used for a given reactor loading and improved selectivity to desired alkylated aromatic products. Further benefits are realized when the layered composition is formed into shapes having a sufficiently high void volume to reduce pressure drop across the alkylation catalyst bed. This is especially relevant for operation involving high recycle rates and consequently low alkylating agent concentrations in the reaction zone. Such conditions are known to promote reduced byproduct formation.

摘要翻译： 公开了一种分层催化剂组合物，其中通过将包含结合的沸石（例如β沸石）的外层粘合到内芯材料（例如堇青石）来制备组合物。 在催化剂制备方法中使用有机粘合剂提供了足够耐机械磨损的组合物，其可以在芳族烷基化方法（例如苯烷基化至乙苯）中商业使用。 与使用分层组合物相关的优点包括用于给定反应器负载的沸石的量的显着减少和对所需烷基化芳族产物的改进的选择性。 当层状组合物形成为具有足够高的空隙体积的形状以减少跨越烷基化催化剂床的压降时，可实现进一步的益处。 这对于涉及高回收率和因此反应区中低烷基化剂浓度的操作特别有用。 已知这种条件促进副产物形成。

公开(公告)号：US5985782A

公开(公告)日：1999-11-16

申请号：US801333

申请日：1997-02-19

申请人： Ben A. Wilson ,  Robert Lyle Patton ,  Vinayan Nair ,  Deng-Yang Jan ,  Hemant B. Gala

发明人： Ben A. Wilson ,  Robert Lyle Patton ,  Vinayan Nair ,  Deng-Yang Jan ,  Hemant B. Gala

IPC分类号： B01J29/70 ,  C10G11/05 ,  C10G47/16 ,  B01J29/06

CPC分类号： B01J29/7019 ,  C10G11/05 ,  C10G47/16 ,  B01J2229/16

摘要： Applicants have prepared a novel zeolite identified as LZ-281. This zeolite has the framework topology of zeolite EMT. The LZ-281 zeolite is prepared by removing framework aluminum atoms from EMC-2 zeolite while simultaneously replacing the aluminum atoms with extraneous silicon atoms. This increases the SiO.sub.2 /Al.sub.2 O.sub.3 ratio versus the starting EMC-2 zeolite and results in the LZ-281 zeolite having increased thermal stability, increased number and/or strength of acid sites and increased activity in hydrocarbon processes requiring strong acid sites.

摘要翻译： 申请人已经制备了一种鉴定为LZ-281的新型沸石。 该沸石具有沸石EMT的骨架拓扑结构。 通过从EMC-2沸石中除去骨架铝原子同时用外来硅原子代替铝原子来制备LZ-281沸石。 这相对于起始的EMC-2沸石增加了SiO 2 / Al 2 O 3比例，并且导致LZ-281沸石具有增加的热稳定性，增加的酸位数和/或强度以及在需要强酸性位点的烃法中增加的活性。

公开(公告)号：US5565088A

公开(公告)日：1996-10-15

申请号：US319175

申请日：1994-10-06

申请人： Vinayan Nair ,  Deng-Yang Jan

发明人： Vinayan Nair ,  Deng-Yang Jan

IPC分类号： C10G65/12 ,  C10G47/20

CPC分类号： C10G65/12

摘要： The invention is a hydrocracking process which produces an increased amount of hydrocarbons useable as diesel fuel by isomerization of high boiling paraffins using a dewaxing catalyst. The process is characterized by the use of a dewaxing catalyst containing a very small amount of a non-noble metal hydrogenation component such as nickel on an intermediate pore nonzeolitic molecular sieve (NZMS) material. This dewaxing catalyst has been found to be very effective in reducing the pour point of a diesel boiling range distillates even in the presence of sulfur levels which adversely affect catalysts containing higher amounts of the same metal component.

摘要翻译： 本发明是一种加氢裂化方法，其通过使用脱蜡催化剂使高沸点烷烃异构化，产生可用作柴油燃料的增加量的烃。 该方法的特征在于在中等孔非沸石分子筛（NZMS）材料上使用含有极少量非贵金属氢化组分如镍的脱蜡催化剂。 已经发现，该脱蜡催化剂在降低柴油沸程馏出物的倾点方面是非常有效的，即使在对含有较高量相同金属组分的催化剂有不利影响的硫含量存在下也是如此。

公开(公告)号：US5393409A

公开(公告)日：1995-02-28

申请号：US28062

申请日：1993-03-08

申请人： Deng-Yang Jan ,  Brian Wood

发明人： Deng-Yang Jan ,  Brian Wood

IPC分类号： B01J35/10 ,  C10G47/16 ,  C10G47/10

CPC分类号： C10G47/16 ,  B01J35/0026 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1061 ,  B01J35/1071 ,  B01J35/108 ,  B01J35/109

摘要： A hydrocracking catalyst and a process using it are described. The catalyst comprises a dealuminated zeolite bound into a highly porous amorphous support matrix. The catalyst is characterized by its low piece density and a bimodal pore distribution, with the unfinished catalyst having a sizeable amount of macropores having diameters between 5,000 and 9,000 Angstroms. A high amount of mesopores between about 56 and about 297 Angstroms is also desired. The presence of pores between 300 to 500 Angstroms and greater than 10,000 Angstroms in diameter is minimized.

摘要翻译： 描述加氢裂化催化剂及其使用方法。 该催化剂包含结合到高度多孔非晶支撑基质中的脱铝沸石。 催化剂的特征在于其低的片密度和双峰孔分布，未完成的催化剂具有相当大量的直径在5000和9,000埃之间的大孔。 也需要约56至约297埃之间的大量介孔。 存在直径在300至500埃和大于10,000埃之间的孔隙最小化。

公开(公告)号：US08470726B2

公开(公告)日：2013-06-25

申请号：US12639973

申请日：2009-12-16

申请人： Mark G. Riley ,  Deng-Yang Jan ,  Stephen W. Sohn ,  Jaime G. Moscoso

发明人： Mark G. Riley ,  Deng-Yang Jan ,  Stephen W. Sohn ,  Jaime G. Moscoso

IPC分类号： B01J29/06

CPC分类号： B01J29/80 ,  B01J23/10 ,  B01J29/08 ,  B01J29/082 ,  B01J29/084 ,  B01J29/70 ,  B01J29/7019 ,  B01J29/7038 ,  C07C2/66 ,  C07C2529/08 ,  C07C2529/70 ,  C07C2529/78 ,  C07C15/02

摘要： A catalyst is presented for use in the production of linear alkylbenzenes. The catalyst includes two zeolites combined to improve the quality of the linear alkylbenzenes. The catalyst includes a first zeolite that is UZM-8 and a second zeolite that is a low silica to alumina ratio zeolite. The second zeolite is also cation exchanged with a rare earth elements to provide a zeolite that increases the alkylation of benzene while reducing the amount of skeletal isomerization.

摘要翻译： 呈现用于生产线性烷基苯的催化剂。 催化剂包括两种沸石结合以改善线性烷基苯的质量。 催化剂包括UZM-8的第一沸石和低二氧化硅与氧化铝比的沸石的第二沸石。 第二沸石也与稀土元素进行阳离子交换以提供增加苯的烷基化同时减少骨架异构化量的沸石。

公开(公告)号：US08350111B2

公开(公告)日：2013-01-08

申请号：US12903177

申请日：2010-10-12

申请人： Deng-Yang Jan ,  Christopher Lepine Standing ,  James Albert Johnson ,  Margo W. Steward ,  Mathias P. Koljack

发明人： Deng-Yang Jan ,  Christopher Lepine Standing ,  James Albert Johnson ,  Margo W. Steward ,  Mathias P. Koljack

IPC分类号： C07C6/12

CPC分类号： C07C6/126 ,  B01J29/084 ,  B01J29/70 ,  B01J29/7007 ,  B01J29/80 ,  B01J37/0009 ,  B01J2229/42 ,  C07C2529/08 ,  C07C2529/70 ,  C07C2529/80 ,  Y02P20/52 ,  C07C15/085

摘要： One exemplary embodiment can be a method for processing polyisopropylbenzene for producing cumene. The method can include passing a transalkylation feed stream to a transalkylation zone, and passing a reaction product to a separation zone. Typically, the separation zone produces a stream including di-isopropylbenzene, tri-isopropylbenzene, and one or more heavy compounds. Moreover, the stream may include at least about 0.7%, by weight, of the one or more heavy compounds based on the weight of the di-isopropylbenzene, tri-isopropylbenzene, and the one or more heavy compounds in the stream, and at least a portion of the stream is recycled to the transalkylation zone.

摘要翻译： 一个示例性实施方案可以是用于处理聚异丙苯以制备枯烯的方法。 该方法可以包括使烷基转移进料流进入烷基转移区，并将反应产物送至分离区。 通常，分离区产生包含二异丙基苯，三异丙基苯和一种或多种重质化合物的物流。 此外，基于二异丙基苯，三异丙基苯和流中的一种或多种重质化合物的重量，流可以包含至少约0.7重量％的一种或多种重质化合物，并且至少 一部分流被再循环到烷基转移区。

公开(公告)号：US20120289754A1

公开(公告)日：2012-11-15

申请号：US13103545

申请日：2011-05-09

申请人： Wugeng Liang ,  Deng-Yang Jan

发明人： Wugeng Liang ,  Deng-Yang Jan

IPC分类号： C07C2/66 ,  B01J19/00

CPC分类号： C07C2/66 ,  B01J29/7007 ,  C07C2529/70 ,  C07C15/073

摘要： Embodiments of methods and apparatuses for producing ethylbenzene are provided. The method comprises the steps of introducing a first feed mixture comprising benzene and ethylene to UZM-8 zeolite-based catalyst at a first predetermined inlet temperature to form a first intermediate outlet stream comprising ethylbenzene and benzene. Ethylene is added to the first intermediate outlet stream to form a second intermediate feed mixture. The second intermediate feed mixture is introduced to beta zeolite-based catalyst at a second predetermined inlet temperature to form ethylbenzene.

摘要翻译： 提供了生产乙苯的方法和设备的实施例。 该方法包括以第一预定入口温度将包含苯和乙烯的第一进料混合物引入到基于UZM-8沸石的催化剂中以形成包含乙苯和苯的第一中间流出物流的步骤。 将乙烯加入到第一中间流出物流中以形成第二中间进料混合物。 将第二中间进料混合物在第二预定入口温度下引入β沸石基催化剂中以形成乙苯。