公开(公告)号：US5122527A

公开(公告)日：1992-06-16

申请号：US699068

申请日：1991-05-13

申请人： Kozo Shiokawa ,  Shinichi Tsuboi ,  Shoko Sasaki ,  Koichi Moriya ,  Yumi Hattori ,  Katsuhiko Shibuya

发明人： Kozo Shiokawa ,  Shinichi Tsuboi ,  Shoko Sasaki ,  Koichi Moriya ,  Yumi Hattori ,  Katsuhiko Shibuya

IPC分类号： A01N43/90 ,  A01N47/12 ,  A01N47/18 ,  C07D471/04 ,  C07D487/04 ,  C07D498/04 ,  C07D513/04

CPC分类号： C07D471/04 ,  A01N43/90 ,  A01N47/18 ,  C07D487/04 ,  C07D513/04

摘要： Nitro-substituted heterocyclic compounds of the formula (I) ##STR1## wherein R is hydrogen or alkyl,Z is an optionally substituted aryl or optionally substituted heterocyclic groun containing at least one atom selected from N, O and S,A is optionally substituted ethylene or optionally substituted trimethylene, andB stands for 2 or 3 members of a heterocyclic ring which is formed, together with the adjacent C-atom and N-atom and at least one of said members may represent a hetero atom and may be optionally substituted, provided that when B stands for 3 members, two of which are carbon atoms and the other one is a nitrogen atom which is located in the middle of the three members, then at least one of said two carbon atoms must be substituted by a keto group. Such compounds being useful as insecticides.

公开(公告)号：US5084467A

公开(公告)日：1992-01-28

申请号：US478862

申请日：1990-02-12

申请人： Kozo Shiokawa ,  Shinichi Tsuboi ,  Koichi Moriya ,  Yumi Hattori ,  Ikuro Honda ,  Katsuhiko Shibuya

发明人： Kozo Shiokawa ,  Shinichi Tsuboi ,  Koichi Moriya ,  Yumi Hattori ,  Ikuro Honda ,  Katsuhiko Shibuya

IPC分类号： A01N43/40 ,  A01N47/42 ,  A01N47/44 ,  C07D213/38 ,  C07D213/61 ,  C07D277/32

CPC分类号： C07D277/32 ,  A01N43/40 ,  A01N47/42 ,  A01N47/44 ,  C07D213/38 ,  C07D213/61 ,  H01L2224/48091 ,  H01L2224/48137 ,  H01L2224/49175 ,  H01L2924/19107 ,  Y10T29/49004 ,  Y10T29/49144 ,  Y10T29/49162

摘要： Insecticidally active nitro compounds of the formula ##STR1## wherein R.sup.1 is hydrogen, cyano or alkyl,R.sup.2 is hydrogen or an organic radical,R.sup.3 is --O--R.sup.4, --S--R.sup.4 or ##STR2## R.sup.4 is an organic radical, R.sup.5 and R.sup.6 are hydrogen or organic radicals,Y is CH or N, andZ is an optionally substituted 5- or 6-membered heterocyclic group,with certain conditions and exceptions.

公开(公告)号：US5081132A

公开(公告)日：1992-01-14

申请号：US518684

申请日：1990-05-03

申请人： Kozo Shiokawa ,  Shinichi Tsuboi ,  Koichi Moriya ,  Yumi Hattori ,  Ikuro Honda ,  Katsuhiko Shibuya

发明人： Kozo Shiokawa ,  Shinichi Tsuboi ,  Koichi Moriya ,  Yumi Hattori ,  Ikuro Honda ,  Katsuhiko Shibuya

IPC分类号： C07D239/48 ,  A01N43/40 ,  A01N43/54 ,  A01N43/56 ,  A01N43/60 ,  A01N43/647 ,  A01N43/78 ,  A01N43/80 ,  A01N43/82 ,  A01N43/824 ,  A01N47/18 ,  C07D213/61 ,  C07D213/74 ,  C07D213/79 ,  C07D239/06 ,  C07D401/04 ,  C07D401/12 ,  C07D401/14 ,  C07D403/12 ,  C07D407/12 ,  C07D413/12 ,  C07D417/12

CPC分类号： C07D401/14 ,  A01N43/40 ,  A01N43/54 ,  A01N43/56 ,  A01N43/60 ,  A01N43/647 ,  A01N43/78 ,  A01N43/80 ,  A01N43/82 ,  A01N47/18 ,  C07D213/74 ,  C07D239/06 ,  C07D401/12 ,  C07D417/12

摘要： Insecticidal nitro-substituted heterocyclic compounds of the formula ##STR1## wherein R.sup.1 represents hydrogen, cyano or C.sub.1-4 alkyl,m represents 0 or 1,n represents 0 or 1,R.sup.2 represents hydrogen or C.sub.1-4 alkyl,R.sup.3 represents hydrogen, C.sub.1-6 alkyl optionally substituted by cyano, halogen or C.sub.1-4 alkoxy, C.sub.3-4 alkenyl, C.sub.3-4 alkynyl, optionally substituted phenyl, optionally substituted benzyl or optionally substituted heterocyclic-methyl,T represents an optionally substituted two- or three-membered divalent or trivalent chain comprising hetero atoms and/or carbon atom, andA represents optionally substituted phenyl or an optionally substituted five- or six-membered heterocyclic radical comprising at least one hetero atom selected from the group consisting of N, O and S.

公开(公告)号：US5061731A

公开(公告)日：1991-10-29

申请号：US543259

申请日：1990-06-25

申请人： Yoshio Kurahashi ,  Kozo Shiokawa ,  Shinzo Kagabu ,  Shinji Sakawa ,  Koichi Moriya

发明人： Yoshio Kurahashi ,  Kozo Shiokawa ,  Shinzo Kagabu ,  Shinji Sakawa ,  Koichi Moriya

IPC分类号： A01N53/00 ,  A01N53/12 ,  C07C61/15

CPC分类号： C07C61/15 ,  A01N53/00

摘要： Novel fungicidally active N-benzyl-cyclopropanecarboxamides of the formula ##STR1## wherein X represents halogen,n represents 1 or 2,R.sup.1 represents hydrogen, halogen or lower alkyl,R.sup.2 represents lower alkyl, halogen-substituted lower alkyl or hydrogen, andR.sup.3 represents hydrogen or lower alkyl.The acid components thereof, other than when R.sup.1 is hydrogen or alkyl and R.sup.2 is hydrogen or alkyl, are also new.

公开(公告)号：US5034524A

公开(公告)日：1991-07-23

申请号：US610495

申请日：1990-11-07

申请人： Kozo Shiokawa ,  Shinichi Tsuboi ,  Koichi Moriya ,  Yumi Hattori ,  Ikuro Honda ,  Katsuhiko Shibuya

发明人： Kozo Shiokawa ,  Shinichi Tsuboi ,  Koichi Moriya ,  Yumi Hattori ,  Ikuro Honda ,  Katsuhiko Shibuya

IPC分类号： A01N43/64 ,  A01N43/653 ,  A01N43/72 ,  A01N43/80 ,  A01N43/832 ,  A01N43/836 ,  A01N43/84 ,  A01N43/88 ,  A01N47/40 ,  A01N51/00 ,  C07D401/06 ,  C07D401/14 ,  C07D403/06 ,  C07D405/06 ,  C07D409/06 ,  C07D413/06 ,  C07D417/06 ,  C07D419/06

CPC分类号： C07D401/06 ,  A01N47/40 ,  A01N51/00 ,  C07D401/14 ,  C07D403/06 ,  C07D405/06 ,  C07D409/06 ,  C07D413/06 ,  C07D417/06 ,  C07D419/06

摘要： Insecticidal heterocyclic compounds of the formula ##STR1## wherein A represents a five-membered or six-membered heteroaryl group containing one to three hetero atoms selected from the group consisting of S, O and N, said heteroaryl group being unsubstituted or substituted by a hologen atom or C.sub.1-4 alkyl group, Z represents a three-membered straight chain, each member being selected from the group consisting of CH.sub.2 -, O, S and N-R.sup.2 with at least one of said three members being O, S or N-R.sup.2, E represents CH.sub.2, O, S or N-R.sup.2, wherein R.sup.2 represents a hydrogen atom, a C.sub.1-4 alkyl group, a C.sub.1-4 alkoxy group or the group ##STR2## wherein R.sup.3 represents a hydrogen atom or halogen atom, X represents CH or N, Y represents a nitro group or cyano group, and R.sup.1 represents a hydrogen atom or methyl group.

公开(公告)号：US4988712A

公开(公告)日：1991-01-29

申请号：US393508

申请日：1989-08-14

申请人： Kozo Shiokawa ,  Shinichi Tsuboi ,  Shoko Sasaki ,  Koichi Moriya ,  Yumi Hattori ,  Katsuhiko Shibuya

发明人： Kozo Shiokawa ,  Shinichi Tsuboi ,  Shoko Sasaki ,  Koichi Moriya ,  Yumi Hattori ,  Katsuhiko Shibuya

IPC分类号： A01N43/40 ,  A01N43/50 ,  A01N43/78 ,  A01N51/00 ,  C07D213/26 ,  C07D213/57 ,  C07D213/74 ,  C07D213/75 ,  C07D213/76 ,  C07D213/77 ,  C07D239/42 ,  C07D277/32 ,  C07D277/48 ,  C07D277/50 ,  C07D401/06 ,  C07D403/06 ,  C07D413/06 ,  C07D417/06

CPC分类号： C07D213/75 ,  A01N43/50 ,  A01N51/00 ,  C07D213/77 ,  C07D239/42 ,  C07D277/32 ,  C07D277/48 ,  C07D277/50 ,  C07D401/06 ,  C07D403/06 ,  C07D413/06 ,  C07D417/06

摘要： Novel insecticidally active heterocyclic compounds of the formula ##STR1## wherein W represents a substituted pyridyl group, or a 5- or 6-membered optionally substituted heterocyclic group containing at least two hetero atoms selected from oxygen, sulfur and nitrogen atoms,R represents a hydrogen atom or an alkyl group,Y represents =N-- or ##STR2## R' represents a hydrogen atom, an alkyl group, an aryl group, an acyl group, an alkoxycarbonyl group or a cyano group,Z represents a nitro group or a cyano group, andT represents 3 or 4 optionally substituted ring members of a 5- or 6-membered unsaturated heterocyclic ring which it forms together with the adjoining carbon atom and nitrogen atom, said 5- or 6-membered unsaturated heterocyclic ring containing 1 to 3 hetero atoms which are selected from oxygen, sulfur and nitrogen atoms and at least one of which is a nitrogen atom.

公开(公告)号：US4849432A

公开(公告)日：1989-07-18

申请号：US17641

申请日：1987-02-24

申请人： Kozo Shiokawa ,  Shinichi Tsuboi ,  Shinzo Kagabu ,  Shoko Sasaki ,  Koichi Moriya ,  Yumi Hattori

发明人： Kozo Shiokawa ,  Shinichi Tsuboi ,  Shinzo Kagabu ,  Shoko Sasaki ,  Koichi Moriya ,  Yumi Hattori

IPC分类号： C07D237/00 ,  A01N43/50 ,  A01N43/54 ,  A01N43/60 ,  A01N43/78 ,  A01N43/86 ,  A01N47/40 ,  C07D277/20 ,  C07D277/28 ,  C07D277/32 ,  C07D277/38 ,  C07D401/06 ,  C07D403/06 ,  C07D413/06 ,  C07D417/06

CPC分类号： C07D401/06 ,  A01N47/40 ,  C07D277/28 ,  C07D403/06 ,  C07D413/06 ,  C07D417/06

摘要： Novel heterocyclic compounds of the formula ##STR1## wherein, R.sup.1 represents a hydrogen atom or an alkyl group, A represents an ethylene group which may be substituted by alkyl or a trimethylene group which may be substituted by alkyl, X represents an oxygen or sulfur atom or the group ##STR2## in which R.sup.2 represents a hydrogen atom of an optionally substituted alkyl, an alkenyl, an alkynyl or an acyl group, and R.sup.3 represents a hydrogen atom or an alkyl group, and Z represents an optionally sibstituted 5- or 6-membered heterocyclic group which contains at least two hetero atoms selected from oxygen, sulfur and nitrogen atoms, or an optionally substituted 3- or 4-pyridyl group.The above defined novel heterocyclic compounds of formula (I) exhibit powerful insecticidal properties.

摘要翻译： 式（I）的新型杂环化合物其中，R1表示氢原子或烷基，A表示可以被可被烷基取代的烷基或三亚甲基取代的亚乙基，X表示氧 或硫原子或其中R 2表示任选取代的烷基，烯基，炔基或酰基的氢原子的基团，且R 3表示氢原子或烷基，Z表示任选取代的5 - 或6元杂环基，或含有至少两个选自氧，硫和氮原子的杂原子，或任选取代的3-或4-吡啶基。 上述定义的式（I）新颖杂环化合物具有强大的杀虫性能。

公开(公告)号：US4806553A

公开(公告)日：1989-02-21

申请号：US64267

申请日：1987-06-18

申请人： Kozo Shiokawa ,  Shinichi Tsuboi ,  Shinzo Kagabu ,  Shoko Sasaki ,  Koichi Moriya ,  Yumi Hattori

发明人： Kozo Shiokawa ,  Shinichi Tsuboi ,  Shinzo Kagabu ,  Shoko Sasaki ,  Koichi Moriya ,  Yumi Hattori

IPC分类号： C07D213/36 ,  A01N43/40 ,  A01N43/54 ,  A01N43/56 ,  A01N43/58 ,  A01N43/60 ,  A01N43/74 ,  A01N43/76 ,  A01N43/78 ,  A01N43/80 ,  A01N43/824 ,  A01N43/828 ,  A01N43/832 ,  A01N47/42 ,  C07D213/38 ,  C07D213/61 ,  C07D213/64 ,  C07D213/70 ,  C07D231/12 ,  C07D237/08 ,  C07D237/12 ,  C07D239/26 ,  C07D239/28 ,  C07D239/30 ,  C07D241/12 ,  C07D261/08 ,  C07D263/32 ,  C07D271/10 ,  C07D275/02 ,  C07D277/20 ,  C07D277/28 ,  C07D277/32 ,  C07D285/04 ,  C07D285/06 ,  C07D285/10 ,  C07D521/00 ,  A61K31/44 ,  C07D213/26

CPC分类号： C07D213/64 ,  A01N43/40 ,  A01N43/74 ,  A01N43/80 ,  A01N47/42 ,  C07D213/38 ,  C07D213/61 ,  C07D213/70 ,  C07D231/12 ,  C07D237/08 ,  C07D237/12 ,  C07D239/26 ,  C07D239/30 ,  C07D241/12 ,  C07D261/08 ,  C07D263/32 ,  C07D271/10 ,  C07D275/02 ,  C07D277/32 ,  C07D285/06 ,  C07D285/10

摘要： There are provided insecticidally active alkylenediamines of the formula ##STR1## wherein W.sup.1 stands for a 5- or 6-membered heterocyclic group which may be substituted, containing at least one hetero atom selected from, O, S and N, R.sup.1, R.sup.2 and R.sup.3 are hydrogen or alkyl and R.sup.4, X, Y and Z have the meanings as given in the specification.The new alkylenediamines can be prepared according to different preparation methods and exhibit a strong insecticidal activity.

摘要翻译： 提供了具有下式的杀虫活性亚烷基二胺：其中W1代表可被取代的含有至少一个选自O，S和N，R 1，R 2和R 3的杂原子的5或6元杂环基 是氢或烷基，R4，X，Y和Z具有说明书中给出的含义。 新的亚烷基二胺可以根据不同的制备方法制备，具有很强的杀虫活性。

公开(公告)号：US4747865A

公开(公告)日：1988-05-31

申请号：US934774

申请日：1986-11-25

申请人： Kozo Shiokawa ,  Koichi Moriya ,  Toshio Goto ,  Atsumi Kamochi ,  Seishi Ito ,  Mitsugu Horita

发明人： Kozo Shiokawa ,  Koichi Moriya ,  Toshio Goto ,  Atsumi Kamochi ,  Seishi Ito ,  Mitsugu Horita

IPC分类号： A01N43/76 ,  A01N43/78 ,  C07D263/58 ,  C07D277/68

CPC分类号： C07D263/58 ,  A01N43/76 ,  C07D277/68

摘要： Novel substituted phenoxyalkanecarboxylic acid esters of the formula ##STR1## in which R.sup.1 and R.sup.2, independently of one another, are a hydrogen atom, a halogen atom, a lower alkyl group or a nitro group, orR.sup.1 and R.sup.2, together with the benzene ring to which they are bonded, are a naphthalene ring,R.sup.3 and R.sup.4, independently of one another, are a hydrogen atom or a methyl group,n is 1 or 2,m is 0 or 1,X is an oxygen atom, a sulfur atom, a sulfonyl group or a group of the formula ##STR2## in which R.sup.6 is a lower alkyl group, R.sup.5 is a hydrogen atom or a halogen atom, andY is an oxygen atom or a sulfur atom, and the use of the new compounds as herbicides.

摘要翻译： 式（Ⅰ）的新型取代的苯氧亚硬脂酸酯：其中R 1和R 2彼此独立地是氢原子，卤原子，低级烷基或硝基，或者R 1和R 2 与它们所键合的苯环一起为萘环，R 3和R 4彼此独立地为氢原子或甲基，n为1或2，m为0或1，X为 氧原子，硫原子，磺酰基或式“IMAGE”的基团，其中R6是低级烷基，R5是氢原子或卤素原子，Y是氧原子或硫原子，和 使用新化合物作为除草剂。

公开(公告)号：US4659370A

公开(公告)日：1987-04-21

申请号：US612933

申请日：1984-05-22

申请人： Junichi Saito ,  Kazuomi Yasui ,  Kozo Shiokawa ,  Atsumi Kamochi

发明人： Junichi Saito ,  Kazuomi Yasui ,  Kozo Shiokawa ,  Atsumi Kamochi

IPC分类号： A01N37/14 ,  A01N39/02 ,  A01N41/10 ,  A01N43/40 ,  C07C67/00 ,  C07C313/00 ,  C07C315/02 ,  C07C315/04 ,  C07C317/00 ,  C07C317/18 ,  C07C323/12 ,  C07C323/16 ,  C07C323/65 ,  C07D213/64 ,  C07D213/643 ,  C07C69/76

CPC分类号： C07D213/643 ,  A01N39/02 ,  A01N41/10 ,  A01N43/40 ,  C07C317/00 ,  C07C321/00 ,  C07C323/00

摘要： Novel substituted phenoxypropionates of the formula ##STR1## in which Ar represents the group ##STR2## or the group ##STR3## in which Y represents a halogen atom or a trifluoromethyl group andb is 1 or 2,R represents a hydrogen atom or a methyl group,X represents a hydrogen atom, a halogen atom, a nitro group, a lower alkyl group or a lower alkoxy group,a and m each independently is 1 or 2, andn is 0, 1 or 2,and their use as herbicides.Novel intermediates of the formulae ##STR4## in which formulae R, X, m, n and a have the meanings given above,Z.sup.1 is a halogen atom andm is a hydrogen atom or an alkali metal atom.

摘要翻译： 其中Ar表示其中Y表示卤素原子或三氟甲基的基团或基团的新颖取代的苯氧基丙酸酯，其中Ar表示1或2，R表示 氢原子或甲基，X表示氢原子，卤素原子，硝基，低级烷基或低级烷氧基，a和m各自独立地为1或2，n为0,1或2 ，以及它们作为除草剂的用途。 式（III）的化合物的新中间体其中式R，X，m，n和a具有上述含义，Z1是卤素原子，m是氢原子或 碱金属原子。