摘要:
Methods are provided for removing CO2 and/or H2S from a gas phase stream, such as a refinery flue gas stream, a coal-fired or petroleum-burning power plant, or a natural gas stream. A gas phase stream containing CO2 and/or H2S can be contacted under effective conditions with an aqueous slurry of supported amine particles. The CO2 and/or H2S can react with the supported amines to form bicarbonates, carbonates, carbamates, sulfide salts, or other species. Because the amine is part of, bonded to, or otherwise supported on a particulate substrate, the reaction product from the amine reaction can also remain bound to the particle. After reacting supported amines with CO2 and/or H2S captured from a gas stream, the supported amines particles can be separated from the aqueous slurry environment for regeneration of the supported amine and release of the CO2 and/or H2S.
摘要:
Novel adsorbent contactors and methods are disclosed herein for use in temperature swing adsorption for gas separation applications, as well as for heat exchange applications.
摘要:
Systems and methods for hydrotreating a liquid fraction of a shale oil stream using hydrogen gas that is concentrated from a gaseous fraction of the shale oil stream. The systems and methods include providing a portion of the gaseous fraction to a sorptive separation assembly and separating a concentrated hydrogen stream from the portion of the gaseous fraction within the sorptive separation assembly. The system and methods further include providing the concentrated hydrogen stream and the liquid fraction to a hydrotreater and reacting the concentrated hydrogen stream with the liquid fraction within the hydrotreater to produce the hydrotreated liquid stream. The systems and methods may include generating the shale oil stream within a subterranean formation using an in situ process, such as an in situ shale oil conversion process and/or providing a supplemental hydrogen stream to the hydrotreater.
摘要:
The separation of a target gas selected from a high pressure gas mixture containing said target gas as well as a product gas using a swing adsorption process unit. A turboexpander is used upstream of the swing adsorber to reduce the pressure of the high pressure gas mixture. A compressor is optionally used downstream of the swing adsorber to increase the pressure of the target gas-containing stream for injecting into a subterranean formation.
摘要:
Novel adsorbent contactors and methods are disclosed herein for use in temperature swing adsorption for gas separation applications, as well as for heat exchange applications.
摘要:
Systems and methods for an oxy-fuel type combustion reaction are provided. In one or more embodiments, a combustion system can include at least two mixing zones, where a first mixing zone at least partially mixes oxygen and carbon dioxide to produce a first mixture and a second mixing zone at least partially mixes the first mixture with a fuel to produce a second mixture. The combustion system can also include a combustion zone configured to combust the second mixture to produce a combustion product. In one or more embodiments, the first mixture can have a spatially varied ratio of oxygen-to-carbon dioxide configured to generate a hot zone in the combustion zone to increase flame stability in the combustion zone.
摘要:
The present invention provides a process for the manufacture of acetylene and other higher hydrocarbons from methane feed using a reverse-flow reactor system, wherein the reactor system includes (i) a first reactor and (ii) a second reactor, the first and second reactors oriented in a series relationship with respect to each other, the process comprising supplying each of first and second reactant through separate channels in the first reactor bed of a reverse-flow reactor such that both of the first and second reactants serve to quench the first reactor bed, without the first and second reactants substantially reacting with each other until reaching the core of the reactor system.
摘要:
Adsorption of CO2 from flue gas streams using temperature swing adsorption. The resulting CO2 rich stream is compressed for sequestration into a subterranean formation and at least a portion of the heat of compression is used in the desorption step of the temperature swing adsorption process.
摘要:
The present invention relates to the selective separation of carbon dioxide (“CO2”) from methane (“CH4”) in streams containing both carbon dioxide and methane utilizing a zeolitic imidazolate framework (“ZIF”) material. Preferably, the stream to be separated is fed to the present process in a substantially gaseous phase. In preferred embodiments, the current invention is utilized in a process to separate carbon dioxide from natural gas streams preferably for sequestration of at least a portion of the carbon dioxide present in the natural gas.
摘要:
Synthesis gas is produced though a cyclic method where the first step of the cycle includes reforming a hydrocarbon feed over a catalyst to synthesis gas in a first zone of a bed and the second step reheats this first zone. A hydrocarbon feed is introduced to a bed along with CO2 and optionally steam where it is reformed into synthesis gas. The synthesis gas is collected at a second zone of the bed and an oxygen-containing gas is then introduced to this second zone of the bed and combusted with a fuel, thereby reheating the first zone to sufficient reforming temperatures. Additionally, a non-combusting gas can also be introduced to the second zone to move heat from the second zone to the first zone.