公开(公告)号：US07670640B2

公开(公告)日：2010-03-02

申请号：US11226355

申请日：2005-09-15

申请人： Takayuki Araki ,  Mihoko Ohashi ,  Yoshito Tanaka ,  Tetsuo Shimizu

发明人： Takayuki Araki ,  Mihoko Ohashi ,  Yoshito Tanaka ,  Tetsuo Shimizu

IPC分类号： B05D5/06

CPC分类号： C09D127/12 ,  C08F8/00 ,  C08F8/14 ,  C08F16/32 ,  C08F214/18 ,  C08F290/04 ,  Y10T428/3154 ,  C08F14/18

摘要： There are provided a curable fluorine-containing polymer which can realize a high hardness by photo-curing while maintaining a low refractive index, an antireflection film possessing improved scratch resistance and abrasion resistance while maintaining a reflection reducing effect, and an antireflection-treated article provided with such an antireflection film. The curable fluorine-containing polymer has a number average molecular weight of from 500 to 1,000,000 and is represented by the formula (1): AM  (1) in which the structural unit M is a structural unit derived from a fluorine-containing ethylenic monomer and represented by the formula (M): wherein X1 and X2 are the same or different and each is H or F; X3 is H, F, CH3 or CF3; X4 and X5 are the same or different and each is H, F or CF3; Rf is an organic group in which 1 to 3 of Y1 (Y1 is a monovalent organic group having 2 to 10 carbon atoms and an ethylenic carbon-carbon double bond at its end) are bonded to a fluorine-containing alkyl group having 1 to 40 carbon atoms or a fluorine-containing alkyl group having 2 to 100 carbon atoms and ether bond; a is 0 or an integer of from 1 to 3; b and c are the same or different and each is 0 or 1, the structural unit A is a structural unit derived from a monomer copolymerizable with the fluorine-containing ethylenic monomer represented by the formula (M), and the structural unit M and the structural unit A are contained in amounts of from 0.1 to 100% by mole and from 0 to 99.9% by mole, respectively.

摘要翻译： 提供了一种可固化的含氟聚合物，其可以通过光固化同时保持低折射率实现高硬度，在保持反射降低效果的同时具有改善的耐擦伤性和耐磨性的抗反射膜，以及提供的抗反射处理制品 具有这样的抗反射膜。 可固化含氟聚合物的数均分子量为500〜1,000,000，由式（1）表示：AM（1）其中，结构单元M是来自含氟乙烯性单体的结构单元， 由式（M）表示：其中X1和X2相同或不同，各自为H或F; X3是H，F，CH3或CF3; X4和X5相同或不同，分别为H，F或CF 3; Rf为1〜3的Y1（Y1为碳原子数为2〜10的一价有机基团，末端为烯属碳 - 碳双键）的1〜3的有机基团与1〜40的含氟烷基 碳原子或碳原子数2〜100的含氟烷基和醚键; a为0或1〜3的整数; b和c相同或不同，分别为0或1，结构单元A是衍生自与式（M）表示的含氟乙烯性单体共聚的单体的结构单元，结构单元M和 结构单元A的含量分别为0.1至100摩尔％和0至99.9摩尔％。

公开(公告)号：USRE41110E1

公开(公告)日：2010-02-09

申请号：US11512391

申请日：2006-08-30

申请人： Takayuki Araki ,  Yoshito Tanaka ,  Masahiro Kumegawa ,  Norihito Otsuki ,  Masami Kato ,  Tetsuo Shimizu

发明人： Takayuki Araki ,  Yoshito Tanaka ,  Masahiro Kumegawa ,  Norihito Otsuki ,  Masami Kato ,  Tetsuo Shimizu

IPC分类号： B32B27/00

CPC分类号： C08F214/262 ,  C08F293/00 ,  C08L53/00 ,  C09D153/00 ,  G03G15/2057 ,  Y10T428/1352

摘要： It is possible to provide the heat resistant material and coating material for OA equipment which comprise a fluorine-containing multi-segment polymer having heat resistance, abrasion resistance, non-sticking property against toner and oil resistance in addition to flexibility and are used particularly on surfaces of fuser roll and belt. Those materials comprise a fluorine-containing multi-segment polymer having an elastomeric fluorine-containing polymer chain segment A and a non-elastomeric fluorine-containing polymer chain segment B, and the elastomeric fluorine-containing polymer chain segment A comprises not less than 90% by mole of perhaloolefin unit as a recurring unit and imparts flexibility to the whole polymer.

摘要翻译： 可以提供包含含氟多层聚合物的OA设备的耐热材料和涂层材料，其具有耐热性，耐磨性，对调色剂的不粘附性和耐油性以及柔性，并且特别用于 定影辊和皮带的表面。 这些材料包括具有弹性体含氟聚合物链段A和非弹性含氟聚合物链段B的含氟多段聚合物，弹性体含氟聚合物链段A包含不少于90％ 的全卤代烯烃单元作为重复单元，并赋予整个聚合物柔性。

公开(公告)号：US20090297822A1

公开(公告)日：2009-12-03

申请号：US12089729

申请日：2006-10-11

申请人： Hirokazu Fujimura ,  Noboru Kubota ,  Masatoshi Hashino ,  Tetsuo Shimizu

发明人： Hirokazu Fujimura ,  Noboru Kubota ,  Masatoshi Hashino ,  Tetsuo Shimizu

IPC分类号： B32B3/10 ,  B29C44/22 ,  B32B5/22

CPC分类号： B01D69/087 ,  B01D69/085 ,  B01D69/088 ,  B01D69/12 ,  B01D71/26 ,  B01D71/34 ,  B01D2325/24 ,  D01D5/24 ,  D01D5/247 ,  D01D5/34 ,  D01F1/08 ,  D01F6/04 ,  D01F6/12 ,  Y10T428/249975 ,  Y10T428/249986 ,  Y10T428/2913 ,  Y10T428/2929

摘要： A porous hollow fiber membrane which has high blocking performance and high water permeability suitable for filtration and the like and exhibits excellent strength, and a process for stably producing the porous hollow fiber membrane are disclosed. The process utilizes a hollow fiber molding nozzle having two or more circular discharge ports which are disposed concentrically. Multilayer melt-extrusion is performed by discharging molten mixtures which include a thermoplastic resin and an organic liquid and differ in composition from the adjacent discharge ports. The resulting product is cooled to solidify to obtain a hollow fiber. The organic liquid is then removed from the hollow fiber by extraction to produce a porous hollow fiber membrane. The molten mixture discharged from at least one circular discharge port includes an inorganic fine powder in addition to the thermoplastic resin and the organic liquid. The inorganic fine powder is removed by extraction after cooling in addition to the organic liquid.

摘要翻译： 公开了一种多孔中空纤维膜，其具有适合于过滤等的高阻隔性和高透水性并且显示出优异的强度，并且公开了一种用于稳定生产多孔中空纤维膜的方法。 该方法利用具有同心设置的两个或更多个圆形排出口的中空纤维成型喷嘴。 通过排出包括热塑性树脂和有机液体的熔融混合物并且与相邻排出口的组成不同，进行多层熔融挤出。 将所得产物冷却固化，得到中空纤维。 然后通过萃取从中空纤维中除去有机液体，生成多孔中空纤维膜。 从至少一个圆形排出口排出的熔融混合物除了热塑性树脂和有机液体之外还包括无机细粉末。 除了有机液体之外，通过萃取除去无机细粉末。

公开(公告)号：US20090092741A1

公开(公告)日：2009-04-09

申请号：US11908650

申请日：2006-03-13

申请人： Kozo Ishida ,  Koji Tominaga ,  Koichiro Matsuda ,  Tetsuo Shimizu ,  Jiro Senda ,  Motohiro Oshima ,  Akiko Komeda

发明人： Kozo Ishida ,  Koji Tominaga ,  Koichiro Matsuda ,  Tetsuo Shimizu ,  Jiro Senda ,  Motohiro Oshima ,  Akiko Komeda

IPC分类号： B05D1/02 ,  B05C5/00

CPC分类号： H01L21/31608 ,  C23C14/3428 ,  C23C16/402 ,  C23C16/4485 ,  C23C16/45523 ,  H01L21/02164 ,  H01L21/02183 ,  H01L21/02214 ,  H01L21/02271 ,  H01L21/31637

摘要： The present claimed invention is a film forming system 1 that forms a film by vaporizing a liquid precursor and then depositing the vaporized liquid precursor on a substrate 2, and comprises a chamber 3 inside of which the substrate 2 is held, an injection valve 4 that directly injects the liquid precursor into the chamber 3, and a control unit 11 that alternately sets a supplying period while the liquid precursor is directly injected into the chamber 3 to supply the liquid precursor in a vaporized state and a supply halt period while the liquid precursor is not supplied into the chamber 3 and controls the supplying period and the supply halt period by periodically opening and closing the injection valve 4 so as to intermittently supply the liquid precursor into the chamber 3, and is characterized by that the control unit 11 controls the supply halt period to be equal to or longer than a migration/evaporation period necessary for atoms or molecules of the liquid precursor deposited on the substrate 2 to migrate and necessary for a reaction by-product material generated on the substrate 2 to evaporate. An object of this invention is to generate a thin film of high grade having less impure substances.

摘要翻译： 本发明是一种成膜系统1，其通过蒸发液体前体形成膜，然后将蒸发的液体前体沉积在基板2上，并且包括在其内部保持有基板2的腔室3，喷射阀4 直接将液体前体注入到室3中，以及控制单元11，其将液体前体直接注入到室3中交替地设置供给周期，以将液体前体供给到蒸发状态和供给停止期间，同时液体前体 不供给到室3中，并且通过周期性地打开和关闭喷射阀4来控制供给周期和供给停止时间，以间歇地将液体前体供给到室3中，并且其特征在于控制单元11控制 供应停止时间等于或长于沉积在其上的液体前体原子或分子所需的迁移/蒸发时间 衬底2迁移并且在衬底2上产生的反应副产物材料所必需的蒸发。 本发明的目的是产生具有较少不纯物质的高级薄膜。

公开(公告)号：US20090050244A1

公开(公告)日：2009-02-26

申请号：US12226039

申请日：2006-12-27

申请人： Koichi Nakagawa ,  Reiko Sugihara ,  Tetsuo Shimizu ,  Shusaku Takagi

发明人： Koichi Nakagawa ,  Reiko Sugihara ,  Tetsuo Shimizu ,  Shusaku Takagi

IPC分类号： C21D6/02 ,  C22C38/02

CPC分类号： C21D9/46 ,  C21D8/0205 ,  C22C38/02 ,  C22C38/04 ,  C22C38/12 ,  C22C38/14

摘要： The present invention provides a hot-rolled high strength steel sheet in which, without using expensive Mo, by effectively using Ti which is an inexpensive element and the amount of precipitation hardening of which is large, both ductility and stretch-flangeability are improved at a tensile strength of 780 MPa or higher, and excellent tensile fatigue properties are exhibited; and a method for producing the hot-rolled high strength steel sheet. A hot-rolled high strength steel sheet having a composition including, in percent by mass, C: 0.06% to 0.15%, Si: 1.2% or less, Mn: 0.5% to 1.6%, P: 0.04% or less, S: 0.005% or less, Al: 0.05% or less, and Ti: 0.03% to 0.20%, the balance being Fe and incidental impurities, wherein the steel sheet has a structure in which the volume fraction of ferrite is 50% to 90%, the balance is substantially bainite, the total volume fraction of ferrite and bainite is 95% or more, precipitates containing Ti are precipitated in the ferrite, and the precipitates have an average diameter of 20 nm or less; and 80% or more of the Ti content in the steel is precipitated.

摘要翻译： 本发明提供一种热成型高强度钢板，其中，通过有效地使用廉价元素的Ti，析出硬化量大，不使用昂贵的Mo，可以提高延展性和拉伸凸缘性， 拉伸强度为780MPa以上，拉伸疲劳特性优异; 以及制造该热轧高强度钢板的方法。 1.一种热塑性高强度钢板，其组成为：C：0.06〜0.15％，Si：1.2％以下，Mn：0.5〜1.6％，P：0.04％以下，S： 0.005％以下，Al：0.05％以下，Ti：0.03％〜0.20％，余量为Fe和附带杂质，其中，铁素体的体积分率为50〜90％的结构， 余量基本上是贝氏体，铁素体和贝氏体的总体积分率为95％以上，含有Ti的析出物析出在铁素体中，析出物的平均直径为20nm以下， 钢中的Ti含量为80％以上。

公开(公告)号：US20070142513A1

公开(公告)日：2007-06-21

申请号：US11312570

申请日：2005-12-21

申请人： Nobuhiko Tsuda ,  Yoshinori Nanba ,  Yasuhiko Sawada ,  Tetsuo Shimizu

发明人： Nobuhiko Tsuda ,  Yoshinori Nanba ,  Yasuhiko Sawada ,  Tetsuo Shimizu

IPC分类号： C08K5/42

CPC分类号： C08K5/42

摘要： The present invention provides a surfactant making it possible to obtain particles comprising a fluoropolymer at a size smaller in diameter in an aqueous dispersion obtained by polymerization in the presence of the same. The present invention is a surfactant comprising a fluorine-containing-sulfobutanedioic-acid-ester derivative represented by the general formula (i): Y—Rf1—(CH2)m—OCOCH(SO3M)-CH2COO—(CH2)n—Rf2—Y  (i) wherein Y represents hydrogen atom or fluorine atom; when Y is hydrogen atom, one of Rf1 and Rf2 is —(CF2CF2)3— and the other is —(CF2CF2)2— or —(CF2CF2)3— and, when Y is fluorine atom, Rf1 and Rf2 are the same or different and each is a divalent hydrocarbon group containing 1 to 4 carbon atoms and containing at least one fluorine atom; m and n are the same or different and each represents an integer of 1 to 3; and M represents NH4, Li, Na, K or H.

摘要翻译： 本发明提供了一种表面活性剂，其可以获得包含通过在其存在下通过聚合获得的水分散体中的直径小的含氟聚合物的颗粒。 本发明是包含由通式（i）表示的含氟磺基丁二酸 - 酯衍生物的表面活性剂：＆lt;线内配方说明=“在线式”末端=“铅”→> Y - （CH 2） - （O 3 M）-CH 2 - （CH 2） ＆lt;＆lt;＆lt; COO-（CH 2）＆gt;＆lt; 2＆lt; 2＆lt; 2＆gt; -Y（i） 其中Y代表氢原子或氟原子; 当Y是氢原子时，Rf 1和Rf 2之一是 - （CF 2 CH 2 CH 2） （CF 2）2 - 或 - （CF 2）2 - - - （CF 2）2 - R 2和R 2可以相同或不同，并且当Y是氟原子时，R f'1和R f'2 < 各自是含有1至4个碳原子并含有至少一个氟原子的二价烃基; m和n相同或不同，各自表示1〜3的整数。 M表示NH 4，Li，Na，K或H.

公开(公告)号：US06930159B1

公开(公告)日：2005-08-16

申请号：US09936495

申请日：2000-03-10

申请人： Shigeru Morita ,  Hirotoshi Sakashita ,  Takayuki Araki ,  Tetsuo Shimizu

发明人： Shigeru Morita ,  Hirotoshi Sakashita ,  Takayuki Araki ,  Tetsuo Shimizu

IPC分类号： C08F16/24 ,  C08F290/06 ,  C08F120/22

CPC分类号： C08F16/24 ,  C08F290/062

摘要： A fluorine-containing allyl ether polymer having a number average molecular weight of 1,000 to 1,000,000 and consisting of chains of at least one repeating unit of the formula: wherein A is an organic group having 1 to 100 carbon atoms.

摘要翻译： 一种数均分子量为1,000至1,000,000的含氟烯丙基醚聚合物，由至少一种下式重复单元的链组成：其中A为具有1至100个碳原子的有机基团。

公开(公告)号：US06894758B1

公开(公告)日：2005-05-17

申请号：US09700129

申请日：2000-03-08

申请人： Takeshi Hagiwara ,  Keiichi Suehiro ,  Tetsuo Shimizu

发明人： Takeshi Hagiwara ,  Keiichi Suehiro ,  Tetsuo Shimizu

IPC分类号： G02F1/13 ,  G02F1/1333 ,  G02F1/1337 ,  G02F1/1345

CPC分类号： G02F1/13452 ,  G02F1/133345 ,  G02F1/1337 ,  G02F2001/13456

摘要： For providing a liquid crystal device comprising a structure capable of uniformly supporting a terrace area in the liquid crystal device, a pair of insulation films 112 are formed on the terrace area 11a so as to cover a part of wiring lines 131a and 131b simultaneously with forming the insulation films 112 on electrodes 111 using the same material as the insulation film on the electrodes, and an orientation film 113 is additionally formed on the insulation films 112. The orientation film 113 is also formed on the insulation films 112 formed on the terrace area 11a, and the orientation film 113 is formed so as to expand out of the outer edge of the insulation films 112.

摘要翻译： 为了提供一种包括能够均匀地支撑液晶装置中的平台区域的结构的液晶装置，在平台区域11a上形成一对绝缘膜112，以覆盖布线131a和131b的一部分 同时使用与电极上的绝缘膜相同的材料在电极111上形成绝缘膜112，并且在绝缘膜112上另外形成取向膜113。 取向膜113也形成在形成在露台区域11a上的绝缘膜112上，并且取向膜113形成为从绝缘膜112的外边缘扩展出来。

公开(公告)号：US06531557B1

公开(公告)日：2003-03-11

申请号：US09242272

申请日：1999-03-12

申请人： Kazutaka Hosokawa ,  Yoshinori Nanba ,  Takahisa Aoyama ,  Tetsuo Shimizu

发明人： Kazutaka Hosokawa ,  Yoshinori Nanba ,  Takahisa Aoyama ,  Tetsuo Shimizu

IPC分类号： C08F21426

CPC分类号： C08F214/262

摘要： A modified polytetrafluoroethylene fine powder containing agglomerates of colloidal particles with an average particle size of from 0.05 to 0.5 &mgr;m which comprise a copolymer of tetrafluoroethylene and an olefin-monomer represented by X(CF2)nOCF═CF2 in which X is a hydrogen atom, a fluorine atom or a chlorine atom, and n is an integer of 1 to 6, and/or C3F7(OCF2CF2CF2)m[OCF(CF3)CF2]pOCF═CF2 in which m and p are independently an integer of 0 to 4, provided that the sum of m and p is not 0 (zero), a content of the olefin monomer being from 0.02 to 0.3 wt. %, wherein the copolymer has a molecular weight distribution Mw/Mn of from 1.5 to 4.5 and a standard specific gravity of from 2.135 to 2.175. This modified polytetrafluoroethylene has good paste extrudability, and provides molded articles having good mechanical properties, in particular, pressure resistance.

摘要翻译： 一种改性聚四氟乙烯细粉末，其含有平均粒径为0.05〜0.5μm的胶体粒子的附聚物，其包含由X（CF 2）n OCF = CF 2（其中X为氢原子）表示的四氟乙烯与烯烃单体的共聚物， 氟原子或氯原子，n为1〜6的整数，和/或C 3 F 7（OCF 2 CF 2 CF 2）m [OCF（CF 3）CF 2] p OCF = CF 2，其中m和p分别为0〜4的整数， m和p的和不为0（零），烯烃单体的含量为0.02-0.3重量％。 ％，其中共聚物的分子量分布Mw / Mn为1.5〜4.5，标准比重为2.135〜2.175。 该改性聚四氟乙烯具有良好的糊料挤出性，并提供具有良好机械性能，特别是耐压性的模制品。

公开(公告)号：US06425963B1

公开(公告)日：2002-07-30

申请号：US09490267

申请日：2000-01-24

申请人： Shinjiro Kaneko ,  Tetsuo Shimizu ,  Osamu Furukimi

发明人： Shinjiro Kaneko ,  Tetsuo Shimizu ,  Osamu Furukimi

IPC分类号： C22C3800

CPC分类号： C21D8/0226 ,  C22C38/001 ,  C22C38/04

摘要： High tensile strength hot-rolled steel sheet suitable for use in interior materials for automobiles and a method for producing the same, in which bake hardenability, fatigue resistance, crash resistance, and resistance to room temperature aging are improved, containing 0.01% to 0.12% by weight of carbon, 2.0% by weight or less of silicon, 0.01% to 3.0% by weight of manganese, 0.2% by weight or less of phosphorus, 0.001% to 0.1% by weight of aluminum, and 0.003% to 0.02% by weight of nitrogen and subjected to hot rolling and cooling at a cooling rate of 50° C./s or more within 0.5 second after hot rolling; the hot-rolled steel sheet has a structure including a ferrite having an average grain diameter of 8 &mgr;m or less as a primary phase, the amount of solute Nitrogen ranges from 0.003% to 0.01%, and the ratio, Ngb/Ng, of an average concentration Ngb of nitrogen dissolved in the ferrite grain boundary to an average concentration Ng of nitrogen dissolved in ferrite grains ranges from 100 to 10,000.

摘要翻译： 适用于汽车内饰材料的高强度热轧钢板及其制造方法，其中烘烤淬透性，耐疲劳性，抗冲击性和耐室温老化性均得到改善，含有0.01％至0.12％ 的碳，2.0重量％以下的硅，0.01〜3.0重量％的锰，0.2重量％以下的磷，0.001〜0.1重量％的铝，0.003〜0.02重量％ 并在热轧后0.5秒内以50℃/ s以上的冷却速度进行热轧冷却; 热轧钢板具有平均粒径为8μm以下的铁素体作为主相的结构，溶质氮的含量为0.003〜0.01％，Ngb / Ng的比例为 溶解在铁素体晶界中的氮的平均浓度Ngb与溶解在铁素体晶粒中的氮的平均浓度Ng的关系为100〜10000。