公开(公告)号：US06890894B2

公开(公告)日：2005-05-10

申请号：US10422658

申请日：2003-04-24

申请人： Daniel Stedman Connor ,  Jeffrey John Scheibel ,  Deborah Jean Back ,  Toan Trinh ,  Phillip Kyle Vinson ,  Roland George Severson ,  Thomas Anthony Cripe ,  James Charles Theophile Roger Burckett-St. Laurent ,  Mark Robert Sivik ,  Errol Hoffman Wahl ,  Gayle Marie Frankenbach ,  Marc Johan Declercq ,  Hugo Jean Marie Demeyere

发明人： Daniel Stedman Connor ,  Jeffrey John Scheibel ,  Deborah Jean Back ,  Toan Trinh ,  Phillip Kyle Vinson ,  Roland George Severson ,  Thomas Anthony Cripe ,  James Charles Theophile Roger Burckett-St. Laurent ,  Mark Robert Sivik ,  Errol Hoffman Wahl ,  Gayle Marie Frankenbach ,  Marc Johan Declercq ,  Hugo Jean Marie Demeyere

IPC分类号： C11D1/04 ,  C11D1/62 ,  C11D1/65 ,  C11D1/66 ,  C11D3/00 ,  C11D3/20 ,  C11D3/43 ,  C11D9/00 ,  C11D10/04

CPC分类号： C11D3/2093 ,  A61K8/361 ,  A61Q19/00 ,  C11D1/04 ,  C11D1/62 ,  C11D3/0015 ,  C11D3/2079 ,  C11D9/005 ,  C11D9/007 ,  C11D10/04

摘要： Novel fatty acids and derivatives thereof such as salts, new surfactant systems comprising one or more of these compounds, consumer products such as laundry products, personal care products, pharmaceutical compositions, industrial cleaners, and the like comprising said compounds or surfactant systems.

摘要翻译： 新型脂肪酸及其衍生物如盐，包含一种或多种这些化合物的新型表面活性剂体系，消费品如洗衣产品，个人护理产品，药物组合物，工业清洁剂等，其包含所述化合物或表面活性剂体系。

公开(公告)号：US06774099B1

公开(公告)日：2004-08-10

申请号：US09889632

申请日：2001-07-19

申请人： Jeffrey John Scheibel ,  Thomas Anthony Cripe ,  Kevin Lee Kott ,  Daniel Stedman Connor ,  James Charles Theophile Roger Burckett-St. Laurent ,  Phillip Kyle Vinson ,  William Michael Scheper ,  Chandrika Kasturi

发明人： Jeffrey John Scheibel ,  Thomas Anthony Cripe ,  Kevin Lee Kott ,  Daniel Stedman Connor ,  James Charles Theophile Roger Burckett-St. Laurent ,  Phillip Kyle Vinson ,  William Michael Scheper ,  Chandrika Kasturi

IPC分类号： C11D1700

CPC分类号： C11D3/0084 ,  C11D1/22 ,  C11D1/75 ,  C11D1/83 ,  C11D3/044 ,  C11D3/046 ,  C11D3/30 ,  C11D3/38618 ,  C11D3/38627

摘要： A hand dishwashing compositions comprising; a) about 0.1% to about 99.9% by weight of said composition of an alkylarylsulfonate surfactant system comprising from about 10% to about 100% by weight of said surfactant system of two or more crystallinity-disrupted alkylarylsulfonate surfactants of formula (B—Ar—D)a(Mq+)b wherein D is SO3—, M is a cation or cation mixture, q is the valence of said cation, a and b are numbers selected such that said composition is electroneutral; Ar is selected from benzene, toluene, and combinations thereof; and B comprises the sum of at least one primary hydrocarbyl moiety containing from 5 to 20 carbon atoms and one or more crystallinity-disrupting moieties, wherein said crystallinity-disrupting moieties interrupt or branch from said hydrocarbyl moiety; and wherein said alkylarylsulfonate surfactant system has crystallinity disruption to the extent that its Sodium Critical Solubility Temperature, as measured by the CST Test, is no more than about 40° C.; and wherein further said alkylarylsulfonate surfactant system has at least one of the following properties: percentage biodegradation, as measured by the modified SCAS test, that exceeds tetrapropylene benzene sulfonate; and weight ratio of nonquaternary to quaternary carbon atoms in B of at least about 5:1; and b) from about 0.00001% to about 99.9% by weight of said composition of a conventional hand dishwashing adjunct; c) from about 0.01% to about 7% by weight of composition of a divalent ion selected from the group consisting of magnesium, calcium and mixtures thereof.

摘要翻译： 一种手洗餐具组合物，其包含： a）约0.1重量％至约99.9重量％的所述组合物的烷基芳基磺酸盐表面活性剂体系，其包含约10重量％至约100重量％的所述表面活性剂体系的两种或更多种结晶度破坏的烷基芳基磺酸盐表面活性剂（B-Ar- D）a（M ）b其中D是SO 3 - ，M是阳离子或阳离子混合物，q是所述阳离子的化合价，a和b是选择的数字，使得所述组合物是电中性的; Ar选自苯，甲苯及其组合; 和B包含至少一个含有5至20个碳原子的一级烃基部分和一种或多种结晶破坏部分的总和，其中所述结晶破坏部分中断或从所述烃基部分分支; 并且其中所述烷基芳基磺酸盐表面活性剂体系具有结晶度破坏程度，其通过CST试验测量的其钠临界溶解度温度不超过约40℃; 并且其中所述烷基芳基磺酸盐表面活性剂体系具有以下特性中的至少一个：通过改性SCAS测试测量的超过四丙烯苯磺酸盐的百分比生物降解; 并且B中非季铵碳原子的重量比至少约为5：1; 和b）所述组合物的常规手洗餐具辅料的约0.00001重量％至约99.9重量％ c）约0.01重量％至约7重量％的组合物，选自镁，钙及其混合物的二价离子。

公开(公告)号：US06593285B1

公开(公告)日：2003-07-15

申请号：US09478908

申请日：2000-01-07

申请人： Jeffrey John Scheibel ,  Thomas Anthony Cripe ,  Kevin Lee Kott ,  Daniel Stedman Connor ,  Phillip Kyle Vinson

发明人： Jeffrey John Scheibel ,  Thomas Anthony Cripe ,  Kevin Lee Kott ,  Daniel Stedman Connor ,  Phillip Kyle Vinson

IPC分类号： C11D1750

CPC分类号： C11D1/37 ,  C11D1/22

摘要： A surfactant composition comprising: alkylarylsulfonate surfactant system comprising at least two isomers of the alkylarylsulfonate surfactant of the formula:  wherein: L is an acyclic aliphatic hydrocarbyl of from 6 to 18 carbon atoms in total; M is a cation or cation mixture and q is the valence thereof; a and b are numbers selected such that said alkylarylsulfonate surfactant is electroneutral; R′, R″ and R′″ are independently selected from H and C1 to C3 alkyl; both of R′ and R″ are nonterminally attached to L and at least one of R′ and R″ is C1 to C3 alkyl; and A is aryl;  wherein: said alkylarylsulfonate surfactant system comprises two or more isomers with respect to positions of attachment of R′, R″ and A to L; in at least about 40% of said composition, A is attached to L in the position which is selected from positions alpha- and beta- to either of the two terminal carbon atoms of L; and  wherein further said alkylarylsulfonate surfactant system has at least one of the following properties: said alkylarylsulfonate surfactant system has a ratio of nonquaternary to quaternary carbon atoms in L of at least about 5:1 by weight, when said quaternary carbon atoms are present; or percentage biodegradation, as measured by the modified SCAS test, that exceeds tetrapropylene benzene sulfonate.

摘要翻译： 一种表面活性剂组合物，其包含：烷基芳基磺酸盐表面活性剂体系，其包含下式的烷基芳基磺酸盐表面活性剂的至少两种异构体：其中：L是总共6至18个碳原子的无环脂族烃基; M是阳离子或阳离子混合物，q是 a和b是选择的数字，使得所述烷基芳基磺酸盐表面活性剂是电中性的; R'，R“和R”'独立地选自H和C 1至C 3烷基; R'和R“都非永久地连接 至L，R'和R“中的至少一个为C 1至C 3烷基; A是芳基; 其中：所述烷基芳基磺酸盐表面活性剂体系包含两个或多个相对于R'，R“和A至L的连接位置的异构体;在至少约40％的所述组合物中，A在选定的位置附着于L 从位于L的两个末端碳原子的α-和β-位置; 并且其中所述烷基芳基磺酸盐表面活性剂体系具有以下性质中的至少一种：当存在所述季碳原子时，所述烷基芳基磺酸盐表面活性剂体系具有至少约5:1重量比的至少约5:1重量比的L中的非季铵碳原子与季碳原子的比例; 如通过改进的SCAS测试所测得的百分比生物降解超过四苯基苯磺酸盐。

公开(公告)号：US06498134B1

公开(公告)日：2002-12-24

申请号：US09889634

申请日：2001-07-19

申请人： Jeffrey John Scheibel ,  Thomas Anthony Cripe ,  Kevin Lee Kott ,  Daniel Stedman Connor ,  Phillip Kyle Vinson ,  William Michael Scheper ,  Chandrika Kasturi

发明人： Jeffrey John Scheibel ,  Thomas Anthony Cripe ,  Kevin Lee Kott ,  Daniel Stedman Connor ,  Phillip Kyle Vinson ,  William Michael Scheper ,  Chandrika Kasturi

IPC分类号： C11D1700

CPC分类号： C11D3/046 ,  C11D1/22 ,  C11D1/72 ,  C11D1/83

摘要： A hand dishwashing composition comprising: i) from about 0.01% to about 99.99% by weight of composition of a surfactant mixture, said surfactant mixture comprising: an alkylarylsulfonate surfactant system comprising at least two alkylarylsulfonate surfactants of the formula (I) wherein L is an acyclic aliphatic hydrocarbyl of from 6 to 18 carbon atoms in total; M is a cation or cation mixture and q is the valence thereof; a and b are numbers selected such that said alkylarylsulfonate surfactant is electroneutral; R′ is selected from H and C1 to C3 alkyl; R″ is selected from H and C1 to C3 alkyl; R′″ is selected from H and C1 to C3 alkyl; both of R′ and R″ are nonterminally attached to L and at least one of R′and R″ is C1 to C3 alkyl; and A is aryl; wherein said alkylarylsulfonate surfactant system comprises two or more isomers with respect to positions of attachment of R′, R″ and A to L; in at least about 60% of said alkylarylsulfonate surfactant system, A is attached to L in the position which is selected from positions alpha- and beta- to either of the two terminal carbon atoms of L; and wherein further said alkylarylsulfonate surfactant system has at least one of the following properties: said alkylarylsulfonate surfactant system has a ratio of nonquaternary to quaternary carbon atoms in L of at least about 5:1 by weight, when said quaternary carbon atoms are present; or percentage biodegradation, as measured by the modified SCAS test, that exceeds tetra propylene benzene sulphonate; ii) from about 0.0001% to about 99.99% by weight of composition of a conventional hand dishwashing adjunct; and iii) from about 0.01% to about 7% by weight of composition of a divalent ion selected from the group consisting of magnesium, calcium and mixtures thereof.

摘要翻译： 一种手洗餐具组合物，其包含：i）组合物的约0.01％至约99.99％的表面活性剂混合物，所述表面活性剂混合物包含：烷基芳基磺酸盐表面活性剂体系，其包含至少两种式（I）的烷基芳基磺酸盐表面活性剂，其中L为 总共6至18个碳原子的无环脂族烃基; M是阳离子或阳离子混合物，q是其化合价; a和b是选择的数字，使得所述烷基芳基磺酸盐表面活性剂是电中性的; R'选自H和C 1至C 3烷基; R“选自H和C 1至C 3烷基; R“'选自H和C 1至C 3烷基; R'和R“都与L非极性相连，R 1和R 2中的至少一个是C 1至C 3烷基; 和A是芳基; 其中所述烷基芳基磺酸盐表面活性剂体系包含关于R'，R“和A至L的连接位置的两个或多个异构体; 在所述烷基芳基磺酸盐表面活性剂体系的至少约60％中，A在选自L的两个末端碳原子的α-和β-位置的位置处连接到L; 并且其中所述烷基芳基磺酸盐表面活性剂体系具有以下特性中的至少一种：当所述季碳原子存在时，所述烷基芳基磺酸盐表面活性剂体系具有至少约5:1重量比的至少约5:1重量比的L中的非季铵碳原子与季碳原子的比率; 或通过改进的SCAS试验测量的生物降解百分比超过四丙烯苯磺酸盐; ii）约0.0001％至约99.99重量％的常规手洗餐具辅料的组成; 和iii）约0.01重量％至约7重量％的组合物，选自镁，钙及其混合物的二价离子。

公开(公告)号：US06342473B1

公开(公告)日：2002-01-29

申请号：US09461590

申请日：1999-12-15

申请人： Kevin Lee Kott ,  Jeffrey John Scheibel ,  Roland George Severson ,  Thomas Anthony Cripe ,  James Charles Theophile Roger Burckett-St. Laurent ,  Joseph Paul Morelli

发明人： Kevin Lee Kott ,  Jeffrey John Scheibel ,  Roland George Severson ,  Thomas Anthony Cripe ,  James Charles Theophile Roger Burckett-St. Laurent ,  Joseph Paul Morelli

IPC分类号： C11D1700

CPC分类号： C11D17/049 ,  C11D1/22 ,  C11D1/37 ,  C11D11/0023

摘要： This invention relates to hard surface cleaning compositions which include modified alkylbenzene sulfonate surfactant mixtures.

摘要翻译： 本发明涉及包含改性烷基苯磺酸盐表面活性剂混合物的硬表面清洁组合物。

公开(公告)号：US20140018279A1

公开(公告)日：2014-01-16

申请号：US13546315

申请日：2012-07-11

申请人： Xinbei Song ,  Jeffrey Scott DuPont ,  Jeffrey John Scheibel ,  Scott Leroy Cron

发明人： Xinbei Song ,  Jeffrey Scott DuPont ,  Jeffrey John Scheibel ,  Scott Leroy Cron

IPC分类号： C11D3/60 ,  C11D17/00

CPC分类号： C11D3/0073 ,  C11D3/378 ,  C11D3/3915 ,  C11D11/0023 ,  C11D17/045

摘要： Automatic dishwashing detergent compositions containing an esterified benzene sulfonate, a peroxide source, and a non-ionic surfactant provide a “3-in-1” benefit of red stain removal on plastics, tea stains on ceramics, and corrosion inhibition on metals.

摘要翻译： 包含酯化苯磺酸盐，过氧化物源和非离子表面活性剂的自动餐具洗涤剂组合物提供了在塑料上的红色去除剂，陶瓷上的茶渍以及对金属的腐蚀抑制作用的“3合1”优点。

公开(公告)号：US08628760B2

公开(公告)日：2014-01-14

申请号：US13182943

申请日：2011-07-14

申请人： John David Carter ,  Elaine Marie Burt ,  Jeffrey John Scheibel ,  David Johnathan Kitko ,  Jun Xu ,  Charles Winston Saunders ,  Kenneth Nathan Price ,  Stephanie Ann Urbin ,  Phillip Richard Green

发明人： John David Carter ,  Elaine Marie Burt ,  Jeffrey John Scheibel ,  David Johnathan Kitko ,  Jun Xu ,  Charles Winston Saunders ,  Kenneth Nathan Price ,  Stephanie Ann Urbin ,  Phillip Richard Green

IPC分类号： A61Q5/12 ,  A61K47/00

CPC分类号： A61K8/342 ,  A61K8/37 ,  A61K8/39 ,  A61K8/416 ,  A61K8/463 ,  A61K2800/34 ,  A61Q5/02 ,  A61Q5/12

摘要： A personal care composition comprising: a near-terminal branched compound according to Formula I; a cosmetically acceptable aqueous carrier; wherein the near-terminal branched compound is not comprised in a gel network.

摘要翻译： 一种个人护理组合物，其包含：根据式I的近端支链化合物; 美容上可接受的水性载体; 其中所述近端支链化合物不包含在凝胶网络中。

公开(公告)号：US20130053300A1

公开(公告)日：2013-02-28

申请号：US13182990

申请日：2011-07-14

申请人： Jeffrey John Scheibel ,  David Johnathan Kitko ,  Jun Xu ,  Charles Winston Saunders ,  Kenneth Nathan Price ,  Stephanie Ann Urbin ,  Phillip Richard Green

发明人： Jeffrey John Scheibel ,  David Johnathan Kitko ,  Jun Xu ,  Charles Winston Saunders ,  Kenneth Nathan Price ,  Stephanie Ann Urbin ,  Phillip Richard Green

IPC分类号： C11D1/37 ,  C11D1/825

CPC分类号： A61K8/342 ,  A61K8/37 ,  A61K8/39 ,  A61K8/416 ,  A61K8/463 ,  A61K2800/34 ,  A61Q5/02 ,  A61Q5/12

摘要： Disclosed herein are novel mixtures of near terminal-branched compounds and derivatives thereof. Further disclosed are methods of making these mixtures, and uses of these mixtures in cleaning compositions (e.g., dishcare, laundry, hard surface cleaners,) and/or personal care compositions (e.g., skin cleansers, shampoo, hair conditioners).

摘要翻译： 本文公开了近末端支化化合物及其衍生物的新型混合物。 还公开了制备这些混合物的方法，以及这些混合物在清洁组合物（例如餐具，衣物，硬表面清洁剂）和/或个人护理组合物（例如，皮肤清洁剂，洗发剂，护发素）中的用途。

公开(公告)号：US08299308B2

公开(公告)日：2012-10-30

申请号：US13236724

申请日：2011-09-20

申请人： Jeffrey John Scheibel ,  Robert Edward Shumate

发明人： Jeffrey John Scheibel ,  Robert Edward Shumate

IPC分类号： C07C47/02 ,  C07C47/21 ,  C11D3/02

CPC分类号： C11D1/16 ,  C07C29/141 ,  C07C29/16 ,  C07C29/175 ,  C07C31/125 ,  C07C43/11 ,  C07C45/50 ,  C07C45/62 ,  C07C47/21 ,  C07C305/06 ,  C07C309/04 ,  C11D1/143 ,  C11D1/146 ,  C11D1/72 ,  C11D1/831 ,  C11D3/2048 ,  C11D3/2065 ,  C11D3/2072 ,  C07C47/02

摘要： A process for preparing a detergent alcohol mixture comprising the steps of providing one or more poly-branched poly-olefins, wherein the poly-branched poly-olefins must contain one non-branched terminal olefin and one or more additional branched olefins in the molecule; hydroformylating said poly-branched poly-olefins to produce a poly-branched olefin containing aldehyde product with one or more olefins or mixture thereof; reducing the aldehyde product of step (b) in the presence of hydrogen and a hydrogenation catalyst to form a poly-branched detergent alcohol mixture; and removing said poly-branched alcohol mixture from said catalyst and branched aldehydes, alcohols and surfactants produced from the products of this process.

摘要翻译： 一种制备洗涤剂醇混合物的方法，包括提供一种或多种多支链聚烯烃的步骤，其中多支链聚烯烃在分子中必须含有一个非支化末端烯烃和一种或多种另外的支链烯烃; 加氢甲酰化所述多支链聚烯烃以制备含有一种或多种烯烃或其混合物的含多元支链烯烃的醛产物; 在氢气和氢化催化剂的存在下还原步骤（b）的醛产物以形成多支链洗涤剂醇混合物; 并从所述催化剂中除去所述多支化醇混合物，并从该方法的产物中制备支链醛，醇和表面活性剂。

公开(公告)号：US20120213726A1

公开(公告)日：2012-08-23

申请号：US13399264

申请日：2012-02-17

申请人： Phillip Richard Green ,  Jeffrey John Scheibel ,  Dimitris Ioannis Collias

发明人： Phillip Richard Green ,  Jeffrey John Scheibel ,  Dimitris Ioannis Collias

IPC分类号： C11D1/22 ,  C11D3/395 ,  C11D3/386 ,  C11D3/37 ,  C11D3/40 ,  A61K8/46 ,  C11D17/06 ,  A61Q5/12 ,  A61Q5/02 ,  A61Q19/02 ,  C07C309/31 ,  C07C303/32 ,  C11D3/30 ,  C11D17/00

CPC分类号： C07C303/08 ,  A61K8/466 ,  A61Q5/02 ,  A61Q5/12 ,  C07C2/64 ,  C07C6/04 ,  C11D1/22 ,  C11D3/187 ,  C07C309/31 ,  C07C11/02 ,  C07C15/107

摘要： The invention is directed to mixtures comprising C10-C14 linear alkylphenyl sulfonates with alkyl groups having a biobased content of at least 50%. These C10-C14 linear alkylphenyl sulfonates are used in consumer product cleaning and personal care compositions (e.g., dishcare, laundry, hard surface cleaners, shampoos, conditioners, and soaps). The invention is further directed to a method of making a mixture of partially or wholly bio-based C10-C14 linear alkylphenyl sulfonates with alkyl groups having a particular bio-based content.

摘要翻译： 本发明涉及包含C10-C14直链烷基苯基磺酸盐与具有至少50％生物基含量的烷基的混合物。 这些C10-C14直链烷基苯基磺酸盐用于消费品清洁和个人护理组合物（例如，保健，洗衣，硬表面清洁剂，洗发剂，调理剂和肥皂）中。 本发明进一步涉及一种制备部分或全部基于生物的C10-C14直链烷基苯基磺酸盐与具有特定生物基含量的烷基的混合物的方法。